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John Wang

Publications and source records attributed to John Wang.

13 recordsLinked to original sources

Multi-Objective Multi-Agent Bandits: From Learning Efficiency to Fairness Optimization

We study multi-objective multi-agent multi-armed bandits (MO-MA-MAB) under stochastic rewards, where agents observe heterogeneous reward vectors and communicate over time-varying graphs. We formulate this emerging problem setting to address \emph{efficient learning}, measured by Pareto regret, and incorporate \emph{fair learning} as an additional goal, captured via social welfare. To measure efficiency, we formulate Pareto regret and develop \textsc{Pareto UCB1 Gossip}, whose novel exploration radius explicitly separates statistical uncertainty in Pareto-based inference from consensus error. To express the fairness constraint, we formulate a Nash Social Welfare objective over preference-scalarized rewards and propose \textsc{Simulated NSW UCB Gossip}, which integrates preference-based reward simulation, gossip-based utility estimation, and UCB-style exploration. We prove that \textsc{Pareto UCB1 Gossip} achieves \(\mathcal{O}(\log T)\) regret and an instance-independent rate of \(\mathcal{O}(\sqrt{T})\), while \textsc{Simulated NSW UCB Gossip} achieves an instance-independent regret bound of \(\mathcal{O}(T^{3/4})\). This separation reveals the cost of imposing the fairness constraint to our efficiency objective: fairness limits information aggregation and slows convergence. Experiments show that our methods consistently outperform baselines, improving performance by approximately \(100\%\) and \(50\%\) in the efficiency and fairness settings, respectively.

cs.LG

A multiscale generative model to understand disorder in domain boundaries

A continuing challenge in atomic resolution microscopy is to identify significant structural motifs and their assembly rules in synthesized materials with limited observations. Here we propose and validate a simple and effective hybrid generative model capable of predicting unseen domain boundaries in a potassium sodium niobate thin film from only a small number of observations, without expensive first-principles calculation. Our results demonstrate that complicated domain boundary structures can arise from simple interpretable local rules, played out probabilistically. We also found new significant tileable boundary motifs and evidence that our system creates domain boundaries with the highest entropy. More broadly, our work shows that simple yet interpretable machine learning models can help us describe and understand the nature and origin of disorder in complex materials.

cond-mat.mtrl-sci

Membrane fouling: microscopic insights into the effects of surface chemistry and roughness

Fouling is a major obstacle and challenge in membrane-based separation processes. Caused by the sophisticated interactions between foulant and membrane surface, fouling strongly depends on membrane surface chemistry and morphology. Current studies in the field have been largely focused on polymer membranes. Herein, we report a molecular simulation study for fouling on alumina and graphene membrane surfaces during water treatment. For two foulants (sucralose and bisphenol A), the fouling on alumina surfaces is reduced with increasing surface roughness; however, the fouling on graphene surfaces is enhanced by roughness. It is unravelled that the foulant-surface interaction becomes weaker in the ridge region of a rough alumina surface, thus allowing foulant to leave the surface and reducing fouling. Such behavior is not observed on a rough graphene surface because of the strong foulant-graphene interaction. Moreover, with increasing roughness, the hydrogen bonds formed between water and alumina surfaces are found to increase in number as well as stability. By scaling the atomic charges of alumina, fouling behavior on alumina surfaces is shifted to the one on graphene surfaces. This simulation study reveals that surface chemistry and roughness play a crucial role in membrane fouling, and the microscopic insights are useful for the design of new membranes towards high-performance water treatment.

cond-mat.soft

Surface-charge-mediated Formation of H-TiO2@Ni(OH)2 Heterostructures for High-Performance Supercapcitors

Supercapacitors or ultracapacitors are promising for efficient energy storage applications, owing to their high power density, high charge-discharge rates, and long cycle life performance. To achieve this goal, a large specific surface area, an high electronic conductivity and a fast cation intercalation de-intercalation process are generally required in the design and preparation of materials for high-performance supercapacitors. Recently, core-shell heterostructures with multifunctionalities are regarded as one of promising materials for supercapacitors or ultracapacitors applications. In particular, one-dimensional (1D) core-shell heterostructures have sparked great scientific and technological interests due to their high versatility and applicability as the essential components in nanoscale electronics, catalysis, chemical sensing, and energy conversion storage devices. Various metal metal oxide, metal metal, metal oxide metal oxide and metal oxide conductive polymers so far have been investigated. Transition metal hydroxide oxide Co3O4, Co(OH)2, MnO2, Mn(OH)2, NiO, Ni(OH)2 and their compounds storing energy by surface faradaic (redox) reactions were generally integrated with conducting scaffold to build core-shell structure. Intensive studies show that an enlarged active surface area of transition metal hydroxide oxide enables a promoted surface redox reaction and enhanced electrochemical performance. Therefore, controllable synthesis of a hierarchically porous construction with high surface areas is critically important for energy storage.

