arXiv subjects

Jesse Smith

Publications and source records attributed to Jesse Smith.

5 recordsLinked to original sources

arXiv2025

Enhancement of hydrogen absorption and hypervalent metal hydride formation in lanthanum using cryogenic ball milling

Rare earth superhydrides exhibit high temperature superconductivity but are difficult to characterize and use in applications due to their high formation and stability pressures, which are typically in excess of 100 GPa. We studied how modification of the rare earth precursor improves hydrogen reactivity and hydrogen uptake for forming such metal hydrides at lower pressures. An elemental lanthanum precursor was milled at liquid nitrogen temperatures for different time intervals. After exposure to gaseous hydrogen at 380 C and 100 bar, we found a systematic enhancement of hydrogen absorption with increasing ball milling time for forming the LaHx, x=2-3 phase. Exposing the precursor to pressures up to 60 GPa with an ammonia borane (BNH6) hydrogen source resulted in a hypervalent LaH4 phase. This LaH4 phase is associated with the suppression of a rhombohedral distortion of the Fm3-m cubic structure after cryomilling the precursor.

cond-mat.mtrl-sci↗

arXiv2024

Use of a Multiscale Vision Transformer to predict Nursing Activities Score from Low Resolution Thermal Videos in an Intensive Care Unit

Excessive caregiver workload in hospital nurses has been implicated in poorer patient care and increased worker burnout. Measurement of this workload in the Intensive Care Unit (ICU) is often done using the Nursing Activities Score (NAS), but this is usually recorded manually and sporadically. Previous work has made use of Ambient Intelligence (AmI) by using computer vision to passively derive caregiver-patient interaction times to monitor staff workload. In this letter, we propose using a Multiscale Vision Transformer (MViT) to passively predict the NAS from low-resolution thermal videos recorded in an ICU. 458 videos were obtained from an ICU in Melbourne, Australia and used to train a MViTv2 model using an indirect prediction and a direct prediction method. The indirect method predicted 1 of 8 potentially identifiable NAS activities from the video before inferring the NAS. The direct method predicted the NAS score immediately from the video. The indirect method yielded an average 5-fold accuracy of 57.21%, an area under the receiver operating characteristic curve (ROC AUC) of 0.865, a F1 score of 0.570 and a mean squared error (MSE) of 28.16. The direct method yielded a MSE of 18.16. We also showed that the MViTv2 outperforms similar models such as R(2+1)D and ResNet50-LSTM under identical settings. This study shows the feasibility of using a MViTv2 to passively predict the NAS in an ICU and monitor staff workload automatically. Our results above also show an increased accuracy in predicting NAS directly versus predicting NAS indirectly. We hope that our study can provide a direction for future work and further improve the accuracy of passive NAS monitoring.

cs.CV↗

arXiv2023

Plastic strain-induced olivine-ringwoodite phase transformation at room temperature: main rules and the mechanism of the deep-focus earthquake

Deep-focus earthquakes that occur at 350-660 km are theorized to be caused by strain-induced olivine-spinel phase transformation (PT). We introduce and apply dynamic rotational diamond anvil cell with rough diamond anvils to deform San Carlos olivine. While olivine was never transformed to spinel at any pressure at room temperature, we obtained olivine-ringwoodite PT under severe plastic shear at 15-28 GPa within seconds. This is conceptual proof of the difference between pressure- and plastic strain-induced PTs and that plastic straining can accelerate this PT from million years to timescales relevant for the earthquake. The PT pressure linearly reduces with increasing plastic strain, corresponding increasing dislocation density and decreasing crystallite size. The main rules of the coupled severe plastic flow, PT, and microstructure evolution are found.

physics.geo-ph↗

arXiv2023

Plastic strain-induced phase transformations in silicon: drastic reduction of transformation pressures, change in transformation sequence, and particle size effect

Pressure-induced phase transformations (PTs) between numerous phases of Si, the most important electronic material, have been studied for decades. This is not the case for plastic strain-induced PTs. Here, we revealed in-situ various unexpected plastic strain-induced PT phenomena. Thus, for 100 nm Si, strain-induced PT Si-I to Si-II (and Si-I to Si-III) initiates at 0.4 GPa (0.6 GPa) versus 16.2 GPa ($\infty$, since it does not occur) under hydrostatic conditions; for 30 nm Si, it is 6.1 GPa versus $\infty$. The predicted theoretical correlation between the direct and inverse Hall-Petch effect of the grain size on the yield strength and the minimum pressure for strain-induced PT is confirmed for the appearance of Si-II. Retaining Si-II at ambient pressure and obtaining reverse Si-II to Si-I PT are achieved, demonstrating the possibilities of manipulating different synthetic paths.

cond-mat.mtrl-sci↗

arXiv2021

Lower pressure phases and metastable states of superconducting photo-induced carbonaceous sulfur hydride

Room-temperature superconductivity was recently discovered in carbonaceous sulfur hydride (C-S-H) close to 3\,Mbar. We report significant differences in the superconducting response of C-S-H, with a maximum $T_{C}$ of 191(1)\,K, below a 1\,Mbar. Variations in intensity of the C-H Raman modes reveal carbon content can vary between crystals synthesized with the same photo-induced method. Synchrotron single crystal x-ray diffraction identifies polymorphism with increasing degrees of covalency. These unique metastable states are highly sensitive to thermodynamic pathways.

cond-mat.supr-con↗