arXiv subjects

Jeremy N. Munday

Publications and source records attributed to Jeremy N. Munday.

At least 19 recordsLinked to original sources

arXiv2026

Casimir-force spectroscopy of broadband optical response

Broadband optical response governs light-matter interactions across photonics, plasmonics, thermal radiation, and quantum fluctuation electrodynamics, yet determining a continuous dielectric function over many decades in frequency typically requires combining multiple spectroscopies, extrapolations, and material models. Here we show that quantum-fluctuation forces provide a route to broadband optical characterization. Casimir interactions depend on the dielectric response of materials across the electromagnetic spectrum, but this information is encoded through Lifshitz theory in a spectrally weighted and nontrivial way. By training physics-constrained supervised learning models on synthetic dielectric spectra and their corresponding Casimir force curves, we invert this relationship and constrain the complex permittivity of materials over more than seven orders of magnitude in frequency and provide an estimate of their values from force-distance data. The reconstruction reveals a direct separation-frequency correspondence: large separations constrain the free-carrier response, whereas shorter separations encode higher-frequency resonant structure. Applying the method to measured force gradients identifies the current experimental limits imposed by measurement noise, restricted separation range, and model complexity. These results establish fluctuation-induced forces as a spectrally weighted route to broadband optical characterization and define the experimental and physical limits that govern what spectral information is accessible from near-field quantum electromagnetic measurements.

quant-ph↗

arXiv2026

Dynamical Casimir photons from rotation of a nonspherical particle

We consider a non-spherical neutral particle spinning in free space and interacting with the electromagnetic quantum vacuum. When the rotation axis is orthogonal to the particle symmetry axis, the scattered field develops frequency sidebands that induce the parametric emission of dynamical Casimir photon pairs. Under the structural constraint of a maximum tip velocity, the emission rate is maximized for a nearly spherical geometry and is further enhanced near a polaritonic resonance. For realistic material parameters, even these optimized upper bounds remain exceedingly small, setting stringent quantitative limits on free-space rotational dynamical Casimir emission with a single nanoparticle.

quant-ph↗

arXiv2025

Enhanced nuclear fusion in the sub-keV energy regime

Nuclear fusion requires overcoming or traversing a repulsive Coulomb barrier of hundreds of kiloelectronvolts, rendering the probability of fusion at sub-keV energies vanishingly small. Yet in condensed matter, the electronic and structural environment of reacting nuclei can profoundly alter fusion rates. Here we demonstrate that deuterium-deuterium fusion within metallic foils exhibits a pronounced enhancement and reaction yield plateau below energies of 2.5 keV- contrary to the expected exponential suppression with decreasing energy. Using a dual-chamber platform that combines electrochemical deuterium loading with ion-beam bombardment, we show that fusion yields in palladium and titanium hydrides are enhanced by over 10^18 compared to theoretical bare-nucleus fusion rates. These results demonstrate that access to low-energy fusion processes can be governed by materials degrees of freedom. This materials-driven fusion regime establishes a reproducible, tunable framework for studying and ultimately engineering nuclear reactions in solids. While the reaction rates reported here are low, these insights into materials-modulated fusion processes offer a potential foundation for understanding how condensed-matter environments could influence future fusion-energy concepts.

nucl-ex↗

arXiv2025

Thermal Effects in the Casimir Torque between Birefringent Plates

The Casimir effect, originating from quantum and thermal fluctuations, is well known for inducing forces between closely spaced surfaces. When these surfaces are optically anisotropic, these interactions can produce a Casimir torque that rotates the surfaces relative to each other. We investigate, for the first time, the influence of thermal fluctuations on the Casimir torque between birefringent plates. Our results reveal that thermal modes significantly diminish the torque, with reductions up to 2 orders of magnitude for highly birefringent materials. Temperature is also shown to alter the angular dependence of the torque, significantly deviating from the typical sinusoidal behavior, and becomes particularly important at large separations that exceed the thermal wavelength. Finally, we demonstrate that systems of dissimilar birefringent plates that exhibit a distance-dependent reversal in the torque's direction can enable precise control of the torque's magnitude and sign through temperature manipulation. These findings advance our understanding of quantum and thermal fluctuation interplay and provide a framework for designing innovative nanoscale sensors and devices leveraging Casimir torque phenomena.

