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Jean-Baptiste Ruffio

Publications and source records attributed to Jean-Baptiste Ruffio.

At least 73 records · Page 4Linked to original sources
arXiv2024

Octofitter: Fast, Flexible, and Accurate Orbit Modelling to Detect Exoplanets

As next-generation imaging instruments and interferometers search for planets closer to their stars, they must contend with increasing orbital motion and longer integration times. These compounding effects make it difficult to detect faint planets but also present an opportunity. Increased orbital motion makes it possible to move the search for planets into the orbital domain, where direct images can be freely combined with the radial velocity and proper motion anomaly, even without a confirmed detection in any single epoch. In this paper, we present a fast and differentiable multimethod orbit-modeling and planet detection code called Octofitter. This code is designed to be highly modular and allows users to easily adjust priors, change parameterizations, and specify arbitrary function relations between the parameters of one or more planets. Octofitter further supplies tools for examining model outputs including prior and posterior predictive checks and simulation-based calibration. We demonstrate the capabilities of Octofitter on real and simulated data from different instruments and methods, including HD 91312, simulated JWST/NIRISS aperture masking interferometry observations, radial velocity curves, and grids of images from the Gemini Planet Imager. We show that Octofitter can reliably recover faint planets in long sequences of images with arbitrary orbital motion. This publicly available tool will enable the broad application of multiepoch and multimethod exoplanet detection, which could improve how future targeted ground- and space-based surveys are performed. Finally, its rapid convergence makes it a useful addition to the existing ecosystem of tools for modeling the orbits of directly imaged planets.

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arXiv2023

Validation of elemental and isotopic abundances in late-M spectral types with the benchmark HIP 55507 AB system

M dwarfs are common host stars to exoplanets but often lack atmospheric abundance measurements. Late-M dwarfs are also good analogs to the youngest substellar companions, which share similar $T_{\rm eff}\sim2300-2800~K$. We present atmospheric analyses for the M7.5 companion HIP 55507 B and its K6V primary star with Keck/KPIC high-resolution ($R\sim35,000$) $K$ band spectroscopy. First, by including KPIC relative radial velocities between the primary and secondary in the orbit fit, we improve the dynamical mass precision by 60% and find $M_B=88.0_{-3.2}^{+3.4}$ $M_{\rm Jup}$, putting HIP 55507 B above the stellar-substellar boundary. We also find that HIP 55507 B orbits its K6V primary star with $a=38^{+4}_{-3}$ AU and $e=0.40\pm0.04$. From atmospheric retrievals of HIP 55507 B, we measure $\rm [C/H]=0.24\pm0.13$, $\rm [O/H]=0.15\pm0.13$, and $\rm C/O=0.67\pm0.04$. Moreover, we strongly detect $\rm ^{13}CO$ ($7.8σ$ significance) and tentatively detect $\rm H_2^{18}O$ ($3.7σ$ significance) in companion's atmosphere, and measure $\rm ^{12}CO/^{13}CO=98_{-22}^{+28}$ and $\rm H_2^{16}O/H_2^{18}O=240_{-80}^{+145}$ after accounting for systematic errors. From a simplified retrieval analysis of HIP 55507 A, we measure $\rm ^{12}CO/^{13}CO=79_{-16}^{+21}$ and $\rm C^{16}O/C^{18}O=288_{-70}^{+125}$ for the primary star. These results demonstrate that HIP 55507 A and B have consistent $\rm ^{12} C/^{13}C$ and $\rm ^{16}O/^{18}O$ to the $<1σ$ level, as expected for a chemically homogeneous binary system. Given the similar flux ratios and separations between HIP 55507 AB and systems with young, substellar companions, our results open the door to systematically measuring $\rm ^{13}CO$ and $\rm H_2^{18}O$ abundances in the atmospheres of substellar or even planetary-mass companions with similar spectral types.

