arXiv subjects

Jingwei Jiang

Publications and source records attributed to Jingwei Jiang.

9 recordsLinked to original sources

arXiv2025

Jahn-Teller-like Distortion in a One-dimensional {\pi}-Conjugated Polymer

Structurally distorting low-dimensional {\pi}-conjugated systems can profoundly influence their electronic properties, but controlling such behavior in extended-width systems remains challenging. Here we demonstrate that a one-dimensional conjugated polymer, poly-(difluorenoheptalene-ethynylene) (PDFHE), undergoes a pronounced out-of-plane backbone distortion, equivalent to a spontaneous symmetry breaking (SSB) of its mirror symmetry. We synthesized PDFHE on noble metal surfaces and characterized its structure and electronic states using low-temperature scanning tunneling microscopy. Rather than adopting a planar, high-symmetry conformation, PDFHE relaxes into non-planar isomers stabilized by a Jahn-Teller-like mechanism that relieves an electronic instability relative to the gapped planar structure. Density functional theory calculations corroborate these findings, revealing that distortion lowers the total polymer energy and enlarges the bandgap, providing a microscopic explanation for the SSB. Our results show that even in mechanically robust extended {\pi}-systems, subtle electron-lattice coupling can spontaneously drive significant structural rearrangements.

cond-mat.mes-hall↗

arXiv2024

LSSInst: Improving Geometric Modeling in LSS-Based BEV Perception with Instance Representation

With the attention gained by camera-only 3D object detection in autonomous driving, methods based on Bird-Eye-View (BEV) representation especially derived from the forward view transformation paradigm, i.e., lift-splat-shoot (LSS), have recently seen significant progress. The BEV representation formulated by the frustum based on depth distribution prediction is ideal for learning the road structure and scene layout from multi-view images. However, to retain computational efficiency, the compressed BEV representation such as in resolution and axis is inevitably weak in retaining the individual geometric details, undermining the methodological generality and applicability. With this in mind, to compensate for the missing details and utilize multi-view geometry constraints, we propose LSSInst, a two-stage object detector incorporating BEV and instance representations in tandem. The proposed detector exploits fine-grained pixel-level features that can be flexibly integrated into existing LSS-based BEV networks. Having said that, due to the inherent gap between two representation spaces, we design the instance adaptor for the BEV-to-instance semantic coherence rather than pass the proposal naively. Extensive experiments demonstrated that our proposed framework is of excellent generalization ability and performance, which boosts the performances of modern LSS-based BEV perception methods without bells and whistles and outperforms current LSS-based state-of-the-art works on the large-scale nuScenes benchmark.

cs.CV↗

arXiv2024

Regioselective On-Surface Synthesis of [3]Triangulene Graphene Nanoribbons

The integration of low-energy states into bottom-up engineered graphene nanoribbons (GNRs) is a robust strategy for realizing materials with tailored electronic band structure for nanoelectronics. Low-energy zero-modes (ZMs) can be introduced into nanographenes (NGs) by creating an imbalance between the two sublattices of graphene. This phenomenon is exemplified by the family of [n]triangulenes. Here, we demonstrate the synthesis of [3]triangulene-GNRs, a regioregular one-dimensional (1D) chain of [3]triangulenes linked by five-membered rings. Hybridization between ZMs on adjacent [3]triangulenes leads to the emergence of a narrow band gap, Eg = 0.7 eV, and topological end states that are experimentally verified using scanning tunneling spectroscopy (STS). Tight-binding and first-principles density functional theory (DFT) calculations within the local spin density approximation (LSDA) corroborate our experimental observations. Our synthetic design takes advantage of a selective on-surface head-to-tail coupling of monomer building blocks enabling the regioselective synthesis of [3]triangulene-GNRs. Detailed ab initio theory provides insight into the mechanism of on-surface radical polymerization, revealing the pivotal role of Au-C bond formation/breakage in driving selectivity.

cond-mat.mes-hall↗

arXiv2023

Engineering Robust Metallic Zero-Mode States in Olympicene Graphene Nanoribbons

Metallic graphene nanoribbons (GNRs) represent a critical component in the toolbox of low-dimensional functional materials technolo-gy serving as 1D interconnects capable of both electronic and quantum information transport. The structural constraints imposed by on-surface bottom-up GNR synthesis protocols along with the limited control over orientation and sequence of asymmetric monomer building blocks during the radical step-growth polymerization has plagued the design and assembly of metallic GNRs. Here we report the regioregular synthesis of GNRs hosting robust metallic states by embedding a symmetric zero-mode superlattice along the backbone of a GNR. Tight-binding electronic structure models predict a strong nearest-neighbor electron hopping interaction between adjacent zero-mode states resulting in a dispersive metallic band. First principles DFT-LDA calculations confirm this prediction and the robust, metallic zero-mode band of olympicene GNRs (oGNRs) is experimentally corroborated by scanning tunneling spectroscopy.

