arXiv subjects

Jennifer Bergner

Publications and source records attributed to Jennifer Bergner.

15 recordsLinked to original sources

arXiv2026

Functionalization of Benzene Ices by Atomic Oxygen

Small aromatic molecules, including functionalized derivatives of benzene, are known to be present throughout the different stages of star and planet formation. In particular, oxygen-bearing monosubstituted aromatics, likely including phenol, have been identified in the coma of comet 67P. This suggests that, earlier in the star and planet formation evolution, icy grains may act as both reservoirs and sites of functionalization for these small aromatics. We investigate the ice-phase reactivity of singlet oxygen atoms (O($^1$D)) with benzene, using ozone as a precursor that is readily photodissociated by relatively low-energy. Our experiments show that O($^1$D) efficiently reacts with benzene, forming phenol, benzene oxide, and oxepine as the main products. Phenol formation is temperature-independent, consistent with a barrierless insertion mechanism. In contrast, the formation of benzene oxide/oxepine shows a slight temperature dependence, suggesting that additional reaction pathways involving either ground-state or excited-state oxygen atoms may contribute. In H$_2$O and \COO ice matrices we find that dilution does not suppress formation of phenol. We extrapolate an experimental upper limit for the benzene-to-phenol conversion fraction of 27-44$\%$ during the lifetime of an interstellar cloud, assuming O($^1$D) production rates based on CO$_2$ ice abundances and a cosmic-ray induced UV field. We compare these estimates with a new analysis of data from the comet 67P, where the C$_6$H$_6$O/C$_6$H$_6$ ratio is 20$\pm$6$\%$. This value lies within our estimated range, suggesting that O($^1$D)-mediated chemistry is a viable pathway for producing oxygenated aromatics in cold astrophysical ices, potentially enriching icy planetesimals with phenol and other biorelevant compounds.

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arXiv2025

Oxygen Isotope Constraints on the Importance of Photochemical Processing in Protoplanetary Disks

Observations have revealed evidence of photochemical processing in protoplanetary disks. This processing occurs in the photon dominated layer, the optically thin regions of the disk high above the disk midplane. It remains unclear, however, how much this photochemical processing impacts the compositions of the planets and their building blocks within the disk. Here we use the oxygen isotopic compositions of Solar System solids, which has been attributed to photochemistry in the solar nebula, to quantitatively evaluate whether this processing could have produced the conditions needed to provide the diversity of compositions seen in the Solar System. We do this by modeling the chemical evolution while fine dust grows into the building blocks of the planets. We find that the oxygen isotopic evolution cannot be attributed to processing in the solar nebula and must instead be inherited from the parent molecular cloud. Further, our results indicate that the observed photochemical processing in protoplanetary disks does not significantly impact the compositions of planets that form within.

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arXiv2025

Locked In Ice: how Pebble Drift and Volatile Entrapment can Significantly Impact Carbon and Oxygen Ratios in Evolving Protoplanetary Discs

The complex interplay between the growth, drift, and sublimation of ice-covered pebbles can strongly influence the volatile distribution and evolution of disc composition, and therefore impact the composition of forming planets. Classic pebble drift models treat volatile species individually as sublimating at their respective snowlines, although observations from the James Webb Space Telescope (JWST) suggest that ices are likely mixed; laboratory studies suggest ice mixtures can exhibit more complex sublimation behaviours, remaining trapped beyond their nominal sublimation temperatures. We present the first model that couples pebble growth and drift with CO entrapment inside water ice - preventing a fraction (up to ~60%) of the CO from sublimating at its snowline, instead desorbing via volcanic desorption at the water crystallisation front, at 130K. Our models show that CO entrapment will significantly impact the carbon and oxygen distributions, enhancing the gas-phase C/O and C/H inside the water snowline by up to a factor of 10 over 1 Myr and a factor of a few around the CO2 snowline; O/H is also increased around the CO2 snowline, but is water-dominated in the inner disc. Entrapment therefore provides a means of introducing more carbon to the inner disc whilst retaining a large amount of water. We discuss connections to planet formation, noting that CO entrapment can increase the gas-phase heavy element content around the water snowline by up to 150%. We also consider links to JWST observations and highlight the importance of entrapment for pebble drift models to accurately model disc composition.