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arXiv2023

Atmospheric metallicity and C/O of HD 189733 b from high-resolution spectroscopy

We present high-resolution $K$-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer (KPIC). Using a Bayesian retrieval framework, we fit the dayside pressure-temperature profile, orbital kinematics, mass-mixing ratios of H$_2$O, CO, CH$_4$, NH$_3$, HCN, and H$_2$S, and the $\rm ^{13}CO/^{12}CO$ ratio. We measure mass fractions of $\rm \log H_2O = -2.0^{+0.4}_{-0.4}$ and $\rm \log CO = -2.2^{+0.5}_{-0.5}$, and place upper limits on the remaining species. Notably, we find $\rm \log CH_4 < -4.5$ at 99\% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative ($\sim3σ$) detection of $\rm ^{13}CO$, and the retrieved posteriors suggest a $\rm ^{12}C/^{13}C$ ratio similar to or substantially less than the local interstellar value. The possible $\rm ^{13}C$ enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially sub-stellar atmospheric $\rm C/O = 0.3\pm0.1$, while the carbon and oxygen abundances are stellar to slightly super-stellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b.

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arXiv2023

Calibration Unit Design for High-Resolution Infrared Spectrograph for Exoplanet Characterization (HISPEC)

The latest generation of high-resolution spectrograph instruments on 10m-class telescopes continue to pursue challenging science cases. Consequently, ever more precise calibration methods are necessary to enable trail-blazing science methodology. We present the High-resolution Infrared SPectrograph for Exoplanet Characterization (HISPEC) Calibration Unit (CAL), designed to facilitate challenging science cases such as Doppler imaging of exoplanet atmospheres, precision radial velocity, and high-contrast high-resolution spectroscopy of nearby exoplanets. CAL builds upon the heritage from the pathfinder instrument Keck Planet Imager and Characterizer (KPIC) and utilizes four near-infrared (NIR) light sources encoded with wavelength information that are coupled into single-mode fibers. They can be used synchronously during science observations or asynchronously during daytime calibrations. A hollow cathode lamp (HCL) and a series of gas absorption cells provide absolute calibration from 0.98 μm to 2.5 μm. A laser frequency comb (LFC) provides stable, time-independent wavelength information during observation and CAL implements a lower finesse astro-etalon as a backup for the LFC. Design lessons from instrumentation like HISPEC will serve to inform the requirements for similar instruments for the ELTs in the future.

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arXiv2023

The development of HISPEC for Keck and MODHIS for TMT: science cases and predicted sensitivities

HISPEC is a new, high-resolution near-infrared spectrograph being designed for the W.M. Keck II telescope. By offering single-shot, R=100,000 between 0.98 - 2.5 um, HISPEC will enable spectroscopy of transiting and non-transiting exoplanets in close orbits, direct high-contrast detection and spectroscopy of spatially separated substellar companions, and exoplanet dynamical mass and orbit measurements using precision radial velocity monitoring calibrated with a suite of state-of-the-art absolute and relative wavelength references. MODHIS is the counterpart to HISPEC for the Thirty Meter Telescope and is being developed in parallel with similar scientific goals. In this proceeding, we provide a brief overview of the current design of both instruments, and the requirements for the two spectrographs as guided by the scientific goals for each. We then outline the current science case for HISPEC and MODHIS, with focuses on the science enabled for exoplanet discovery and characterization. We also provide updated sensitivity curves for both instruments, in terms of both signal-to-noise ratio and predicted radial velocity precision.

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arXiv2023

Vortex Fiber Nulling for Exoplanet Observations: Implementation and First Light

Vortex fiber nulling (VFN) is a single-aperture interferometric technique for detecting and characterizing exoplanets separated from their host star by less than a diffracted beam width. VFN uses a vortex mask and single mode fiber to selectively reject starlight while coupling off-axis planet light with a simple optical design that can be readily implemented on existing direct imaging instruments that can feed light to an optical fiber. With its axially symmetric coupling region peaking within the inner working angle of conventional coronagraphs, VFN is more efficient at detecting new companions at small separations than conventional direct imaging, thereby increasing the yield of on-going exoplanet search campaigns. We deployed a VFN mode operating in K band ($2.0{-}2.5~μ$m) on the Keck Planet Imager and Characterizer (KPIC) instrument at the Keck II Telescope. In this paper we present the instrument design of this first on-sky demonstration of VFN and the results from on-sky commissioning, including planet and star throughput measurements and predicted flux-ratio detection limits for close-in companions. The instrument performance is shown to be sufficient for detecting a companion $10^3$ times fainter than a $5^{\mathrm{th}}$ magnitude host star in 1 hour at a separation of 50 mas (1.1$λ/D$). This makes the instrument capable of efficiently detecting substellar companions around young stars. We also discuss several routes for improvement that will reduce the required integration time for a detection by a factor ${>}$3.

