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Jihye Hwang

Publications and source records attributed to Jihye Hwang.

At least 19 recordsLinked to original sources

ALMA Reveals an Explosive Outflow Candidate in IRAS 16119--5048

We present a multiwavelength study of the massive star formation region IRAS 16119-5048 (I16119) using ALMA ATOMS Band 3 and QUARKS Band 6 observations, complemented by archival ATCA radio continuum and Spitzer mid-infrared data. The CO (2-1) emission reveals a system of high-velocity streamer-like structures around the central region. Using dendrogram analysis of velocity-channel maps followed by linking in position-position-velocity space, we identify 16 approximately radially distributed streamers whose projected trajectories converge toward a common central region. The kinetic energy of the outflows is at least an order of magnitude lower than those of most known explosive outflows, while their mass entrainment and momentum rates are high compared with typical protostellar outflows, suggesting that I16119 may represent a low-energy explosive outflow candidate. Dense-gas and photodissociation-region tracers reveal shell-like structures associated with the 8 $\mu$m emission, indicating that feedback from the H II region may influence the streamer morphology. The 1.3 mm continuum resolves 27 dense cores along a fragmented filamentary structure. Their separations are consistent with thermal Jeans or cylindrical fragmentation, while the collect-and-collapse scenario is unsupported. The dense cores also show evidence of mass segregation, with the most massive cores concentrated near the inferred explosive centre. We suggest that I16119 is a plausible low-energy explosive outflow candidate, possibly triggered by dynamical interactions among centrally concentrated massive cores. However, the complex velocity structure and possible contamination from individual core-driven outflows prevent a definitive classification. More sensitive, higher angular-resolution observations are required to confirm the nature of the outflow.

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Magnetic Fields in Massive Star-forming Regions (MagMaR). IX. Radiative Torque Alignment and Disruption in NGC6334I

Intense radiation from high-mass stars is expected to significantly affect dust grain alignment and evolution through RAdiative Torques (RATs). We investigate this effect in a massive star-forming region, NGC6334I, using 1.2 mm dust continuum polarization observations from the Atacama Large Millimeter/submillimeter Array. The polarization fraction spans from $\lesssim1\%$ to $\sim10\%$ and decreases with increasing column density, remaining below $2\%$ in dense cores despite high temperatures ($\sim100$ K), where efficient grain alignment by RATs is expected. We investigate how grain alignment, grain growth, grain disruption, B-field tangling, and local physical conditions affect the polarization properties of MM1, MM2, MM3, and their surroundings. Polarization angle dispersion shows that B-field tangling contributes to depolarization at moderate densities but cannot fully explain the lowest polarization fractions. Using RAT-based grain alignment and polarization modeling, we find that reduced alignment efficiency and high optical depth reproduce the low polarization in the densest regions. MM2 shows evidence of grain growth, with maximum grain sizes $a_{\max}\sim0.35-1.0~\mu$m, while MM1 exhibits smaller values of $\sim0.35-0.50~\mu$m. Accounting for optical depth increases the inferred grain sizes in MM1 to $\sim1.0-2.0~\mu$m. Analytical estimates of radiative torque disruption from the intense outburst suggest that micron-sized grains in high-temperature, moderate-density regions can fragment into submicron grains. Alternatively, high optical depth may also explain the low polarization in the densest regions even in the presence of micron-sized grains. Incorporating the B-field inclination effect indicates a transition from predominantly plane-of-sky fields at low densities to more line-of-sight-aligned configurations at high densities.

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Multiscale Synthetic observations of Polarized dust emission: On the origin of Depolarization effect from Molecular clouds to Starless cores and Constraints on Dust Physics

