arXiv subjects

Jonathan I. Lunine

Publications and source records attributed to Jonathan I. Lunine.

At least 19 recordsLinked to original sources

arXiv2025

Coupled 1D Chemical Kinetic-Transport and 2D Hydrodynamic Modeling Supports a modest 1-1.5x Supersolar Oxygen Abundance in Jupiter's Atmosphere

Understanding the deep atmospheric composition of Jupiter provides critical constraints on its formation and the chemical evolution of the solar nebula. In this study, we combine one-dimensional thermochemical kinetic-transport modeling with two-dimensional hydrodynamic simulations to constrain Jupiter's deep oxygen abundance using carbon monoxide (CO) as a proxy tracer. Leveraging a comprehensive chemical network generated by Reaction Mechanism Generator (RMG), we assess the impact of updated reaction rates, including the often-neglected but thermochemically significant Hidaka reaction (CH3OH + H -> CH3 + H2O). Our 1D-2D coupled approach supports a modest supersolar oxygen enrichment of 1.0-1.5x the solar value. We also present a method for deriving Jupiter's eddy diffusion coefficient Kzz = 3e6 to 5e7 cm2/s) from 2D hydrodynamic simulations using the quasi steady-state approach. This method is applicable to exoplanet atmospheres, where Kzz remains highly uncertain despite its strong influence on atmospheric chemistry. Finally, our results imply a significantly elevated planetary carbon-to-oxygen (C/O) ratio of ~2.9, highlighting the importance of clarifying the mechanisms behind the preferential accretion of carbon-rich material during Jupiter's formation. By integrating thermochemical and hydrodynamic processes, our study offers a more complete framework for constraining chemical and dynamical processes in (exo)planetary atmospheres.

astro-ph.EP↗

arXiv2024

The Origin and Evolution of Saturn: A Post-Cassini Perspective

The Saturn System has been studied in detail by the Cassini-Huygens Mission. A major thrust of those investigations has been to understand how Saturn formed and evolved and to place Saturn in the context of other gas giants and planetary systems in general. Two models have been proposed for the formation of the giant planets,the core accretion model and the disk instability model. The heavy element enrichment, core size, and internal structure of Saturn, compared to Jupiter strongly favor the core accretion model as for Jupiter. Two features of the core accretion model that are distinct from the disk instability model are the growth of a core with a mass several times that of the Earth, followed by runaway collapse of gas onto the core once a mass threshold is reached. The heavy element core grows slowly over millions of years through accretion of cm-m sized pebbles, even larger bodies, and moon sized embryos in the gaseous disk. The abundance pattern of heavy elements is thus a key constraint on formation models. C, N, S, and P at Saturn are presently known to varying degree of uncertainty. The He to H ratio in the atmosphere is crucial for understanding heat balance, interior processes, and planetary evolution, but present values at Saturn range from low to high, allowing for a wide range of possibilities. While the very low values are favored to explain excess luminosity, high values might indicate presence of layered convection in the interior, resulting in slow cooling. Additional insight into Saturn's formation comes from the unique data on the rings from Cassini's Grand Finale orbits. While the solar system is the only analog for the extra solar systems, detection of the alkali metals and water in giant exoplanets is useful for understanding the formation and evolution of Saturn, where such data are presently lacking.

astro-ph.EP↗

arXiv2024

A broad set of solar and cosmochemical data indicates high C-N-O abundances for the solar system

