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Jinhua He

Publications and source records attributed to Jinhua He.

At least 37 records · Page 2Linked to original sources

PDRs4All IV. An embarrassment of riches: Aromatic infrared bands in the Orion Bar

(Abridged) Mid-infrared observations of photodissociation regions (PDRs) are dominated by strong emission features called aromatic infrared bands (AIBs). The most prominent AIBs are found at 3.3, 6.2, 7.7, 8.6, and 11.2 $μ$m. The most sensitive, highest-resolution infrared spectral imaging data ever taken of the prototypical PDR, the Orion Bar, have been captured by JWST. We provide an inventory of the AIBs found in the Orion Bar, along with mid-IR template spectra from five distinct regions in the Bar: the molecular PDR, the atomic PDR, and the HII region. We use JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science Program, PDRs4All (ID: 1288). We extract five template spectra to represent the morphology and environment of the Orion Bar PDR. The superb sensitivity and the spectral and spatial resolution of these JWST observations reveal many details of the AIB emission and enable an improved characterization of their detailed profile shapes and sub-components. While the spectra are dominated by the well-known AIBs at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $μ$m, a wealth of weaker features and sub-components are present. We report trends in the widths and relative strengths of AIBs across the five template spectra. These trends yield valuable insight into the photochemical evolution of PAHs, such as the evolution responsible for the shift of 11.2 $μ$m AIB emission from class B$_{11.2}$ in the molecular PDR to class A$_{11.2}$ in the PDR surface layers. This photochemical evolution is driven by the increased importance of FUV processing in the PDR surface layers, resulting in a "weeding out" of the weakest links of the PAH family in these layers. For now, these JWST observations are consistent with a model in which the underlying PAH family is composed of a few species: the so-called 'grandPAHs'.

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PDRs4All II: JWST's NIR and MIR imaging view of the Orion Nebula

The JWST has captured the most detailed and sharpest infrared images ever taken of the inner region of the Orion Nebula, the nearest massive star formation region, and a prototypical highly irradiated dense photo-dissociation region (PDR). We investigate the fundamental interaction of far-ultraviolet photons with molecular clouds. The transitions across the ionization front (IF), dissociation front (DF), and the molecular cloud are studied at high-angular resolution. These transitions are relevant to understanding the effects of radiative feedback from massive stars and the dominant physical and chemical processes that lead to the IR emission that JWST will detect in many Galactic and extragalactic environments. Due to the proximity of the Orion Nebula and the unprecedented angular resolution of JWST, these data reveal that the molecular cloud borders are hyper structured at small angular scales of 0.1-1" (0.0002-0.002 pc or 40-400 au at 414 pc). A diverse set of features are observed such as ridges, waves, globules and photoevaporated protoplanetary disks. At the PDR atomic to molecular transition, several bright features are detected that are associated with the highly irradiated surroundings of the dense molecular condensations and embedded young star. Toward the Orion Bar PDR, a highly sculpted interface is detected with sharp edges and density increases near the IF and DF. This was predicted by previous modeling studies, but the fronts were unresolved in most tracers. A complex, structured, and folded DF surface was traced by the H2 lines. This dataset was used to revisit the commonly adopted 2D PDR structure of the Orion Bar. JWST provides us with a complete view of the PDR, all the way from the PDR edge to the substructured dense region, and this allowed us to determine, in detail, where the emission of the atomic and molecular lines, aromatic bands, and dust originate.

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Improved Inner Approximation for Aggregating Power Flexibility in Active Distribution Networks and its Applications

Concise and reliable modeling for aggregating power flexibility of distributed energy resources in active distribution networks (ADNs) is a crucial technique for coordinating transmission and distribution networks. Our recent research has successfully derived an explicit expression for the exact aggregation model (EAM) of power flexibility at the substation level under linearized distribution network constraints. The EAM, however, is impractical for decision-making purposes due to its exponential complexity. In this paper, we propose an inner approximation method for aggregating flexibility in ADNs that utilizes the properties of the EAM to improve performance. Specifically, the geometric prototype of the inner approximation model is defined according to a subset of the coefficient vector set of the EAM, which enhances the accuracy. On the other hand, the computation efficiency of the inner approximation is also significantly improved by exploiting the regularity of coefficient vectors in the EAM in the parameter calculation process. The inner approximated flexibility model of ADNs is further incorporated into the security-constrained unit commitment problem as an application. Numerical simulations verify the effectiveness of the proposed method.