cond-mat.mtrl-sci↗

arXiv2023

Low Energy Excitations in a [4]Triangulene Honeycomb Antiferromagnet

Carbon-based synthetic lattices offer a versatile platform for the realization and control of correlated quantum effects at the nanoscale. Advances in on-surface synthesis have facilitated the fabrication of increasingly complex molecular frameworks, opening new avenues for the exploration and engineering of custom tailored electronic and magnetic phases. Here, we report the design, on-surface synthesis, and characterization of a two-dimensional (2D) covalent organic framework (COF) assembled from D3h symmetric S = 3/2 [4]triangulene building blocks arranged in a honeycomb structure. Combined scanning probe microscopy and spectroscopy, corroborated by first-principles density functional theory (DFT) and GW calculations, establish an antiferromagnetic (AFM) insulating ground state. Low energy spectroscopy resolves spin excitations in both one-dimensional (1D) chains and extended 2D networks, providing direct insight into the emergent spin dynamics and establishing a modular platform to explore quantum magnetism in a pi-conjugated organic system.

cond-mat.str-el↗

arXiv2021

Tuning color centers at a twisted interface

Color center is a promising platform for quantum technologies, but their application is hindered by the typically random defect distribution and complex mesoscopic environment. Employing cathodoluminescence, we demonstrate that an ultraviolet-emitting single photon emitter can be readily activated and controlled on-demand at the twisted interface of two hexagonal boron nitride flakes. The brightness of the color center can be enhanced by two orders of magnitude by altering the twist angle. Additionally, a brightness modulation of nearly 100% of this color center is achieved by an external voltage. Our ab-initio GW calculations suggest that the emission is correlated to nitrogen vacancies and that a twist-induced moiré potential facilitates electron-hole recombination. This mechanism is further exploited to draw nanoscale color center patterns using electron beams.

cond-mat.mtrl-sci↗

arXiv2020

Topology Classification from Chiral Symmetry: Chiral Phase Index and Spin Correlations in Graphene Nanoribbons

Topology concepts have significantly deepened of our understanding in recent years of the electronic properties of one-dimensional (1D) nano structures such as the graphene nanoribbons. Controlling topological electronic properties of GNRs has been demonstrated in both theoretical studies and experimental realization. Most previous works rely on classification theory requiring both time reversal and spatial symmetry of a unit cell in the 1D bulk material that is commensurate to its boundary. To access boundary structures that lead to unit cell with no spatial symmetry and to generalize the theory, we propose here another classification scheme, using chiral symmetry, to arrive at a Z classification that is not only applicable to GNRs with arbitrary terminations, but also to any general 1D chiral structures. This theory, combining with Lieb's theorem, moreover enables access to the electron's spin degree of freedom, allowing for investigation of spin physics.

cond-mat.mtrl-sci↗

arXiv2019

Inducing Metallicity in Graphene Nanoribbons via Zero-Mode Superlattices

The design and fabrication of robust metallic states in graphene nanoribbons (GNRs) is a significant challenge since lateral quantum confinement and many-electron interactions tend to induce electronic band gaps when graphene is patterned at nanometer length scales. Recent developments in bottom-up synthesis have enabled the design and characterization of atomically-precise GNRs, but strategies for realizing GNR metallicity have been elusive. Here we demonstrate a general technique for inducing metallicity in GNRs by inserting a symmetric superlattice of zero-energy modes into otherwise semiconducting GNRs. We verify the resulting metallicity using scanning tunneling spectroscopy as well as first-principles density-functional theory and tight binding calculations. Our results reveal that the metallic bandwidth in GNRs can be tuned over a wide range by controlling the overlap of zero-mode wavefunctions through intentional sublattice symmetry-breaking.

cond-mat.mtrl-sci↗

arXiv2016

Unusually stable helical coil allotrope of phosphorus

We have identified an unusually stable helical coil allotrope of phosphorus. Our ab initio Density Functional Theory calculations indicate that the uncoiled, isolated straight 1D chain is equally stable as a monolayer of black phosphorus dubbed phosphorene. The coiling tendency and the attraction between adjacent coil segments add an extra stabilization energy of about 12 meV/atom to the coil allotrope, similar in value to the approximately 16 meV/atom inter-layer attraction in bulk black phosphorus. Thus, the helical coil structure is essentially as stable as black phosphorus, the most stable phosphorus allotrope known to date. With an optimum radius of 2.4 nm, the helical coil of phosphorus may fit well and even form inside wide carbon nanotubes.

cond-mat.mes-hall↗