arXiv subjects

Johan De Keyser

Publications and source records attributed to Johan De Keyser.

15 recordsLinked to original sources

arXiv2024

Evidence for Abiotic Dimethyl Sulfide in Cometary Matter

Technological progress related to astronomical observatories such as the recently launched James Webb Space Telescope (JWST) allows searching for signs of life beyond our Solar System, namely in the form of unambiguous biosignature gases in exoplanetary atmospheres. The tentative assignment of a $1-2.4\sigma$ spectral feature observed with JWST in the atmosphere of exoplanet K2-18b to the biosignature gas dimethyl sulfide (DMS; sum formula C$_2$H$_6$S) raised hopes that, although controversial, a second genesis had been found. Terrestrial atmospheric DMS is exclusively stemming from marine biological activity and no natural abiotic source has been identified - neither on Earth nor in space. Therefore, DMS is considered a robust biosignature. Since comets possess a pristine inventory of complex organic molecules of abiotic origin, we have searched high-resolution mass spectra collected at comet 67P/Churyumov-Gerasimenko, target of the European Space Agency's Rosetta mission, for the signatures of DMS. Previous work reported the presence of a C2H6S signal when the comet was near its equinox but distinction of DMS from its structural isomer ethanethiol remained elusive. Here we reassess these and evaluate additional data. Based on differences in the electron ionization induced fragmentation pattern of the two isomers, we show that DMS is significantly better compatible with the observations. Deviations between expected and observed signal intensities for DMS are $<1\sigma$, while for ethanethiol they are $2-4\sigma$. The local abundance of DMS relative to methanol deduced from these data is (0.13$\pm$0.04)%. Our results provide the first evidence for the existence of an abiotic synthetic pathway to DMS in pristine cometary matter and hence motivate more detailed studies of the sulfur chemistry in such matter and its analogs. [...]

astro-ph.EP↗

arXiv2023

Volatiles in the H$_2$O and CO$_2$ ices of comet 67P/Churyumov-Gerasimenko

ESA's Rosetta spacecraft at comet 67P/Churyumov-Gerasimenko (67P) was the first mission that accompanied a comet over a substantial fraction of its orbit. On board was the ROSINA mass spectrometer suite to measure the local densities of the volatile species sublimating from the ices inside the comet's nucleus. Understanding the nature of these ices was a key goal of Rosetta. We analyzed the primary cometary molecules at 67P, namely H$_2$O and CO$_2$, together with a suite of minor species for almost the entire mission. Our investigation reveals that the local abundances of highly volatile species, such as CH$_4$ and CO, are reproduced by a linear combination of both H$_2$O and CO$_2$ densities. These findings bear similarities to laboratory-based temperature programmed desorption experiments of amorphous ices and imply that highly volatile species are trapped in H$_2$O and CO$_2$ ices. Our results do not show the presence of ices dominated by these highly volatile molecules. Most likely, they were lost due to thermal processing of 67P's interior prior to its deflection to the inner solar system. Deviations in the proportions co-released with H$_2$O and CO$_2$ can only be observed before the inbound equinox, when the comet was still far from the sun and the abundance of highly volatile molecules associated with CO$_2$ outgassing were lower. The corresponding CO$_2$ is likely seasonal frost, which sublimated and lost its trapped highly volatile species before re-freezing during the previous apparition. CO, on the other hand, was elevated during the same time and requires further investigation.

astro-ph.EP↗

arXiv2022

High D/H ratios in water and alkanes in comet 67P/Churyumov-Gerasimenko measured with the Rosetta/ROSINA DFMS