cond-mat.mtrl-sci

Utilization of Strong Charge Transfer Efficiency at 2H-1T Phase Boundary of MoS2 for Superb High-Performance Charge Storage

Transition metal dichalcogenides like MoS2 can exist many phases like the semiconducting 2H and the metallic 1T phases which have shown intriguing properties for energy and electrocatalytic applications. However, the 2H and 1T phases normally distribute coherently in a single-layered MoS2 sheet which is accompanied with ubiquitous hetero-phase boundaries. In this work, by using density functional theory and electrochemical measurement, we report strong charge transfer ability between 2H/1T phase boundary of MoS2 and graphene which accounts for a superb coexistence of gravimetric and volumetric capacitances of 272 F g-1 and 685 F cm-3. As a proof-of-concept application, a flexible solid-state asymmetric supercapacitor based on MoS2/graphene is fabricated, showing a remarkable energy and power densities (46.3 mWh cm-3 and 3.013 Wcm-3). Our work shows the promise of promoting the efficiency of charge flow and energy storage through engineering phase boundary and interface in phase-change materials.

physics.app-ph

Microstructural Evolution of Charged Defects in the Fatigue Process of Polycrystalline BiFeO3 Thin Films

Fatigue failure in ferroelectrics has been intensively investigated in the past few decades. Most of the mechanisms discussed for ferroelectric fatigue have been built on the "hypothesis of variation in charged defects", which however are rarely evidenced by experimental observation. Here, using a combination of complex impedance spectra techniques, piezoresponse force microscopy and first-principles theory, we examine the microscopic evolution and redistribution of charged defects during the electrical cycling in BiFeO3 thin films. The dynamic formation and melting behaviors of oxygen vacancy (VO) order are identified during the fatigue process. It reveals that the isolated VO tend to self-order along grain boundaries to form a planar-aligned structure, which blocks the domain reversals. Upon further electrical cycling, migration of VO within vacancy clusters is accommodated with a lower energy barrier (~0.2 eV) and facilitates the formation of nearby-electrode layer incorporated with highly concentrated VO. The interplay between the macroscopic fatigue and microscopic evolution of charged defects clearly demonstrates the role of ordered VO cluster in the fatigue failure of BiFeO3 thin films.

cond-mat.mtrl-sci

Unit cell determination of epitaxial thin films based on reciprocal space vectors by high-resolution X-ray diffractometry

A new approach, based on reciprocal space vectors (RSVs), is developed to determine Bravais lattice types and accurate lattice parameters of epitaxial thin films by high-resolution X-ray diffractometry (HR-XRD). The lattice parameters of single crystal substrates are employed as references to correct the systematic experimental errors of RSVs of thin films. The general procedure is summarized, involving correction of RSVs, derivation of raw unit cell, subsequent conversion to the Niggli unit cell and the Bravais unit cell by matrix calculation.Two methods of this procedure are described in 3D reciprocal space and 6D G6-space, respectively. The estimation of standard error in the lattice parameters derived by this new approach is discussed. The whole approach is illustrated by examples of experimental data. The error of the best result is 0.0006 Å for the lattice parameter of ITO (Indium tin oxide) film. This new RSV method provides a practical and concise route to crystal structure study of epitaxial thin films, which could also be applied to the investigation of surface and interface structures.

cond-mat.mtrl-sci

Oxygen-vacancy-mediated Negative Differential Resistance in La and Mg co-substituted BiFeO3 Thin Film

The conductive characteristics of Bi0.9La0.1Fe0.96Mg0.04O3(BLFM) thin film are investigated at various temperatures and a negative differential resistance (NDR) is observed in the thin film, where a leakage current peak occurs upon application of a downward electric field above 80 oC. The origin of the NDR behavior is shown to be related to the ionic defect of oxygen vacancies (VO..) present in the film. On the basis of analyzing the leakage mechanism and surface potential behavior, the NDR behavior can be understood by considering the competition between the polarized distribution and neutralization of VO...

cond-mat.mtrl-sci

Origin of the Enhanced Polarization in La and Mg Co-substituted BiFeO3 Thin Film during the Fatigue Process

We have studied the polarization fatigue of La and Mg co-substituted BiFeO3 thin film, where a polarization peak is observed during the fatigue process. The origin of such anomalous behavior is analyzed on the basis of the defect evolution using temperature-dependent impedance spectroscopy. It shows that the motion of oxygen vacancies (VO..) is associated with a lower energy barrier, accompanied by the injection of electrons into the film during the fatigue process. A qualitative model is proposed to explain the fatigue behavior, which involves the modification of the Schottky barrier upon the accumulation of VO.. at the metal-dielectric interface.

