arXiv subjects

John L. Bohn

Publications and source records attributed to John L. Bohn.

At least 73 records · Page 4Linked to original sources

arXiv2012

A Dielectric Superfluid of Polar Molecules

We show that, under achievable experimental conditions, a Bose-Einstein condensate (BEC) of polar molecules can exhibit dielectric character. In particular, we derive a set of self-consistent mean-field equations that couple the condensate density to its electric dipole field, leading to the emergence of polarization modes that are coupled to the rich quasiparticle spectrum of the condensate. While the usual roton instability is suppressed in this system, the coupling can give rise to a phonon-like instability that is characteristic of a dielectric material with a negative static dielectric function.

cond-mat.quant-gas↗

arXiv2012

Statistical Aspects of Ultracold Resonant Scattering

Compared to purely atomic collisions, ultracold collisions involving molecules have the potential to support a much larger number of Fano-Feshbach resonances due to the huge amount of ro-vibrational states available. In order to handle such ultracold atom-molecule collisions, we formulate a theory that incorporates the ro-vibrational Fano-Feshbach resonances in a statistical manner while treating the physics of the long-range scattering, which is sensitive to such things as hyperfine states, collision energy and any applied electromagnetic fields, exactly within multichannel quantum defect theory. Uniting these two techniques, we can assess the influence of highly resonant scattering in the threshold regime, and in particular its dependence on the hyperfine state selected for the collision. This allows us to explore the onset of Ericson fluctuations in the regime of overlapping resonances, which are well-known in nuclear physics but completely unexplored in the ultracold domain.

physics.atom-ph↗

arXiv2011

Universalities in ultracold reactions of alkali polar molecules

We consider ultracold collisions of ground-state, heteronuclear alkali dimers that are susceptible to four-center chemical reactions 2 AB -> A2 + B2 even at sub-microKelvin temperature. These reactions depend strongly on species, temperature, electric field, and confinement in an optical lattice. We calculate ab initio van der Walls coefficients for these interactions, and use a quantum formalism to study the scattering properties of such molecules under an external electric field and optical lattice. We also apply a quantum threshold model to explore the dependence of reaction rates on the various parameters. We find that, among the heteronuclear alkali fermionic species, LiNa is the least reactive, whereas LiCs is the most reactive. For the bosonic species, LiK is the most reactive in zero field, but all species considered - LiNa, LiK, LiRb, LiCs, and KRb - share a universal reaction rate once a sufficiently high electric field is applied.

physics.atom-ph↗

arXiv2011

On Measuring the Electron Electric Dipole Moment in Trapped Molecular Ions

Trapped diatomic molecular ions could prove to be a sensitive probe for a permanent electron electric dipole moment (eEDM). We propose to use a ground or metastable $^3Δ_1$ level, due to its high polarizability and large EDM enhancement factor. Ions allow for simple trapping and long interrogation times, but require a time-varying electric bias field in order to probe the eEDM. We discuss experimental design as well as challenges in performing a precision spectroscopic measurement in rapidly time-varying electric fields.

physics.atom-ph↗

arXiv2011

Chemical pathways in ultracold reactions of SrF molecules

We present a theoretical investigation of the chemical reaction SrF + SrF $\rightarrow$ products, focusing on reactions at ultralow temperatures. We find that bond swapping, SrF + SrF $\rightarrow$ Sr$_2$ + F$_2$, is energetically forbidden at these temperatures. Rather, the only energetically allowed reaction is SrF + SrF $\rightarrow$ SrF$_2$ + Sr, and even then only singlet states of the SrF$_2$ trimer can form. A calculation along a reduced reaction path demonstrates that this abstraction reaction is barrierless, and proceeds by one SrF molecule "handing off" a fluorine atom to the other molecule.

physics.atom-ph↗

arXiv2010

Emergent structure in a dipolar Bose gas in a one-dimensional lattice

We consider an ultracold dipolar Bose gas in a one-dimensional lattice. For a sufficiently large lattice recoil energy, such a system becomes a series of non-overlapping Bose-Einstein condensates that interact via the long-range dipole-dipole interaction (ddi). We model this system via a coupled set of non-local Gross-Pitaevskii equations (GPEs) for lattices of both infinite and finite extent. We find significantly modified stability properties in the lattice due to the softening of a discrete roton-like mode, as well as "islands" in parameter space where biconcave densities are predicted to exist that only exist in the presence of the other condensates on the lattice. We solve for the elementary excitations of the system to check the dynamical stability of these solutions and to uncover the nature of their collapse. By solving a coupled set of GPEs exactly on a full numeric grid, we show that this emergent biconcave structure can be realized in a finite lattice with atomic $^{52}$Cr.

