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Jianbin Zhou

Publications and source records attributed to Jianbin Zhou.

3 recordsLinked to original sources

MaP-AVR: A Meta-Action Planner for Agents Leveraging Vision Language Models and Retrieval-Augmented Generation

Embodied robotic AI systems designed to manage complex daily tasks rely on a task planner to understand and decompose high-level tasks. While most research focuses on enhancing the task-understanding abilities of LLMs/VLMs through fine-tuning or chain-of-thought prompting, this paper argues that defining the planned skill set is equally crucial. To handle the complexity of daily environments, the skill set should possess a high degree of generalization ability. Empirically, more abstract expressions tend to be more generalizable. Therefore, we propose to abstract the planned result as a set of meta-actions. Each meta-action comprises three components: {move/rotate, end-effector status change, relationship with the environment}. This abstraction replaces human-centric concepts, such as grasping or pushing, with the robot's intrinsic functionalities. As a result, the planned outcomes align seamlessly with the complete range of actions that the robot is capable of performing. Furthermore, to ensure that the LLM/VLM accurately produces the desired meta-action format, we employ the Retrieval-Augmented Generation (RAG) technique, which leverages a database of human-annotated planning demonstrations to facilitate in-context learning. As the system successfully completes more tasks, the database will self-augment to continue supporting diversity. The meta-action set and its integration with RAG are two novel contributions of our planner, denoted as MaP-AVR, the meta-action planner for agents composed of VLM and RAG. To validate its efficacy, we design experiments using GPT-4o as the pre-trained LLM/VLM model and OmniGibson as our robotic platform. Our approach demonstrates promising performance compared to the current state-of-the-art method. Project page: https://map-avr.github.io/.

cs.RO

Surface molecular engineering to enable processing of sulfide solid electrolytes in humid ambient air

Sulfide solid state electrolytes are promising candidates to realize all solid state batteries due to their superior ionic conductivity and excellent ductility. However, their hypersensitivity to moisture requires processing environments that are not compatible with todays lithium ion battery manufacturing infrastructure. Herein, we present a reversible surface modification strategy that enables the processability of sulfide SSEs under humid ambient air. We demonstrate that a long chain alkyl thiol, undecanethiol, is chemically compatible with the electrolyte with negligible impact on its ion conductivity. Importantly, the thiol modification extends the amount of time that the sulfide SSE can be exposed to air with 33 percent relative humidity with limited degradation of its structure while retaining a conductivity of above 1 mS per cm for up to 2 days, a more than 100 fold improvement in protection time over competing approaches. Experimental and computational results reveal that the thiol group anchors to the SSE surface, while the hydrophobic hydrocarbon tail provides protection by repelling water. The modified Li6PS5Cl SSE maintains its function after exposure to ambient humidity when implemented in a Li0.5In LiNi0.8Co0.1Mn0.1O2 ASSB. The proposed protection strategy based on surface molecular interactions represents a major step forward towards cost competitive and energy efficient sulfide SSE manufacturing for ASSB applications.

cond-mat.mtrl-sci

Superionic surface Li-ion transport in carbonaceous materials

Unlike Li-ion transport in the bulk of carbonaceous materials, little is known about Li-ion diffusion on their surface. In this study, we have discovered an ultra-fast Li-ion transport phenomenon on the surface of carbonaceous materials, particularly when they have limited Li insertion capacity along with a high surface area. This is exemplified by a carbon black, Ketjen Black (KB). An ionic conductivity of 18.1 mS cm-1 at room temperature is observed, far exceeding most solid-state ion conductors. Theoretical calculations reveal a low diffusion barrier for the surface Li species. The species is also identified as Li*, which features a partial positive charge. As a result, lithiated KB functions effectively as an interlayer between Li and solid-state electrolytes (SSE) to mitigate dendrite growth and cell shorting. This function is found to be electrolyte agnostic, effective for both sulfide and halide SSEs. Further, lithiated KB can act as a high-performance mixed ion/electron conductor that is thermodynamically stable at potentials near Li metal. A graphite anode mixed with KB instead of a solid electrolyte demonstrates full utilization with a capacity retention of ~85% over 300 cycles. The discovery of this surface-mediated ultra-fast Li-ion transport mechanism provides new directions for the design of solid-state ion conductors and solid-state batteries.

cond-mat.mtrl-sci