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ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): Detection of extremely high density compact structure of prestellar cores and multiple substructures within

Prestellar cores are self-gravitating dense and cold structures within molecular clouds where future stars are born. They are expected, at the stage of transitioning to the protostellar phase, to harbor centrally concentrated dense (sub)structures that will seed the formation of a new star or the binary/multiple stellar systems. Characterizing this critical stage of evolution is key to our understanding of star formation. In this work, we report the detection of high density (sub)structures on the thousand-au scale in a sample of dense prestellar cores. Through our recent ALMA observations towards the Orion molecular cloud, we have found five extremely dense prestellar cores, which have centrally concentrated regions $\sim$ 2000 au in size, and several $10^7$ $cm^{-3}$ in average density. Masses of these centrally dense regions are in the range of 0.30 to 6.89 M$_\odot$. {\it For the first time}, our higher resolution observations (0.8$'' \sim $ 320 au) further reveal that one of the cores shows clear signatures of fragmentation; such individual substructures/fragments have sizes of 800 -1700 au, masses of 0.08 to 0.84 M$_\odot$, densities of $2 - 8\times 10^7$ $cm^{-3}$ and separations of $\sim 1200$ au. The substructures are massive enough ($\gtrsim 0.1~M_\odot$) to form young stellar objects and are likely examples of the earliest stage of stellar embryos which can lead to widely ($\sim$ 1200 au) separated multiple systems.

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Evidence of high-mass star formation through multi-scale mass accretion in hub-filament-system clouds

We present a statistical study of a sample of 17 hub-filament-system (HFS) clouds of high-mass star formation using high-angular resolution ($\sim$1-2 arcsecond) ALMA 1.3mm and 3mm continuum data. The sample includes 8 infrared (IR)-dark and 9 IR-bright types, which correspond to an evolutionary sequence from the IR-dark to IR-bright stage. The central massive clumps and their associated most massive cores are observed to follow a trend of increasing mass ($M$) and mass surface density ($Σ$) with evolution from IR-dark to IR-bright stage. In addition, a mass-segregated cluster of young stellar objects (YSOs) are revealed in both IR-dark and IR-bright HFSs with massive YSOs located in the hub and the population of low-mass YSOs distributed over larger areas. Moreover, outflow feedback in all HFSs are found to escape preferentially through the inter-filamentary diffuse cavities, suggesting that outflows would render a limited effect on the disruption of the HFSs and ongoing high-mass star formation therein. From the above observations, we suggest that high-mass star formation in the HFSs can be described by a multi-scale mass accretion/transfer scenario, from hub-composing filaments through clumps down to cores, that can naturally lead to a mass-segregated cluster of stars.

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Disk dissipation, giant planet formation and star-formation-rate fluctuations in the past three-million-year history of Gould's Belt

Although episodic star formation (SF) had been suggested for nearby SF regions, a panoramic view to the latest episodic SF history in the solar neighborhood is still missing. By uniformly constraining the slope $α$ of infrared spectral energy distributions (SEDs) of young stellar objects (YSOs) in the 13 largest Gould's Belt (GB) protoclusters surveyed by Spitzer Space Telescope, we have constructed a cluster-averaged histogram of $α$ representing YSO evolution lifetime as a function of the $α$ value. Complementary to the traditional SED classification scheme (0, I, F, II, III) that is based on different $α$ values, a staging scheme (A,B,C,D,E) of SED evolution is advised on the basis of the $α$ statistical features that can be better matched to the physical stages of disk dissipation and giant planet formation. This has also allowed us to unravel the fluctuations of star formation rate (SFR) in the past three-million-year (3 Myr) history of these GB protoclusters. Diverse evolutionary patterns such as single peak, double peaks and on-going acceleration of SFR are revealed. The SFR fluctuations are between $20\%\sim60\%$ ($\sim40\%$ on average) and no dependence on the average SFR or the number of SFR episodes is found. However, spatially close protoclusters tend to share similar SFR fluctuation trends, indicating that the driving force of the fluctuations should be at size scales beyond the typical cluster sizes of several parsec.