We examine the role of refractory organics as a major C carrier in the outer protosolar nebula and its implications for the compositions of large Kuiper belt objects (KBOs) and CI chondrites. By utilizing Rosetta measurements of refractory organics in comet 67P/Churyumov-Gerasimenko, we show that they would make up a large fraction of the protosolar C inventory in the KBO-forming region based on the current widely adopted solar abundances. However, this would free up too much O to form water ice, producing solid material that is not sufficiently rock-rich to explain the uncompressed density of the Pluto-Charon system and other large KBOs; the former has been argued as the most representative value we have for the bulk composition of large KBOs (Barr & Schawmb 2016, Bierson & Nimmo 2019). This inconsistency further highlights the solar abundances problem - an ongoing challenge in reconciling spectroscopically determined heavy element abundances with helioseismology constraints. By employing a new dataset from solar CNO neutrinos and solar wind measurements of C, N, and O, we show that the uncompressed density of the Pluto-Charon system can be reproduced over a wide range of scenarios. We show that a lack of sulfates in Ryugu and Bennu samples implies a lower amount of water ice initially accreted into CI chondrite parent bodies than previously thought. These data are found to be consistent with the solar C/O ratio implied by the new dataset. Our predictions can be tested by future neutrino, helioseismology, and cosmochemical measurements.

astro-ph.EP↗

arXiv2024

JWST Thermal Emission of the Terrestrial Exoplanet GJ 1132b

We present thermal emission measurements of GJ 1132b spanning 5--12 um obtained with the Mid-Infrared Instrument Low-Resolution Spectrometer (MIRI/LRS) on the James Webb Space Telescope (JWST). GJ 1132b is an M-dwarf rocky planet with Teq=584 K and an orbital period of 1.6 days. We measure a white-light secondary eclipse depth of 140+/-17 ppm, which corresponds to a dayside brightness temperature of Tp,dayside= 709+/-31 K using improved star and planet parameters. This measured temperature is only 1 sigma below the maximum possible dayside temperature of a bare rock (i.e., assuming a zero albedo planet with no heat redistribution, Tmax = 746+14/-11 K). The emission spectrum is consistent with a featureless blackbody, which agrees with a wide range of possible surface compositions. By comparing forward models to the dayside emission spectrum, we rule out Earth-thickness (P ~ 1 bar) atmospheres with at least 1% H2O, atmospheres of any modeled thickness (10^-4 -- 10^2 bar) that contain at least 1% CO2, and thick, Venus-like atmospheres (P>~100 bar) with at least 1 ppm CO2 or H2O. We therefore conclude that GJ 1132b likely does not have a significant atmosphere. This finding supports the concept of a universal 'Cosmic Shoreline' given the high level of bolometric and XUV irradiation received by the planet.

astro-ph.EP↗

arXiv2024

Insights on the Formation Conditions of Uranus and Neptune from their Deep Elemental Compositions

This study, placed in the context of the preparation for the Uranus Orbiter Probe mission, aims to predict the bulk volatile compositions of Uranus and Neptune. Using a protoplanetary disk model, it examines the evolution of trace species through vapor and solid transport as dust and pebbles. Due to the high carbon abundance found in their envelopes, the two planets are postulated to have formed at the carbon monoxide iceline within the protosolar nebula. The time evolution of the abundances of the major volatile species at the location of the CO iceline is then calculated to derive the abundance ratios of the corresponding key elements, including the heavy noble gases, in the feeding zones of Uranus and Neptune. Supersolar metallicity in their envelopes likely results from accreting solids in these zones. Two types of solids are considered: pure condensates (Case 1) and a mixture of pure condensates and clathrates (Case 2). The model, calibrated to observed carbon enrichments, predicts deep compositions. In Case 1, argon is deeply depleted, while nitrogen, oxygen, krypton, phosphorus, sulfur, and xenon are significantly enriched relative to their protosolar abundances in the two planets. Case 2 predicts significant enrichments for all species, including argon, relative to their protosolar abundances. Consequently, Case 1 predicts near-zero Ar/Kr or Ar/Xe ratios, while Case 2 suggests these ratios are 0.1 and 0.5-1 times their protosolar ratios. Both cases predict a bulk sulfur-to-nitrogen ratio consistent with atmospheric measurements.