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arXiv2023

Assessing the C/O Ratio Formation Diagnostic: A Potential Trend with Companion Mass

The carbon-to-oxygen (C/O) ratio in an exoplanet atmosphere has been suggested as a potential diagnostic of planet formation. Now that a number of exoplanets have measured C/O ratios, it is possible to examine this diagnostic at a population level. Here, we present an analysis of currently measured C/O ratios of directly imaged and transit/eclipse planets. First, we derive atmospheric parameters for the substellar companion HD 284149 AB b using data taken with the OSIRIS integral field spectrograph at the W.M. Keck Observatory and report two non-detections from our ongoing imaging spectroscopy survey with Keck/OSIRIS. We find an effective temperature of $T_\mathrm{eff} = 2502$ K, with a range of 2291-2624 K, $\log g=4.52$, with a range of 4.38-4.91, and [M/H] = 0.37, with a range of 0.10-0.55. We derive a C/O of 0.59$^{+0.15}_{-0.30}$ for HD 284149 AB b. We add this measurement to the list of C/O ratios for directly imaged planets and compare them with those from a sample of transit/eclipse planets. We also derive the first dynamical mass estimate for HD 284149 AB b, finding a mass of $\sim$28 $M_\mathrm{Jup}$. There is a trend in C/O ratio with companion mass ($M_{\mathrm{Jup}}$), with a break seen around 4$M_{\mathrm{Jup}}$. We run a Kolmogorov-Smirnov and an Anderson-Darling test on planets above and below this mass boundary, and find that they are two distinct populations. This could be additional evidence of two distinct populations possibly having two different formation pathways, with companion mass as an indicator of most likely formation scenario.

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arXiv2023

On-sky speckle nulling through a single-mode fiber with the Keck Planet Imager and Characterizer

The Keck Planet Imager and Characterizer (KPIC) is an instrument at the Keck II telescope that enables high-resolution spectroscopy of directly imaged exoplanets and substellar companions. KPIC uses single-mode fibers to couple the adaptive optics system to Keck's near-infrared spectrometer (NIRSPEC). However, KPIC's sensitivity at small separations is limited by the leakage of stellar light into the fiber. Speckle nulling uses a deformable mirror to destructively interfere starlight with itself, a technique typically used to reduce stellar signal on a focal-plane imaging detector. We present the first on-sky demonstration of speckle nulling through an optical fiber with KPIC, using NIRSPEC to collect exposures that measure speckle phase for quasi-real-time wavefront control while also serving as science data. We repeat iterations of measurement and correction, each using at least 5 exposures. We show a decrease in the on-sky leaked starlight by a factor of 2.6 to 2.8 in the targeted spectral order, at a spatial separation of 2.0 λ/D in K-band. This corresponds to an estimated factor of 2.6 to 2.8 decrease in the required exposure time to reach a given SNR, relative to conventional KPIC observations. The performance of speckle nulling is limited by instability in the speckle phase: when the loop is opened, the null-depth degrades by a factor of 2 on the timescale of a single phase measurement, which would limit the suppression that can be achieved. Future work includes exploring gradient-descent methods, which may be faster and thereby able to achieve deeper nulls. In the meantime, the speckle nulling algorithm demonstrated in this work can be used to decrease stellar leakage and improve the signal-to-noise of science observations.

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arXiv2023

The Orbital Eccentricities of Directly Imaged Companions Using Observable-Based Priors: Implications for Population-level Distributions

The eccentricity of a sub-stellar companion is an important tracer of its formation history. Directly imaged companions often present poorly constrained eccentricities. A recently developed prior framework for orbit fitting called ''observable-based priors'' has the advantage of improving biases in derived orbit parameters for objects with minimal phase coverage, which is the case for the majority of directly imaged companions. We use observable-based priors to fit the orbits of 21 exoplanets and brown dwarfs in an effort to obtain the eccentricity distributions with minimized biases. We present the objects' individual posteriors compared to their previously derived distributions, showing in many cases a shift toward lower eccentricities. We analyze the companions' eccentricity distribution at a population level, and compare this to the distributions obtained with the traditional uniform priors. We fit a Beta distribution to our posteriors using observable-based priors, obtaining shape parameters $α= 1.09^{+0.30}_{-0.22}$ and $β= 1.42^{+0.33}_{-0.25}$. This represents an approximately flat distribution of eccentricities. The derived $α$ and $β$ parameters are consistent with the values obtained using uniform priors, though uniform priors lead to a tail at high eccentricities. We find that separating the population into high and low mass companions yields different distributions depending on the classification of intermediate mass objects. We also determine via simulation that the minimal orbit coverage needed to give meaningful posteriors under the assumptions made for directly imaged planets is $\approx$ 15% of the inferred period of the orbit.