Isotopic abundances in comets are key to understanding the history and origin of material in the Solar System. Deuterium-to-hydrogen (D/H) ratios in water are available for several comets. However, no long-term studies of the D/H ratio in water of a comet during its passage around the Sun have been reported. Linear alkanes are important organic molecules, which have been found on several Solar System bodies, including comets. To date, only upper limits of isotopic ratios for D/H and 13C/12C in linear alkanes are available. The aim of this work is a detailed analysis of the D/H ratio in water during the whole Rosetta mission. In addition, a first determination of the D/H and 13C/12C ratios in the first four linear alkanes in the coma of 67P/Churyumov-Gerasimenko is provided. We analysed in situ measurements from the Rosetta/ROSINA Double Focusing Mass Spectrometer (DFMS). The D/H ratio from HDO/H2O and the 16O/17O ratio from H216O/H217O did not change during 67P's passage around the Sun between 2014 and 2016. All D/H ratio measurements were compatible, within 1$σ$, with the mean value of $5.01\times10^{-4}$ and its relative variation of 2.0%. This suggests that the D/H ratio in 67P's coma is independent of heliocentric distance, level of cometary activity, as well as spacecraft location with respect to the nucleus. Additionally, the 16O/17O ratio could be determined with a higher accuracy than previously possible, yielding a value of 2347 with a relative variation of 2.3%. For the alkanes, the D/H ratio is between 4.1 and 4.8 times higher than in H2O, while the 13C/12C ratio is compatible, within uncertainties, with data for other Solar System objects. The relatively high D/H ratio in alkanes is in line with other cometary organic molecules and suggests that these organics may be inherited from the presolar molecular cloud from which the Solar System formed.

astro-ph.EP↗

arXiv2021

Refractory elements in the gas phase for comet 67P/Churyumov-Gerasimenko

Results. We found that gas-phase silicon was present throughout the Rosetta mission. Furthermore, the presence of sodium and iron atoms near the comet's perihelion confirms that sputtering cannot be the sole release process for refractory elements into the gas phase. Nickel was found to be below the detection limit. The search for parent species of any of the identified gas phase refractories has not been successful. Upper limits for a suite of possible fragment species (SiH, SiC, NaH, etc.) of larger parent and daughter species have been obtained. Furthermore, Si did not exhibit the same drop in signal as do common cometary gases when the spacecraft is pointed away from the nucleus. The combined results suggest that a direct release of elemental species from small grains on the surface of the nucleus or from small grains in the surrounding coma is a more likely explanation than the previous assumption of release via the dissociation of gaseous parent molecules.

astro-ph.EP↗

arXiv2020

Prestellar grain-surface origins of deuterated methanol in comet 67P/Churyumov-Gerasimenko

Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of mono- and di-deuterated methanol in a cometary coma is presented for comet 67P/Churyumov-Gerasimenko using Rosetta-ROSINA data. D-methanol (CH3OD and CH2DOH combined) and D2-methanol (CH2DOD and CHD2OH combined) have an abundance of 5.5+/-0.46 and 0.00069+/-0.00014 per cent relative to normal methanol. The data span a methanol deuteration fraction (D/H ratio) in the 0.71-6.6 per cent range, accounting for statistical corrections for the location of D in the molecule and including statistical error propagation in the ROSINA measurements. It is argued that cometary CH2DOH forms from CO hydrogenation to CH3OH and subsequent H-D substitution reactions in CH3-R. CHD2OH is likely produced from deuterated formaldehyde. Meanwhile, CH3OD and CH2DOD, could form via H-D exchange reactions in OH-R in the presence of deuterated water ice. Methanol formation and deuteration is argued to occur at the same epoch as D2O formation from HDO, with formation of mono-deuterated water, hydrogen sulfide, and ammonia occurring prior to that. The cometary D-methanol/methanol ratio is demonstrated to agree most closely with that in prestellar cores and low-mass protostellar regions. The results suggest that cometary methanol stems from the innate cold (10-20 K) prestellar core that birthed our Solar System. Cometary volatiles individually reflect the evolutionary phases of star formation from cloud to core to protostar.