Submillimeter observations of polarized dust emission from molecular clouds to starless cores frequently report a decrease in polarization fraction (p) with increasing dust emission intensity (I). This feature is commonly attributed to the alignment loss of dust grains or the geometrical effects of magnetic fields, yet, the detailed contributions remain unclear. To investigate the mechanism responsible for the depolarization, we use POLARIS to perform the multiscale synthetic dust polarization observations at $850\mu m$ from magnetically aligned dust grains by RAdiative Torques (RATs) mechanism. We adopt three collapsing cloud models with different magnetic energy levels and explore the effects of grain magnetic properties and grain growth on dust polarization. The field geometrical effect is the dominant depolarization mechanism at $N_{\rm H}<10^{21}-10^{22}\rm cm^{-2}$. We find that if grains grow beyond $>0.5\mu m$ and are superparamagnetic (SPM) with large iron clusters, RATs remain effective at high column densities, and grain alignment loss contributes to depolarization only at $N_{\rm H} > 10^{23}\rm cm^{-2}$. If neither of these conditions is satisfied, the alignment loss (in cases of insufficient grain growth); or the reduced grain alignment efficiency by gaseous damping (for paramagnetic grains or SPM grains with small iron cluster sizes) can become the dominant depolarization mechanism at $N_{\rm H} > 10^{22}\rm cm^{-2}$, regardless of how tangled the magnetic field lines in our simulation. Finally, we show that the depolarization mechanism and the underlying dust physical properties inside starless cores may be identified through the $p-I$ slope and the mean p at the core center.

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The ALMA-QUARKS Survey: Properties of Hot Molecular Fragments in the Massive Protocluster IRAS 17233-3606

To investigate the physical mechanisms of fragmentation within the hot molecular core of the massive protocluster IRAS 17233-3606 (G351.78-0.54), we carried out a detailed analysis of continuum and lines, using the ALMA Band 3 data from the ATOMS survey and Band 6 data from the QUARKS survey. The low-resolution 3 mm data reveal a massive hot core MM1 with a mass of ~81.3 Msun, and a prominent ultracompact (UC) HII region MM2, while the high-resolution data resolve MM1 into 11 hot molecular fragments (HMFs). These HMFs exhibit hot (Trot = 100-310 K) CH3CN and CH3OH emission and high column densities (NH2 > 10^23 cm^-2), indicating their potential to form massive stars. Based on outflows, masers, HII regions, and f[CH3CN/CH3O] abundance ratios, the evolutionary sequences of the 11 HMFs are categorized as phases I to IV. The mean minimum-spanning tree (MST) separation (~1.8 x 10^3 au) of the HMFs is nearly half of the thermal Jeans length (~3.3 x 10^3 au). Together with the Q parameter Q = 0.77 and virial parameter alpha_vir = 0.84 of MM1, these results suggest an evolutionary scenario in which fragmentation is initially driven by thermal instability, followed by global gravitational contraction and growth through active accretion. Meanwhile, feedback from the B2-type zero-age main-sequence (ZAMS) star and the UC HII region significantly influence the morphology and chemical properties of MM1 and MM2. This heterogeneity highlights the role of diverse physical processes taking place in high-mass protoclusters.

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Measuring Magnetic Field Strengths in Galactic Star-forming Regions via the Zeeman Effect with the SKA

Magnetic fields thread the interstellar medium from the largest to the smallest scales and play an important role in molecular cloud evolution and star formation. Quantifying this requires measurements of the field strengths, and the most direct way to measure them is via the Zeeman effect in spectral lines. The effect is subtle for the typical field strengths expected from theory, from a few $\mu$G in diffuse molecular clouds to a few 10s of mG in dense star-forming regions, and detections are scarce. Existing measurements of magnetic field strength suggest dense clouds and cores are marginally supercritical (cannot prevent collapse, but can inhibit it), but may be biased due to small sample sizes. Zeeman effect measurements tracing different scales and densities within molecular clouds can reveal the variation of field strengths, providing critical measurements to address the question of whether star formation is primarily regulated by magnetic fields or turbulence on different scales. Observations with SKA precursors such MeerKAT and FAST are beginning to increase the number of Zeeman effect detections in nearby star-forming regions. The SKA will extend their reach to many regions within our Galaxy that are best representative of where most stars form, while zooming in on the densest star-forming regions, providing a statistical basis for the role of magnetic fields in molecular cloud evolution and star formation. We present predictions and plans for Zeeman effect observations with the SKA telescopes, demonstrating the significant advances they will provide for studies of magnetic fields in molecular clouds.