cond-mat.mtrl-sci

Oxygen-vacancy-related relaxation and scaling behaviors of Bi0.9La0.1Fe0.98Mg0.02O3 (La,Mg-codoped BiFeO3) ferroelectric thin film

Oxygen-vacancies-related dielectric relaxation and scaling behaviors of Bi0.9La0.1Fe0.98Mg0.02O3 (BLFM) thin film have been investigated by temperature-dependent impedance spectroscopy from 40 oC up to 200 oC. We found that hopping electrons and single-charged oxygen vacancies (VO.) coexist in the BLFM thin film and make contribution to dielectric response of grain and grain boundary respectively. The activation energy for VO. is shown to be 0.94 eV in the whole temperature range investigated, whereas the distinct activation energies for electrons are 0.136 eV below 110oC and 0.239 eV above 110oC in association with hopping along the Fe2+- VO.-Fe3+ chain and hopping between Fe2+-Fe3+, respectively, indicating different hopping processes for electrons. Moreover, it has been found that hopping electrons is in form of long rang movement, while localized and long range movement of oxygen vacancies coexist in BLFM film. The Cole-Cole plots in modulus formalism show a poly-dispersive nature of relaxation for oxygen vacancies and a unique relaxation time for hopping electrons. The scaling behavior of modulus spectra further suggests that the distribution of relaxation times for oxygen vacancies is temperature independent.

cond-mat.mtrl-sci

Highly (111)-orientated BiFeO3 thin film deposited on La0.67Sr0.33MnO3 buffered Pt/TiO2/SiO2/Si (100) substrate

Multiferroic BiFeO3 (BFO) thin film exhibiting desired ferroelectric and enhanced magnetic properties was grown on La0.67Sr0.33MnO3 (LSMO) buffered Pt/TiO2/SiO2/Si substrates by off-axis RF magnetic sputtering, where a highly (111)-oriented texture was obtained. The BFO/LSMO thin film exhibits excellent ferroelectric and dielectric behaviors (2Pr ~210.7 μC/cm2, 2Ec~435 kV/cm, εr ~116.8, and tanδ ~ 2.7% at 1 kHz), together with a long fatigue endurance up to 1010 switching cycles at amplitude of 300 kV/cm. An enhancement in magnetic behavior was also observed with Ms=89.5 emu/cm3, which is largely contributed from the magnetic layer of LSMO. The coexistence of ferroelectric and ferromagnetic properties in the double layered BFO/LSMO thin film makes it a promising candidate system for applications where the magnetoelectric behavior is required.

cond-mat.mtrl-sci

Tachyacoustic Cosmology: An Alternative to Inflation

We consider an alternative to inflation for the generation of superhorizon perturbations in the universe in which the speed of sound is faster than the speed of light. We label such cosmologies, first proposed by Armendariz-Picon, {\it tachyacoustic}, and explicitly construct examples of non-canonical Lagrangians which have superluminal sound speed, but which are causally self-consistent. Such models possess two horizons, a Hubble horizon and an acoustic horizon, which have independent dynamics. Even in a decelerating (non-inflationary) background, a nearly scale-invariant spectrum of perturbations can be generated by quantum perturbations redshifted outside of a shrinking acoustic horizon. The acoustic horizon can be large or even infinite at early times, solving the cosmological horizon problem without inflation. These models do not, however, dynamically solve the cosmological flatness problem, which must be imposed as a boundary condition. Gravitational wave modes, which are produced by quantum fluctuations exiting the Hubble horizon, are not produced.

astro-ph.CO

Variable Stars in Galactic Globular Clusters

Based on a search of the literature up to May 2001, the number of known variable stars in Galactic globular clusters is approximately 3000. Of these, more than 2200 have known periods and the majority (approximately 1800) are of the RR Lyrae type. In addition to the RR Lyrae population, there are approximately 100 eclipsing binaries, 120 SX Phe variables, 60 Cepheids (including population II Cepheids, anomalous Cepheids and RV Tauri) and 120 SR/red variables. The mean period of the fundamental mode RR Lyrae variables is 0.585, for the overtone variables it is 0.342 (0.349 for the first-overtone pulsators and 0.296 for the second-overtone pulsators) and approximately 30% are overtone pulsators. These numbers indicate that about 65% of RR Lyrae variables in Galactic globular clusters belong to Oosterhoff type I systems. The mean period of the RR Lyrae variables in the Oosterhoff type I clusters seems to be correlated with metal abundance in the sense that the periods are longer in the more metal poor clusters. Such a correlation does not exist for the Oosterhoff type II clusters. Most of the Cepheids are in clusters with blue horizontal branches.

astro-ph