astro-ph.EP↗

arXiv2020

CHO-bearing molecules in Comet 67P/Churyumov-Gerasimenko

In 2004, the Rosetta spacecraft was sent to comet 67P/Churyumov-Gerasimenko for the first ever long-term investigation of a comet. After its arrival in 2014, the spacecraft spent more than two years in immediate proximity to the comet. During these two years, the ROSINA Double Focusing Mass Spectrometer (DFMS) onboard Rosetta discovered a coma with an unexpectedly complex chemical composition that included many oxygenated molecules. Determining the exact cometary composition is an essential first step to understanding of the organic rich chemistry in star forming regions and protoplanetary disks that are ultimately conserved in cometary ices. In this study a joint approach of laboratory calibration and space data analysis was used to perform a detailed identification and quantification of CHO-compounds in the coma of 67P/Churyumov-Gerasimenko. The goal was to derive the CHO-compound abundances relative to water for masses up to 100 u. For this study, the May 2015 post-equinox period represent the best bulk abundances of comet 67P/Churyumov-Gerasimenko. A wide variety of CHO-compounds were discovered and their bulk abundances were derived. Finally, these results are compared to abundances of CHO-bearing molecules in other comets, obtained mostly from ground-based observations and modelling.

astro-ph.EP↗

arXiv2019

Elemental and molecular abundances in comet 67P/Churyumov-Gerasimenko

Comets are considered to be some of the most pristine and unprocessed solar system objects accessible to in-situ exploration. Investigating their molecular and elemental composition takes us on a journey back to the early period of our solar system and possibly even further. In this work, we deduce the bulk abundances of the major volatile species in comet 67P/Churyumov-Gerasimenko, the target of the European Space Agency's Rosetta mission. The basis are measurements obtained with the ROSINA instrument suite on board the Rosetta orbiter during a suitable period of high outgassing near perihelion. The results are combined with both gas and dust composition measurements published in the literature. This provides an integrated inventory of the major elements present in the nucleus of 67P/Churyumov-Gerasimenko. Similar to comet 1P/Halley, which was visited by ESA's Giotto spacecraft in 1986, comet 67P/Churyumov-Gerasimenko also shows near-solar abundances of oxygen and carbon, whereas hydrogen and nitrogen are depleted compared to solar. Still, the degree of devolatilization is lower than that of inner solar system objects, including meteorites and the Earth. This supports the idea that comets are among the most pristine objects in our solar system.

astro-ph.EP↗

arXiv2019

A Case for Electron-Astrophysics

A grand-challenge problem at the forefront of physics is to understand how energy is transported and transformed in plasmas. This fundamental research priority encapsulates the conversion of plasma-flow and electromagnetic energies into particle energy, either as heat or some other form of energisation. The smallest characteristic scales, at which electron dynamics determines the plasma behaviour, are the next frontier in space and astrophysical plasma research. The analysis of astrophysical processes at these scales lies at the heart of the field of electron-astrophysics. Electron scales are the ultimate bottleneck for dissipation of plasma turbulence, which is a fundamental process not understood in the electron-kinetic regime. Since electrons are the most numerous and most mobile plasma species in fully ionised plasmas and are strongly guided by the magnetic field, their thermal properties couple very efficiently to global plasma dynamics and thermodynamics.

physics.space-ph↗

arXiv2019

Cometary Plasma Science -- A White Paper in response to the Voyage 2050 Call by the European Space Agency

Comets hold the key to the understanding of our solar system, its formation and its evolution, and to the fundamental plasma processes at work both in it and beyond it. A comet nucleus emits gas as it is heated by the sunlight. The gas forms the coma, where it is ionised, becomes a plasma and eventually interacts with the solar wind. Besides these neutral and ionised gases, the coma also contains dust grains, released from the comet nucleus. As a cometary atmosphere develops when the comet travels through the solar system, large-scale structures, such as the plasma boundaries, develop and disappear, while at planets such large-scale structures are only accessible in their fully grown, quasi-steady state. In situ measurements at comets enable us to learn both how such large-scale structures are formed or reformed and how small-scale processes in the plasma affect the formation and properties of these large scale structures. Furthermore, a comet goes through a wide range of parameter regimes during its life cycle, where either collisional processes, involving neutrals and charged particles, or collisionless processes are at play, and might even compete in complicated transitional regimes. Thus a comet presents a unique opportunity to study this parameter space, from an asteroid-like to a Mars- and Venus-like interaction. Fast flybys of comets have made many new discoveries, setting the stage for a multi-spacecraft mission to accompany a comet on its journey through the solar system. This white paper reviews the present-day knowledge of cometary plasmas, discusses the many questions that remain unanswered, and outlines a multi-spacecraft ESA mission to accompany a comet that will answer these questions by combining both multi-spacecraft observations and a rendezvous mission, and at the same time advance our understanding of fundamental plasma physics and its role in planetary systems.

