arXiv subjects

Jeremy England

Publications and source records attributed to Jeremy England.

7 recordsLinked to original sources

arXiv2025

Emergent order from mixed chaos at low temperature

This paper explores a novel connection between a thermodynamic and a dynamical systems perspective on emergent dynamical order. We provide evidence for a conjecture that Hamiltonian systems with mixed chaos spontaneously find regular behavior when minimally coupled to a thermal bath at sufficiently low temperature. Numerical evidence across a diverse set of five dynamical systems supports this conjecture, and allows us to quantify corollaries about the organization timescales and disruption of order at higher temperatures. Balancing the damping-induced phase-space contraction against thermal exploration, we are able to predict the transition temperatures in terms of the relaxation timescales, indicating a novel nonequilibrium fluctuation-dissipation relation, and formally connecting the thermodynamic and dynamical systems views. Our findings suggest that for a wide range of real-world systems, coupling to a cold thermal bath leads to emergence of robust, non-trivial dynamical order, rather than a mere reduction of motion as in equilibrium.

nlin.AO↗

arXiv2019

Active regeneration unites high- and low-temperature features in cooperative self-assembly

Cytoskeletal filaments are capable of self-assembly in the absence of externally supplied chemical energy, but the rapid turnover rates essential for their biological function require a constant flux of ATP or GTP hydrolysis. The same is true for two-dimensional protein assemblies employed in the formation of vesicles from cellular membranes, which rely on ATP-hydrolyzing enzymes to rapidly disassemble upon completion of the process. Recent observations suggest that the nucleolus, p granules and other three-dimensional membraneless organelles may also demand dissipation of chemical energy to maintain their fluidity. Cooperative binding plays a crucial role in the dynamics of these higher-dimensional structures, but is absent from classic models of 1-dimensional cytoskeletal assembly. In this Letter, we present a thermodynamically consistent model of actively regeneration with cooperative assembly, and compute the maximum turnover rate and minimum disassembly time as a function of the chemical driving force and the binding energy. We find that these driven structures resemble different equilibrium states above and below the nucleation barrier. In particular, we show that the maximal acceleration under large binding energies unites infinite-temperature local fluctuations with low-temperature nucleation kinetics.

physics.bio-ph↗

arXiv2018

Least Rattling Feedback from Strong Time-scale Separation

In most interacting many-body systems associated with some "emergent phenomena," we can identify sub-groups of degrees of freedom that relax on dramatically different time-scales. Time-scale separation of this kind is particularly helpful in nonequilibrium systems where only the fast variables are subjected to external driving; in such a case, it may be shown through elimination of fast variables that the slow coordinates effectively experience a thermal bath of spatially-varying temperature. In this work, we investigate how such a temperature landscape arises according to how the slow variables affect the character of the driven quasi-steady-state reached by the fast variables. Brownian motion in the presence of spatial temperature gradients is known to lead to the accumulation of probability density in low temperature regions. Here, we focus on the implications of attraction to low effective temperature for the long-term evolution of slow variables. After quantitatively deriving the temperature landscape for a general class of overdamped systems using a path integral technique, we then illustrate in a simple dynamical system how the attraction to low effective temperature has a fine-tuning effect on the slow variable, selecting configurations that bring about exceptionally low force fluctuation in the fast-variable steady-state. We furthermore demonstrate that a particularly strong effect of this kind can take place when the slow variable is tuned to bring about orderly, integrable motion in the fast dynamics that avoids thermalizing energy absorbed from the drive. We thus point to a potentially general feedback mechanism in multi-time-scale active systems, that leads to the exploration of slow variable space, as if in search of fine-tuning for a "least rattling" response in the fast coordinates.

cond-mat.stat-mech↗

arXiv2017

Limits of Predictions in Thermodynamic Systems: A Review

The past twenty years have seen a resurgence of interest in nonequilibrium thermodynamics, thanks to advances in the theory of stochastic processes and in their thermodynamic interpretation. Fluctuation theorems provide fundamental constraints on the dynamics of systems arbitrarily far from thermal equilibrium. Thermodynamic uncertainty relations bound the dissipative cost of precision in a wide variety of processes. Concepts of excess work and excess heat provide the basis for a complete thermodynamics of nonequilibrium steady states, including generalized Clausius relations and thermodynamic potentials. But these general results carry their own limitations: fluctuation theorems involve exponential averages that can depend sensitively on unobservably rare trajectories; steady-state thermodynamics makes use of a dual dynamics that lacks any direct physical interpretation. This review aims to present these central results of contemporary nonequilibrium thermodynamics in such a way that the power of each claim for making physical predictions can be clearly assessed, using examples from current topics in soft matter and biophysics.

cond-mat.stat-mech↗

arXiv2016

Dissipation bounds all steady-state current fluctuations

Near equilibrium, small current fluctuations are described by a Gaussian with a linear-response variance regulated by the dissipation. Here, we demonstrate that dissipation still plays a dominant role in structuring large fluctuations arbitrarily far from equilibrium. In particular, we prove a linear-response-like bound on the large deviation function for currents in Markov jump processes. We find that nonequilibrium current fluctuations are always more likely than what is expected from a linear-response analysis. As a small-fluctuations corollary, we derive a recently-conjectured uncertainty bound on the variance of current fluctuations.

cond-mat.stat-mech↗

arXiv2015

Far-from-Equilibrium Distribution from Near-Steady-State Work Fluctuations

A longstanding goal of nonequilibrium statistical mechanics has been to extend the conceptual power of the Boltzmann distribution to driven systems. We report some new progress towards this goal. Instead of writing the nonequilibrium steady-state distribution in terms of perturbations around thermal equilibrium, we start from the linearized driven dynamics of observables about their stable fixed point, and expand in the strength of the nonlinearities encountered during typical fluctuations away from the fixed point. The first terms in this expansion retain the simplicity of known expansions about equilibrium, but can correctly describe the statistics of a certain class of systems even under strong driving. We illustrate this approach by comparison with a numerical simulation of a sheared Brownian colloid, where we find that the first two terms in our expansion are sufficient to account for the shear thinning behavior at high shear rates.

cond-mat.stat-mech↗

arXiv2014

Statistical Physics of Adaptation

All living things exhibit adaptations that enable them to survive and reproduce in the natural environment that they inhabit. From a biological standpoint, it has long been understood that adaptation comes from natural selection, whereby maladapted individuals do not pass their traits effectively to future generations. However, we may also consider the phenomenon of adaptation from the standpoint of physics, and ask whether it is possible to delineate what the difference is in terms of physical properties between something that is well-adapted to its surrounding environment, and something that is not. In this work, we undertake to address this question from a theoretical standpoint. Building on past fundamental results in far-from-equilibrium statistical mechanics, we demonstrate a generalization of the Helmholtz free energy for the finite-time stochastic evolution of driven Newtonian matter. By analyzing this expression term by term, we are able to argue for a general tendency in driven many-particle systems towards self-organization into states formed through exceptionally reliable absorption and dissipation of work energy from the surrounding environment. Subsequently, we illustrate the mechanism of this general tendency towards physical adaptation by analyzing the process of random hopping in driven energy landscapes.

physics.bio-ph↗