Jinfei Dai | Searcharxiv

arXiv2025

Light-Emitting Diodes based on Metal Halide Perovskite and Perovskite Related Nanocrystals

Light-emitting diodes (LEDs) based on halide perovskite nanocrystals have attracted extensive attention due to their considerable luminescence efficiency, wide color gamut, high color purity, and facile material synthesis. Since the first demonstration of LEDs based on MAPbBr3 nanocrystals were reported in 2014, the community has witnessed a rapid development in their performances. In this review, we provide a historical perspective of the development of LEDs based on halide perovskite nanocrystals and then present a comprehensive survey of current strategies to high-efficiency lead-based perovskite nanocrystals LEDs, including synthesis optimization, ion doping/alloying and shell coating. We then review the basic characteristics and emission mechanisms of lead-free perovskite and perovskite-related nanocrystals emitters in environmentally friendly LEDs, from the standpoint of different emission colors. Finally, we cover the progress in LED applications and provide an outlook of the opportunities and challenges for future developments in this field.

cond-mat.mtrl-sci↗

arXiv2020

Impermeable Inorganic Walls Sandwiching Photoactive Layer toward Inverted Perovskite Solar and Indoor-Photovoltaic Devices

Interfaces between the perovskite active layer and the charge-transport layers (CTLs) play a critical role in both efficiency and stability of halide-perovskite photovoltaics. One of the major concerns is that surface defects of perovskite could cause detrimental nonradiative recombination and material degradation. In this work, we addressed this challenging problem by inserting ultrathin alkali-fluoride (AF) films between the tri-cation lead-iodide perovskite layer and both CTLs. This bilateral inorganic walls strategy makes use of both physical-blocking and chemical-anchoring functionalities of the continuous, uniform and compact AF framework: on the one hand, the uniformly distributed alkali-iodine coordination at the perovskite-AF interfaces effectively suppresses the formation of iodine-vacancy defects at the surfaces and grain boundaries of the whole perovskite film, thus reducing the trap-assisted recombination at the perovskite-CTL interfaces and therewith the open-voltage loss; on the other hand, the impermeable AF buffer layers effectively prevent the bidirectional ion migration at the perovskite-CTLs interfaces even under harsh working conditions. As a result, a power-conversion efficiency (PCE) of 22.02% (certified efficiency 20.4%) with low open-voltage deficit (< 0.4V) was achieved for the low-temperature processed inverted planar perovskite solar cells. Exceptional operational stability (500 h, ISOS-L-2) and thermal stability (1000 h, ISOS-D-2) were obtained. Meanwhile, a 35.7% PCE was obtained under dim-light source (1000 lux white LED light) with the optimized device, which is among the best records in perovskite indoor photovoltaics.

cond-mat.mtrl-sci↗