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ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -- XI. From inflow to infall in hub-filament systems

We investigate the presence of hub-filament systems in a large sample of 146 active proto-clusters, using H$^{13}$CO$^{+}$ J=1-0 molecular line data obtained from the ATOMS survey. We find that filaments are ubiquitous in proto-clusters, and hub-filament systems are very common from dense core scales ($\sim$0.1 pc) to clump/cloud scales ($\sim$1-10 pc). The proportion of proto-clusters containing hub-filament systems decreases with increasing dust temperature ($T_d$) and luminosity-to-mass ratios ($L/M$) of clumps, indicating that stellar feedback from H{\sc ii} regions gradually destroys the hub-filament systems as proto-clusters evolve. Clear velocity gradients are seen along the longest filaments with a mean velocity gradient of 8.71 km s$^{-1}$pc$^{-1}$ and a median velocity gradient of 5.54 km s$^{-1}$pc$^{-1}$. We find that velocity gradients are small for filament lengths larger than $\sim$1~pc, probably hinting at the existence of inertial inflows, although we cannot determine whether the latter are driven by large-scale turbulence or large-scale gravitational contraction. In contrast, velocity gradients below $\sim$1~pc dramatically increase as filament lengths decrease, indicating that the gravity of the hubs or cores starts to dominate gas infall at small scales. We suggest that self-similar hub-filament systems and filamentary accretion at all scales may play a key role in high-mass star formation.

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ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): How do dense core properties affect the multiplicity of protostars?

During the transition phase from a prestellar to a protostellar cloud core, one or several protostars can form within a single gas core. The detailed physical processes of this transition, however, still remain unclear. We present 1.3 mm dust continuum and molecular line observations with the Atacama Large Millimeter/submillimeter Array (ALMA) toward 43 protostellar cores in the Orion Molecular Cloud Complex ($λ$ Orionis, Orion B, and Orion A) with an angular resolution of $\sim$ 0.35" ($\sim$ 140 au). In total, we detect 13 binary/multiple systems. We derive an overall multiplicity frequency (MF) of 28$\%$ $\pm$ 4$\%$ and a companion star fraction (CSF) of 51$\%$ $\pm$ 6$\%$, over a separation range of 300-8900 au. The median separation of companions is about 2100 au. The occurrence of stellar multiplicity may depend on the physical characteristics of the dense cores. Notably, those containing binary/multiple systems tend to show higher gas density and Mach number than cores forming single stars. The integral-shaped filament (ISF) of Orion A giant molecular cloud (GMC), which has the highest gas density and hosts high-mass star formation in its central region (the Orion Nebula cluster), shows the highest MF and CSF among the Orion GMCs. In contrast, the $λ$ Orionis Giant Molecular Cloud (GMC) has a lower MF and CSF than the Orion B and Orion A GMCs, indicating that feedback from HII regions may suppress the formation of multiple systems. We also find that the protostars comprising a binary/multiple system are usually at different evolutionary stages.

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ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): Evidence for a Molecular Jet Launched at an Unprecedented Early Phase of Protostellar evolution

Protostellar outflows and jets play a vital role in star formation as they carry away excess angular momentum from the inner disk surface, allowing the material to be transferred toward the central protostar. Theoretically, low velocity and poorly collimated outflows appear from the beginning of the collapse, at the first hydrostatic core (FHSC) stage. With growing protostellar core mass, high-density jets are launched which entrain an outflow from the infalling envelope. Until now, molecular jets have been observed at high velocity ($\gtrsim$ 100 km/s) in early Class\,0 protostars. We, for the first time, detect a dense molecular jet in SiO emission with small-velocity ($\sim$ 4.2 km\,s$^{-1}$, deprojected $\sim$ 24 km\,s$^{-1}$) from source G208.89-20.04Walma (hereafter, G208Walma) using ALMA Band\,6 observations. This object has some characteristics of FHSCs, such as a small outflow/jet velocity, extended 1.3\,mm continuum emission, and N$_2$D$^+$ line emission. Additional characteristics, however, are typical of early protostars: collimated outflow and SiO jet. The full extent of the outflow corresponds to a dynamical time scale of $\sim$ 930$^{+200}_{-100}$ years. The spectral energy distribution also suggests a very young source having an upper limit of T$_{bol}$ $\sim$ 31 K and L$_{bol}$ $\sim$ 0.8 L$_\sun$. We conclude that G208Walma is likely in the transition phase from FHSC to protostar, and the molecular jet has been launched within a few hundred years of initial collapse. Therefore, G208Walma may be the earliest object discovered in the protostellar phase with a molecular jet.

