arXiv subjects

Ji Qi

Publications and source records attributed to Ji Qi.

At least 73 records · Page 4Linked to original sources

arXiv2023

Mastering the Task of Open Information Extraction with Large Language Models and Consistent Reasoning Environment

Open Information Extraction (OIE) aims to extract objective structured knowledge from natural texts, which has attracted growing attention to build dedicated models with human experience. As the large language models (LLMs) have exhibited remarkable in-context learning capabilities, a question arises as to whether the task of OIE can be effectively tackled with this paradigm? In this paper, we explore solving the OIE problem by constructing an appropriate reasoning environment for LLMs. Specifically, we first propose a method to effectively estimate the discrepancy of syntactic distribution between a LLM and test samples, which can serve as correlation evidence for preparing positive demonstrations. Upon the evidence, we introduce a simple yet effective mechanism to establish the reasoning environment for LLMs on specific tasks. Without bells and whistles, experimental results on the standard CaRB benchmark demonstrate that our $6$-shot approach outperforms state-of-the-art supervised method, achieving an $55.3$ $F_1$ score. Further experiments on TACRED and ACE05 show that our method can naturally generalize to other information extraction tasks, resulting in improvements of $5.7$ and $6.8$ $F_1$ scores, respectively.

cs.CL↗

arXiv2023

GOAL: A Challenging Knowledge-grounded Video Captioning Benchmark for Real-time Soccer Commentary Generation

Despite the recent emergence of video captioning models, how to generate vivid, fine-grained video descriptions based on the background knowledge (i.e., long and informative commentary about the domain-specific scenes with appropriate reasoning) is still far from being solved, which however has great applications such as automatic sports narrative. In this paper, we present GOAL, a benchmark of over 8.9k soccer video clips, 22k sentences, and 42k knowledge triples for proposing a challenging new task setting as Knowledge-grounded Video Captioning (KGVC). Moreover, we conduct experimental adaption of existing methods to show the difficulty and potential directions for solving this valuable and applicable task. Our data and code are available at https://github.com/THU-KEG/goal.

cs.CV↗

arXiv2023

Tree-of-Mixed-Thought: Combining Fast and Slow Thinking for Multi-hop Visual Reasoning

There emerges a promising trend of using large language models (LLMs) to generate code-like plans for complex inference tasks such as visual reasoning. This paradigm, known as LLM-based planning, provides flexibility in problem solving and endows better interpretability. However, current research is mostly limited to basic scenarios of simple questions that can be straightforward answered in a few inference steps. Planning for the more challenging multi-hop visual reasoning tasks remains under-explored. Specifically, under multi-hop reasoning situations, the trade-off between accuracy and the complexity of plan-searching becomes prominent. The prevailing algorithms either address the efficiency issue by employing the fast one-stop generation or adopt a complex iterative generation method to improve accuracy. Both fail to balance the need for efficiency and performance. Drawing inspiration from the dual system of cognition in the human brain, the fast and the slow think processes, we propose a hierarchical plan-searching algorithm that integrates the one-stop reasoning (fast) and the Tree-of-thought (slow). Our approach succeeds in performance while significantly saving inference steps. Moreover, we repurpose the PTR and the CLEVER datasets, developing a systematic framework for evaluating the performance and efficiency of LLMs-based plan-search algorithms under reasoning tasks at different levels of difficulty. Extensive experiments demonstrate the superiority of our proposed algorithm in terms of performance and efficiency. The dataset and code will be release soon.

cs.CL↗

arXiv2023

Robust Training of Machine Learning Interatomic Potentials with Dimensionality Reduction and Stratified Sampling

Machine learning interatomic potentials (MLIPs) enable the accurate simulation of materials at larger sizes and time scales, and play increasingly important roles in the computational understanding and design of materials. However, MLIPs are only as accurate and robust as the data they are trained on. In this work, we present DImensionality-Reduced Encoded Clusters with sTratified (DIRECT) sampling as an approach to select a robust training set of structures from a large and complex configuration space. By applying DIRECT sampling on the Materials Project relaxation trajectories dataset with over one million structures and 89 elements, we develop an improved materials 3-body graph network (M3GNet) universal potential that extrapolate more reliably to unseen structures. We further show that molecular dynamics (MD) simulations with universal potentials such as M3GNet can be used in place of expensive \textit{ab initio} MD to rapidly create a large configuration space for target materials systems. Combined with DIRECT sampling, we develop a highly reliable moment tensor potential for Ti-H system without the need for iterative optimization. This work paves the way towards robust high throughput development of MLIPs across any compositional complexity.

