arXiv subjects

John A. Rogers

Publications and source records attributed to John A. Rogers.

6 recordsLinked to original sources

arXiv2026

Biodegradable, Millimeter-Scale Light-Emitting Sensors for Distributed Environmental Monitoring-Functional Pixie Dust

Methods for large-area, precise monitoring across natural environments are of growing interest due to pressing needs for sustainable management of rapidly increasing anthropogenic activities. Established approaches involve sparse spatial sampling and/or sequential measurements, while emerging techniques exploit miniaturized electronics or passive optical methods. Various constraints in scalability, costs, robustness, operational range and other factors create a need for alternatives. Here, we introduce a concept that overcomes many of these limitations through the combined use of chemically induced light emission and chemically responsive optical filter elements in millimeter-scale systems that we refer to as functional pixie dust (fPD) sensors, designed specifically for monitoring natural water systems during nighttime to eliminate background optical interference and to enhance remote analysis. These floating devices act as Lagrangian tracers to follow surface flows and to simultaneously measure the concentrations of key chemical species along their trajectories. Optimized designs exploit environmentally compatible constituent materials that are also degradable through natural processes to benign end products, thereby eliminating the need for recovery. Spatially and spectrally resolved ratiometric measurement schemes ensure robust operation and ability to address practical requirements in range, operational lifetime, time response and sensitivity. Demonstrations include distributed measurements of pH, Hg2+, and NO2-, each of relevance to industrial discharge, toxic metal contamination, and nitrogen-rich runoff, adapted for static concentration gradients, flow-driven transport conditions, and outdoor aquatic settings. The results establish a framework for environmental sensing using degradable, self-powered microsystems capable of scalable deployment and remote readout.

physics.app-ph↗

arXiv2023

The physical origin of aneurysm growth, dissection, and rupture

Rupture of aortic aneurysms is by far the most fatal heart disease, with a mortality rate exceeding 80%. There are no reliable clinical protocols to predict growth, dissection, and rupture because the fundamental physics driving aneurysm progression is unknown. Here, via in-vitro experiments, we show that a blood-wall, fluttering instability manifests in synthetic arteries under pulsatile forcing. We establish a phase space to prove that the transition from stable flow to unstable aortic flutter is accurately predicted by a flutter instability parameter derived from first principles. Time resolved strain maps of the evolving system reveal the dynamical characteristics of aortic flutter that drive aneurysm progression. We show that low level instability can trigger permanent aortic growth, even in the absence of material remodeling. Sufficiently large flutter beyond a secondary threshold localizes strain in the walls to the length scale clinically observed in aortic dissection. Lastly, significant physical flutter beyond a tertiary threshold can ultimately induce aneurysm rupture via failure modes reported from necropsy. Resolving the fundamental physics of aneurysm progression directly leads to clinical protocols that forecast growth as well as intercept dissection and rupture by pinpointing their physical origin.

q-bio.TO↗

arXiv2021

A dynamically reprogrammable metasurface with self-evolving shape morphing

Dynamic shape-morphing soft materials systems are ubiquitous in living organisms; they are also of rapidly increasing relevance to emerging technologies in soft machines, flexible electronics, and smart medicines. Soft matter equipped with responsive components can switch between designed shapes or structures, but cannot support the types of dynamic morphing capabilities needed to reproduce natural, continuous processes of interest for many applications. Challenges lie in the development of schemes to reprogram target shapes post fabrication, especially when complexities associated with the operating physics and disturbances from the environment can prohibit the use of deterministic theoretical models to guide inverse design and control strategies. Here, we present a mechanical metasurface constructed from a matrix of filamentary metal traces, driven by reprogrammable, distributed Lorentz forces that follow from passage of electrical currents in the presence of a static magnetic field. The resulting system demonstrates complex, dynamic morphing capabilities with response times within 0.1 s. Implementing an in-situ stereo-imaging feedback strategy with a digitally controlled actuation scheme guided by an optimization algorithm, yields surfaces that can self-evolve into a wide range of 3-dimensional (3D) target shapes with high precision, including an ability to morph against extrinsic or intrinsic perturbations. These concepts support a data-driven approach to the design of dynamic, soft matter, with many unique characteristics.

cond-mat.mtrl-sci↗

arXiv2013

High Performance Piezoelectric Devices Based on Aligned Arrays of Nanofibers of Poly[(vinylidenefluoride-co-trifluoroethylene]

Multifunctional capability, flexible design, rugged lightweight construction, and self-powered operation are desired attributes for electronics that directly interface with the human body or with advanced robotic systems. For these and related applications, piezoelectric materials, in forms that offer the ability to bend and stretch, are attractive for pressure/force sensors and mechanical energy harvesters. In this paper we introduce a large area, flexible piezoelectric material that consists of sheets of electrospun fibers of the polymer poly[(vinylidenefluoride-co-trifluoroethylene]. The flow and mechanical conditions associated with the spinning process yield free-standing, three-dimensional architectures of aligned arrangements of such fibers, in which the polymer chains adopt strongly preferential orientations. The resulting material offers exceptional piezoelectric characteristics, to enable, as an example, ultra-high sensitivity for measuring pressure, even at exceptionally small values (0.1 Pa). Quantitative analysis provides detailed insights into the pressure sensing mechanisms, and engineering design rules. Applications range from self-powered micro-mechanical elements, to self-balancing robots and sensitive impact detectors.

cond-mat.mtrl-sci↗

arXiv2010

Theoretical and Experimental Studies of Schottky Diodes That Use Aligned Arrays of Single Walled Carbon Nanotubes

We present theoretical and experimental studies of Schottky diodes that use aligned arrays of single walled carbon nanotubes. A simple physical model, taking into account the basic physics of current rectification, can adequately describe the single-tube and array devices. We show that for as grown array diodes, the rectification ratio, defined by the maximum-to-minimum-current-ratio, is low due to the presence of m-SWNT shunts. These tubes can be eliminated in a single voltage sweep resulting in a high rectification array device. Further analysis also shows that the channel resistance, and not the intrinsic nanotube diode properties, limits the rectification in devices with channel length up to ten micrometer.

cond-mat.mes-hall↗

arXiv2006

Gate Capacitance Coupling of Singled-walled Carbon Nanotube Thin-film Transistors

The electrostatic coupling between singled-walled carbon nanotube (SWNT) networks/arrays and planar gate electrodes in thin-film transistors (TFTs) is analyzed both in the quantum limit with an analytical model and in the classical limit with finite-element modeling. The computed capacitance depends on both the thickness of the gate dielectric and the average spacing between the tubes, with some dependence on the distribution of these spacings. Experiments on transistors that use sub-monolayer, random networks of SWNTs verify certain aspects of these calculations. The results are important for the development of networks or arrays of nanotubes as active layers in TFTs and other electronic devices.

cond-mat.mtrl-sci↗