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arXiv2023

Keck/KPIC Emission Spectroscopy of WASP-33b

We present Keck/KPIC high-resolution ($R\sim35,000$) $K$-band thermal emission spectroscopy of the ultra-hot Jupiter WASP-33b. The use of KPIC's single-mode fibers greatly improves both blaze and line-spread stabilities relative to slit spectrographs, enhancing the cross-correlation detection strength. We retrieve the dayside emission spectrum with a nested sampling pipeline which fits for orbital parameters, the atmospheric pressure-temperature profile, and molecular abundances.We strongly detect the thermally-inverted dayside and measure mass-mixing ratios for CO ($\log\rm CO_{MMR} = -1.1^{+0.4}_{-0.6}$), H$_2$O ($\log\rm H_2O_{MMR} = -4.1^{+0.7}_{-0.9}$) and OH ($\log\rm OH_{MMR} = -2.1^{+0.5}_{-1.1}$), suggesting near-complete dayside photodissociation of H$_2$O. The retrieved abundances suggest a carbon- and possibly metal-enriched atmosphere, with a gas-phase C/O ratio of $0.8^{+0.1}_{-0.2}$, consistent with the accretion of high-metallicity gas near the CO$_2$ snow line and post-disk migration or with accretion between the soot and H$_2$O snow lines. We also find tentative evidence for $\rm ^{12}CO/^{13}CO \sim 50$, consistent with values expected in protoplanetary disks, as well as tentative evidence for a metal-enriched atmosphere (2--15$\times$ solar). These observations demonstrate KPIC's ability to characterize close-in planets and the utility of KPIC's improved instrumental stability for cross-correlation techniques.

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arXiv2023

Detecting Exoplanets Closer to Stars with Moderate Spectral Resolution Integral-Field Spectroscopy

While radial velocity surveys have demonstrated that the population of gas giants peaks around $3~\text{au}$, the most recent high-contrast imaging surveys have only been sensitive to planets beyond $\sim~10~\text{au}$. Sensitivity at small angular separations from stars is currently limited by the variability of the point spread function. We demonstrate how moderate-resolution integral field spectrographs can detect planets at smaller separations ($\lesssim~0.3$ arcseconds) by detecting the distinct spectral signature of planets compared to the host star. Using OSIRIS ($R$ $\approx$ 4000) at the W. M. Keck Observatory, we present the results of a planet search via this methodology around 20 young targets in the Ophiuchus and Taurus star-forming regions. We show that OSIRIS can outperform high-contrast coronagraphic instruments equipped with extreme adaptive optics and non-redundant masking in the $0.05-0.3$ arcsecond regime. As a proof of concept, we present the $34σ$ detection of a high-contrast M dwarf companion at $\approx0.1$" with a flux ratio of $\approx0.92\%$ around the field F2 star HD 148352. We developed an open-source Python package, breads, for the analysis of moderate-resolution integral field spectroscopy data in which the planet and the host star signal are jointly modeled. The diffracted starlight continuum is forward-modeled using a spline model, which removes the need for prior high-pass filtering or continuum normalization. The code allows for analytic marginalization of linear hyperparameters, simplifying posterior sampling of other parameters (e.g., radial velocity, effective temperature). This technique could prove very powerful when applied to integral field spectrographs like NIRSpec on the JWST and other upcoming first-light instruments on the future Extremely Large Telescopes.