cond-mat.mtrl-sci↗

arXiv2023

Machine Learning Moment Tensor Potential for Modelling Dislocation and Fracture in L1$_0$-TiAl and D0$_{19}$-Ti$_3$Al Alloys

Dual-phase $γ$-TiAl and $α_2$-Ti$_{3}$Al alloys exhibit high strength and creep resistance at high temperatures. However, they suffer from low tensile ductility and fracture toughness at room temperature. Experimental studies show unusual plastic behaviour associated with ordinary and superdislocations, making it necessary to gain a detailed understanding on their core properties in individual phases and at the two-phase interfaces. Unfortunately, extended superdislocation cores are widely dissociated beyond the length scales practical for routine first-principles density-functional theory (DFT) calculations, while extant interatomic potentials are not quantitatively accurate to reveal mechanistic origins of the unusual core-related behaviour in either phases. Here, we develop a highly-accurate moment tensor potential (MTP) for the binary Ti-Al alloy system using a DFT dataset covering a broad range of intermetallic and solid solution structures. The optimized MTP is rigorously benchmarked against both previous and new DFT calculations, and unlike existing potentials, is shown to possess outstanding accuracy in nearly all tested mechanical properties, including lattice parameters, elastic constants, surface energies, and generalized stacking fault energies (GSFE) in both phases. The utility of the MTP is further demonstrated by producing dislocation core structures largely consistent with expectations from DFT-GSFE and experimental observations. The new MTP opens the path to realistic modelling and simulations of bulk lattice and defect properties relevant to the plastic deformation and fracture processes in $γ$-TiAl and $α_2$-Ti$_{3}$Al dual-phase alloys.

cond-mat.mtrl-sci↗

arXiv2023

Significant Light Extraction and Power Efficiency Enhancement of Organic Light Emitting Diodes by Subwavelength Dielectric-Nanomesh Using Large-area Nanoimprint

To improve the power efficiency of light emitting diodes (OLEDs), we developed a novel OLED structure, termed Dielectric-Nanomesh OLED (DNM-OLED), fabricated by large-area nanoimprint lithography (NIL). A dielectric-nanomesh substrate with a subwavelength nanomesh grating patterned into glass releases the photons trapped in ITO and organic layers by guided modes into leaky modes. And the dielectric-nanomesh substrate modifies the entire OLED layers into a corrugated configuration, which further lowers the parasitic resistance and hence the operating voltage. For a red phosphorescent OLED in our demonstration, with the DNM-OLED structure, the light extraction efficiency was enhanced by 1.33 fold and the operating voltage was lowered by 46%, acting together, leading to a 1.8-fold enhancement in power efficiency. Besides red OELDs, the DNM-OLED structure was also shown to be able to work for green and blue OELDs and achieved enhanced light extraction efficiency (1.31 fold for green light, 1.45 fold for blue light) without further structure modification, which demonstrated the light extraction enhancement by the DNM-OLED is broadband.

physics.optics↗

arXiv2023

Over 100% Light Extraction Enhancement of Organic Light Emitting Diodes Using Flat Moire Micro-Lens Array Fabricated by Double Nanoimprint Lithography Over a Large Area

To improve the light extraction efficiency of organic light emitting diodes (OLEDs), we developed a novel substrate, i.e., a metamaterial based flat Moire micro-lens array formed using double nanoimprint, termed Mlens-array, consisting of a hexagonal moiré pattern pillar array. By choosing a low refractive index dielectric material for the pillar array and a high refractive index dielectric material for the layer capped on top of the pillar array, we fabricated the Mlens-array behaving as a conventional convex optical micro-lens array. The Mlens-array was fabricated on a 4-inch wafer-size glass substrate by double-cycle compositional nanoimprint lithography (NIL) which is easy for achieving high throughput fabrication in large-scale. Applying the Mlens-array substrate in a typical green-emitting OLED, the light extraction efficiency was enhanced by over 100% (2.08-fold) compared to a control device fabricated on the conventional planar glass substrate.