cond-mat.quant-gas↗

arXiv2010

Anisotropic superfluidity in a dipolar Bose gas

We study the superfluid character of a dipolar Bose-Einstein condensate (DBEC) in a quasi-two dimensional (q2D) geometry. In particular, we allow for the dipole polarization to have some non-zero projection into the plane of the condensate so that the effective interaction is anisotropic in this plane, yielding an anisotropic dispersion for propagation of quasiparticles. By performing direct numerical simulations of a probe moving through the DBEC, we observe the sudden onset of drag or creation of vortex-antivortex pairs at critical velocities that depend strongly on the direction of the probe's motion. This anisotropy emerges because of the anisotropic manifestation of a roton-like mode in the system.

cond-mat.quant-gas↗

arXiv2010

Dynamics of ultracold molecules in confined geometry and electric field

We present a time-independent quantum formalism to describe the dynamics of molecules with permanent electric dipole moments in a two-dimensional confined geometry such as a one-dimensional optical lattice, in the presence of an electric field. Bose/Fermi statistics and selection rules play a crucial role in the dynamics. As examples, we compare the dynamics of confined fermionic and bosonic polar KRb molecules under different confinements and electric fields. We show how chemical reactions can be suppressed, either by a "statistical suppression" which applies for fermions at small electric fields and confinements, or by a "potential energy suppression", which applies for both fermions and bosons at high electric fields and confinements. We also explore collisions that transfer molecules from one state of the confining potential to another. Although these collisions can be significant, we show that they do not play a role in the loss of the total number of molecules in the gas.

physics.atom-ph↗

arXiv2010

A Simple Quantum Model of Ultracold Polar Molecule Collisions

We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of long-range forces before they ultimately encounter one another, followed by a probability for the reaction to occur once they do. In this way, the electric-field dependence should be readily parametrized in terms of a pair of fitting parameters (along with a $C_6$ coefficient) for each asymptotic value of partial wave quantum numbers $|L,M \rangle$. From this, the electric field dependence of the collision rates follows automatically. We present examples for reactive species such as KRb, and non-reactive species, such as RbCs.

quant-ph↗

arXiv2010

Product state control of bi-alkali chemical reactions

We consider ultracold, chemically reactive scattering collisions of the diatomic molecules KRb. When two such molecules collide in an ultracold gas, we find that they are energetically forbidden from reacting to form the trimer species K$_2$Rb or Rb$_2$K, hence can only react via the bond-swapping reaction 2KRb $\to$ K$_2$ + Rb$_2$. Moreover, the tiny energy released in this reaction can in principle be set to zero by applying electric or microwave fields, implying a means of controlling the available reaction channels in a chemical reaction.

physics.atom-ph↗

arXiv2010

Electric field suppression of ultracold confined chemical rates

We consider ultracold collisions of polar molecules confined in a one dimensional optical lattice. Using a quantum scattering formalism and a frame transformation method, we calculate elastic and chemical quenching rate constants for fermionic molecules. Taking KRb molecules as a prototype, we find that the rate of quenching collisions is enhanced at zero electric field as the confinement is increased, but that this rate is suppressed when the electric field is turned on. For molecules with 500 nK of collision energy, for realistic molecular densities, and for achievable experimental electric fields and trap confinements, we predict lifetimes of KRb molecules of 1 s. We find a ratio of elastic to quenching collision rates of about 100, which may be sufficient to achieve efficient experimental evaporative cooling of polar KRb molecules.

physics.atom-ph↗

arXiv2010

Stability and Excitations of a Dipolar Bose-Einstein Condensate with a Vortex

We study the stability of singly- and doubly-quantized vortex states of harmonically trapped dipolar Bose-Einstein Condensates (BECs) by calculating the low-lying excitations of these condensates. We map the dynamical stability of these vortices as functions of the dipole-dipole interaction strength and trap geometry by finding where their excitations have purely real energy eigenvalues. In contrast to BECs with purely contact interactions, we find that dipolar BECs in singly-quantized vortex states go unstable to modes with an increasing number of angular and radial nodes for more oblate trap aspect ratios, corresponding to \emph{local} collapse that occurs on a characteristic length scale. Additionally, we find that dipolar BECs in doubly-quantized vortex states are unstable to decay into a different topological state (with two singly-quantized vortices) for all interaction strengths when the trap geometry is sufficiently prolate to make the dipoles attractive, and in windows of interaction strength when the trap geometry is sufficiently oblate to make the dipoles repulsive.