astro-ph.EP↗

arXiv2024

Recipes for forming a carbon-rich giant planet

The exploration of carbon-to-oxygen ratios has yielded intriguing insights into the composition of close-in giant exoplanets, giving rise to a distinct classification: carbon-rich planets, characterized by a carbon-to-oxygen ratio $\ge$ 1 in their atmospheres, as opposed to giant planets exhibiting carbon-to-oxygen ratios close to the protosolar value. In contrast, despite numerous space missions dispatched to the outer solar system and the proximity of Jupiter, Saturn, Uranus, and Neptune, our understanding of the carbon-to-oxygen ratio in these giants remains notably deficient. Determining this ratio is crucial as it serves as a marker linking a planet's volatile composition directly to its formation region within the disk. This article provides an overview of the current understanding of the carbon-to-oxygen ratio in the four gas giants of our solar system and explores why there is yet no definitive dismissal of the possibility that Jupiter, Saturn, Uranus, or Neptune could be considered carbon-rich planets. Additionally, we delve into the three primary formation scenarios proposed in existing literature to account for a bulk carbon-to-oxygen ratio $\ge$ 1 in a giant planet. A significant challenge lies in accurately inferring the bulk carbon-to-oxygen ratio of our solar system's gas giants. Retrieval methods involve integrating in situ measurements from entry probes equipped with mass spectrometers and remote sensing observations conducted at microwave wavelengths by orbiters. However, these methods fall short of fully discerning the deep carbon-to-oxygen abundance in the gas giants due to their limited probing depth, typically within the 10-100 bar range.

astro-ph.EP↗

arXiv2024

Moderate D/H Ratios in Methane Ice on Eris and Makemake as Evidence of Hydrothermal or Metamorphic Processes in Their Interiors: Geochemical Analysis

Dwarf planets Eris and Makemake have surfaces bearing methane ice of unknown origin. D/H ratios were recently determined from James Webb Space Telescope (JWST) observations of Eris and Makemake, giving us new clues to decipher the origin of methane. Here, we develop geochemical models to test if the origin of methane could be primordial, derived from CO$_2$ or CO ("abiotic"), or sourced by organics ("thermogenic"). We find that primordial methane is inconsistent with the observational data, whereas both abiotic and thermogenic methane can have D/H ratios that overlap the observed ranges. This suggests that Eris and Makemake either never acquired a significant amount of methane during their formation, or their original inventories were removed and then replaced by a source of internally produced methane. Because producing abiotic or thermogenic methane likely requires temperatures above ~150°C, we infer that Eris and Makemake have rocky cores that underwent substantial radiogenic heating. Their cores may still be warm/hot enough to make methane. This heating could have driven hydrothermal circulation at the bottom of an ice-covered ocean to generate abiotic methane, and/or metamorphic reactions involving accreted organic matter could have occurred in response to heating in the deeper interior, generating thermogenic methane. Additional analyses of relevant thermal evolution model results and theoretical predictions of the D/H ratio of methane in the solar nebula support our findings of elevated subsurface temperatures and an apparent lack of primordial methane on Eris and Makemake. It remains an open question whether their D/H ratios may have evolved subsequent to methane outgassing. Recommendations are given for future activities to further test proposed scenarios of abiotic and thermogenic methane production on Eris and Makemake, and to explore these worlds up close.

astro-ph.EP↗

arXiv2024

Formation of the Trappist-1 system in a dry protoplanetary disk

A key feature of the Trappist-1 system is its monotonic decrease in bulk density with growing distance from the central star, which indicates an ice mass fraction that is zero in the innermost planets, b and c, and about 10\% in planets d through h. Previous studies suggest that the density gradient of this system could be due to the growth of planets from icy planetesimals that progressively lost their volatile content during their inward drift through the protoplanetary disk. Here we investigate the alternative possibility that the planets formed in a dry protoplanetary disk populated with pebbles made of phyllosilicates, a class of hydrated minerals with a water fraction possibly exceeding 10 wt\%. We show that the dehydration of these minerals in the inner regions of the disk and the outward diffusion of the released vapor up to the ice-line location allow the condensation of ice onto grains. Pebbles with water mass fractions consistent with those of planets d--h would have formed at the snow-line location. In contrast, planets b and c would have been accreted from drier material in regions closer to the star than the phyllosilicate dehydration line.

