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Jincan Chen

Publications and source records attributed to Jincan Chen.

At least 19 recordsLinked to original sources

Quantum Coherence as a Thermodynamic Resource Beyond the Classical Uncertainty Bound

Thermodynamic uncertainty relations (TURs) establish a fundamental trade-off between current precision and entropy production in nonequilibrium systems, yet the role of genuine quantum coherence in these bounds remains unresolved. Here we develop a general framework that explicitly incorporates quantum coherence into TURs for Markovian open quantum systems. By combining the quantum Cramér-Rao inequality with a Dyson series expansion of the parametrically deformed Lindblad dynamics, we derive a generalized TUR containing a coherence-sensitive correction that naturally separates classical and quantum contributions. The coherent term originates from the off-diagonal components of the nonequilibrium steady-state density matrix and systematically relaxes the classical precision-dissipation bound, allowing enhanced current precision without additional entropy production. Applying our theory to a three-level quantum maser, we demonstrate that steady-state coherence enables precision beyond the classical limit over a broad parameter regime while remaining consistent with the generalized bound. Our results identify quantum coherence as a genuine thermodynamic resource and provide a unified framework bridging classical and quantum uncertainty relations.

quant-ph

Balancing Power, Efficiency, and Constancy under Broken Time-Reversal Symmetry

We derive general trade-off relations among the power, efficiency, and constancy for two-terminal thermoelectric systems in the linear response regime. Constancy, which quantifies the steadiness of the heat engine, is measured by its fluctuations. The bounds of the efficiency, power and fluctuations are valid even when time-reversal symmetry is broken, revealing how such a symmetry breaking alters the fundamental constraints on steady-state energy conversion. Our results extend and refine previously established universal trade-offs, offering deeper insight into the performance limits in nonequilibrium thermodynamics. Guided by this bound, heat engines with broken time-reversal symmetry can be operated at near-Carnot efficiency while maintaining finite power output and fluctuations, enabling them to outperform their traditional counterparts.

cond-mat.stat-mech

Fluctuation-Dissipation Limits in Quantum Thermoelectric Transport

As a fundamental measure of stability in nonequilibrium thermodynamics, fluctuations provide critical insight into the performance and reliability of heat engines. In this work, we establish universal fluctuation-dissipation bounds that directly link energy-current fluctuations to both the entropy production rate and steady-state transport currents. Our results are applicable to arbitrary temperature and chemical potential gradients and hold for all steady states within the framework of quantum scattering theory. These bounds remain robust even in regimes where quantum effects break classical thermodynamic uncertainty relations. We demonstrate their validity by using boxcar transmission functions and further derive constraints on the power output from the perspective of fluctuations and dissipation, offering a unified thermodynamic guideline for the design and evaluation of nanoscale and quantum thermal devices.

cond-mat.stat-mech

Unlocking inaccessible performance of the quantum refrigerator with catalysts

Quantum thermal machines offer promising platforms for exploring the fundamental limits of thermodynamics at the microscopic scale. The previous study demonstrated that the incorporation of a catalyst can significantly enhance the performance of a heat engine by broadening its operational regime and achieving a more favorable trade-off between work output and efficiency. Building on this powerful framework and innovative idea, here we further extend the concept to a two-stroke quantum refrigerator that extracts heat from a cold reservoir via discrete strokes powered by external work. The working medium consists of two two-level systems (TLSs) and two heat reservoirs at different temperatures and is assisted by an auxiliary system acting as a catalyst. Remarkably, the catalyst remains unchanged after each cycle, ensuring that heat extraction is driven entirely by the work input. We show that the presence of the catalyst leads to two significant enhancements: it enables the coefficient of performance (COP) and cooling capacity to exceed the Otto bound and allows the refrigerator to operate in frequency and temperature regimes that are inaccessible without a catalyst. Furthermore, through a comparison with catalytic heat engines, our analysis reveals that two distinct permutation types are necessary to simultaneously enhance the COP and operational range of refrigerators, in contrast to heat engines for which a single permutation suffices. These results highlight the potential of catalytic mechanisms to broaden the operational capabilities of quantum thermal devices and to surpass conventional thermodynamic performance limits.

quant-ph

Geometric Bound for Trade-off Relation in Quantum Tricycle

We establish a finite-time quantum tricycle driven by an external field and investigate its thermodynamic performance in the slow-driving regime. By developing a perturbative expansion of heat with respect to operation time, we capture the dynamics of heat exchange processes beyond the quasistatic limit. Within a geometric framework, we derive fundamental bounds on trade-offs between the cooling rate, coefficient of performance, and dissipation, governed by the thermodynamic length and trajectory geometry in control space. Our findings unveil intrinsic limits to the performance of quantum thermal machines and highlight the role of geometry in shaping finite-time thermodynamics. This work advances the fundamental understanding of quantum thermodynamic processes and offers guiding principles for the design of next-generation quantum technologies.