cond-mat.other↗

arXiv2010

Angular collapse of dipolar Bose-Einstein condensates

We explore the structure and dynamics of dipolar Bose-Einstein condensates (DBECs) near their threshold for instability. Near this threshold a DBEC may exhibit nontrivial, biconcave density distributions, which are associated with instability against collapse into "angular roton" modes. Here we discuss experimental signatures of these novel features. In the first, we infer local collapse of the DBEC from the experimental stability diagram. In the second, we explore the dynamics of collapse and find that a nontrivial angular distribution is a signature of the DBEC possessing a biconcave structure.

cond-mat.quant-gas↗

arXiv2010

Manifestations of the Roton Mode in Dipolar Bose-Einstein Condensates

We investigate the structure of trapped Bose-Einstein condensates (BECs) with long-range anisotropic dipolar interactions. We find that a small perturbation in the trapping potential can lead to dramatic changes in the condensate's density profile for sufficiently large dipolar interaction strengths and trap aspect ratios. By employing perturbation theory, we relate these oscillations to a previously-identified "roton-like" mode in dipolar BECs. The same physics is responsible for radial density oscillations in vortex states of dipolar BECs that have been predicted previously.

cond-mat.other↗

arXiv2010

Critical superfluid velocity in a trapped dipolar gas

We investigate the superfluid properties of a dipolar Bose-Einstein condensate (BEC) in a fully three-dimensional trap. Specifically, we calculate a superfluid critical velocity for this system by applying the Landau criterion to its discrete quasiparticle spectrum. We test this critical velocity by direct numerical simulation of condensate depletion as a blue-detuned laser moves through the condensate. In both cases, the presence of the roton in the spectrum serves to lower the critical velocity beyond a critical particle number. Since the shape of the dispersion, and hence the roton minimum, is tunable as a function of particle number, we thereby propose an experiment that can simultaneously measure the Landau critical velocity of a dipolar BEC and demonstrate the presence of the roton in this system.

cond-mat.quant-gas↗

arXiv2010

Strong dependence of ultracold chemical rates on electric dipole moments

We use the quantum threshold laws combined with a classical capture model to provide an analytical estimate of the chemical quenching cross sections and rate coefficients of two colliding particles at ultralow temperatures. We apply this quantum threshold model (QT model) to indistinguishable fermionic polar molecules in an electric field. At ultracold temperatures and in weak electric fields, the cross sections and rate coefficients depend only weakly on the electric dipole moment d induced by the electric field. In stronger electric fields, the quenching processes scale as d^{4(L+1/2)} where L>0 is the orbital angular momentum quantum number between the two colliding particles. For p-wave collisions (L=1) of indistinguishable fermionic polar molecules at ultracold temperatures, the quenching rate thus scales as d^6. We also apply this model to pure two dimensional collisions and find that chemical rates vanish as d^{-4} for ultracold indistinguishable fermions. This model provides a quick and intuitive way to estimate chemical rate coefficients of reactions occuring with high probability.

physics.atom-ph↗

arXiv2009

Zero Sound in Dipolar Fermi Gases

We study the propagation of sound in a homogeneous dipolar gas at zero temperature, known as zero sound. We find that undamped sound propagation is possible only in a range of solid angles around the direction of polarization of the dipoles. Above a critical dipole moment, we find an unstable mode, by which the gas collapses locally perpendicular to the dipoles' direction.

cond-mat.quant-gas↗

arXiv2009

Berry-like phases in structured atoms and molecules

Quantum mechanical phases arising from a periodically varying Hamiltonian are considered. These phases are derived from the eigenvalues of a stationary, ``dressed'' Hamiltonian that is able to treat internal atomic or molecular structure in addition to the time variation. In the limit of an adiabatic time variation, the usual Berry phase is recovered. For more rapid variation, non-adiabatic corrections to the Berry phase are recovered in perturbation theory, and their explicit dependence on internal structure emerges. Simple demonstrations of this formalism are given, to particles containing interacting spins, and to molecules in electric fields.

physics.atm-clus↗