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John W. Noonan

Publications and source records attributed to John W. Noonan.

At least 19 recordsLinked to original sources

An Enriched Methane D/H Ratio in the Interstellar Object 3I/ATLAS

Interstellar objects are interlopers from other planetary systems, and their volatile compositions provide a glimpse into planet formation around their host star. We present near-infrared spectra of the coma of interstellar object 3I/ATLAS measured with the James Webb Space Telescope. Our results demonstrate an unexpectedly high D/H = $(3.33\pm0.31)\%$ for methane and represent an exceedingly rare detection of deuterated organic molecules in an interstellar object. This D/H ratio exceeds any other value for methane measured in the solar system, and is a factor of $14\pm2$ higher than that measured in comet 67P/Churyumov-Gerasimenko by the Rosetta spacecraft, the only other comet for which CH$_3$D has been detected. Both 3I/ATLAS and 67P/Churyumov-Gerasimenko show a higher degree of methane dueteration compared to water, consistent with trends seen in other solar system bodies and the nearby interstellar medium, where deuteration in organics exceeds that of water by up to an order of magnitude. The D/H ratio in methane itself is observationally unconstrained in extrasolar sources to date, but the enriched ratio in 3I/ATLAS is similar to those measured in methanol and formaldehyde toward primitive environments. The elevated D/H ratio for methane in 3I/ATLAS is consistent with the hypothesis that its ices formed in a cold, low metallicity interstellar or protostellar environment under a high cosmic ray irradiation rate (Cordiner et al. 2026).

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JWST Characterization of Earth Quasi-Satellite (469219) Kamo`oalewa

Near-Earth asteroid (469219) Kamo`oalewa is a uniquely stable quasi-satellite of the Earth and a target of the Tianwen-2 spacecraft mission. Here we report observations taken with JWST's NIRSpec instrument in integral field unit (IFU) mode in February 2026. The JWST reflectance spectrum is notably less red (more neutral) from $1.0-2.5$ $μm$ than previous ground-based spectrophotometric observations. New observations made with LBT in April 2026, observed and processed similarly to the 2021 observations, find $zJ$ colors in agreement with JWST. Kamo`oalewa's infrared colors appear more similar to S, V, or E-type silicate asteroids and unlike the reddened, space-weathered lunar-like silicates suggested by previous observations. In agreement with the ground-based spectrum, we detect a faint silicate absorption feature at $0.93\pm 0.01$ $μm$. We do not detect a 2.0 $μm$ silicate absorption. Models of Kamo`oalewa's faint thermal emission (beginning near 4.5 $μm$) find a mean diameter of $D=18\pm2\mathrm{m}$ and best-fit visible albedo $p_V = 0.59^{+0.25}_{-0.17}$, with models as low as $p_V = 0.36$ providing adequate model fits. This combination of color, albedo, and absorption bands is similar to oldhamite-bearing enstatite-rich compositions. Kamo`oalewa's brightness variations over the course of the JWST program provides independent confirmation of its rotation period of 27.9 minutes, with an axis ratio $\sim1.4$ ($D\sim15-21$ m).

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Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance ($r_H$) of $2.37-2.41$ au. These measurements of CO, CO$_2$, H$_2$O, CH$_3$OH, and CH$_4$ sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the H$_2$O ice line -- the region between $r_H$ = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and CO$_2$ begin to control the overall activity. CO was the most abundant molecule, followed by H$_2$O and CO$_2$, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for H$_2$O were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

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Emerging Diversity Among the Main-Belt Comets: Insights from JWST and Ground-Based Observations of 457P/Lemmon-PANSTARRS