quant-ph

Theoretical bound of the efficiency of learning

A unified thermodynamic formalism describing the efficiency of learning is proposed. First, we derive an inequality, which is more strength than Clausius's inequality, revealing the lower bound of the entropy-production rate of a subsystem. Second, the inequality is transformed to determine the general upper limit for the efficiency of learning. In particular, we exemplify the bound of the efficiency in nonequilibrium quantum-dot systems and networks of living cells. The framework provides a fundamental trade-off relationship between energy and information inheriting in stochastic thermodynamic processes.

cond-mat.stat-mech

Performance optimization of Nernst-based thermionic engines

In this paper, we examine the power and efficiency of the thermionic device utilizing the Nernst effect, with a specific focus on its potential application as an engine. The device operates by utilizing the vertical heat current to generate a horizontal particle current against the chemical potential. By considering the influence of a strong magnetic field, we derive analytical expressions for the current and heat flux. These expressions are dependent on the temperature and chemical potential of heat reservoirs, providing valuable insights into the device performance. The impact of driving temperatures on the performance of the thermionic engine has been assessed through numerical analysis. The research findings will guide the experimental design of Nernst-based thermionic engines.

cond-mat.stat-mech

Optimal neutralization of negative space charges in photon-enhanced thermionic emission devices under bidirectional discharge

In this study, we innovatively modeled photon-enhanced thermionic emission (PETE) devices, incorporating positive ion injection and bidirectional discharge's effects on the space charge barrier simultaneously. Compared to previous models, our model allows the positive ion distribution function to be compatible with scenarios in which the anode motive is either higher or lower than the cathode motive, and also adapts to significant anode discharge. Through numerical simulations and parametric analyses, we found that: (1) As the ratio of the positive ion increases, the capability for space charge neutralization becomes stronger. (2) The lower the electron affinity is, the smaller the ratio of positive ions are required. (3) When the anode temperature is higher or the anode work function is lower, the impact of reverse discharge on the net current density is more pronounced. Conversely, when the anode temperature is higher or the anode work function is greater, the ratio of positive ions required to achieve complete space charge neutralization increases. This study further elucidates the mechanisms and characteristics of space charge neutralization effects in PETE devices, providing a theoretical foundation for optimizing their design. Additionally, the accompanying theory and algorithm possess the potential to spark innovative research across diverse fields.

physics.acc-ph

Centenary progress from the Nernst theorem to the Nernst statement

It is found from textbooks that there are the different versions of the schematic diagram related to the Nernst equation, and consequently, it leads to some discussion related to the Nernst equation and the discovery of other meaningful schematic diagrams never appearing in literature. It is also found that through the introduction of a new function, the schematic diagram of the Nernst equation in the isothermal process of any thermodynamic system can be generated in a unified way and that the Nernst equation can be re-obtained from the experimental data of low-temperature chemical reactions without any artificial additional assumptions. The results obtained here show clearly that the centenary progress from the Nernst theorem to the Nernst statement is completed.

cond-mat.stat-mech

Hot-carrier photocatalysts with energy-selective contacts based on quantum wells and dots

In this paper, we simulate the function of hot-carrier photocatalysts (HCPCs) with quantum well and quantum dot energy-selective contacts (ESCs) in the water-splitting reaction. The transport equations for these ESCs are derived by using ballistic transport theory. The results indicate that thermalization loss from non-ideal ESCs is a primary factor diminishing the efficiency of HCPCs. The performance of HCPCs can be enhanced by optimizing the position of ESCs and the width of the extraction energy. Notably, HCPCs with quantum dot ESCs demonstrate superior performance compared to those with quantum well ESCs.

physics.app-ph

The effect of space charge on photon-enhanced thermionic emission in the presence of the bidirectional discharge

The bidirectional space charge effects in photon-enhanced thermionic emission (PETE) devices are investigated systematically. First, we precisely determine the carrier concentrations and cathode temperatures by taking into account the electron recycling effect, energy balance constraints, and space charge effects arising from the concurrent discharge of the cathode and anode. Next, we analyze the impact of critical parameters, including anode properties and operating conditions, on the space charge barrier distribution and the overall performance of the device. The results demonstrate that the impact of reverse discharge on the net current becomes more pronounced when the PETE device operates at high anode temperatures, low anode work functions, and with a moderate solar concentration ratio and gap width. This discovery not only deepens our understanding of the bidirectional space charge effect, but also provides valuable guidance for the future optimization of PETE device performance.

