arXiv subjects

Jinliang Li

Publications and source records attributed to Jinliang Li.

4 recordsLinked to original sources

arXiv2026

Carbon Layer Orientation and Closed-Pore Construction Achieving Ultra-Low Specific Surface Area Hard Carbon for High-Performance Na-ion Storage

Addressing the critical trade-off between initial Coulombic efficiency (ICE) and reversible capacity in hard carbon anodes for Na-ion batteries (NIBs), we introduce a novel coupling strategy that combines carbon layer orientation reconstruction with closed-pore construction to produce hard carbon with an ultra-low specific surface area. We demonstrate that the nanographite domains within the hard carbon precursor undergo entropy-driven orientation reconstruction through the synergistic regulation of heteroatom doping and medium-temperature carbonization. This process not only increases interlayer spacing and promotes structural disorder but also enables the formation of dense, closed pores and ultramicropores at domain boundaries via confined atomic migration, while simultaneously encapsulating surface open pores within internal closed ones. Due to this unique pore architecture, our hard carbon exhibits an ultra-low specific surface area of 1.89 m2 g-1 with a markedly higher proportion of closed pores. As a result, our hard carbon achieves a remarkable reversible capacity of 342.3 mAh g-1 at 20 mA g-1, with an exceptional ICE of 90.4% and a dominant plateau capacity of 262.3 mAh g-1 (76.6%) for NIBs. We believe this coupling strategy provides a new paradigm for the structural engineering of high-ICE anode materials in advanced NIBs.

cond-mat.mtrl-sci↗

arXiv2026

Fast Online Learning with Gaussian Prior-Driven Hierarchical Unimodal Thompson Sampling

We study a type of Multi-Armed Bandit (MAB) problems in which arms with a Gaussian reward feedback are clustered. Such an arm setting finds applications in many real-world problems, for example, mmWave communications and portfolio management with risky assets, as a result of the universality of the Gaussian distribution. Based on the Thompson Sampling algorithm with Gaussian prior (TSG) algorithm for the selection of the optimal arm, we propose our Thompson Sampling with Clustered arms under Gaussian prior (TSCG) specific to the 2-level hierarchical structure. We prove that by utilizing the 2-level structure, we can achieve a lower regret bound than we do with ordinary TSG. In addition, when the reward is Unimodal, we can reach an even lower bound on the regret by our Unimodal Thompson Sampling algorithm with Clustered Arms under Gaussian prior (UTSCG). Each of our proposed algorithms are accompanied by theoretical evaluation of the upper regret bound, and our numerical experiments confirm the advantage of our proposed algorithms.

cs.LG↗

arXiv2026

Beyond Static Snapshots: Dynamic Modeling and Forecasting of Group-Level Value Evolution with Large Language Models

Social simulation is critical for mining complex social dynamics and supporting data-driven decision making. LLM-based methods have emerged as powerful tools for this task by leveraging human-like social questionnaire responses to model group behaviors. Existing LLM-based approaches predominantly focus on group-level values at discrete time points, treating them as static snapshots rather than dynamic processes. However, group-level values are not fixed but shaped by long-term social changes. Modeling their dynamics is thus crucial for accurate social evolution prediction--a key challenge in both data mining and social science. This problem remains underexplored due to limited longitudinal data, group heterogeneity, and intricate historical event impacts. To bridge this gap, we propose a novel framework for group-level dynamic social simulation by integrating historical value trajectories into LLM-based human response modeling. We select China and the U.S. as representative contexts, conducting stratified simulations across four core sociodemographic dimensions (gender, age, education, income). Using the World Values Survey, we construct a multi-wave, group-level longitudinal dataset to capture historical value evolution, and then propose the first event-based prediction method for this task, unifying social events, current value states, and group attributes into a single framework. Evaluations across five LLM families show substantial gains: a maximum 30.88\% improvement on seen questions and 33.97\% on unseen questions over the Vanilla baseline. We further find notable cross-group heterogeneity: U.S. groups are more volatile than Chinese groups, and younger groups in both countries are more sensitive to external changes. These findings advance LLM-based social simulation and provide new insights for social scientists to understand and predict social value changes.

cs.SI↗

arXiv2025

Data-Augmented Machine Learning for Predicting Biomass-Derived Hard Carbon Anode Performance in Sodium-Ion Batteries

Biomass-derived hard carbon has become the most promising anode material for sodium-ion batteries (SIBs) due to its high capacity and excellent cycling stability. However, the effects of synthesis parameters and structural features on hard carbon's (HC) electrochemical performance are still unclear, requiring time-consuming and resource-intensive experimental investigations. Machine learning (ML) offers a promising solution by training on large datasets to predict hard carbon performance more efficiently, saving time and resources. In this study, four ML models were used to predict the capacity and initial Coulombic efficiency (ICE) of HC. Data augmentation based on the TabPFN technique was employed to improve model robustness under limited data conditions, and the relationships between features and electrochemical performance were examined. Notably, the XGBoost model achieved an R2 of 0.854 and an RMSE of 23.290 mAh g-1 for capacity prediction, and an R2 of 0.868 and an RMSE of 3.813% for ICE prediction. Shapley Additive Explanations (SHAP) and Partial Dependence Plot (PDP) analyses identified carbonization temperature (Temperature_2) as the most important factor influencing both capacity and ICE. Furthermore, we used bamboo as the precursor to synthesize four hard carbons based on the predictive approach. The electrochemical performance of these samples closely matched our predictions. By leveraging machine-learning approach, this study provides an efficient framework for accelerating the screening process of biomass-derived hard carbon candidates.

physics.chem-ph↗