We present JWST NIRSpec and NIRCam observations of 457P/Lemmon-PANSTARRS, a main-belt comet that displayed activity around its 2020 perihelion and that was observed to regain activity during its 2024 perihelion by a ground-based observing campaign. The previous successful measurements of water production from two main-belt comets by the JWST NIRSpec instrument confirmed the hypothesis that H2O reservoirs are responsible for activity in dynamically stable main-belt comets. However, the main-belt comets observed with JWST thus far, 238P/Read and 358P/PANSTARRS, occupy orbits in the outer main-belt, with main-belt comets with smaller semi-major axes not yet sensitively tested for H2O. We find that despite clearly displaying dust activity in both ground-based and JWST imaging over a broad period, there were no corresponding H2O, CO, CO2, or CH3OH emissions within sensitive upper limits; notable given 457P is the first main-belt comet with a semi-major axis within the 5:2 mean-motion resonance with Jupiter. We show that we were sensitive to production rates of gas predicted by the dust/gas ratios of 238P and 358P, and hypothesize that 457P may be more depleted than its companions; Q(H2O) must be less than 2x10^24 molecules/s, or 0.035 kg/s. Further surveying of main-belt comets across the parameter space of semi-major axis and eccentricity will shed light on whether 457P represents an edge member of a spectrum or a distinct subclass of main-belt comets.

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Characterization of the Volatile Properties of 133P/Elst-Pizarro and Other Main-Belt Comets with JWST and Ground-Based Observations

We report results from an analysis of the volatile composition and evolution of main-belt comet (MBC) 133P/Elst-Pizarro using JWST NIRSpec and NIRCam observations and ground-based observations during its 2024 active apparition, and also assess the body of JWST MBC observations acquired to date. Using NIRSpec, we measure water vapor outgassing rates at two points in 133P's orbit, finding Q(H2O)=(1.9+/-0.6)x10^25 molecules/s on UT 2024 June 12 (at a true anomaly of nu=8 deg and heliocentric distance of rh=2.674 au), and Q(H2O)=(1.4+/-0.4)x10^25 molecules/s on UT 2024 October 14 (at nu=37.4 deg and rh=2.747 au). These measurements nominally represent a decline of ~25% in Q(H2O) between the visits, although they are also consistent with no change within uncertainties. We do not detect CO, CO2, or CH3OH, placing 133P's hypervolatile depletion (Q(CO2)/Q(H_2O)<0.009) at a similar level found for previously observed MBCs. We find log(Afrho/Q(H2O)) values for the three MBCs for which water vapor outgassing has been successfully detected that are consistent within uncertainties with an average value of log(Afrho/Q(H2O))=-24.6+/-0.2. Lastly, we find no clear correlations of water production rates with nucleus size, semimajor axis, or heliocentric distance among MBCs observed by JWST so far, but would particularly encourage future JWST observations of additional MBCs interior to the 5A:2J MMR with Jupiter and at high inclinations, as well as multiple observations of MBCs during single active apparitions to further investigate areas of interest identified from the current sample of JWST-observed MBCs.

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Water D/H in 3I/ATLAS as a Probe of Formation Conditions in Another Planetary System

Water reservoirs in the Solar System exhibit a deuterium enrichment that links back to the physical environment at the time of stellar birth. Gas-phase and ice-grain deuterium enrichments occur through chemical processes that operate at low temperatures ($<$~30~K) pointing towards an origin in the prestellar molecular cloud or in the outer parts of the protoplanetary disk. However, not all stars are born in environments similar to our Sun, nor do their subsequent evolutionary histories follow the same path. These environmental differences can be traced by the water deuterium-to-hydrogen (D/H) ratio. Here we use ALMA observations of the interstellar comet 3I/ATLAS to constrain the water D/H ratio in extrasolar cometary material. With a water D/H value of [D/H]$_{\mathrm{H_2O}} > 6.6\times10^{-3}$, 3I/ATLAS shows a deuterium enrichment exceeding Earth's ocean value by more than a factor of $\gtrsim40$ and typical Solar System cometary values by more than a factor of $\gtrsim30$. The elevated deuterium enrichment points to water that formed under colder, less irradiated conditions and from less thermally processed material, consistent with an origin in a planetary system that formed under different physical and chemical conditions than our own.

