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John Bowlan

Publications and source records attributed to John Bowlan.

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Duel-Evolve: Reward-Free Test-Time Scaling via LLM Self-Preferences

Many applications seek to optimize LLM outputs at test time by iteratively proposing, scoring, and refining candidates over a discrete output space. Existing methods use a calibrated scalar evaluator for the target objective to guide search, but for many tasks such scores are unavailable, too sparse, or unreliable. Pairwise comparisons, by contrast, are often easier to elicit, still provide useful signal on improvement directions, and can be obtained from the LLM itself without external supervision. Building on this observation, we introduce Duel-Evolve, an evolutionary optimization algorithm that replaces external scalar rewards with pairwise preferences elicited from the same LLM used to generate candidates. Duel-Evolve aggregates these noisy candidate comparisons via a Bayesian Bradley-Terry model, yielding uncertainty-aware estimates of candidate quality. These quality estimates guide allocation of the comparison budget toward plausible optima using Double Thompson Sampling, as well as selection of high-quality parents to generate improved candidates. We evaluate Duel-Evolve on MathBench, where it achieves 20 percentage points higher accuracy over existing methods and baselines, and on LiveCodeBench, where it improves over comparable iterative methods by over 12 percentage points. Notably, the method requires no reward model, no ground-truth labels during search, and no hand-crafted scoring function. Results show that pairwise self-preferences provide strong optimization signal for test-time improvement over large, discrete output spaces.

cs.LG

Evidence for the Alternating Next-Nearest Neighbor model in the dynamic behavior of a frustrated antiferromagnet

X-ray photon correlation spectroscopy (XPCS) enables us to study dynamics of antiferromagnets. Using coherent soft X-ray diffraction, we resonantly probe Mn and Co Bragg peaks in the frustrated magnetic chain compound Lu2CoMnO6 significantly below the Neel temperature. Bragg peaks of incommensurate order slide towards commensurate 'up up down down' order with decreasing temperature. Antiferromagnetic inhomogeneities produce speckle within the Bragg peaks, whose dynamics are probed by XPCS and compared to the classic Axial Next-Nearest Neighbor Interaction model of frustration. The data supports a novel model prediction: with decreasing temperature the dynamics become faster.

cond-mat.str-el

Manipulating Multiple Order Parameters via Oxygen Vacancies: The case of Eu0.5Ba0.5TiO3-δ

Controlling functionalities, such as magnetism or ferroelectricity, by means of oxygen vacancies (VO) is a key issue for the future development of transition metal oxides. Progress in this field is currently addressed through VO variations and their impact on mainly one order parameter. Here we reveal a new mechanism for tuning both magnetism and ferroelectricity simultaneously by using VO. Combined experimental and density-functional theory studies of Eu0.5Ba0.5TiO3-δ, we demonstrate that oxygen vacancies create Ti3+ 3d1 defect states, mediating the ferromagnetic coupling between the localized Eu 4f7 spins, and increase an off-center displacement of Ti ions, enhancing the ferroelectric Curie temperature. The dual function of Ti sites also promises a magnetoelectric coupling in the Eu0.5Ba0.5TiO3-δ.

cond-mat.mtrl-sci

Effects of biaxial strain on the improper multiferroicity in h-LuFeO3 films

Elastic strain is potentially an important approach in tuning the properties of the improperly multiferroic hexagonal ferrites, the details of which have however been elusive due to the experimental difficulties. Employing the method of restrained thermal expansion, we have studied the effect of isothermal biaxial strain in the basal plane of h-LuFeO3 (001) films. The results indicate that a compressive biaxial strain significantly enhances the ferrodistortion, and the effect is larger at higher temperatures. The compressive biaxial strain and the enhanced ferrodistortion together, cause an increase in the electric polarization and a reduction in the canting of the weak ferromagnetic moments in h-LuFeO3, according to our first principle calculations. These findings are important for understanding the strain effect as well as the coupling between the lattice and the improper multiferroicity in h-LuFeO3. The experimental elucidation of the strain effect in h-LuFeO3 films also suggests that the restrained thermal expansion can be a viable method to unravel the strain effect in many other epitaxial thin film materials.

