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Jinyu Ye

Publications and source records attributed to Jinyu Ye.

5 recordsLinked to original sources

Quantization Degradation in Large Language Models: A Signal-Noise Perspective

Post-training quantization reduces the deployment cost of large language models, yet how severely a quantized model degrades is not determined by bit-width alone. We systematically study weight-only post-training quantization across bit-widths, quantization methods, model scales and downstream tasks on multiple model families. We observe that such degradation varies substantially across these factors: 4-bit quantization usually preserves performance, 2-bit often causes broad degradation, and at 3-bit, degradation becomes apparent but varies markedly with task type, quantization method and model scale. To explain this variability, we use the signal-to-noise ratio (SNR) to measure how strongly quantization perturbs full-precision representations. We trace degradation back to two linked processes: how quantization errors arise within individual modules, and how they accumulate across layers. First, a source SNR decomposition shows that newly introduced errors depend on three factors: the magnitude of the weight error, the strength of the task-specific signal, and how strongly the quantization error aligns with task-specific activations. Different factors affect these components in distinct ways. Second, a cross-layer propagation analysis shows that these errors can be attenuated, preserved, or amplified as they pass across layers, and that larger models benefit from weaker error amplification. Together, these results establish that quantization degradation is governed by how errors are introduced at the source and how they accumulate across the network.

cs.AI

From Signal Degradation to Computation Collapse: Uncovering the Two Failure Modes of LLM Quantization

Post-Training Quantization (PTQ) is critical for the efficient deployment of Large Language Models (LLMs). While 4-bit quantization is widely regarded as an optimal trade-off, reducing the precision to 2-bit usually triggers a catastrophic ``performance cliff.'' It remains unclear whether the underlying mechanisms differ fundamentally. Consequently, we conduct a systematic mechanistic analysis, revealing two qualitatively distinct failure modes: Signal Degradation, where the computational patterns remain intact but information precision is impaired by cumulative error; and Computation Collapse, where key components fail to function, preventing correct information processing and destroying the signal in the early layers. Guided by this diagnosis, we conduct mechanism-aware interventions, demonstrating that targeted, training-free repair can mitigate Signal Degradation, but remains ineffective for Computation Collapse. Our findings provide a systematic diagnostic framework for PTQ failures and suggest that addressing Computation Collapse requires structural reconstruction rather than mere compensation.

cs.CL

Task-Stratified Knowledge Scaling Laws for Post-Training Quantized Large Language Models

Post-Training Quantization (PTQ) is a critical strategy for efficient Large Language Models (LLMs) deployment. However, existing scaling laws primarily focus on general performance, overlooking crucial fine-grained factors and how quantization differentially impacts diverse knowledge capabilities. To address this, we establish Task-Stratified Knowledge Scaling Laws. By stratifying capabilities into memorization, application, and reasoning, we develop a framework that unifies model size, bit-width, and fine-grained factors: group size and calibration set size. Validated on 293 diverse PTQ configurations, our framework demonstrates strong fit and cross-architecture consistency. It reveals distinct sensitivities across knowledge capabilities: reasoning is precision-critical, application is scale-responsive, and memorization is calibration-sensitive. We highlight that in low-bit scenarios, optimizing these fine-grained factors is essential for preventing performance collapse. These findings provide an empirically-backed foundation for designing knowledge-aware quantization strategies.

cs.CL

Effects of pristine and photoaged tire wear particles and their leachable additives on key nitrogen removal processes and nitrous oxide accumulation in estuarine sediments

Global estuaries and coastal regions, acting as critical interfaces for mitigating nitrogen flux to marine, concurrently contend with contamination from tire wear particles (TWPs). However, the effects of pristine and photoaged TWP (P-TWP and A-TWP) and their leachates (P-TWPL and A-TWPL) on key nitrogen removal processes in estuarine sediments remain unclear. This study explored the responses of denitrification rate, anammox rate, and nitrous oxide (N2O) accumulation to P-TWP, A-TWP, P-TWPL, and A-TWPL exposures in estuarine sediments, and assessed the potential biotoxic substances in TWPL. Results indicate that P-TWP inhibited the denitrification rate and increased N2O accumulation without significantly impacting the anammox rate. A-TWP intensified the denitrification rate inhibition by further reducing narG gene abundance and NAR activity, and also decreased the hzo gene abundance, HZO activity, and Candidatus Kuenenia abundance, thereby slowing the anammox rate. N2O accumulation was lower after A-TWP exposure than P-TWP, with the NIR/NOS and NOR/NOS activity ratios closely associated with N2O accumulation. Batch experiments indicated that photoaging promoted Zn release from TWPL, significantly contributing to the inhibited denitrification rate and increased N2O accumulation by TWP. In addition, TWP drives changes in microbial community structure through released additives, with the abundance of DNB and AnAOB closely linked to the Zn, Mn, and As concentrations in TWPL. This study offers insights into assessing the environmental risks of TWPs in estuarine ecosystems.

q-bio.PE

Adding salt to expand voltage window of humid ionic liquids

Humid hydrophobic ionic liquids, widely used as electrolytes, have narrowed electrochemical windows, because their water, absorbed on the electrode surface, gets involved in electrolysis. In this work, we performed molecular dynamics simulations to explore effects of adding Li-salt in humid ionic liquids on the water adsorbed on the electrode surface. Results reveal that most of water molecules are pushed away from both cathode and anode, by adding salt. The water remained on the electrode is almost bound with Li+, which has significantly lowered activity. The Li+-bonding and re-arrangement of the surface-adsorbed water both facilitate the inhibition of water electrolysis, and thus prevent the reduction of electrochemical windows of humid hydrophobic ionic liquids. This finding is testified by cyclic voltammetry measurements where salt-in-humid ionic liquids exhibit enhanced electrochemical windows. Our work provides the underlying mechanism and a simple but practical approach for protection of humid ionic liquids from performance degradation.

physics.app-ph