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arXiv2023

Testing the Interaction Between a Substellar Companion and a Debris Disk in the HR 2562 System

The HR 2562 system is a rare case where a brown dwarf companion resides in a cleared inner hole of a debris disk, offering invaluable opportunities to study the dynamical interaction between a substellar companion and a dusty disk. We present the first ALMA observation of the system as well as the continued GPI monitoring of the companion's orbit with 6 new epochs from 2016 to 2018. We update the orbital fit and, in combination with absolute astrometry from GAIA, place a 3$σ$ upper limit of 18.5 $M_J$ on the companion's mass. To interpret the ALMA observations, we used radiative transfer modeling to determine the disk properties. We find that the disk is well resolved and nearly edge on. While the misalignment angle between the disk and the orbit is weakly constrained due to the short orbital arc available, the data strongly support a (near) coplanar geometry for the system. Furthermore, we find that the models that describe the ALMA data best have an inner radius that is close to the companion's semi-major axis. Including a posteriori knowledge of the system's SED further narrows the constraints on the disk's inner radius and place it at a location that is in reasonable agreement with, possibly interior to, predictions from existing dynamical models of disk truncation by an interior substellar companion. HR\,2562 has the potential over the next few years to become a new testbed for dynamical interaction between a debris disk and a substellar companion.

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arXiv2023

Detecting exomoons from radial velocity measurements of self-luminous planets: application to observations of HR 7672 B and future prospects

The detection of satellites around extrasolar planets, so called exomoons, remains a largely unexplored territory. In this work, we study the potential of detecting these elusive objects from radial velocity monitoring of self-luminous directly imaged planets. This technique is now possible thanks to the development of dedicated instruments combining the power of high-resolution spectroscopy and high-contrast imaging. First, we demonstrate a sensitivity to satellites with a mass ratio of 1-4% at separations similar to the Galilean moons from observations of a brown-dwarf companion (HR 7672 B; Kmag=13; 0.7" separation) with the Keck Planet Imager and Characterizer (KPIC; R~35,000 in K band) at the W. M. Keck Observatory. Current instrumentation is therefore already sensitive to large unresolved satellites that could be forming from gravitational instability akin to binary star formation. Using end-to-end simulations, we then estimate that future instruments such as MODHIS, planned for the Thirty Meter Telescope, should be sensitive to satellites with mass ratios of ~1e-4. Such small moons would likely form in a circumplanetary disk similar to the Jovian satellites in the solar system. Looking for the Rossiter-McLaughlin effect could also be an interesting pathway to detecting the smallest moons on short orbital periods. Future exomoon discoveries will allow precise mass measurements of the substellar companions that they orbit and provide key insight into the formation of exoplanets. They would also help constrain the population of habitable Earth-sized moons orbiting gas giants in the habitable zone of their stars.

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arXiv2022

Non Common Path Aberrations Correction

The primary goal of this thesis was the correction of Non-Common-Path-Aberrations in the SPHERE instrument for helping it meeting its contrast requirements. SPHERE's purpose is the search and characterization of giant exo-planets around nearby stars. The author implemented a method called Electric Field Conjugation that he tested in simulation as well as on the real system. A full week was booked in SPHERE schedule a few days before the second commissioning in June 2014. It gave the opportunity to the author to travel to the VLT in Chile and experiment directly on the system. The contrast gain objective of another order of magnitude in a medium-sized area has successfully been reached bringing SPHERE raw speckle contrast from about $10^{-6}$ to $10^{-7}$. The algorithm has therefore proven its value and will be further investigated and hopefully automated by the SPHERE team based on the codes developed by the author. However it is important to keep in mind that Electric Field Conjugation is more effective for follow-up studies in order to improve the quality of the observations. Indeed the area for a good correction is very limited. It can't be used for exo-planets discovery unless the corrected area is made big enough but the performance will be less.

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arXiv2022

Deep orbital search for additional planets in the HR 8799 system

The HR 8799 system hosts four massive planets orbiting 15 and 80 AU. Studies of the system's orbital stability and its outer debris disk open the possibility of additional planets, both interior to and exterior to the known system. Reaching a sufficient sensitivity to search for interior planets is very challenging due to the combination of bright quasi static speckle noise close to the stellar diffraction core and relatively fast orbital motion. In this work, we present a deep L-band imaging campaign using NIRC2 at Keck comprising 14 observing sequences. We further re-reduce archival data for a total of 16.75 hours, one of the largest uniform datasets of a single direct imaging target. Using a Bayesian modeling technique for detecting planets in images while compensating for plausible orbital motion, we then present deep limits on the existence of additional planets in the HR 8799 system. The final combination shows a tentative candidate, consistent with 4-7 $M_{jup}$ at 4-5 AU, detected with an equivalent false alarm probability better than $3σ$. This analysis technique is widely applicable to archival data and to new observations from upcoming missions that revisit targets at multiple epochs.