astro-ph.EP↗

arXiv2019

A comparison between the two lobes of comet 67P/Churyumov-Gerasimenko based on D/H ratios in H2O measured with the Rosetta/ROSINA DFMS

The nucleus of the Jupiter-family comet 67P/Churyumov-Gerasimenko was discovered to be bi-lobate in shape when the European Space Agency spacecraft Rosetta first approached it in July 2014. The bi-lobate structure of the cometary nucleus has led to much discussion regarding the possible manner of its formation and on how the composition of each lobe might compare with that of the other. During its two-year-long mission from 2014 to 2016, Rosetta remained in close proximity to 67P/Churyumov-Gerasimenko, studying its coma and nucleus in situ. Based on lobe-specific measurements of HDO and H2O performed with the ROSINA DFMS mass spectrometer on board Rosetta, the Deuterium-to-Hydrogen ratios in water from the two lobes could be compared. No appreciable difference was observed, suggesting that both lobes formed in the same region and are homogeneous in their Deuterium-to-Hydrogen ratios.

astro-ph.EP↗

arXiv2019

The $^{16}$O/$^{18}$O ratio in Water in the Coma of Comet 67P / Churyumov-Gerasimenko measured with the Rosetta / ROSINA Double-Focusing Mass Spectrometer

The European Space Agency (ESA) spacecraft Rosetta accompanied the Jupiter-family comet (JFC) 67P / Churyumov-Gerasimenko for over two years along its trajectory through the inner solar system. Between 2014 and 2016, it performed almost continuous in-situ measurements of the comet's gaseous atmosphere in close proximity to its nucleus. In this study, the $^{16}$O/$^{18}$O ratio of H$_2$O in the coma of 67P / Churyumov-Gerasimenko, as measured by the ROSINA DFMS mass spectrometer on board Rosetta, was determined from the ratio of H${_2}^{16}$O / H${_2}^{18}$O and $^{16}$OH / $^{18}$OH. The value of 445 $\pm$ 35 represents an $\sim$ 11% enrichment of $^{18}$O compared with the terrestrial ratio of 498.7 $\pm$ 0.1. This cometary value is consistent with the comet containing primordial water, in accordance with leading self-shielding models. These models predict primordial water to be between 5% to 20% enriched in heavier oxygen isotopes compared to terrestrial water. Addendum: The $^{16}$O/$^{17}$O ratio of H$_2$O in the coma of 67P / Churyumov-Gerasimenko.

astro-ph.EP↗

arXiv2018

Krypton isotopes and noble gas abundances in the coma of comet 67P/Churyumov-Gerasimenko

The ROSINA mass spectrometer DFMS on board ESA's Rosetta spacecraft detected the major isotopes of the noble gases argon, krypton, and xenon in the coma of comet 67P/Churyumov-Gerasimenko. Earlier, it has been shown that xenon exhibits an isotopic composition distinct from anywhere else in the solar system. However, argon isotopes, within error, were shown to be consistent with solar isotope abundances. This discrepancy suggested an additional exotic component of xenon in comet 67P/Churyumov-Gerasimenko. Here we show that also krypton exhibits an isotopic composition close to solar. Furthermore, we found a depletion compared to solar of argon with respect to krypton and of krypton with respect to xenon, which is a necessity to postulate an addition of exotic xenon in the comet.

astro-ph.EP↗

arXiv2018

Non-resonant Alfvénic instability activated by high temperature of ion beams in compensated-current astrophysical plasmas