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arXiv2025

First Detections of PN, PO, and PO+ toward a Shocked Low-mass Starless Core

Phosphorus is a key element that plays an essential role in biological processes important for living organisms on Earth. The origin and connection of phosphorus-bearing molecules to early Solar system objects and star-forming molecular clouds is therefore of great interest, yet there are limited observations throughout different stages of low-mass ($M < $ a few M$_\odot$) star formation. Observations from the Yebes 40 m and IRAM 30 m telescopes detect for the first time in the 7mm, 3mm, and 2mm bands multiple transitions of PN and PO, as well as a single transition of PO$^{+}$, toward a low-mass starless core. The presence of PN, PO and PO$^{+}$ is kinematically correlated with bright SiO(1-0) emission. Our results reveal not only that shocks are the main driver of releasing phosphorus from dust grains and into the gas-phase, but that the emission originates from gas not affiliated with the shock itself, but quiescent gas that has been shocked in the recent past. From radiative transfer calculations, the PO/PN abundance ratio is found to be $3.1^{+0.4}_{-0.6}$, consistent with other high-mass and low-mass star-forming regions. This first detection of PO$^{+}$ toward any low-mass star-forming region reveals a PO$^{+}$/PO ratio of $0.0115^{+0.0008}_{-0.0009}$, a factor of ten lower than previously determined from observations of a Galactic Center molecular cloud, suggesting its formation can occur under more standard Galactic cosmic-ray ionization rates. These results motivate the need for additional observations that can better disentangle the physical mechanisms and chemical drivers of this precursor of prebiotic chemistry.

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arXiv2024

Key Science Goals for the Next Generation Very Large Array (ngVLA): Update from the ngVLA Science Advisory Council (2024)

In 2017, the next generation Very Large Array (ngVLA) Science Advisory Council, together with the international astronomy community, developed a set of five Key Science Goals (KSGs) to inform, prioritize and refine the technical capabilities of a future radio telescope array for high angular resolution operation from 1.2 - 116 GHz with 10 times the sensitivity of the Jansky VLA and ALMA. The resulting KSGs, which require observations at centimeter and millimeter wavelengths that cannot be achieved by any other facility, represent a small subset of the broad range of astrophysical problems that the ngVLA will be able address. This document presents an update to the original ngVLA KSGs, taking account of new results and progress in the 7+ years since their initial presentation, again drawing on the expertise of the ngVLA Science Advisory Council and the broader community in the ngVLA Science Working Groups. As the design of the ngVLA has also matured substantially in this period, this document also briefly addresses initial expectations for ngVLA data products and processing that will be needed to achieve the KSGs. The original ngVLA KSGs endure as outstanding problems of high priority. In brief, they are: (1) Unveiling the Formation of Solar System Analogues; (2) Probing the Initial Conditions for Planetary Systems and Life with Astrochemistry; (3) Charting the Assembly, Structure, and Evolution of Galaxies from the First Billion Years to the Present; (4) Science at the Extremes: Pulsars as Laboratories for Fundamental Physics; (5) Understanding the Formation and Evolution of Stellar and Supermassive Black Holes in the Era of Multi-Messenger Astronomy.