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Evolution of starless cores in massive clumps seen by the ALMA ASHES and QUARKS surveys

We present a systematic comparative analysis of 324 starless cores in early-phase infrared-dark clouds (IRDCs; ASHES survey) and evolved-phase infrared-bright clouds (IRBCs; QUARKS survey) using 1.3 mm continuum and line data by the Atacama Large Millimeter/submillimeter Array (ALMA). Despite having comparable sizes ($\sim$2500 au),starless cores in IRBCs exhibit systematically higher median mass ($1.5\,M_{\odot}$ vs. $0.6\,M_{\odot}$), number density, and surface density--enhancements of approximately a factor of two relative to starless cores in IRDCs. Starless cores in IRBCs also display relatively stronger non-thermal motions ($\rm\sigma \sim 0.5\,km\,s^{-1}$ vs. $\rm0.3\,km\,s^{-1}$), higher total virial parameters (median $\alpha_{\mathrm{vir,tot}} \sim$ 2.3 vs. 1.0), and steeper density profiles, indicating more centrally concentrated structures in feedback-driven, turbulence-enhanced environments. These findings support a dual evolutionary origin: (i) new core formation in evolved IRBCs under altered initial conditions, and (ii) subsequent dynamical mass growth via accretion from extended reservoirs. The prevalence of low-mass starless cores--even in late-stage IRBC environments--challenges models requiring massive prestellar cores and instead favors competitive-like dynamical mass accretion scenarios for high-mass star formation.

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Magnetic field Topology and Star Formation in the Cepheus B Filamentary cloud under External Feedback

We present a detailed study of the Cep B molecular cloud based on sub-mm dust polarization and $^{13}$CO (J=3--2) spectral line observations obtained with SCUBA-2/POL-2 and HARP on the James Clerk Maxwell Telescope (JCMT). The 850 $\mu$m dust continuum map reveals a prominent filamentary structure oriented Northwest--Southeast (NW-SE), with the magnetic field (B-field) displaying a distinct morphology-curving into a bow-like shape near the filament head and aligning along the spine toward the tail. The filament is thermally supercritical, with its line mass exceeding the critical value for an isothermal filament, indicating that self-gravity drives radial contraction. The mass-to-flux ratio suggests that the filament is magnetically subcritical on global scales, implying that B-fields provide significant support against collapse. Despite this, the presence of dense cores and embedded star formation indicates that collapse proceeds locally. The observed core spacing spans a range of values, with the largest separations comparable to the expected fragmentation scale for a self-gravitating filament undergoing sausage instability, suggesting that gravitational instability sets the primary fragmentation scale. Smaller separations and non-uniform spacing may indicate the influence of local variations and hierarchical fragmentation. Overall, Cep B represents a system in which gravity drives fragmentation, B-fields regulate its evolution, and external feedback shapes both its morphology and star formation activity at the head of the filament.

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BISTRO Survey: Gravity-Dominated and Magnetically Regulated Star Formation in M17 SW

We present high-resolution magnetic field maps of the M17 SW molecular cloud using JCMT 850 $\mu$m dust polarization at a scale of 14$''$. The magnetic field exhibits a distinct arc-like structure that encircles three dense clumps (C1, C2, and C3). By combining polarization data with ammonia line observations, the plane-of-sky magnetic field strength, measured using the Skalidis-Tassis method to minimize angle dispersion errors, ranges from 0.1 to 2.4 mG (mean: 0.54 mG). Energy budget analysis reveals a hierarchy dominated by gravity ($e_G \approx 10^{-7.8}$ erg cm$^{-3}$), which exceeds both magnetic ($e_B \approx 10^{-8.3}$ erg cm$^{-3}$) and turbulent ($e_k \approx 10^{-8.7}$ erg cm$^{-3}$) energies. Since all three energy densities lie within one order of magnitude, gravitational dominance acts primarily as the global driver, while the system remains in a state of near-equipartition. Structurally, the northeastern boundary shows magnetic field lines perpendicular to the shock front, consistent with compression from the adjacent HII region. Within the cloud, magnetic field lines generally align with gravity to assist collapse, but turn perpendicular to gravity within curved accretion bridges. This configuration provides support against radial collapse while guiding gas flow. Kinematic evidence suggests that these channels transport material from Clump C3 onto the massive Clump C2. Star formation in M17 SW is globally driven by gravity but locally regulated by the magnetic field structure.