quant-ph↗

arXiv2024

Casimir repulsion with biased semiconductors

Quantum and thermal fluctuations are fundamental to a plethora of phenomena within quantum optics, including the Casimir effect that acts between closely separated surfaces typically found in MEMS and NEMS devices. Particularly promising for engineering and harnessing these forces are systems out of thermal equilibrium. Recently, semiconductors with external bias have been proposed to study the nonequilibrium Casimir force. Here, we explore systems involving moderately biased semiconductors that exhibit strong repulsive Casimir forces, and we determine the effects of bias voltage, semiconductor bandgap energy, and separation for experimentally accessible configurations. Modes emitted from the semiconductors exert a repulsive force on a near surface that overcomes the attractive equilibrium Casimir force contribution at submicron distances. For the geometry of two parallel planes, those modes undergo Fabry-Pérot interference resulting in an oscillatory force behavior as a function of separation. Utilizing the proximity-force approximation, we predict that the repulsive force exerted on a gold sphere is well within the accuracy of typical Casimir force experiments. Our work opens up new possibilities of controlling forces at the nano- and micrometer scale with applications in sensing and actuation in nanotechnology.

quant-ph↗

arXiv2023

Enhanced repulsive Casimir forces between gold and thin magnetodielectric plates

We calculate repulsive Casimir forces between metallic and magnetic plates and quantitatively probe the magnetic plate's properties as tuning knobs for the repulsion. Namely, the plate's thickness and its low-frequency permittivity and permeability. For a thin magnetic plate ($\leq 10\,\text{nm}$), we find that repulsion can exist as long as $μ(0) \geq ε(0)$. We also explore the effect of temperature on the repulsion and transition distance between attractive and repulsive interactions. We show how the parameters can be tuned to allow repulsion at sub-micron separation regimes, making it potentially accessible to known high-resolution measurement techniques using magnetic van der Waals materials.

quant-ph↗

arXiv2022

Electrically switchable Casimir forces using transparent conductive oxides

Casimir forces between charge-neutral bodies originate from quantum vacuum fluctuations of electromagnetic fields, which exhibit a critical dependence on material's electromagnetic properties. Over the years, in-situ modulation of material's optical properties has been enabled through various means and has been widely exploited in a plethora of applications such as electro-optical modulation, transient color generation, bio- or chemical sensing, etc. Yet Casimir force modulation has been hindered by difficulty in achieving high modulation signals due to the broadband nature of the Casimir interaction. Here we propose and investigate two configurations that allow for in-situ modulation of Casimir forces through electrical gating of a metal-insulator-semiconductor (MIS) junction comprised of transparent conductive oxide (TCO) materials. By switching the gate voltage on and off, a force modulation of > 400 pN is predicted due to substantive charge carrier accumulation in the TCO layer, which can be easily measured using state-of-the-art force measurement techniques in an atomic force microscope (AFM). We further examine the influence of the oxide layer thickness on the force modulation, suggesting the importance of the fine control of the oxide layer deposition. Our work provides a promising pathway for modulating the Casimir effect in-situ with experimentally measurable force contrast.

physics.app-ph↗

arXiv2022

The Effect of Epsilon-Near-Zero (ENZ) Modes on the Casimir Interaction between Ultrathin Films

Vacuum fluctuation-induced interactions between macroscopic metallic objects result in an attractive force between them, a phenomenon known as the Casimir effect. This force is the result of both plasmonic and photonic modes. For very thin films, field penetration through the films will modify the allowed modes. Here, we investigate the Casimir interaction between two ultrathin films from the perspective of the force distribution over real frequencies for the first time and find pronounced repulsive contributions to the force due to the highly confined and nearly dispersion-free epsilon-near-zero (ENZ) modes that only exist in ultrathin films. These contributions are found to persistently occur around the ENZ frequency of the film and are irrespective of the inter-film separation. We further associate the ENZ modes with a striking thickness dependence in the averaged force density for conductive thin films, a metric signifying a thin-film's acceleration due to Casimir effect. Our results shed light on the role of the unique vacuum fluctuation modes existing in ultrathin ENZ materials, which may offer significant potential for engineering the motion of objects in nanomechanical systems.

quant-ph↗

arXiv2022

Radiative energy bandgap of nanostructures coupled with quantum emitters around the epsilon-near-zero (ENZ) frequency

Epsilon-near-zero (ENZ) materials have been demonstrated to exhibit unique electromagnetic properties. Here we propose the concept of radiative energy bandgap for an ENZ nanoparticle coupled with a quantum emitter (QE). The radiative emission of the coupled QE-nanoparticle can be significantly suppressed around the ENZ frequency and substantially enhanced otherwise, yielding an effective energy bandgap for radiation. This suppression is effectively invariant with respect to the particle size and is therefore an intrinsic property of the ENZ material. Our concept also heralds an alternative pathway to quench the emission from a QE, which may find potential application in quantum information storage.