physics.acc-ph

Performance optimization of a finite-time quantum tricycle

We establish a finite-time external field-driven quantum tricycle model. Within the framework of slow driving perturbation, the perturbation expansion of heat in powers of time can be derived during the heat exchange processes. Employing the method of Lagrange multiplier, we optimize the cooling performance of the tricycle by considering the cooling rate and the figure of merit, which is the product of the coefficient of performance and cooling rate, as objective functions. Our findings reveal the optimal operating region of the tricycle, shedding light on its efficient performance.

quant-ph

Efficiency bounds for bipartite information-driven thermodynamic systems

This study introduces a novel approach to derive a lower bound for the entropy production rate of a subsystem by utilizing the Cauchy-Schwarz inequality. It extends to establishing comprehensive upper and lower bounds for the efficiency of two subsystems. These bounds are applicable to a wide range of Markovian stochastic processes, which enhances the accuracy in depicting the range of energy conversion efficiency between subsystems. Empirical validation is conducted using a two-quantum-dot system model, which serves to confirm the effectiveness of our inequality in refining the boundaries of efficiency.

cond-mat.stat-mech

Breakthrough of a cross-century problematic issue:The perfect statements of the third law of thermodynamics

The third law of thermodynamics has been verified experimentally, but how to perfectly express such a law in theory has become a cross-century problematic issue. It is found from the recent researches that by introducing an innovative method, the Nernst equation can be obtained directly from the experimental data of chemical reactions at low temperatures without the need for artificial additional assumptions appearing in textbooks, so that the Nernst theorem should be replaced by the Nernst statement. The heat capacity statement proposed recently can be also obtained from the experimental data of the heat capacity at low temperatures. The heat capacity statement and the Nernst statement are proved to be mutually derivable and the two are equivalent. The unattainability statement of absolute zero temperature is only a coloration of the Nernst statement or the heat capacity statement. Simultaneously, the defects and deficiencies related to the contents of the third law of thermodynamics appearing in textbooks are pointed out and corrected. The results obtained show clearly that the Nernst theorem and the unattainability statement of absolute zero temperature should be withdrawn from the statements of the third law of thermodynamics. It is important to find that the Nernst statement and the heat capacity statement are two equivalent statements of the third law of thermodynamics, which can solve the centennial debate problems of the third law of thermodynamics and supply the perfect statements for the third law of thermodynamics.

cond-mat.stat-mech

Rederivation of Nernst's equation without any additional assumptions

It is found that without any additional assumptions, Nernst's equation can be re-deduced from the experimental data obtained from the thermodynamic systems at ultra-low temperatures, and consequently, the physical content included by Nernst's equation should not be referred to as Nernst's postulate or Nernst's theorem. It should be called the Nernst statement. This discovery will play an important role in improving the theoretical framework of thermodynamics. It can effectively prevent some artificial assumptions into the third law of thermodynamics, making which be a true reflection of the objective world. It solves the awkward problem caused by using a thermodynamic theorem as the core contents of a thermodynamic law for over a hundred years.

cond-mat.stat-mech

Performance improvement of a fractional quantum Stirling heat engine

To investigate the impact of fractional parameter on the thermodynamic behaviors of quantum systems, we incorporate fractional quantum mechanics into the cycle of a quantum Stirling heat engine and examine the influence of fractional parameter on the regeneration and efficiency. We propose a novel approach to control the thermodynamic cycle that leverages the fractional parameter structure and evaluates its effectiveness. Our findings reveal that by tuning the fractional parameter, the region of the cycle with the perfect regeneration and the Carnot efficiency can be expanded.

quant-ph

On the equivalence of the Nernst theorem and its consequence

One general consequence of the Nernst theorem is derived, i.e., the various heat capacities of a thermodynamic system under different constraints approach zero as the temperature approaches absolute zero. The temperature dependence of the heat capacity of any thermodynamic system at ultra-low temperatures is revealed through this consequence. Moreover, the general form and the simplest expression of the heat capacities of thermodynamic systems at ultra-low temperatures are deduced. Some significant discussion and results are given. One new research method is provided by using this consequence. Finally, the equivalence between the Nernst theorem and its consequence is rigorously proved, so that this consequence may be referred to another description of the third law of thermodynamics.

cond-mat.stat-mech