arXiv subjects

Joerg Enderlein

Publications and source records attributed to Joerg Enderlein.

4 recordsLinked to original sources

arXiv2018

Characterizing the Quantum Confined Stark Effect in Semiconductor Quantum Dots and Nanorods for Single-Molecule Electrophysiology

We optimized the performance of quantum confined Stark effect QCSE based voltage nanosensors. A high throughput approach for single particle QCSE characterization was developed and utilized to screen a library of such nanosensors. Type II ZnSe CdS seeded nanorods were found to have the best performance among the different nanosensors evaluated in this work. The degree of correlation between intensity changes and spectral changes of the excitons emission under applied field was characterized. An upper limit for the temporal response of individual ZnSe CdS nanorods to voltage modulation was characterized by high throughput, high temporal resolution intensity measurements using a novel photon counting camera. The measured 3.5 us response time is limited by the voltage modulation electronics and represents about 30 times higher bandwidth than needed for recording an action potential in a neuron.

cond-mat.mes-hall↗

arXiv2012

Polymer dynamics, fluorescence correlation spectroscopy, and the limits of optical resolution

In recent years, fluorescence correlation spectroscopy has been increasingly applied for the study of polymer dynamics on the nanometer scale. The core idea is to extract, from a measured autocorrelation curve, an effective mean-square displacement function that contains information about the underlying conformational dynamics. The paper presents a fundamental study of the applicability of fluorescence correlation spectroscopy for the investigation of nanoscale conformational and diffusional dynamics. We find that fluorescence correlation spectroscopy cannot reliably elucidate processes on length scales much smaller than the resolution limit of the optics used and that its improper use can yield spurious results for the observed dynamics.

physics.chem-ph↗

arXiv2010

Self-diffusion and Cooperative Diffusion in Semidilute Polymer Solutions as measured by Fluorescence Correlation Spectroscopy

We present a comprehensive investigation of polymer diffusion in the semidilute regime by fluorescence correlation spectroscopy (FCS) and dynamic light scattering (DLS). Using single-labeled polystyrene chains, FCS leads to the self-diffusion coefficient while DLS gives the cooperative diffusion coefficient for exactly the same molecular weights and concentrations. Using FCS we observe a new fast mode in the semidilute entangled concentration regime beyond the slower mode which is due to self-diffusion. Comparison of FCS data with data obtained by DLS on the same polymers shows that the second mode observed in FCS is identical to the cooperative diffusion coefficient measured with DLS. An in-depth analysis and a comparison with current theoretical models demonstrates that the new cooperative mode observed in FCS is due to the effective long-range interaction of the chains through the transient entanglement network.

cond-mat.soft↗

arXiv2004

Gaussian, Hermite-Gaussian, and Laguerre-Gaussian beams: A primer

The paper aims at presenting a didactic and self-contained overview of Gauss-Hermite and Gauss-Laguerre laser beam modes. The usual textbook approach for deriving these modes is to solve the Helmoltz electromagnetic wave equation within the paraxial approximation. Here, a different technique is presented: Using the plane wave representation of the fundamental Gaussian mode as seed function, all higher-order beam modes are derived by acting with differential operators on this fundamental solution. Even special beam modes as the recently introduced Bessel beams are easily described within that framework.

physics.optics↗