cond-mat.mtrl-sci

Magnetism and exchange interaction of small rare-earth clusters; Tb as a representative

Here we follow, both experimentally and theoretically, the development of magnetism in Tb clusters from the atomic limit, adding one atom at a time. The exchange interaction is, surprisingly, observed to drastically increase compared to that of bulk, and to exhibit irregular oscillations as a function of the interatomic distance. From electronic structure theory we find that the theoretical magnetic moments oscillate with cluster size in exact agreement with experimental data. Unlike the bulk, the oscillation is not caused by the RKKY mechanism. Instead, the inter-atomic exchange is shown to be driven by a competition between wave-function overlap of the 5d shell and the on-site exchange interaction, which leads to a competition between ferromagnetic double-exchange and antiferromagnetic super-exchange. This understanding opens up new ways to tune the magnetic properties of rare-earth based magnets with nano-sized building blocks.

physics.atm-clus

Structure of Magnetic Lanthanide Clusters from Far-IR Spectroscopy: Tb (n = 5-9)

Small lanthanide clusters have interesting magnetic properties, but their structures are unknown. We have identified the structures of small terbium cluster cations Tb (n = 5-9) in the gas phase, by analysis of their vibrational spectra. The spectra have been measured via IR multiple photon dissociation of their complexes with Ar atoms in the 50-250 1/cm range with an infrared free electron laser. Density functional theory calculations using a 4f-in-core effective core potential (ECP) accurately reproduce the experimental far-IR spectra. The ECP corresponds to a 4f85d16s2 trivalent configuration of terbium. The assigned structures are similar to those observed in several other transition metal systems. From this, we conclude that the bonding in Tb clusters is through the interactions between the 5d and 6s electrons, and that the 4f electrons have only an indirect effect on the cluster structures.

physics.atm-clus

How Metallic are Small Sodium Clusters?

Cryogenic cluster beam experiments have provided crucial insights into the evolution of the metallic state from the atom to the bulk. Surprisingly, one of the most fundamental metallic properties, the ability of a metal to efficiently screen electric fields, is still poorly understood in small clusters. Theory has predicted that many small Na clusters are unable to screen charge inhomogeneities and thus have permanent dipole moments. High precision electric deflection experiments on cryogenically cooled Na$_N$ ($N<200$) clusters show that the electric dipole moments are at least an order of magnitude smaller than predicted, and are consistent with zero, as expected for a metal. The polarizabilities of Na clusters also show metal spheroid behavior, with fine size oscillations caused by the shell structure.

physics.atm-clus

Bistability of Free Cobalt and Iron Clusters

The cobalt and iron clusters CoN, FeN (20 < N < 150) measured in a cryogenic molecular beam are found to be bistable with magnetic moments per atom both μN/N 2μB in the ground states and μN */N μB in the metastable excited states (for iron clusters, μN ~3NμB and μN* NμB). This energy gap between the two states vanish for large clusters, which explains the rapid convergence of the magnetic moments to the bulk value and suggests that ground state for the bulk involves a superposition of the two, in line with the fluctuating local orders in the bulk itinerant ferromagnetism.

cond-mat.str-el

Non-classical dipoles in cold niobium clusters

Electric deflections of niobium clusters in molecular beams show that they have permanent electric dipole moments at cryogenic temperatures but not higher temperatures, indicating that they are ferroelectric. Detailed analysis shows that the deflections cannot be explained in terms of a rotating classical dipole, as claimed by Anderson et al. The shapes of the deflected beam profiles and their field and temperature dependences indicates that the clusters can exist in two states, one with a dipole and the other without. Cluster with dipoles occupy lower energy states. Excitations from the lower states to the higher states can be induced by low fluence laser excitation. This causes the dipole to vanish.

cond-mat.str-el