physics.optics↗

arXiv2023

Enhancing Light Extraction of Organic Light Emitting Diodes by Deep-Groove High-index Dielectric Nanomesh Using Large-area Nanoimprint

To solve the conventional conflict between maintaining good charge transport property and achieving high light extraction efficiency when using micro/nanostructure patterned substrates to extract light from organic light emitting diodes (OLEDs), we developed a novel OLED structure, termed High-index Deep-Groove Dielectric Nanomesh OLED (HDNM-OLED), fabricated by large-area nanoimprint lithography (NIL). The key component is a nanostructure-patterned substrate embedded with a high-index deep-groove nanomesh and capped with a low-index planarization layer. The high-index and deep-groove nanomesh efficiently releases the tapped photons to achieve significantly enhanced light extraction. And the planarization layer helps to maintain the good charge transport property of the organic active layers deposited on top of it. For a green phosphorescent OLED in our demonstration, with the HDNM-OLED structure, compared to planar conventional ITO-OLED structure, the external quantum efficiency (EQE) was enhanced by 1.85-fold from 26% to 48% and power efficiency was enhanced by 1.86-fold from 42lm/W to 79lm/W. Besides green OELDs, the HDNM-OLED structure was also shown to be able to work for red and blue-emitting OELDs and achieved enhanced light extraction efficiency (1.58-fold for red light, 1.86-fold for blue light) without further structure modification, which demonstrated the light extraction enhancement by the HDNM-OLED is broadband.

physics.optics↗

arXiv2023

Syntactically Robust Training on Partially-Observed Data for Open Information Extraction

Open Information Extraction models have shown promising results with sufficient supervision. However, these models face a fundamental challenge that the syntactic distribution of training data is partially observable in comparison to the real world. In this paper, we propose a syntactically robust training framework that enables models to be trained on a syntactic-abundant distribution based on diverse paraphrase generation. To tackle the intrinsic problem of knowledge deformation of paraphrasing, two algorithms based on semantic similarity matching and syntactic tree walking are used to restore the expressionally transformed knowledge. The training framework can be generally applied to other syntactic partial observable domains. Based on the proposed framework, we build a new evaluation set called CaRB-AutoPara, a syntactically diverse dataset consistent with the real-world setting for validating the robustness of the models. Experiments including a thorough analysis show that the performance of the model degrades with the increase of the difference in syntactic distribution, while our framework gives a robust boundary. The source code is publicly available at https://github.com/qijimrc/RobustOIE.

cs.CL↗

arXiv2022

Compositionally Complex Perovskite Oxides as a New Class of Li-Ion Solid Electrolytes

Compositionally complex ceramics (CCCs), including high-entropy ceramics (HECs) as a subclass, offer new opportunities of materials discovery beyond the traditional methodology of searching new stoichiometric compounds. Herein, we establish new strategies of tailoring CCCs via a seamless combination of (1) non-equimolar compositional designs and (2) controlling microstructures and interfaces. Using oxide solid electrolytes for all-solid-state batteries as an exemplar, we validate these new strategies via discovering a new class of compositionally complex perovskite oxides (CCPOs) to show the possibility of improving ionic conductivities beyond the limit of conventional doping. As an example (amongst the 28 CCPOs examined), we demonstrate that the ionic conductivity can be improved by >60% in (Li0.375Sr0.4375)(Ta0.375Nb0.375Zr0.125Hf0.125)O3-δ, in comparison with the state-of-art (Li0.375Sr0.4375)(Ta0.75Zr0.25)O3-δ (LSTZ) baseline, via maintaining comparable electrochemical stability. Furthermore, the ionic conductivity can be improved by another >70% via grain boundary (GB) engineering, achieving >270% of the LSTZ baseline. This work suggests transformative new strategies for designing and tailoring HECs and CCCs, thereby opening a new window for discovering materials for energy storage and many other applications.

cond-mat.mtrl-sci↗

arXiv2022

Self-supervised remote sensing feature learning: Learning Paradigms, Challenges, and Future Works