Context: Compensated-current systems are established in response to hot ion beams in terrestrial foreshock regions, around supernova remnants, and in other space and astrophysical plasmas. Aims: We study a non-resonant reactive instability of Alfvén waves (AWs) propagating quasi-parallel to the background magnetic field $\mathbf{B}_{0}$ in such systems. Methods: The instability is investigated analytically in the framework of kinetic theory applied to the hydrogen plasmas penetrated by hot proton beams. Results: The instability arises at parallel wavenumbers $k_{z}$ that are sufficiently large to demagnetize the beam ions, $k_{z}V_{Tb}/ω_{Bi}\gtrsim $ $1$ (here $V_{Tb}$ is the beam thermal speed along $\mathbf{B}_{0}$ and $ω_{Bi}$ is the ion-cyclotron frequency). The Alfvén mode is then made unstable by the imbalance of perturbed currents carried by the magnetized background electrons and partially demagnetized beam ions. The destabilizing effects of the beam temperature and the temperature dependence of the instability threshold and growth rate are demonstrated for the first time. The beam temperature, density, and bulk speed are all destabilizing and can be combined in a single destabilizing factor $α_{b}$ triggering the instability at {$α_{b}>$ $α_{b}^{\mathrm{thr}}$}, where the threshold varies in a narrow range $2.43\leq $ $α_{b}^{\mathrm{thr}}\leq $ $4.87$. New analytical expressions for the instability growth rate and its boundary in the parameter space are obtained and can be directly compared with observations. Two applications to terrestrial foreshocks and foreshocks around supernova remnants are shortly discussed. In particular, our results suggest that the ions reflected by the shocks around supernova remnants can drive stronger instability than the cosmic rays.

physics.space-ph↗

arXiv2016

MHD-kinetic transition in imbalanced Alfvénic turbulence

Alfvénic turbulence in space is usually imbalanced: amplitudes of waves propagating parallel and anti-parallel to the mean magnetic field $B_0$ are unequal. It is commonly accepted that the turbulence is driven by (counter-)collisions between these counter-propagating wave fractions. Contrary to this, we found a new ion-scale dynamical range of the turbulence established by (co-)collisions among waves co-propagating in the same direction along $B_0$. Co-collisions become stronger than counter-collisions and produce steep non-universal spectra above certain wavenumbers dependent on the imbalance. Spectral indexes of the strong turbulence vary around -3, such that steeper spectra follow larger imbalances. Intermittency steepens the -3 spectra further, up to -3.7. Our theoretical predictions are compatible with steep variable spectra observed in the solar wind at ion kinetic scales, but further verifications are needed by correlating observed spectra with measured imbalances.

physics.space-ph↗

arXiv2011

Turbulent spectra and spectral kinks in the transition range from MHD to kinetic Alfvén turbulence

A weakly dispersive sub-range (WDR) of kinetic Alfvén turbulence is distinguished and investigated for the first time in the context of MHD/kinetic turbulence transition. We found perpendicular wavenumber spectra ~ k^{-3} and ~ k^{-4} formed in WDR by strong and weak turbulence of kinetic Alfvén waves (KAWs), respectively. These steep WDR spectra connect shallower spectra in the MHD and strongly dispersive KAW sub-ranges, which results in a specific double-kink (2-k) pattern often seen in observed turbulent spectra. The first kink occurs where MHD turbulence transforms into weakly dispersive KAW turbulence; the second one is between weakly and strongly dispersive KAW sub-ranges. Our analysis suggests that the partial turbulence dissipation due to amplitude-dependent super-adiabatic ion heating may occur in the vicinity of the first spectral kink. A threshold-like nature of this process results in a conditional selective dissipation affecting only largest over-threshold amplitudes and decreasing intermittency in the range below the first spectral kink. Several recent counter-intuitive observational findings can be explained by the selective dissipation coupled to the nonlinear interaction among weakly dispersive KAWs.

physics.space-ph↗