Molecular Similarity and Water Diversity in Coeval Binary Disks: JWST/MIRI Observations of Sz 65 and Sz 66
We present JWST/MIRI Medium Resolution Spectrometer spectra of the wide-separation (projected separation $= 980$ au) binary protoplanetary disks Sz 65 (K7; $0.68~M_{\odot}$) and Sz 66 (M3; $0.30~M_{\odot}$), reduced using the uniform pipeline of the JWST Disk Infrared Spectral Chemistry Survey. Both disks show rich molecular emission, including H$_2$O, CO$_2$, HCN, C$_2$H$_2$, and OH. The scaled spectra of the two disks exhibit remarkably similar H$_2$O, CO$_2$, and HCN line emission in the 13--18 $μ$m region, with the only notable difference being stronger C$_2$H$_2$ emission in the primary (Sz 65). Beyond 18 $μ$m, the difference in H$_2$O line emission between the two disks increases. Both the flux ratios and the slab-model-derived mass ratios of cold to hot H$_2$O ($\sim$200 K to $\sim$750 K) and warm to hot H$_2$O ($\sim$450 K to $\sim$750 K) are significantly higher in the secondary (Sz 66). Because binary stars share nearly the same age and metallicity, and as both disks appear compact in millimeter emission ($<30$ au), we suggest that the excess cold H$_2$O in the secondary is best explained by its unstructured dust disk, in contrast to the primary, which shows gaps at 6 and 20 au. The enhanced cold water in the secondary is consistent with efficient pebble drift across the water snow line and increased H$_2$O vapor from the sublimation of icy mantles. Our results demonstrate that wide-separation binaries can serve as powerful control samples for isolating the impact of individual disk properties on inner-disk chemistry and evolution.