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Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS

Interstellar objects provide the only directly observable samples of icy planetesimals formed around other stars, and can therefore provide insight into the diversity of physical and chemical conditions occurring during exoplanet formation. Here we report isotopic measurements of the interstellar comet 3I/ATLAS, which reveal an elemental composition unlike any Solar System body. The water in 3I/ATLAS is enriched in deuterium, at a level of D/H = (0.95 +- 0.06)%, which is more than an order of magnitude higher than in known comets, while its range of 12C/13C ratios (141-191 for CO2 and 123-172 for CO) exceeds typical values found in the Solar System, as well as nearby interstellar clouds and protoplanetary disks. Such extreme isotopic signatures indicate formation at temperatures $\lesssim30$ K in a relatively metal-poor environment, early in the history of the Galaxy. When interpreted with respect to models for Galactic chemical evolution, the carbon isotopic composition implies that 3I/ATLAS accreted roughly 10-12 billion years ago, following an early period of intense star formation. 3I/ATLAS thus represents a preserved fragment of an ancient planetary system, and provides direct evidence for active ice chemistry and volatile-rich planetesimal formation in the young Milky Way.

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Sequential Fragmentation of C/2025 K1 (ATLAS) After Its Near-Sun Passage

Comet C/2025 K1 (ATLAS) reached perihelion at 0.33 au on 2025 October 8. Daily monitoring by the LCO Outbursting Objects Key Project revealed a major activity increase between November 2 and 4, accompanied by rapid changes in coma morphology. Serendipitous HST/STIS acquisition images obtained on November 8-10 captured the comet only days after this event and resolved five fragments, providing an early high-resolution view of a nucleus in the process of disruption. Fragment motions and morphologies indicate a hierarchical fragmentation sequence, including a slow secondary split of fragment II. Back extrapolation shows that both the primary and secondary breakups preceded their associated photometric outbursts by roughly one to three days. This consistent lag, together with the appearance of thin, short-lived arclets around fragment I in the first HST epoch, suggests that freshly exposed interior material warms rapidly but requires time before dust can be released efficiently. Given the comet's close perihelion passage, rotational instability driven by enhanced outgassing torques is a plausible contributor to nucleus disintegration and dust release, and may represent the primary source of the observed brightening. These combined ground- and space-based observations provide rare, time-resolved constraints on the thermal and structural evolution of a fragmented comet near perihelion and highlight the scientific value of capturing a nucleus within days of disruption, when thermal adjustment, dust mantle re-formation, and outgassing-driven torques jointly govern the onset of activity.

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Habitable from the start: How initial planetary formation conditions may create habitable worlds

The breadth of topics that encompass the search for life has expanded and evolved significantly since the emergence of the field of astrobiology. Initial astrobiology centered investigations focused on detecting biosignatures in the Martian soil with the Viking lander. The field now encompasses identification of biosignatures throughout the galaxy and habitable worlds, planets with sufficient liquid water and prebiotic chemistry to support life. This evolution mirrors the improvement in our understanding of environments that may harbor life. The bulk planetary chemistry governs the habitability of a planet, which is in turn set by the early solar system environment and planet formation processes. Therefore, investigations of solar and exoplanetary systems as a whole would provide insights into the factors that make a planet habitable. Bulk planetary chemistry govern planetary atmospheres, core sizes, magnetic fields, heat engines, volatile inventories, and silicate mantle compositions. We therefore advocate for investigations of formation conditions that establish planetary chemistry, and by extension, habitability.

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Near-Discovery SOAR Photometry of the Third Interstellar Object: 3I/ATLAS

3I/ATLAS was discovered on UT 2025 July 1 and joins a limited but growing population of detected $\sim10^2-10^3$ m scale interstellar objects. In this paper we report photometric observations of 3I/ATLAS from the nights of UT 2025 July 3, UT 2025 July 9, and UT 2025 July 10 obtained with the Southern Astrophysical Research Telescope (SOAR). The photometric observations are taken with the Goodman High Throughput Spectrograph (HTS) in the $r'$-band. These data provide 28 photometric data points to the rapidly growing composite light curve of 3I/ATLAS. They reveal that the object did not exhibit obvious long-term variability in its brightness when these observations were taken. These observations appear to have captured two moderate and independent brightening events on UT 2025 July 9, and UT 2025 July 10. However, we perform a series of stellar contamination, stacking, and aperture experiments that demonstrate that the increases in brightness by $\sim0.8$ magnitudes appear to be a result of poor seeing and stellar contamination by close-proximity field stars. We report the mean brightnesses of 3I/ATLAS on each night of magnitude 18.14, 17.55, and 17.54 for UT 2025 July 3, 9, and 10, respectively. Moreover, the presence of cometary activity in extant images obtained contemporaneously with these data precludes them from revealing insights into the rotation of the nucleus. We conclude that the activity of 3I/ATLAS on UT 2025 July 9 and UT July 10 was consistent with the near-discovery activity levels, with no obvious outburst activity.