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ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -- VIII. A search for hot cores by using C$_2$H$_5$CN, CH$_3$OCHO and CH$_3$OH lines

Hot cores characterized by rich lines of complex organic molecules are considered as ideal sites for investigating the physical and chemical environments of massive star formation. We present a search for hot cores by using typical nitrogen- and oxygen-bearing complex organic molecules (C$_2$H$_5$CN, CH$_3$OCHO and CH$_3$OH), based on ALMA Three-millimeter Observations of Massive Star-forming regions (ATOMS). The angular resolutions and line sensitivities of the ALMA observations are better than 2 arcsec and 10 mJy/beam, respectively. A total of 60 hot cores are identified with 45 being newly detected, in which the complex organic molecules have high gas temperatures ($>$ 100 K) and small source sizes ($<$ 0.1 pc). So far this is the largest sample of hot cores observed with similar angular resolution and spectral coverage. The observations have also shown nitrogen and oxygen differentiation in both line emission and gas distribution in 29 hot cores. Column densities of CH$_3$OH and CH$_3$OCHO increase as rotation temperatures rise. The column density of CH$_3$OCHO correlates tightly with that of CH$_3$OH. The pathways for production of different species are discussed. Based on the spatial position difference between hot cores and UC~H{\sc ii} regions, we conclude that 24 hot cores are externally heated while the other hot cores are internally heated. The observations presented here will potentially help establish a hot core template for studying massive star formation and astrochemistry.

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ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -- VII. A catalogue of SiO clumps from ACA observations

To understand the nature of SiO emission, we conducted ACA observations of the SiO (2-1) lines toward 146 massive star-forming regions, as part of the ALMA Three-millimeter Observations of Massive Star-forming regions (ATOMS) survey. We detected SiO emission in 128 (87.7$\%$) sources and identified 171 SiO clumps, 105 of which are spatially separated from 3 mm continuum emission. A large amount of the SiO line profiles (60$\%$) are non-Gaussian. The velocity dispersion of the SiO lines ranges from 0.3 to 5.43 km s$^{-1}$. In 63 sources the SiO clumps are associated with H$_\rm{II}$ regions characterized by H40$α$ emission. We find that 68$\%$ (116) of the SiO clumps are associated with strong outflows. The median velocity dispersion of the SiO line for outflow sources and non-outflow sources is 1.91 km s$^{-1}$ and 0.99 km s$^{-1}$, respectively. These results indicate that outflow activities could be connected to strongly shocked gas. The velocity dispersion and [SiO]/[H$^{13}$CO$^+$] intensity ratio do not show any correlation with the dust temperature and particle number density of clumps. We find a positive correlation between the SiO line luminosity and the bolometric luminosity, implying stronger shock activities are associated with more luminous proto-clusters. The SiO clumps in associations with H$_\rm{II}$ regions were found to show a steeper feature in $L_\rm{sio}$/$L_\rm{bol}$. The SiO line luminosity and the fraction of shocked gas have no apparent evidence of correlation with the evolutionary stages traced by luminosity to mass ratio ($L_\rm{bol}/M$).

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PDRs4All: A JWST Early Release Science Program on radiative feedback from massive stars

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the Universe, from the era of vigorous star formation at redshifts of 1-3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template datasets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template datasets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations.

