arXiv subjects

Jeroen Rodenburg

Publications and source records attributed to Jeroen Rodenburg.

4 recordsLinked to original sources

arXiv2019

Interparticle torques suppress motility-induced phase separation for rodlike particles

To study the role of torque in motility-induced phase separation (MIPS), we simulate a system of self-propelled particles whose shape varies smoothly from isotropic (disks/spheres) to weakly elongated (rods). We construct the phase diagrams of 2D active disks, 3D active spheres and 2D/3D active rods of aspect ratio $l/σ=2$. A stability analysis of the homogeneous isotropic phase allows us to predict the onset of MIPS based on the effective swimming speed and rotational diffusion of the particles. Both methods find suppression of MIPS as the particle shape is elongated. We propose a suppression mechanism based on the duration of collisions, and argue that this mechanism can explain both the suppression of MIPS found here for rodlike particles and the enhancement of MIPS found for particles with Vicsek interactions.

cond-mat.stat-mech↗

arXiv2018

Ratchet-induced variations in bulk states of an active ideal gas

We study the distribution of active, noninteracting particles over two bulk states separated by a ratchet potential. By solving the steady-state Smoluchowski equations in a flux-free setting, we show that the ratchet potential affects the distribution of particles over the bulks, and thus exerts an influence of infinitely long range. As we show, crucial for having such a long-range influence is an external potential that is nonlinear. We characterize how the difference in bulk densities depends on activity and on the ratchet potential, and we identify power law dependencies on system parameters in several limiting cases. While weakly active systems are often understood in terms of an effective temperature, we present an analytical solution that explicitly shows that this is not possible in the current setting. Instead, we rationalize our results by a simple transition state model, that presumes particles to cross the potential barrier by Arrhenius rates modified for activity. While this model does not quantitatively describe the difference in bulk densities for feasible parameter values, it does reproduce - in its regime of applicability - the complete power law behavior correctly.

cond-mat.soft↗

arXiv2018

Chemical potential in active systems: predicting phase equilibrium from bulk equations of state?

We derive a microscopic expression for a quantity $μ$ that plays the role of chemical potential of Active Brownian Particles (ABPs) in a steady state in the absence of vortices. We show that $μ$ consists of (i) an intrinsic chemical potential similar to passive systems, which depends on density and self-propulsion speed, but not on the external potential, (ii) the external potential, and (iii) a newly derived one-body swim potential due to the activity of the particles. Our simulations on active Brownian particles show good agreement with our Fokker-Planck calculations, and confirm that $μ(z)$ is spatially constant for several inhomogeneous active fluids in their steady states in a planar geometry. Finally, we show that phase coexistence of ABPs with a planar interface satisfies not only mechanical but also diffusive equilibrium. The coexistence can be well-described by equating the bulk chemical potential and bulk pressure obtained from bulk simulations for systems with low activity but requires explicit evaluation of the interfacial contributions at high activity.

cond-mat.soft↗

arXiv2017

Van't Hoff's law for active suspensions: the role of the solvent chemical potential

We extend Van't Hoff's law for the osmotic pressure to a suspension of active Brownian particles. The propelled particles exert a net reaction force on the solvent, and thereby either drive a measurable solvent flow from the connecting solvent reservoir through the semipermeable membrane, or increase the osmotic pressure and cause the suspension to rise to heights as large as micrometers for experimentally realized microswimmers described in the literature. The increase in osmotic pressure is caused by the background solvent being, in contrast to passive suspensions, no longer at the chemical potential of the solvent reservoir. The difference in solvent chemical potentials depends on the colloid-membrane interaction potential, which implies that the osmotic pressure is a state function of a state that itself is influenced by the membrane potential.

cond-mat.soft↗