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Precovery Observations of 3I/ATLAS from TESS Suggests Possible Distant Activity

3I/ATLAS is the third macroscopic interstellar object detected traversing the Solar System. Since its initial discovery on UT 01 July 2025, hundreds of hours on a range of observational facilities have been dedicated to measure the physical properties of this object. These observations have provided astrometry to refine the orbital solution, photometry to measure the color, a rotation period and secular light curve, and spectroscopy to characterize the composition of the coma. Here, we report precovery photometry of 3I/ATLAS as observed with NASA's Transiting Exoplanet Survey Satellite (TESS). 3I/ATLAS was observed nearly continuously by TESS from UT 07 May 2025 to 02 June 2025. We use the shift-stack method to create deep stack images to recover the object. These composite images reveal that 3I/ATLAS has an average TESS magnitude of $T_\textrm{mag} = 20.83 \pm 0.05, 19.28 \pm 0.05$ and an absolute visual magnitude of $H_V = 13.72 \pm 0.35; 12.52 \pm 0.35$, the latter being consistent with magnitudes reported in July 2025. When coupled with recent HST images deriving a nucleus size of R$<$2.8 km (H$>$15.4), our measurements suggest that 3I/ATLAS may have been active out at $\sim 6$ au. Additionally, we extract a $\sim 20$ day light curve and find no statistically significant evidence of a nucleus rotation period. Nevertheless, the data presented here are some of the earliest precovery images of 3I/ATLAS and may be used in conjunction with future observations to constrain the properties of our third interstellar interloper.

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Discovery and Preliminary Characterization of a Third Interstellar Object: 3I/ATLAS

We report initial observations aimed at the characterization of a third interstellar object. This object, 3I/ATLAS or C/2025 N1 (ATLAS), was discovered on 2025 July 1 UT and has an orbital eccentricity of $e\sim6.1$, perihelion of $q\sim 1.36$ au, inclination of $\sim175^\circ$, and hyperbolic velocity of $V_\infty\sim 58$ km s$^{-1}$. We report deep stacked images obtained using the Canada-France-Hawaii Telescope and the Very Large Telescope that resolve a compact coma. Using images obtained from several smaller ground-based telescopes, we find minimal light curve variation for the object over a $\sim4$ day time span. The visible/near-infrared spectral slope of the object is 17.1$\pm$0.2 %/100 nm, comparable to other interstellar objects and primitive solar system small bodies (comets and D-type asteroids). 3I/ATLAS will be observable through early September 2025, then unobservable by Earth-based observatories near perihelion due to low solar elongation. It will be observable again from the ground in late November 2025. Although this limitation unfortunately prohibits detailed Earth-based observations at perihelion when the activity of 3I/ATLAS is likely to peak, spacecraft at Mars could be used to make valuable observations at this time.