Deep learning has achieved great success in learning features from massive remote sensing images (RSIs). To better understand the connection between feature learning paradigms (e.g., unsupervised feature learning (USFL), supervised feature learning (SFL), and self-supervised feature learning (SSFL)), this paper analyzes and compares them from the perspective of feature learning signals, and gives a unified feature learning framework. Under this unified framework, we analyze the advantages of SSFL over the other two learning paradigms in RSIs understanding tasks and give a comprehensive review of the existing SSFL work in RS, including the pre-training dataset, self-supervised feature learning signals, and the evaluation methods. We further analyze the effect of SSFL signals and pre-training data on the learned features to provide insights for improving the RSI feature learning. Finally, we briefly discuss some open problems and possible research directions.

cs.CV↗

arXiv2022

ConstGCN: Constrained Transmission-based Graph Convolutional Networks for Document-level Relation Extraction

Document-level relation extraction with graph neural networks faces a fundamental graph construction gap between training and inference - the golden graph structure only available during training, which causes that most methods adopt heuristic or syntactic rules to construct a prior graph as a pseudo proxy. In this paper, we propose $\textbf{ConstGCN}$, a novel graph convolutional network which performs knowledge-based information propagation between entities along with all specific relation spaces without any prior graph construction. Specifically, it updates the entity representation by aggregating information from all other entities along with each relation space, thus modeling the relation-aware spatial information. To control the information flow passing through the indeterminate relation spaces, we propose to constrain the propagation using transmitting scores learned from the Noise Contrastive Estimation between fact triples. Experimental results show that our method outperforms the previous state-of-the-art (SOTA) approaches on the DocRE dataset.

cs.CL↗

arXiv2022

Full Poincaré polarimetry enabled through physical inference

While polarisation sensing is vital in many areas of research, with applications spanning from microscopy to aerospace, traditional approaches are limited by method-related error amplification or accumulation, placing fundamental limitations on precision and accuracy in single-shot polarimetry. Here, we put forward a new measurement paradigm to circumvent this, introducing the notion of a universal full Poincaré generator to map all polarisation analyser states into a single vectorially structured light field, allowing all vector components to be analysed in a single-shot with theoretically user-defined precision. To demonstrate the advantage of our approach, we use a common GRIN optic as our mapping device and show mean errors of <1% for each vector component, enhancing the sensitivity by around three times, allowing us to sense weak polarisation aberrations not measurable by traditional single-shot techniques. Our work paves the way for next-generation polarimetry, impacting a wide variety of applications relying on weak vector measurement.

physics.optics↗

arXiv2022

Glassy crystals with colossal multi-baroresponsivities

As a nontrivial solid state of matter, the glassy-crystal state embraces physical features of both crystalline and amorphous solids, where a long-range ordered periodic structure formed by the mass centers of constituent molecules accommodates orientational glasses. Here, we discover and validate a glassy-crystal state in 2-amino-2-methyl-1,3-propanediol (AMP, C4H11NO2) by neutron scattering and complementary broadband dielectric spectroscopy (BDS) measurements. The freezing process of the dynamic orientational disorder is manifested at relaxation times well described by the Vogel-Fulcher-Tammann (VFT) law and the strongly frequency-dependent freezing temperature ranging from around 225 K at 0.1 Hz to above room temperature in the GHz region. At room temperature, the supercooled state is extremely sensitive to pressure such that a few MPa pressure can induce crystallization to the ordered crystal state, eventually leading to a temperature increase by 48 K within 20 s, a significant reduction of visible light transmittance from about 95% to a few percentages, and a remarkable decrease of electrical conductivity by three orders of magnitude. These ultrasensitive baroresponsivities might find their applications in low-grade waste heat recycling, pressure sensors and non-volatile memory devices. It is expected that glassy crystals serve as an emerging platform for exploiting exotic states of matter and the associated fantastic applications.

cond-mat.mtrl-sci↗

arXiv2022

Synthetic control of structure and conduction properties in Na-Y-Zr-Cl solid electrolytes