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From inter-filamentary gas to filaments and hubs: gas flows in the Mon R2 hub-filament system

Hub-filament systems (HFSs) play an important role in the formation of massive stars and star clusters. Although the velocity structures along dense filaments have been studied, the gas kinematics in the low density inter-filament regions has not been investigated. We use $^{13}$CO ($J$ = 1--0) and C$^{18}$O ($J$ = 1--0) observations obtained with the Nobeyama 45 m telescope to study the gas dynamics towards the Monoceros R2 (Mon R2) HFS. From the $^{13}$CO and C$^{18}$O data, tracing low- and high-density gas, respectively, we identify velocity coherent structures and divide them into filaments (Fs) and inter-filamentary regions (IFs). We estimate velocity gradients ($\Delta v$) and mass accretion rates ($\dot{M}$) along ($\parallel$) and across ($\perp$) the Fs and IFs. The mean ratio of $\dot{M}_\parallel$ to $\dot{M}_\perp$ in Fs is 6.8, while that in IFs is 1.5. These results show that the overall gas within both Fs and IFs flows directly into the hub and the gas flows faster along the Fs than the IFs. In addition, we found that at least 30\% of the gas mass in the IFs may flow towards the Fs replenishing the latter with new matter. Our study reveals the importance of considering the total gas mass reservoir, both low- and high-density, infalling into the hub and promoting the formation of massive stars, which are preferentially located in the hub of Mon R2.

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ALMA-QUARKS view of W49N: Multipolar episodic outflow associated with the most energetic Galactic water maser

We present a detailed investigation of a multipolar episodic molecular outflow in the mini-starburst region W49N, which hosts the most luminous water maser in the Galaxy. Using high-resolution ($\sim$0.3 arcsec) Atacama Large Millimeter/submillimeter Array (ALMA) observations of the $\mathrm{^{12}CO}$ emission as part of the ALMA-QUARKS survey, we analyze the morphology and kinematics of the outflow. Our observations reveal four newly identified outflow lobes in addition to the previously known central bipolar jet. These lobes appear more jet-like rather than exhibiting wide opening angles. Based on the $\mathrm{^{12}CO}$ (2-1) and $\mathrm{^{13}CO}$ (2-1) emission, we provide a more reliable estimate of the outflow's physical parameters, confirming it as one of the most energetic outflows in the Galaxy. Notably, these newly discovered lobes exhibit chains of knots, a characteristic signature of episodic ejection. Furthermore, two of the lobes display prominent S-shaped wiggles, suggestive of a precessing jet. The discovery of these features -- commonly observed in outflows from low-mass protostars -- in such an extreme massive star-forming environment provides compelling evidence that some underlying physical mechanisms for launching outflows are conserved across a wide range of stellar masses.

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The dominance of turbulence over magnetism in the formation of massive star cluster seeds

High-mass stars form in protoclusters, where gravo-magnetic processes shape collapsing clouds and clumps to be elongated preferentially perpendicular to magnetic (B) fields. Yet it remains unclear whether gravo-magnetic processes still govern the formation of smaller-scale condensations in massive-star-forming protoclusters, which are crucial for understanding the stellar initial mass function and multiplicity. Here we report the first statistical evidence that the condensation elongations are preferentially aligned with local B fields, based on high-resolution data from the largest dust polarization survey toward 30 massive star-forming regions with the Atacama Large Millimeter/submillimeter Array (ALMA). Our clustered massive star formation simulations reveal that this more parallel alignment is exclusively observed in models where initial turbulence dominates B fields. In contrast, models with initial B fields dominating turbulence distinctly exhibit a more perpendicular alignment. The comparison between observations and simulations suggests that turbulence could play a more important role than B fields in the formation of condensations in the context of clustered massive star formation, contradicting the prediction of classical magnetically regulated models. Moreover, we find a possibly turbulence-induced preferential misalignment between the B field and rotation axis of condensations, which may potentially reduce the magnetic braking efficiency and facilitate the formation of large protostellar disks. Our findings indicate that turbulence could be critical in determining the initial stellar properties.

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The ALMA-QUARKS Survey: Evidence of an Explosive Molecular Outflow in IRAS 15520--5234

We present a study of the massive protocluster IRAS 15520$-$5234, which displays evidence of an explosive molecular outflow that unleashed a kinetic energy of at least 10$^{48}$ erg. The protocluster contains 16 dense cores detected in the ALMA band 6 continuum emission maps, having masses in the range from 0.2 to 11.0 M$_{\odot}$. Our analysis of CO $(2-1)$ emission reveals 28 well collimated outflow fingers, the majority of which follow a Hubble-Lema\^itre velocity law. The outflow fingers show no preferred orientation in the plane of sky and emerge from a common center of origin. We estimate the total mass, momentum, and kinetic energy of the outflow fingers and find that the values are at least one order of magnitude higher than the typical bipolar outflows associated with massive protostars. The morphology and kinematics of the outflow fingers suggest that the outflow associated with IRAS 15520$-$5234 is explosive in nature. We calculate the dynamical age of the explosive event to be approximately 6550 years. Additionally, we estimate the frequency of such explosive outflows in the Galaxy, which is one event every 83 years. Finally, we speculate that the rearrangement of masses within the massive protocluster and the dynamical interaction among the massive cores may result in the formation of such an energetic event.

