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John Goold

Publications and source records attributed to John Goold.

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New Spin Squeezing and Other Entanglement Tests for Two Mode Systems of Identical Bosons

For any quantum state representing a physical system of identical particles, the density operator must satisfy the symmetrisation principle (SP) and for massive particles also conform to super-selection rules (SSR) that prohibit coherences between differing total particle numbers. Here we consider bi-partitite states for systems of massive bosons, where both the system and subsystems are modes (or sets of modes), particles being associated with differing mode occupancies. To define non-entangled or separable states the subsystem density operators are also required to satisfy the SP and conform to SSR, in contrast to some other approaches. Whilst in the presence of these additional constraints some of the known entanglement criteria are still valid, we present a detailed treatment to establish the validity of known criteria and derive new ones.

quant-ph↗

Quantum Entanglement for Systems of Identical Bosons. Spin Squeezing and Other Entanglement Tests in Two Mode Systems

The concept of entangled quantum states is considered in the context of systems of identical particles, based on the requirement that in order to represent physical states both for the overall system and the sub-systems which may be entangled, the density operators must satisfy the symmetrisation principle and global and local super-selection rules that prohibit states in which there are coherences between differing particle numbers. These requirements and their justification are fully discussed. In the second quantisation approach used, both the system and the sub-systems are modes (or sets of modes) rather than particles, particles being associated with different occupancies of the modes. The definition of entangled states is based on first defining the non-entangled states - after specifying which modes constitute the sub-systems. This paper mainly focuses on two mode entanglement for massive bosons. Several inequalities involving variances and mean values of operators involving mode annihilation, creation operators have been proposed as tests for two mode entangled states, including the inequalities that define spin squeezing. Spin squeezing criteria in two mode systems are examined, and spin squeezing is best considered for principle spin operator components where the covariance matrix is diagonal. It is shown that the presence of spin squeezing in at least one of the spin components requires entanglement of the relevant pair of modes. Several of the other proposed tests for entanglement, including ones based on the sum of the variances for two spin components are considered. All of the tests are still valid when the present concept of entanglement based on the symmetrisation and super-selection rule criteria is applied, but further tests have been obtained here. Sometimes the new tests are satisfied whilst than those obtained in other papers are not.

quant-ph↗

Comment on "Quantum Szilard Engine"

In a recently published letter [S. W. Kim, T. Sagawa, S. DeLiberato, and M. Ueda, PRL 106, 070401 (2011)] the influence of particle statistics on extractable work in the Szilard engine was discussed. We point out that the expressions given there suggest no work extraction is possible in the low temperature limit if more than two particles are used and thus are not optimal. We argue that the optimal extractable work is in general higher and in particular non-decreasing in the number of particles.

quant-ph↗

Experimental reconstruction of work distribution and verification of fluctuation relations at the full quantum level

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski relations: taking into account fluctuations in non-equilibrium dynamics, such relations connect equilibrium properties of thermodynamical relevance with explicit non-equilibrium features. Although the experimental verification of such fundamental relations in the classical domain has encountered some success, their quantum mechanical version requires the assessment of the statistics of work performed by or onto an evolving quantum system, a step that has so far encountered considerable difficulties in its implementation due to the practical difficulty to perform reliable projective measurements of instantaneous energy states. In this paper, by exploiting a radical change in the characterization of the work distribution at the quantum level, we report the first experimental verification of the quantum Jarzynski identity and the Tasaki-Crooks relation following a quantum process implemented in a Nuclear Magnetic Resonance (NMR) system. Our experimental approach has enabled the full characterisation of the out-of-equilibrium dynamics of a quantum spin in a statistically significant way, thus embodying a key step towards the grounding of quantum-systems thermodynamics.

quant-ph↗

Emergent thermodynamics in a quenched quantum many-body system

We study the statistics of the work done, the fluctuation relations and the irreversible entropy production in a quantum many-body system subject to the sudden quench of a control parameter. By treating the quench as a thermodynamic transformation we show that the emergence of irreversibility in the nonequilibrium dynamics of closed many-body quantum systems can be accurately characterized. We demonstrate our ideas by considering a transverse quantum Ising model that is taken out of equilibrium by the instantaneous switching of the transverse field.