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arXiv2024

Star and Planet Formation with the Single Aperture Large Telescope for Universe Studies (SALTUS) Space Observatory

The Single Aperture Large Telescope for Universe Studies (SALTUS) is a far-infrared space mission concept with unprecedented spatial and spectral resolution. Saltus consists of a 14-m inflatable primary, providing 16 times the sensitivity and 4 times the angular resolution of Herschel, and two cryogenic detectors spanning a wavelength range of 34-660 microns and spectral resolving power of 300 - 1e7. Spectroscopic observations in the far-infrared offer many unique windows into the processes of star and planet formation. These include observations of low energy water transitions, the H2 mass tracer HD, many CHONS constraining molecules such as NH3 and H2S, and emission lines from the phonon modes of molecular ices. Observing these species will allow us to build a statistical sample of protoplanetary disk masses, characterize the water snowline, identify Kuiper Belt like debris rings around other stars, and trace the evolution CHONS from prestellar cores, through to protoplanetary disks and debris disks. This paper details details several key star and planet formation science goals achievable with SALTUS.

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arXiv2024

Single Aperture Large Telescope for Universe Studies (SALTUS): Science Overview

The SALTUS Probe mission will provide a powerful far-infrared (far-IR) pointed space observatory to explore our cosmic origins and the possibility of life elsewhere. The observatory employs an innovative deployable 14-m aperture, with a sunshield that will radiatively cool the off-axis primary to <45K. This cooled primary reflector works in tandem with cryogenic coherent and incoherent instruments that span the 34 to 660 micron far-IR range at both high and moderate spectral resolutions.

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arXiv2023

Acceleration of 1I/`Oumuamua from radiolytically produced H$_2$ in H$_2$O ice

In 2017, 1I/`Oumuamua was identified as the first known interstellar object in the Solar System. Although typical cometary activity tracers were not detected, `Oumuamua exhibited a significant non-gravitational acceleration. To date there is no explanation that can reconcile these constraints. Due to energetic considerations, outgassing of hyper-volatile molecules is favored over heavier volatiles like H$_2$O and CO$_2$. However, there are are theoretical and/or observational inconsistencies with existing models invoking the sublimation of pure H$_2$, N$_2$, and CO. Non-outgassing explanations require fine-tuned formation mechanisms and/or unrealistic progenitor production rates. Here we report that the acceleration of `Oumuamua is due to the release of entrapped molecular hydrogen which formed through energetic processing of an H$_2$O-rich icy body. In this model, `Oumuamua began as an icy planetesimal that was irradiated at low temperatures by cosmic rays during its interstellar journey, and experienced warming during its passage through the Solar System. This explanation is supported by a large body of experimental work showing that H$_2$ is efficiently and generically produced from H$_2$O ice processing, and that the entrapped H$_2$ is released over a broad range of temperatures during annealing of the amorphous water matrix. We show that this mechanism can explain many of `Oumuamua's peculiar properties without fine-tuning. This provides further support that `Oumuamua originated as a planetesimal relic broadly similar to Solar System comets.

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arXiv2023

Protoplanetary Disk Science with the Orbiting Astronomical Satellite Investigating Stellar Systems (OASIS) Observatory

The Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS) is a NASA Astrophysics MIDEX-class mission concept, with the stated goal of following water from galaxies, through protostellar systems, to Earth's oceans. This paper details the protoplanetary disk science achievable with OASIS. OASIS's suite of heterodyne receivers allow for simultaneous, high spectral resolution observations of water emission lines spanning a large range of physical conditions within protoplanetary disks. These observations will allow us to map the spatial distribution of water vapor in disks across evolutionary stages and assess the importance of water, particularly the location of the midplane water snowline, to planet formation. OASIS will also detect the H2 isotopologue HD in 100+ disks, allowing for the most accurate determination of total protoplanetary disk gas mass to date. When combined with the contemporaneous water observations, the HD detection will also allow us to trace the evolution of water vapor across evolutionary stages. These observations will enable OASIS to characterize the time development of the water distribution and the role water plays in the process of planetary system formation.