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The Nearby Evolved Stars Survey II: Constructing a volume-limited sample and first results from the James Clerk Maxwell Telescope

The Nearby Evolved Stars Survey (NESS) is a volume-complete sample of $\sim$850 Galactic evolved stars within 3\,kpc at (sub-)mm wavelengths, observed in the CO $J = $ (2$-$1) and (3$-$2) rotational lines, and the sub-mm continuum, using the James Clark Maxwell Telescope and Atacama Pathfinder Experiment. NESS consists of five tiers, based on distances and dust-production rate (DPR). We define a new metric for estimating the distances to evolved stars and compare its results to \emph{Gaia} EDR3. Replicating other studies, the most-evolved, highly enshrouded objects in the Galactic Plane dominate the dust returned by our sources, and we initially estimate a total DPR of $4.7\times 10^{-5}$ M$_\odot$ yr$^{-1}$ from our sample. Our sub-mm fluxes are systematically higher and spectral indices are typically shallower than dust models typically predict. The 450/850 $μ$m spectral indices are consistent with the blackbody Rayleigh--Jeans regime, suggesting a large fraction of evolved stars have unexpectedly large envelopes of cold dust.

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The HASHTAG project: The First Submillimeter Images of the Andromeda Galaxy from the Ground

Observing nearby galaxies with submillimeter telescopes on the ground has two major challenges. First, the brightness is significantly reduced at long submillimeter wavelengths compared to the brightness at the peak of the dust emission. Second, it is necessary to use a high-pass spatial filter to remove atmospheric noise on large angular scales, which has the unwelcome by-product of also removing the galaxy's large-scale structure. We have developed a technique for producing high-resolution submillimeter images of galaxies of large angular size by using the telescope on the ground to determine the small-scale structure (the large Fourier components) and a space telescope (Herschel or Planck) to determine the large-scale structure (the small Fourier components). Using this technique, we are carrying out the HARP and SCUBA-2 High Resolution Terahertz Andromeda Galaxy Survey (HASHTAG), an international Large Program on the James Clerk Maxwell Telescope, with one aim being to produce the first high-fidelity high-resolution submillimeter images of Andromeda. In this paper, we describe the survey, the method we have developed for combining the space-based and ground-based data, and present the first HASHTAG images of Andromeda at 450 and 850um. We also have created a method to predict the CO(J=3-2) line flux across M31, which contaminates the 850um band. We find that while normally the contamination is below our sensitivity limit, the contamination can be significant (up to 28%) in a few of the brightest regions of the 10 kpc ring. We therefore also provide images with the predicted line emission removed.

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Characterization of dense Planck clumps observed with Herschel and SCUBA-2

We aim to characterize a diverse selection of dense, potentially star-forming cores, clumps, and clouds within the Milky Way in terms of their dust emission and SF activity. We studied 53 fields that have been observed in the JCMT SCUBA-2 continuum survey SCOPE and have been mapped with Herschel. We estimated dust properties by fitting Herschel observations with modified blackbody functions, studied the relationship between dust temperature and dust opacity spectral index $β$, and estimated column densities. We extracted clumps from the SCUBA-2 850 $μ$m maps with the FellWalker algorithm and examined their masses and sizes. Clumps are associated with young stellar objects found in several catalogs. We estimated the gravitational stability of the clumps with virial analysis. The clumps are categorized as unbound starless, prestellar, or protostellar. We find 529 dense clumps, typically with high column densities from (0.3-4.8)$\times 10^{22}$ cm$^{-2}$, with a mean of (1.5$\pm$0.04)$\times10^{22}$ cm$^{-2}$, low temperatures ($T\sim $10-20 K), and estimated submillimeter $β$ =1.7$\pm$0.1. We detect a slight increase in opacity spectral index toward millimeter wavelengths. Masses of the sources range from 0.04 $M_\odot$ to 4259 $M_\odot$. Mass, linear size, and temperature are correlated with distance. Furthermore, the estimated gravitational stability is dependent on distance, and more distant clumps appear more virially bound. Finally, we present a catalog of properties of the clumps.Our sources present a large array of SF regions, from high-latitude, nearby diffuse clouds to large SF complexes near the Galactic center. Analysis of these regions will continue with the addition of molecular line data, which will allow us to study the densest regions of the clumps in more detail.