cond-mat.stat-mech↗

Non-Markovianity, Loschmidt echo and criticality: a unified picture

A simple relationship between recently proposed measures of non-Markovianity and the Loschmidt echo is established, holding for a two-level system (qubit) undergoing pure dephasing due to a coupling with a many-body environment. We show that the Loschmidt echo is intimately related to the information flowing out from and occasionally back into the system. This, in turn, determines the non-Markovianity of the reduced dynamics. In particular, we consider a central qubit coupled to a quantum Ising ring in the transverse field. In this context, the information flux between system and environment is strongly affected by the environmental criticality; the qubit dynamics is shown to be Markovian exactly and only at the critical point. Therefore non-Markovianity is an indicator of criticality in the model considered here.

quant-ph↗

Toward quantum simulations of biological information flow

Recent advances in the spectroscopy of biomolecules have highlighted the possibility of quantum coherence playing an active role in biological energy transport. The revelation that quantum coherence can survive in the hot and wet environment of biology has generated a lively debate across both the physics and biology communities. In particular, it remains unclear to what extent non-trivial quantum effects are utilised in biology and what advantage, if any, they afford. We propose an analogue quantum simulator, based on currently available techniques in ultra-cold atom physics, to study a model of energy and electron transport based on the Holstein Hamiltonian By simulating the salient aspects of a biological system in a tunable laboratory setup, we hope to gain insight into the validity of several theoretical models of biological quantum transport in a variety of relevant parameter regimes.

quant-ph↗

Measurement and Particle Statistics in the Szilard Engine

A Szilard Engine is a hypothetical device which is able to extract work from a single thermal reservoir by measuring the position of particles within the engine. We derive the amount of work that can be extracted from such a device in the low temperature limit. Interestingly, we show this work is determined by the information gain of the initial measurement rather than by the number and type of particles which constitute the working substance. Our work provides another clear connection between information gain and extractable work in thermodynamical processes.

quant-ph↗

Quantum coherent contributions in biological electron transfer

Many biological electron transfer (ET) reactions are mediated by metal centres in proteins. NADH:ubiquinone oxidoreductase (complex I) contains an intramolecular chain of seven iron-sulphur (FeS) clusters, one of the longest chains of metal centres in biology and a test case for physical models of intramolecular ET. In biology, intramolecular ET is commonly described as a diffusive hopping process, according to the semi-classical theories of Marcus and Hopfield. However, recent studies have raised the possibility that non-trivial quantum mechanical effects play a functioning role in certain biomolecular processes. Here, we extend the semi-classical model for biological ET to incorporate both semi-classical and coherent quantum phenomena using a quantum master equation based on the Holstein Hamiltonian. We test our model on the structurally-defined chain of FeS clusters in complex I. By exploring a wide range of realistic parameters we find that, when the energy profile for ET along the chain is relatively flat, just a small coherent contribution can provide a robust and significant increase in ET rate (above the semi-classical diffusive-hopping rate), even at physiologically-relevant temperatures. Conversely, when the on-site energies vary significantly along the chain the coherent contribution is negligible. For complex I, a crucial respiratory enzyme that is linked to many neuromuscular and degenerative diseases, our results suggest a new contribution towards ensuring that intramolecular ET does not limit the rate of catalysis. For the emerging field of quantum biology, our model is intended as a basis for elucidating the general role of coherent ET in biological ET reactions.

q-bio.BM↗

Non-locality of Two Ultracold Trapped Atoms

We undertake a detailed analysis of the non-local properties of the fundamental problem of two trapped, distinguishable neutral atoms which interact with a short range potential characterised by an s-wave scattering length. We show that this interaction generates continuous variable (CV) entanglement between the external degrees of freedom of the atoms and consider its behaviour as a function of both, the distance between the traps and the magnitude of the inter-particle scattering length. We first quantify the entanglement in the ground state of the system at zero temperature and then, adopting a phase-space approach, test the violation of the Clauser-Horn-Shimony-Holt inequality at zero and non-zero temperature and under the effects of general dissipative local environments.

quant-ph↗