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The Volatile Composition and Activity Evolution of Main-Belt Comet 358P/PANSTARRS

We report the detection of water vapor associated with main-belt comet 358P/PANSTARRS on UT 2024 January 8-9 using the NIRSPEC instrument aboard JWST. We derive a water production rate of Q(H2O)=(5.0+/-0.2)x10^25 molecules/s, marking only the second direct detection of sublimation products of any kind from a main-belt comet, after 238P/Read. Similar to 238P, we find a remarkable absence of hypervolatile species, finding Q(CO2)<7.6x10^22 molecules/s, corresponding to Q(CO2)/Q(H2O)<0.2%. Upper limits on CH3OH and CO emission are also estimated. Photometry from ground-based observations show that the dust coma brightened and faded slowly over ~250 days in 2023-2024, consistent with photometric behavior observed in 2012-2013, but also indicate a ~2.5x decline in the dust production rate between these two periods. Dynamical dust modeling shows that the coma's morphology as imaged by JWST's NIRCAM instrument on 2023 November 22 can be reproduced by asymmetric dust emission from a nucleus with a mid-range obliquity (~80 deg) with a steady-state mass loss rate of ~0.8 kg/s. Finally, we find similar Afrho-to-gas ratios of log10(Afrho/Q(H2O))=-24.8+/-0.2 for 358P and log10(Afrho/QH2O)=-24.4+/-0.2 for 238P, suggesting that Afrho could serve as an effective proxy for estimating water production rates in other active main-belt comets. The confirmation of water vapor outgassing in both main-belt comets observed by JWST to date reinforces the use of recurrent activity near perihelion as an indicator of sublimation-driven activity in active asteroids.

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Jupiter Co-Orbital Comet P/2023 V6 (PANSTARRS): Orbital History and Modern Activity State

The discovery of the transient Jupiter co-orbital comet P/2019 LD2 (ATLAS) drew significant interest. Not only will LD2 transition between being a Centaur and a Jupiter Family Comet (JFC) in 2063, the first time this process can be observed as it happens, it is also very active for its large heliocentric distance. We present observations and orbital integrations of the newly discovered transient Jupiter co-orbital comet P/2023 V6 (PANSTARRS), the second such object known. Despite similar modern orbits, V6 is significantly (15 times) less active than LD2 and most JFCs as determined via Afrho measurements at the same heliocentric distance. We find V6 is co-orbital between 2020 and 2044, twice the duration of LD2, but it will not become a JFC soon. We interpret these differences in activity as evolutionary, with V6 having lost a significant fraction of its near-surface ice compared to LD2 by previously being warmer. While V6's pre-encounter orbit was somewhat warmer than LD2's, future thermal modeling will be needed to understand if this can explain their differences or if a more significant difference further into the past is required. This is more evidence that LD2 is a pristine and ice-rich object, and thus it may display very strong activity when it becomes a JFC. We sue the differences between V6 and LD2 to discuss the interpretation of cometary activity at large heliocentric distances as well as the small end of the crater record of the Galilean Satellites. Continuing observations of both objects are highly encouraged.

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Dynamical feasibility of (3) Juno as a parent body of the H chondrites

We test the hypothesis that (3) Juno is a parent body of the H chondrites with dynamical modeling of an asteroid-family-forming impact and comparison to current observational data. Using a dynamical model that includes the Yarkovsky force on a simulated Juno family and a simplified cosmic ray exposure age model we examine the expected distribution of Juno family members in both the main belt and near-Earth orbits over 300 Myrs and the cosmic ray exposure distribution for fragments exiting the main belt via the 3:1J, 5:2J, and 8:3J mean motion resonances. We find that the smallest modeled ($D<$10 m) family members of (3) Juno cannot be directly responsible for the observed H chondrite flux and that the breakup of larger family members creates an CRE distribution that resembles the measured H chondrite CRE distribution but is still unable to adequately explain the significant number of H chondrites with CRE ages of 6-8 Myrs. A similar model was performed for the asteroid (6) Hebe, another parent body candidate, and produced a CRE age distribution that is inconsistent with the measured H chondrite CRE ages. We also find from our dynamical models that we can expect $<$7 km-scale Juno family members in near-Earth orbits in the present day, consistent with the recent discovery of the shock-darkened H chondrite-like asteroid (52768) 1998 OR$_{2}$.