physics.optics↗

arXiv2021

Engineering Casimir interactions with epsilon-near-zero materials

In this paper we theoretically demonstrate the tunability of the Casimir force both in sign and magnitude between parallel plates coated with dispersive materials. We show that this force, existing between uncharged plates, can be tuned by carefully choosing the value of the plasma frequency (i.e., the epsilon-near-zero frequency) of the coating in the neighborhood of the resonance frequency of the cavity. The coating layer enables a continuous variation of the force between four limiting values when a coating is placed on each plate. We explore the consequences of such variation when pairs of electric and magnetic conductors (i.e. low and high impedance surfaces) are used as substrates on either side, showing that this continuous variation results in changes in the sign of the force, leading to both stable and unstable conditions, which could find interesting potential applications in nanomechanics including nanoparticle tweezing.

quant-ph↗

arXiv2020

Control of hot-carrier relaxation time in Au-Ag thin films through alloying

The plasmon resonance of a structure is primarily dictated by its optical properties and geometry, which can be modified to enable hot-carrier photodetectors with superior performance. Recently, metal-alloys have played a prominent role in tuning the resonance of plasmonic structures through chemical composition engineering. However, it has been unclear how alloying modifies the time dynamics of generated hot-carriers. In this work, we elucidate the role of chemical composition on the relaxation time of hot-carriers for the archetypal Aux Ag1-x thin-film system. Through time-resolved optical spectroscopy measurements in the visible wavelength range, we measure composition-dependent relaxation times that vary up to 8x for constant pump fluency. Surprisingly, we find that the addition of 2% of Ag into Au films can increase the hot carrier lifetime by approximately 35% under fixed fluence, as a result of a decrease in optical loss. Further, the relaxation time is found to be inversely proportional to the imaginary part of the permittivity. Our results indicate that alloying is a promising approach to effectively control hot-carrier relaxation time in metals.

physics.optics↗

arXiv2019

Surface Plasmon Assisted Control of Hot-Electron Relaxation Time

Surface plasmon mediated hot carrier generation is widely utilized for the manipulation of the electron-photon interactions in many types of optoelectronic devices including solar cells, photodiodes, and optical modulators. A diversity of plasmonic systems such as nanoparticles, resonators, and waveguides have been introduced to enhance hot carrier generation; however, the impact of the propagating surface plasmons on hot carrier lifetime has not been clearly demonstrated. Here, we systematically study the hot carrier relaxation in thin film gold (Au) samples under surface plasmon coupling with the Kretschmann configuration. We observe that the locally confined electric field at the surface of the metal significantly affects the hot carrier distribution and electron temperature, which results in a slowing of the hot electrons relaxation time, regardless of the average value of the absorbed power in the Au thin film. This result could be extended to other plasmonic nanostructures, enabling the control of hot carrier lifetimes throughout the optical frequency range.

physics.optics↗

arXiv2019

Sensitivity and accuracy of Casimir force measurements in air

Quantum electrodynamic fluctuations cause an attractive force between metallic surfaces. At separations where the finite speed of light affects the interaction, it is called the Casimir force. Thermal motion determines the fundamental sensitivity limits of its measurement at room temperature, but several other systematic errors contribute uncertainty as well and become more significant in air relative to vacuum. Here we discuss the viability of several measurement techniques in air (force modulation, frequency modulation, and quasi-static deflection), characterize their sensitivity and accuracy by identifying several dominant sources of uncertainty, and compare the results to the fundamental sensitivity limits dictated by thermal motion and to the uncertainty inherent to calculations of the Casimir force. Finally, we explore prospects for mitigating the sources of uncertainty to enhance the range and accuracy of Casimir force measurements.

quant-ph↗

arXiv2018

Dynamic optical properties of metal hydrides

Metal hydrides often display dramatic changes in optical properties upon hydrogenation. These shifts make them prime candidates for many tunable optical devices, such as optical hydrogen sensors and switchable mirrors. While some of these metals, such as palladium, have been well studied, many other promising materials have only been characterized over a limited optical range and lack direct in situ measurements of hydrogen loading, limiting their potential applications. Further, there have been no systematic studies that allow for a clear comparison between these metals. In this work, we present such a systematic study of the dynamically tunable optical properties of Pd, Mg, Zr, Ti, and V throughout hydrogenation with a wavelength range of 250 - 1690 nm. These measurements were performed in an environmental chamber, which combines mass measurements via a quartz crystal microbalance with ellipsometric measurements in up to 7 bar of hydrogen gas, allowing us to determine the optical properties during hydrogen loading. In addition, we demonstrate a further tunability of the optical properties of titanium and its hydride by altering annealing conditions, and we investigate the optical and gravimetric hysteresis that occurs during hydrogenation cycling of palladium. Finally, we demonstrate several nanoscale optical and plasmonic structures based on these dynamic properties. We show structures that, upon hydrogenation, demonstrate five orders of magnitude change in reflectivity, resonance shifts of >200 nm, and relative transmission switching of >3000%, suggesting a wide range of applications.