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Molecular Cloud Cores with High Deuterium Fractions: Nobeyama Mapping Survey

We present the results of on-the-fly mapping observations of 44 fields containing 107 SCUBA-2 cores in the emission lines of molecules, N$_2$H$^+$, HC$_3$N, and CCS at 82$-$94 GHz using the Nobeyama 45-m telescope. This study aimed at investigating the physical properties of cores that show high deuterium fractions and might be close to the onset of star formation. We found that the distributions of the N$_2$H$^+$ and HC$_3$N line emissions are approximately similar to that of 850-$μ$m dust continuum emission, whereas the CCS line emission is often undetected or is distributed in a clumpy structure surrounding the peak position of the 850-$μ$m dust continuum emission. Occasionally (12%), we observe the CCS emission which is an early-type gas tracer toward the young stellar object, probably due to local high excitation. Evolution toward star formation does not immediately affect nonthermal velocity dispersion.

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ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP) II. Survey overview: a first look at 1.3 mm continuum maps and molecular outflows

Planck Galactic Cold Clumps (PGCCs) are contemplated to be the ideal targets to probe the early phases of star formation. We have conducted a survey of 72 young dense cores inside PGCCs in the Orion complex with the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.3\,mm (band 6) using three different configurations (resolutions $\sim$ 0$\farcs$35, 1$\farcs$0, and 7$\farcs$0) to statistically investigate their evolutionary stages and sub-structures. We have obtained images of the 1.3\,mm continuum and molecular line emission ($^{12}$CO, and SiO) at an angular resolution of $\sim$ 0$\farcs$35 ($\sim$ 140\,au) with the combined arrays. We find 70 substructures within 48 detected dense cores with median dust-mass $\sim$ 0.093\,M$_{\sun}$ and deconvolved size $\sim$ 0$\farcs$27. Dense substructures are clearly detected within the central 1000\,au of four candidate prestellar cores. The sizes and masses of the substructures in continuum emission are found to be significantly reduced with protostellar evolution from Class\,0 to Class\,I. We also study the evolutionary change in the outflow characteristics through the course of protostellar mass accretion. A total of 37 sources exhibit CO outflows, and 20 ($>$50\%) show high-velocity jets in SiO. The CO velocity-extents ($Δ$Vs) span from 4 to 110 km/s with outflow cavity opening angle width at 400\,au ranging from $[Θ_{obs}]_{400}$ $\sim$ 0$\farcs$6 to 3$\farcs$9, which corresponds to 33$\fdg$4$-$125$\fdg$7. For the majority of the outflow sources, the $Δ$Vs show a positive correlation with $[Θ_{obs}]_{400}$, suggesting that as protostars undergo gravitational collapse, the cavity opening of a protostellar outflow widens and the protostars possibly generate more energetic outflows.

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Molecular Cloud Cores with High Deuterium Fraction: Nobeyama Single-Pointing Survey

We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($λ$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense cores on the verge of star formation for the study of the initial conditions of star formation. We observed these cores in eight molecular lines at 76-94 GHz using the Nobeyama 45-m telescope. We find that early-type molecules (e.g., CCS) have low detection rates and that late-type molecules (e.g., N$_2$H$^+$, c-C$_3$H$_2$) and deuterated molecules (e.g., N$_2$D$^+$, DNC) have high detection rates, suggesting that most of the cores are chemically evolved. The deuterium fraction (D/H) is found to decrease with increasing distance, indicating that it suffers from differential beam dilution between the D/H pair of lines for distant cores ($>$1 kpc). For $λ$ Orionis, Orion A, and B located at similar distances, D/H is not significantly different, suggesting that there is no systematic difference in the observed chemical properties among these three regions. We identify at least eight high D/H cores in the Orion region and two at high latitudes, which are most likely to be close to the onset of star formation. There is no clear evidence of the evolutionary change in turbulence during the starless phase, suggesting that the dissipation of turbulence is not a major mechanism for the beginning of star formation as judged from observations with a beam size of 0.04 pc.

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