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arXiv2022

Phase II of the Keck Planet Imager and Characterizer: system-level laboratory characterization and preliminary on-sky commissioning

The Keck Planet Imager and Characterizer (KPIC) is a series of upgrades for the Keck II Adaptive Optics (AO) system and the NIRSPEC spectrograph to enable diffraction-limited, high-resolution ($R>30,000$) spectroscopy of exoplanets and low-mass companions in the K and L bands. Phase I consisted of single-mode fiber injection/extraction units (FIU/FEU) used in conjunction with an H-band pyramid wavefront sensor. Phase II, deployed and commissioned in 2022, adds a 1000-actuator deformable mirror, beam-shaping optics, a vortex coronagraph, and other upgrades to the FIU/FEU. The use of single-mode fibers provides a gain in stellar rejection, a substantial reduction in sky background, and an extremely stable line-spread function on the spectrograph. In this paper we present the results of extensive system-level laboratory testing and characterization showing the instrument's Phase II throughput, stability, repeatability, and other key performance metrics prior to delivery and during installation at Keck. We also demonstrate the capabilities of the various observing modes enabled by the new system modules using internal test light sources. Finally, we show preliminary results of on-sky tests performed in the first few months of Phase II commissioning along with the next steps for the instrument. Once commissioning of Phase II is complete, KPIC will continue to characterize exoplanets at an unprecedented spectral resolution, thereby growing its already successful track record of 23 detected exoplanets and brown dwarfs from Phase I. Using the new vortex fiber nulling (VFN) mode, Phase II will also be able to search for exoplanets at small angular separations less than 45 milliarcseconds which conventional coronagraphs cannot reach.

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arXiv2022

Retrieving C and O Abundance of HR 8799 c by Combining High- and Low-Resolution Data

The formation and evolution pathway for the directly-imaged multi-planetary system HR 8799 remains mysterious. Accurate constraints on the chemical composition of the planetary atmosphere(s) are key to solving the mystery. We perform a detailed atmospheric retrieval on HR 8799~c to infer the chemical abundances and abundance ratios using a combination of photometric data along with low- and high-resolution spectroscopic data (R$\sim$20-35,000). We specifically retrieve [C/H], [O/H], and C/O and find them to be 0.55$^{+0.36}_{-0.39}$, 0.47$^{+0.31}_{-0.32}$, and 0.67$^{+0.12}_{-0.15}$ at 68\% confidence. The super-stellar C and O abundances, yet a stellar C/O ratio, reveal a potential formation pathway for HR 8799~c. Planet c, and likely the other gas giant planets in the system, formed early on (likely within $\sim$1 Myr), followed by further atmospheric enrichment in C and O through the accretion of solids beyond the CO iceline. The enrichment either preceded or took place during the early phase of the inward migration to the planet current locations.

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arXiv2022

A Clear View of a Cloudy Brown Dwarf Companion from High-Resolution Spectroscopy

Direct imaging studies have mainly used low-resolution spectroscopy ($R\sim20-100$) to study the atmospheres of giant exoplanets and brown dwarf companions, but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances (e.g. C/O, metallicity). This precludes clear insights into the formation mechanisms of these companions. The Keck Planet Imager and Characterizer (KPIC) uses adaptive optics and single-mode fibers to transport light into NIRSPEC ($R\sim35,000$ in $K$ band), and aims to address these challenges with high-resolution spectroscopy. Using an atmospheric retrieval framework based on petitRADTRANS, we analyze KPIC high-resolution spectrum ($2.29-2.49~μ$m) and archival low-resolution spectrum ($1-2.2~μ$m) of the benchmark brown dwarf HD 4747 B ($m=67.2\pm1.8~M_{\rm{Jup}}$, $a=10.0\pm0.2$ au, $T_{\rm eff}\approx1400$ K). We find that our measured C/O and metallicity for the companion from the KPIC high-resolution spectrum agree with that of its host star within $1-2σ$. The retrieved parameters from the $K$ band high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum are highly sensitive to our chosen cloud model. Finally, we detect CO, H$_2$O, and CH$_4$ (volume mixing ratio of log(CH$_4$)=$-4.82\pm0.23$) in this L/T transition companion with the KPIC data. The relative molecular abundances allow us to constrain the degree of chemical disequilibrium in the atmosphere of HD 4747 B, and infer a vertical diffusion coefficient that is at the upper limit predicted from mixing length theory.

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