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arXiv2021

Ice inheritance in dynamical disk models

The compositions of planet-forming disks are set by a combination of material inherited from the interstellar medium and material reprocessed during disk formation and evolution. Indeed, comets and primitive meteorites exhibit interstellar-like isotopic ratios and/or volatile compositions, supporting that some pristine material was incorporated intact into icy planetesimals in the Solar Nebula. To date, the survival of volatile interstellar material in the disk stage has not been modeled using realistic disk physics. Here, we present a modeling framework to track the destruction of interstellar ices on dust grains undergoing transport processes within a disk, with a particular focus on explaining the incorporation of pristine material into icy planetesimals. We find it is difficult to explain inheritance through the local assembly of comets, as ice destruction is rapid for small (<10um) grains in the inner few tens of au. Instead, a plausible pathway to inheritance is to form pebbles at larger disk radii, which then drift inwards to the comet-forming zone with their ices mostly preserved. Small grains beyond ~100 au can experience ice photodissociation at the tens of percent level, however little of the ice is actually lost from the grain, likely making this a robust site for in situ ice chemistry. Our models also indicate that many complex organic species should survive passage through the disk intact. This raises the possibility that organics synthesized in the interstellar medium can be delivered to terrestrial planets by icy body impact and thus potentially participate in origins of life chemistry.

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arXiv2020

The TW Hya Rosetta Stone Project III: Resolving the Gaseous Thermal Profile of the Disk

The thermal structure of protoplanetary disks is a fundamental characteristic of the system that has wide reaching effects on disk evolution and planet formation. In this study, we constrain the 2D thermal structure of the protoplanetary disk TW Hya structure utilizing images of seven CO lines. This includes new ALMA observations of 12CO J=2-1 and C18O J=2-1 as well as archival ALMA observations of 12CO J=3-2, 13CO J=3-2, 6-5, C18O J= 3-2, 6-5. Additionally, we reproduce a Herschel observation of the HD J=1-0 line flux, the spectral energy distribution, and utilize a recent quantification of CO radial depletion in TW Hya. These observations were modeled using the thermochemical code RAC2D, and our best fit model reproduces all spatially resolved CO surface brightness profiles. The resulting thermal profile finds a disk mass of 0.025 Msun and a thin upper layer of gas depleted of small dust with a thickness of approx 1.2% of the corresponding radius. Using our final thermal structure, we find that CO alone is not a viable mass tracer as its abundance is degenerate with the total H2 surface density. Different mass models can readily match the spatially resolved CO line profiles with disparate abundance assumptions. Mass determination requires additional knowledge and, in this work, HD provides the additional constraint to derive the gas mass and supports the inference of CO depletion in the TW Hya disk. Our final thermal structure confirms the use of HD as a powerful probe of protoplanetary disk mass. Additionally, the method laid out in this paper is an employable strategy for extraction of disk temperatures and masses in the future.

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arXiv2020

An unbiased ALMA spectral survey of the LkCa 15 and MWC 480 protoplanetary disks

The volatile contents of protoplanetary disks both set the potential for planetary chemistry and provide valuable probes of defining disk system characteristics such as stellar mass, gas mass, ionization, and temperature structure. Current disk molecular inventories are fragmented, however, giving an incomplete picture: unbiased spectral line surveys are needed to assess the volatile content. We present here an overview of such a survey of the protoplanetary disks around the Herbig Ae star MWC 480 and the T Tauri star LkCa 15 in ALMA Band 7, spanning $\sim$36 GHz from 275--317 GHz and representing an order of magnitude increase in sensitivity over previous single-dish surveys. We detect 14 molecular species (including isotopologues), with 5 species (C$^{34}$S, $^{13}$CS, H$_{2}$CS, DNC, and C$_2$D) detected for the first time in protoplanetary disks. Significant differences are observed in the molecular inventories of MWC~480 and LkCa~15, and we discuss how these results may be interpreted in light of the different physical conditions of these two disk systems.

