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Jonas Klein

Publications and source records attributed to Jonas Klein.

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Is She Even Relevant? When BERT Ignores Explicit Gender Cues

Gender bias in large language models has primarily been investigated for English, while languages with grammatical or morphological gender remain comparatively understudied. This paper investigates how and when gender information emerges in a Dutch BERT model trained from scratch, offering one of the first checkpoint-level analyses of bias formation in a Transformer architecture for a language combining overt morphological gender marking and generic forms. By extracting contextual embeddings throughout training, we construct dynamic gender subspaces using linear SVMs to trace when gender becomes linearly encoded and how this encoding evolves over time. Contextual embeddings are often assumed to integrate contextual cues robustly, allowing models to adjust the representation of a word depending on its more local usage. We therefore test whether explicit gender cues in controlled sentence templates (e.g., Zij is een loodgieter ('She is a plumber')) can override learned statistical associations (plumber -> male). Our findings challenge this assumption: although gender becomes clearly linearly separable around epoch 20 and is distributed across multiple embedding dimensions, the model struggles to update its internal gender representation in light of explicit contextual cues in short sentence templates. Stereotypical gender-profession pairings are predicted far more accurately than anti-stereotypical ones, and generic forms in Dutch systematically default to a male interpretation, even when the context explicitly denotes a female referent. Together, our results seem to indicate that contextualization in the representations learned by our Dutch BERT model is not sufficiently dynamic along the probed gender direction: explicit gender cues in anti-stereotypical contexts are not reliably reflected in the resulting representations, resulting in persistent male-default behaviour.

cs.CL

Reactive additive capillary stamping with double network hydrogel-derived aerogel stamps under solvothermal conditions

Integration of solvothermal reaction products into complex thin-layer architectures is frequently achieved by combinations of layer transfer and subtractive lithography, whereas direct additive substrate patterning with solvothermal reaction products has remained challenging. We report reactive additive capillary stamping under solvothermal conditions as a parallel contact-lithographic access to patterns of solvothermal reaction products in thin-layer configurations. To this end, corresponding precursor inks are infiltrated into mechanically robust mesoporous aerogel stamps derived from double-network hydrogels (DNHGs). The stamp is then brought into contact with a substrate to be patterned under solvothermal reaction conditions inside an autoclave. The precursor ink forms liquid bridges between the topographic surface pattern of the stamp and the substrate. Evaporation-driven enrichment of the precursors in these liquid bridges along with their liquid-bridge-guided conversion into the solvothermal reaction products yields large-area submicron patterns of the solvothermal reaction products replicating the stamp topography. As example, we prepared thin hybrid films, which contained ordered monolayers of superparamagnetic submicron nickel ferrite dots prepared by solvothermal capillary stamping surrounded by nickel electrodeposited in a second, orthogonal substrate functionalization step. The submicron nickel ferrite dots acted as magnetic hardener halving the remanence of the ferromagnetic nickel layer. In this way, thin-layer electromechanical systems, transformers and positioning systems may be customized.

physics.app-ph

Solvent-Free High-Temperature Capillary Stamping of Stimuli-Responsive Polymers: Wettability Management by Orthogonal Substrate Functionalization

The wettability of surfaces determines their antifouling, antifogging, anti-icing, and self-cleaning properties as well as their usability for sensing, oil-water separation, water collection, and water purification. Solvent-free high-temperature capillary stamping of stimuli-responsive polymers yielding arrays of stimuli-responsive polymer microdots on differently modified substrates enables the flexible generation of switchable surfaces with different water contact angles (WCAs). Potential problems associated with the deposition of polymer solutions, such as the handling of volatile organic solvents, phase separation induced by solvent evaporation, and capillarity-driven flow processes, are circumvented. We used composite stamps with topographically patterned contact surfaces consisting of metallic nickel cores and porous MnO2 coatings taking up the stimuli-responsive polymers. The short transport paths from the MnO2 contact layers to the counterpart substrates enabled the stamping of polymer melts containing components impeding flow, such as carbon nanotubes (CNTs). Thus-obtained arrays of polymer-CNT hybrid microdots prevent problems associated with continuous coatings including delamination and crack propagation. Moreover, the range within which the properties of the stamped stimuli-responsive polymer microdots are switchable can be tuned by orthogonal substrate modification. As an example, we stamped hybrid microdots consisting of poly(2-(methacryloyloxy)ethyl ferrocenecarboxylate) (PFcMA) and CNTs onto indium tin oxide (ITO) substrates. Coating the ITO substrates with a poly(ethylene oxide)-terminated silane shifted the WCAs obtained by switching the PFcMA between its oxidized and reduced states by nearly 50{\deg}.

cond-mat.soft

Phenolic Resin Dual-Use Stamps for Capillary Stamping and Decal Transfer Printing

We report an optimized two-step thermopolymerization process carried out in contact with micropatterned molds that yields porous phenolic resin dual-use stamps with topographically micropatterned contact surfaces. With these stamps, two different parallel additive substrate manufacturing methods can be executed: capillary stamping and decal transfer microlithography. Under moderate contact pressures, the porous phenolic resin stamps are used for non-destructive ink transfer to substrates by capillary stamping. Continuous ink supply through the pore systems to the contact surfaces of the porous phenolic resin stamps enables multiple successive stamp-substrate contacts for lithographic ink deposition under ambient conditions. No deterioration of the quality of the deposited pattern occurs and no interruptions for ink replenishment are required. Under high contact pressure, porous phenolic resin stamps are used for decal transfer printing. In this way, the tips of the stamps' contact elements are lithographically transferred to counterpart substrates. The granular nature of the phenolic resin facilitates the rupture of the contact elements upon stamp retraction. The deposited phenolic resin micropatterns characterized by abundance of exposed hydroxyl groups are used as generic anchoring sites for further application-specific functionalizations. As example, we deposited phenolic resin micropatterns on quartz crystal microbalance resonators and further functionalized them with polyethylenimine for preconcentration sensing of humidity and gaseous formic acid. We envision that also preconcentration coatings for other sensing methods, such as attenuated total reflection infrared spectroscopy and surface plasmon resonance spectroscopy, are accessible by this functionalization algorithm

cond-mat.mtrl-sci