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Ice, Ice, Maybe? Investigating 46P/Wirtanen's Inner Coma For Icy Grains

The release of volatiles from comets is usually from direct sublimation of ices on the nucleus, but for very or hyper-active comets other sources have to be considered to account for the total production rates. In this work, we present new near-infrared imaging and spectroscopic observations of 46P/Wirtanen taken during its close approach to the Earth on 2018 December 19 with the MMIRS instrument at the MMT Observatory to search for signatures of icy or ice-rich grains in its inner coma that might explain its previously reported excess water production. The morphology of the images does not suggest any change in grain properties within the field of view, and the NIR spectra do not show the characteristic absorption features of water ice. Using a new MCMC-based implementation of the spectral modeling approach of Protopapa et al. (2018), we estimate the areal water ice fraction of the coma to be less than 0.6%. When combined with slit-corrected Afrho values for the J, H, and K bands and previously measured dust velocities for this comet, we estimate an icy grain production rate of less than 4.6 kg/s. This places a strict constraint on the water production rate from pure icy grains in the coma, and in turn we find that for the 2018-2019 apparition approximately 64% of 46P's surface was sublimating water near perihelion. WE then discuss 46P's modern properties within the context of other (formerly) hyper-active comets to understand how these complex objects evolve.

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The Volatile Carbon to Oxygen Ratio as a Tracer for the Formation Locations of Interstellar Comets

Based on the occurrence rates implied by the discoveries of 1I/`Oumuamua and 2I/Borisov, the forthcoming Rubin Observatory Legacy Survey of Space and Time (LSST) should detect $\ge1$ interstellar objects every year (Hoover et al. 2021). We advocate for future measurements of the production rates of H$_2$O, CO$_2$ and CO in these objects to estimate their carbon to oxygen ratios, which traces formation locations within their original protoplanetary disks. We review similar measurements for Solar System comets, which indicate formation interior to the CO snowline. By quantifying the relative processing in the interstellar medium and Solar System, we estimate that production rates will not be representative of primordial compositions for the majority of interstellar comets. Preferential desorption of CO and CO$_2$ relative to H$_2$O in the interstellar medium implies that measured C/O ratios represent lower limits on the primordial ratios. Specifically, production rate ratios of ${\rm Q}({\rm CO})/{\rm Q}({\rm H_2O})<.2$ and ${\rm Q}({\rm CO})/{\rm Q}({\rm H_2O})>1$ likely indicate formation interior and exterior to the CO snowline, respectively. The high C/O ratio of 2I/Borisov implies that it formed exterior to the CO snowline. We provide an overview of the currently operational facilities capable of obtaining these measurements that will constrain the fraction of ejected comets that formed exterior to the CO snowline. This fraction will provide key insights into the efficiency of and mechanisms for cometary ejection in exoplanetary systems.

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The Nature of Low-Albedo Small Bodies from 3-$μ$m Spectroscopy: One Group that Formed Within the Ammonia Snow Line and One that Formed Beyond It

We present evidence, via a large survey of 191 new spectra along with previously-published spectra, of a divide in the 3-$μ$m spectral properties of the low-albedo asteroid population. One group ("Sharp-types" or ST, with band centers $<$ 3 $μ$m) has a spectral shape consistent with carbonaceous chondrite meteorites, while the other group ("not-Sharp-types" or NST, with bands centered $>$ 3 $μ$m) is not represented in the meteorite literature but is as abundant as the STs among large objects. Both groups are present in most low-albedo asteroid taxonomic classes, and except in limited cases taxonomic classifications based on 0.5-2.5-$μ$m data alone cannot predict whether an asteroid is ST or NST. Statistical tests show the STs and NSTs differ in average band depth, semi-major axis, and perihelion at confidence levels $\ge$98\%, while not showing significant differences in albedo. We also show that many NSTs have a 3-$μ$m absorption band shape like Comet 67P, and likely represent an important small-body composition throughout the solar system. A simple explanation for the origin of these groups is formation on opposite sides of the ammonia snow line, with the NST group accreting H2O and NH3 and the ST group only accreting H2O, with subsequent thermal and chemical evolution resulting in the minerals seen today. Such an explanation is consistent with recent dynamical modeling of planetesimal formation and delivery, and suggests that much more outer solar system material was delivered to the main asteroid belt than would be thought based on the number of D-class asteroids found today.

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