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The ALMA-QUARKS Survey: Discovery of Dusty Fibrils inside Massive Star-forming Clumps

We report the discovery of more than 323 superfine dusty filamentary structures (fibrils) inside 121 massive star forming clumps that are located in widely different Galactic environments (Galactocentric distances of $\sim$0.5-12.7 kpc). These fibrils are identified from the 1.3~mm continuum emission in the ALMA-QUARKS survey, which has a linear resolution of $\sim900$ AU for a source at $\sim$3 kpc, using the \textit{FilFinder} software. Using \textit{RadFil} software, we find that the typical width of these fibrils is $\sim$0.01 pc, which is about ten times narrower than that of dusty filaments in nearby clouds identified by the \textit{Herschel} Space Observatory. The mass ($M$) versus length ($L$) relation for these fibrils follows $M\propto L^{2}$, similar to that of Galactic filaments identified in space (e.g., \textit{Herschel}) and ground-based single-dish (e.g., \textit{APEX}) surveys. However, these fibrils are significantly denser ($\mathrm{N_{H_2} = 10^{23}-10^{24}\ cm^{-2}}$) than the filaments found in previous \textit{Herschel} surveys ($\mathrm{N_{H_2} = 10^{20}-10^{23}\ cm^{-2}}$). This work contributes a large sample of superfine fibrils in massive clumps, following the identification of large 0.1-pc wide filaments and associated internal velocity coherent fibers in nearby molecular clouds, further emphasizing the crucial role played by filamentary structures in star formation at various physical scales.

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MAJORS II: HCO+& HCN Abundances in W40

We present observations of HCN and HCO$^+$ J = $3 - 2$ in the central $424'' \times 424''$ region of the W40 massive star forming region. The observations were taken as part of a pilot project for the MAJORS large program at the JCMT telescope. By incorporating prior knowledge of N(H$_2$) and $T_K$, assuming a constant density, and using the RADEX radiative transfer code we found that the HCN and HCO$^+$ abundances range from $X$(HCN) = $0.4-7.0 \times 10^{-8}$ and $X$(HCO$^+$) = $0.4-7.3 \times 10^{-9}$. Additional modelling using the NAUTILUS chemical evolution code, that takes H$_2$ density variations into account, however, suggests the HCN and HCO$^+$ abundances may be fairly constant. Careful modelling of three different positions finds $X$(HCN) = $1.3-1.7 \times 10^{-8}$, $X$(HCO$^+$) = $1.3-3.1 \times 10^{-9}$. Cross-comparison of the two models also provides a crude estimate of the gas density producing the HCN and HCO$^+$ emission, with H$_2$ densities in the range $5 \times 10^4 - 5 \times 10^5$ cm$^{-3}$, suggesting that the HCN and HCO$^+$ emission does indeed arise from dense gas. High UV intensity (e.g. $G_o >$ a few thousand) has no effect on the abundances in regions where the visual extinction is large enough to effectively shield the gas from the UV field. In regions where $A_V < 6$, however, the abundance of both species is lowered due to destructive reactions with species that are directly affected by the radiation field.

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The ALMA-ATOMS survey: Methanol emission in a large sample of hot molecular cores

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the excitation and abundance of methanol nuclear spin isomers and their relationship to chemical complexity in massive star-forming cores. We identify 20 methanol transitions, including A- and E-type lines in the v=0 state and E-type lines in the v$_{t}$=1 state, and detect 94 HMC candidates. Rotational temperature analysis under the LTE assumption yields average values of 194 $\pm$ 33 K for CH$_{3}$OH-E v$_{t}$=1, 178 $\pm$ 33 K for CH$_{3}$OH-A v=0, and 75 $\pm$ 33K for CH$_{3}$OH-E v=0. Emission from COMs other than methanol is detected in 87 of the 94 cores, with the CH$_{3}$OH-E v$_{t}$=1 line intensity showing a strong correlation with the channel detection ratio (CDR). These results demonstrate that CH$_{3}$OH-E v$_{t}$=1 lines are reliable tracers of HMCs and chemical complexity, and that the CDR provides a robust indicator of molecular richness. The temperature difference between A- and E-type methanol transitions is driven by anomalously strong J(2,J-2)$-$J(-1,J-1) lines, highlighting the importance of analyzing methanol symmetry types separately.