In the development of low cost, sustainable, and energy-dense batteries, chloride-based compounds are promising catholyte materials for solid-state batteries owing to their high Na-ion conductivities and oxidative stabilities. The ability to further improve Na-ion conduction, however, requires an understanding of the impact of long-range and local structural features on transport in these systems. In this study, we leverage different synthesis methods to control polymorphism and cation disorder in Na-Y-Zr-Cl solid electrolytes and interrogate the impact on Na-ion conduction. We demonstrate the existence of a more conductive P2$_1$/n polymorph of Na$_2$ZrCl$_6$ formed upon ball milling. In Na$_3$YCl$_6$, the R$\bar{3}$ polymorph is shown to be more conductive than its P2$_1$/n counterpart owing to the presence of intrinsic vacancies and disorder on the Y sublattice. Transition metal ordering in the Na$_{2.25}$Y$_{0.25}$Zr$_{0.75}$Cl$_6$ composition strongly impacts Na-ion transport, where a greater mixing of Y$^{3+}$ and Zr$^{4+}$ on the transition metal sublattice facilitates ion migration through partial activation of Cl rotations at relevant temperatures. Overall, Na-ion transport sensitively depends on the phases and transition metal distributions stabilized during synthesis. These results are likely generalizable to other halide compositions and indicate that achieving control over the synthetic protocol and resultant structure is key in the pursuit of improved catholytes for high voltage solid-state sodium-ion batteries.

cond-mat.mtrl-sci↗

arXiv2022

Selective clustering ensemble based on kappa and F-score

Clustering ensemble has an impressive performance in improving the accuracy and robustness of partition results and has received much attention in recent years. Selective clustering ensemble (SCE) can further improve the ensemble performance by selecting base partitions or clusters in according to diversity and stability. However, there is a conflict between diversity and stability, and how to make the trade-off between the two is challenging. The key here is how to evaluate the quality of the base partitions and clusters. In this paper, we propose a new evaluation method for partitions and clusters using kappa and F-score, leading to a new SCE method, which uses kappa to select informative base partitions and uses F-score to weight clusters based on stability. The effectiveness and efficiency of the proposed method is empirically validated over real datasets.

cs.LG↗

arXiv2022

Atomic-scale origin of the low grain-boundary resistance in perovskite solid electrolytes

Oxide solid electrolytes (OSEs) have the potential to achieve improved safety and energy density for lithium-ion batteries, but their high grain-boundary (GB) resistance is a general bottleneck. In the most well studied perovskite OSE, Li3xLa2/3-xTiO3 (LLTO), the ionic conductivity of GBs is about three orders of magnitude lower than that of the bulk. In contrast, the related Li0.375Sr0.4375Ta0.75Zr0.25O3 (LSTZ0.75) perovskite exhibits low GB resistance for reasons yet unknown. Here, we used aberration-corrected scanning transmission electron microscopy and spectroscopy, along with an active learning moment tensor potential, to reveal the atomic scale structure and composition of LSTZ0.75 GBs. Vibrational electron energy loss spectroscopy is applied for the first time to characterize the otherwise unmeasurable Li distribution in GBs of LSTZ0.75. We found that Li depletion, which is a major reason for the low GB ionic conductivity of LLTO, is absent for the GBs of LSTZ0.75. Instead, the low GB resistivity of LSTZ0.75 is attributed to the formation of a unique defective cubic perovskite interfacial structure that contained abundant vacancies. Our study provides insights into the atomic scale mechanisms of low GB resistivity and sheds light on possible paths for designing OSEs with high total ionic conductivity.

cond-mat.mtrl-sci↗

arXiv2021

Ultrasensitive barocaloric material for room-temperature solid-state refrigeration

Solid-state refrigeration based on caloric effects is an energetically efficient and environmentally friendly technology, which is deemed as a potential alternative to the conventional vapor-compression technology. One of the greatest obstacles to the real application is the huge driving fields. Here, we report a giant barocaloric effect in inorganic NH4I with maximum entropy changes of ΔS_BCE^max ~89 J K-1 kg-1 around room temperature, associated with the orientationally order-disorder phase transition. The phase transition temperature, Tt, varies dramatically with pressure in a rate of dTt/dP ~0.81 K MPa-1, which leads to a very much small saturation driving pressure of ΔP ~20 MPa, an unprecedentedly large caloric strength of |ΔS_BCE^max/ΔP| ~4.45 J K-1 kg-1 MPa-1, as well as a broad temperature window of ~68 K under an 80 MPa driving pressure. Comprehensive characterization of the crystal structure and dynamics by neutron scattering measurements reveals a strong reorientation-vibration coupling that is responsible for the large pressure sensitivity of Tt. This work is expected to advance the practical application of barocaloric refrigeration.

cond-mat.mtrl-sci↗