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arXiv2019

Realizing the Unique Potential of ALMA to Probe the Gas Reservoir of Planet Formation

Understanding the origin of the astonishing diversity of exoplanets is a key question for the coming decades. ALMA has revolutionized our view of the dust emission from protoplanetary disks, demonstrating the prevalence of ring and spiral structures that are likely sculpted by young planets in formation. To detect kinematic signatures of these protoplanets and to probe the chemistry of their gas accretion reservoir will require the imaging of molecular spectral line emission at high angular and spectral resolution. However, the current sensitivity of ALMA limits these important spectral studies to only the nearest protoplanetary disks. Although some promising results are emerging, including the identification of the snowlines of a few key molecules and the first attempt at detecting a protoplanet's spiral wake, it is not yet possible to search for these important signatures in a population of disks in diverse environments and ages. Harnessing the tremendous power of (sub)mm observations to pinpoint and characterize the chemistry of planets in formation will require a major increase of ALMA's spectral sensitivity (5-10x), increase in instantaneous bandwidth (2x) at high spectral resolution, and improved angular resolution (2x) in the 2030 era.

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arXiv2018

The Distribution and Excitation of CH$_3$CN in a Solar Nebula Analog

Cometary studies suggest that the organic composition of the early Solar Nebula was rich in complex nitrile species such a CH$_3$CN. Recent ALMA detections in protoplanetary disks suggest that these species may be common during planet and comet formation, but connecting gas phase measurements to cometary abundances first requires constraints on formation chemistry and distributions of these species. We present here the detection of seven spatially resolved transitions of CH$_3$CN in the protoplanetary disk around the T-Tauri star TW Hya. Using a rotational diagram analysis we find a disk-averaged column density of N$_T$=1.45$^{+0.19}_{-0.15}\times10^{12}$ cm$^{-2}$ and a rotational temperature of T$_{rot}$=32.7$^{+3.9}_{-3.4}$ K. A radially resolved rotational diagram shows the rotational temperature to be constant across the disk, suggesting that the CH$_3$CN emission originates from a layer at z/r$\sim$0.3. Through comparison of the observations with predictions from a disk chemistry model, we find that grain-surface reactions likely dominate CH$_3$CN formation and that in situ disk chemistry is sufficient to explain the observed CH$_3$CN column density profile without invoking inheritance from the protostellar phase. However, the same model fails to reproduce a Solar System cometary abundance of CH$_3$CN relative to H$_2$O in the midplane, suggesting that either vigorous vertical mixing or some degree of inheritance from interstellar ices occurred in the Solar Nebula.

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arXiv2015

CO and N$_2$ desorption energies from water ice

The relative desorption energies of CO and N$_2$ are key to interpretations of observed interstellar CO and N$_2$ abundance patterns, including the well-documented CO and N$_2$H$^+$ anti-correlations in disks, protostars and molecular cloud cores. Based on laboratory experiments on pure CO and N$_2$ ice desorption, the difference between CO and N$_2$ desorption energies is small; the N$_2$-to-CO desorption energy ratio is 0.93$\pm$0.03. Interstellar ices are not pure, however, and in this study we explore the effect of water ice on the desorption energy ratio of the two molecules. We present temperature programmed desorption experiments of different coverages of $^{13}$CO and $^{15}$N$_2$ on porous and compact amorphous water ices and, for reference, of pure ices. In all experiments, $^{15}$N$_2$ desorption begins a few degrees before the onset of $^{13}$CO desorption. The $^{15}$N$_2$ and $^{13}$CO energy barriers are 770 and 866 K for the pure ices, 1034-1143 K and 1155-1298 K for different sub-monolayer coverages on compact water ice, and 1435 and 1575 K for $\sim$1 ML of ice on top of porous water ice. For all equivalent experiments, the N$_2$-to-CO desorption energy ratio is consistently 0.9. Whenever CO and N$_2$ ice reside in similar ice environments (e.g. experience a similar degree of interaction with water ice) their desorption temperatures should thus be within a few degrees of one another. A smaller N$_2$-to-CO desorption energy ratio may be present in interstellar and circumstellar environments if the average CO ice molecules interacts more with water ice compared to the average N$_2$ molecules.

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