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John L. Bohn

Publications and source records attributed to John L. Bohn.

94 records · Page 6Linked to original sources

Magnetic field effects in ultracold molecular collisions

We investigate the collisional stability of magnetically trapped ultracold molecules, taking into account the influence of magnetic fields. We compute elastic and spin-state-changing inelastic rate constants for collisions of the prototype molecule $^{17}$O$_2$ with a $^3$He buffer gas as a function of the magnetic field and the translational collision energy. We find that spin-state-changing collisions are suppressed by Wigner's threshold laws as long as the asymptotic Zeeman splitting between incident and final states does not exceed the height of the centrifugal barrier in the exit channel. In addition, we propose a useful one-parameter fitting formula that describes the threshold behavior of the inelastic rates as a function of the field and collision energy. Results show a semi-quantitative agreement of this formula with the full quantum calculations, and suggest useful applications also to different systems. As an example, we predict the low-energy rate constants relevant to evaporative cooling of molecular oxygen.

quant-ph↗

Ultracold collisions of oxygen molecules

Collision cross sections and rate constants between two ground- state oxygen molecules are investigated theoretically at translational energies below $\sim 1$K and in zero magnetic field. We present calculations for elastic and spin- changing inelastic collision rates for different isotopic combinations of oxygen atoms as a prelude to understanding their collisional stability in ultracold magnetic traps. A numerical analysis has been made in the framework of a rigid- rotor model that accounts fully for the singlet, triplet, and quintet potential energy surfaces in this system. The results offer insights into the effectiveness of evaporative cooling and the properties of molecular Bose- Einstein condensates, as well as estimates of collisional lifetimes in magnetic traps. Specifically, $^{17}O_{2}$ looks like a good candidate for ultracold studies, while $^{16}O_{2}$ is unlikely to survive evaporative cooling. Since $^{17}O_{2}$ is representative of a wide class of molecules that are paramagnetic in their ground state we conclude that many molecules can be successfully magnetically trapped at ultralow temperatures.

physics.atom-ph↗

Inelastic Collisions of Ultracold Polar Molecules

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-field-seeking to strong-field-seeking states are estimated using a simple model. The rates are found to be quite large, of order 10^{-12} - 10^{-10} cm^3/sec, and moreover to grow rapidly in an externally applied electric field. It is argued that these results are generic for polar molecules, and that therefore polar molecules should be trapped by other than electrostatic means.

physics.atom-ph↗

Cooper Pairing in Ultracold K-40 Using Feshbach Resonances

We point out that the fermionic isotope K-40 is a likely candidate for the formation of Cooper pairs in an ultracold atomic gas. Specifically, in an optical trap that simultaneously traps the spin states |9/2,-9/2> and |9/2,-7/2>, there exists a broad magnetic field Feshbach resonance at B = 196 gauss that can provide the required strong attractive interaction between atoms. An additional resonance, at B = 191 gauss, could generate p-wave pairing between identical |9/2,-7/2> atoms. A Cooper-paired degenerate Fermi gas could thus be constructed with existing ultracold atom technology.

cond-mat↗