cond-mat.mtrl-sci↗

arXiv2017

Effect of lateral tip motion on multifrequency atomic force microscopy

In atomic force microscopy (AFM), the angle relative to the vertical ($θ_{i}$) that the tip apex of a cantilever moves is determined by the tilt of the probe holder and the geometries of the cantilever and actuated eigenmode $i$. Even though the effects of $θ_{i}$ on static and single-frequency AFM are known (increased effective spring constant, sensitivity to sample anisotropy, etc), the higher eigenmodes used in multifrequency force microscopy lead to additional effects that have not been fully explored. Here we use Kelvin probe force microscopy (KPFM) to investigate how $θ_{i}$ affects not only the signal amplitude and phase, but can also lead to behaviors such as destabilization of the KPFM voltage feedback loop. We find that longer cantilevers and modified sample orientations improve voltage feedback loop stability, even though variations to scanning parameters such as cantilever shake amplitude and lift height do not.

cond-mat.mes-hall↗

arXiv2017

Alignment-dependent decay rate of an atomic dipole near an optical nanofiber

We study the modification of the atomic spontaneous emission rate, i.e. Purcell effect, of $^{87}$Rb in the vicinity of an optical nanofiber ($\sim$500 nm diameter). We observe enhancement and inhibition of the atomic decay rate depending on the alignment of the induced atomic dipole relative to the nanofiber. Finite-difference time-domain simulations are in quantitative agreement with the measurements when considering the atoms as simple oscillating linear dipoles. This is surprising since the multi-level nature of the atoms should produce a different radiation pattern, predicting smaller modification of the lifetime than the measured ones. This work is a step towards characterizing and controlling atomic properties near optical waveguides, fundamental tools for the development of quantum photonics.

quant-ph↗

arXiv2016

Mid-infrared time-resolved photoconduction in black phosphorus

Black phosphorus has attracted interest as a material for use in optoelectronic devices due to many favorable properties such as a high carrier mobility, field-effect, and a direct bandgap that can range from 0.3 eV in its bulk crystalline form to 2 eV for a single atomic layer. The low bandgap energy for bulk black phosphorus allows for direct transition photoabsorption that enables detection of light out to mid-infrared frequencies. In this work we characterize the room temperature optical response of a black phosphorus photoconductive detector at wavelengths ranging from 1.56 $μ$m to 3.75 $μ$m. Pulsed autocorrelation measurements in the near-infrared regime reveal a strong, sub-linear photocurrent nonlinearity with a response time of 1 ns, indicating that gigahertz electrical bandwidth is feasible. Time resolved photoconduction measurements covering near- and mid-infrared frequencies show a fast 65 ps rise time, followed by a carrier relaxation with a time scale that matches the intrinsic limit determined by autocorrelation. The sublinear photoresponse is shown to be caused by a reduction in the carrier relaxation time as more energy is absorbed in the black phosphorus flake and is well described by a carrier recombination model that is nonlinear with excess carrier density. The device exhibits a measured noise-equivalent power of 530 pW/$\sqrt{\text{Hz}}$ which is the expected value for Johnson noise limited performance. The fast and sensitive room temperature photoresponse demonstrates that black phosphorus is a promising new material for mid-infrared optoelectronics.

cond-mat.mtrl-sci↗

arXiv2016

Fast, high-resolution surface potential measurements in air with heterodyne Kelvin probe force microscopy

Kelvin probe force microscopy (KPFM) adapts an atomic force microscope to measure electric potential on surfaces at nanometer length scales. Here we demonstrate that Heterodyne-KPFM enables scan rates of several frames per minute in air, and concurrently maintains spatial resolution and voltage sensitivity comparable to frequency-modulation KPFM, the current spatial resolution standard. Two common classes of topography-coupled artifacts are shown to be avoidable with H-KPFM. A second implementation of H-KPFM is also introduced, in which the voltage signal is amplified by the first cantilever resonance for enhanced sensitivity. The enhanced temporal resolution of H-KPFM can enable the imaging of many dynamic processes, such as such as electrochromic switching, phase transitions, and device degredation (battery, solar, etc.), which take place over seconds to minutes and involve changes in electric potential at nanometer lengths.

cond-mat.mes-hall↗