arXiv subjects

Jefferson A. O. Galindo

Publications and source records attributed to Jefferson A. O. Galindo.

3 recordsLinked to original sources

arXiv2026

Real-time ESR tracking for sub-micron 3D magnetic mapping with VB- quantum sensors in hexagonal boron nitride

The discovery of spin-dependent luminescent properties of negatively charged boron-vacancy centers ($V^-_B$) in hexagonal boron nitride (hBN) enabled a new platform for quantum sensing with van der Waals materials. Particularly, the possibility of performing optically detected magnetic resonance (ODMR) for determining the electron spin resonance (ESR) frequencies of hBN color centers became a strong tool for quantum sensing of magnetic fields with submicrometric resolution. However, due to low ODMR contrast, current techniques proposed for mapping DC magnetic fields require hours of integration to obtain a magnetic image of a micron-sized region. In this work, we report the implementation of a frequency-tracking approach for real-time monitoring of ESR frequencies of localized $V^-_B$ centers in hBN. With this technique, magnetic field monitoring was used to map the field pattern generated by a micron-sized conical magnetic tip in only a few minutes. By controlling the magnetic sample's position relative to the quantum sensor, three-dimensional magnetic mapping of the field was achieved with diffraction-limited resolution and shot-noise-limited sensitivity of 54 $μ$T$/\sqrt{\text{Hz}}$. Magnetic field gradients of 3.6 $\pm$ 0.2 $μ$T/nm were measured with our system, in which a maximum detected field rate of 6 mT/s was achieved. The results of this study establish spin resonance frequency-tracking as a viable technique and fast method for minute-scale magnetic imaging, reducing acquisition times by at least one order of magnitude if compared to conventional techniques.

physics.chem-ph↗

arXiv2026

Absolute Primary Nanothermometry Using Individual Stark Sublevels of Rare-Earth-doped Crystals

We present two independent optical methods for absolute primary thermometry using rare-earth-doped nanoparticles. Both approaches rely exclusively on the internal energy levels and population dynamics of the dopant ions, eliminating the need for external temperature references. We experimentally demonstrate the concepts by using Y$_2$O$_3$: Yb$^{3+}$/Er$^{3+}$ nanoparticles, exploiting Boltzmann distribution between individual Stark sublevels of the Er$^{3+}$ ions, emitting in the green spectral region ($\sim$550 nm) and in the near-infrared spectral region ($\sim$1600 nm). Our strategy establishes rare-earth-based luminescence thermometers as genuine absolute primary probes, conceptually comparable to Johnson noise and acoustic gas thermometers, but with the fundamental advantage of possibly being employed at the nanoscale, potentially down to the single-ion limit, with optical readout and over wide temperature ranges.

physics.chem-ph↗

arXiv2025

Boltzmann Thermometry at Cryogenic Temperatures Exploiting Stark Sublevels in Er$^{3+}$/Yb$^{3+}$-Codoped Yttrium Oxide Nanoparticles

The development of reliable luminescent nanothermometers for cryogenic applications is essential for advancing quantum technologies, superconducting systems, and other fields that require precise, high-spatial-resolution temperature monitoring. Lanthanide-doped systems are vastly employed to this purpose, and typically perform optimally at or above room temperature when manifold-to-manifold transitions are used. In this work we exploit individual Stark sublevels to demonstrate an optical thermometer based on Er$^{3+}$/Yb$^{3+}$ codoped yttria (Y$_2$O$_3$) nanoparticles that operates effectively across the temperature range from 25 K to 175 K. This is achieved due to the pronounced crystal field environment of the the Y$_2$O$_3$ host matrix, leading to well-separated Stark lines in the luminescence spectrum of the Er$^{3+}$ ions. By applying the Luminescence Intensity Ratio (LIR) method to transitions originating from two Stark components of the $^4$S$_{3/2}$ manifold of the Er$^{3+}$ ions, we achieve thermal sensitivities up to 1.25 % K$^{-1}$ at 100 K and temperature resolutions reaching 0.2 K. Our results further experimentally confirm recently published theoretical predictions, demonstrating that thermometric performance is not directly dependent on the average (barycenter) difference of the involved electronic energy levels when using individual Stark transitions to evaluate the LIR. The proposed procedure gives an energy gap calibration that matches the one determined by sample spectroscopy for non-overlapping lines in the luminescence spectrum. These insights provide a robust foundation for the design of high-performance cryogenic thermometers based on rare-earth-doped materials.

physics.chem-ph↗