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FIRESTORM I: Stellar Feedback and Gas Kinematics in the Evolved W40 Hub-Filament System

The FIRESTORM project--Feedback-Induced Regions and Emission from Star-forming Tracers of ObseRvable Molecular Gas--has targeted four star-forming regions to quantify the impact of stellar feedback on star formation. In this paper, we present multiwavelength results for one of the targets, the nearby high-mass star-forming region W40. Using dense-gas tracers C$^{18}$O(1--0) and H$^{13}$CO$^+$(1--0), we identified six velocity-coherent filaments: five at \vlsr $\sim$\,7.5\kms\! and one at \vlsr $\sim$\,5\kms. Four of these converge towards an infrared-bright cluster hosting the most massive star of the region (IRS 1A South, O9.5V), forming a hub-filament system (HFS). Key physical parameters, including filament lengths, widths, masses, velocity dispersions, and line masses, are derived. Five dense clumps traced by N$_2$H$^+$(1--0) exhibit subsonic to transonic turbulence, contrasting with the supersonic motions of their parental filaments, indicating turbulence dissipation. A deficit of emission at \vlsr $\sim$\,7\kms\! in several molecular lines, along with a blueshifted absorption dip in the HCN(1--0) profile, suggests that emission from OB-heated gas is being absorbed by a cold foreground cloud. A bridge-like feature in position-velocity space connects the \vlsr $\sim$\,5 and $\sim$\,7.5\kms\! filaments, and spatially coinciding with dense condensations and radio continuum peaks. These findings suggest that a past interaction--likely a cloud-cloud collision--triggered the formation of HFS and ultimately the central massive cluster.

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The ALMA-QUARKS survey: Evidence of a candidate high-mass prestellar core aside a bright-rimmed cloud IRAS 18290-0924

Although frequently reported in observations, the definitive confirmation of high-mass prestellar cores has remained elusive, presenting a persistent challenge in star formation studies. Using two-band observational data from the 3mm ATOMS and 1.3mm QUARKS surveys, we report a high-mass prestellar core candidate, C2, located on the side of the bright-rimmed cloud IRAS 18290-0924. The C2 core identified from the 3mm continuum data of the ATOMS survey ($\sim$2 arcsecond, $\rm\sim 10000~au$ at 5.3 kpc) has a mass ranging from 27-68 $M_{\odot}$ for temperatures 10-22K within a radius of $\sim$2800 au. The highest-resolution ($\sim$0.3 arcsecond, $\rm\sim 1500 au$) observations of this source presented to date from the QUARKS survey reveal no evidence of further fragmentation. Further analysis of a total $\sim$10 GHz band width of molecular line survey does not find star-formation activity (e.g., outflows, ionized gas) associated with the core, with a few molecular lines of cold gas detected only. Additionally, virial analysis indicates the C2 core is gravitationally bound ($\alpha_{\rm vir} \sim0.1-0.3$) and thus could be undergoing collapse toward star formation. These results strongly establish a candidate for a high-mass prestellar core, contributing to the very limited number of such sources known to date.

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The ALMA-ATOMS-QUARKS survey: Resolving a chemically rich massive protostellar outflow

We present a comprehensive study on the physical and chemical structures of a chemically rich bipolar outflow in a high-mass star forming region IRAS 16272$-$4837 (SDC335), utilizing high-resolution spectral line data at 1.3 mm and 3 mm dual-bands from the ALMA ATOMS and QUARKS surveys. The high-velocity jet is enveloped by a lower-velocity outflow cavity, containing bright knots that show enhanced molecular intensities and elevated excitation temperatures. Along the outflow, we have identified 35 transitions from 22 molecular species. By analyzing the spatial distribution and kinematics of these molecular lines, we find that the molecular inventory in the outflow is regulated by three processes: (i) direct entrainment from the natal molecular core by the outflow; (ii) shock-induced release of molecules or atoms from dust grains; and (iii) thermal desorption and gas-phase reactions driven by shock heating. These results confirm that outflows are not only dynamical structures but also active chemical factories, where entrainment, shocks, and thermal processing jointly enrich the molecular content. Our findings confirmed that outflow chemistry has multi-origin nature, and provide critical insights into chemical evolution during high-mass star formation.

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