astro-ph.EP↗

arXiv2023

On the hypothesis of an inverted Z-gradient inside Jupiter

Models of Jupiter s interior struggle to agree with measurements of the atmospheric composition. Interior models favour a subsolar or solar abundance of heavy elements Z while atmospheric measurements suggest a supersolar abundance. One potential solution may be the presence of an inverted Z-gradient, namely an inward decrease of Z, which implies a larger heavy element abundance in the atmosphere than in the outer envelope. We investigate two scenarios in which the inverted Z gradient is located either where helium rain occurs (Mbar level) or at upper levels (kbar level) where a radiative region could exist. We aim to assess how plausible these scenarios are. We calculate interior and evolution models of Jupiter with such inverted Z-gradient and use constraints on the stability and the formation of an inverted Z-gradient. We find that an inverted Z-gradient at the location of helium rain cannot work as it requires a late accretion and of too much material. We find interior models with an inverted Z-gradient at upper levels, due to a radiative zone preventing downward mixing, that could satisfy the present gravity field of the planet. However, our evolution models suggest that this second scenario might not be in place. An inverted Z-gradient in Jupiter could be stable. Yet, its presence either at the Mbar level or kbar level is rather unlikely.

astro-ph.EP↗

arXiv2023

Highly depleted alkali metals in Jupiter's deep atmosphere

Water and ammonia vapors are known to be the major sources of spectral absorption at pressure levels observed by the microwave radiometer (MWR) on Juno. However, the brightness temperatures and limb darkening observed by the MWR at its longest wavelength channel of 50 cm (600 MHz) in the first 9 perijove passes indicate the existence of an additional source of opacity in the deep atmosphere of Jupiter (pressures beyond 100 bar). The absorption properties of ammonia and water vapor, and their relative abundances in Jupiter's atmosphere do not provide sufficient opacity in deep atmosphere to explain the 600 MHz channel observation. Here we show that free electrons due to the ionization of alkali metals, i.e. sodium, and potassium, with sub-solar metallicity [M/H] (log based 10 relative concentration to solar) in the range of [M/H] = -2 to [M/H] = -5 can provide the missing source of opacity in the deep atmosphere. If the alkali metals are not the source of additional opacity in the MWR data, then their metallicity at 1000 bars can only be even lower. The upper bound of -2 on the metallicity of the alkali metals contrasts with the other heavy elements -- C, N, S, Ar, Kr, and Xe -- which are all enriched relative to their solar abundances having a metallicity of approximately +0.5.

astro-ph.EP↗

arXiv2023

Early stages of Galilean moon formation in a water-depleted environment

A key feature of the Galilean satellite system is its monotonic decrease in bulk density with distance from Jupiter, indicating an ice mass fraction that is zero in the innermost moon Io, and about half in the outer moons Ganymede and Callisto. Jupiter formation models, and perhaps the Juno spacecraft water measurements, are consistent with the possibility that the Jovian system may have formed, at least partly, from ice-poor material. And yet, models of the formation of the Galilean satellites usually assume abundant water ice in the system. Here, we investigate the possibility that the Jovian circumplanetary disk was populated with ice-depleted chondritic minerals, including phyllosilicates. We show that the dehydration of such particles and the outward diffusion of the released water vapor allow condensation of significant amounts of ice in the formation region of Ganymede and Callisto in the Jovian circumplanetary disk. Our model predicts that Europa, Ganymede and Callisto should have accreted little if any volatiles other than water ice, in contrast to the comet-like composition of Saturn's moon Enceladus. This mechanism allows for the presence of ice-rich moons in water-depleted formation environments around exoplanets as well.

astro-ph.EP↗

arXiv2023

Evolution of the reservoirs of volatiles in the protosolar nebula

The supersolar abundances of volatiles observed in giant planets suggest that a compositional gradient was present at the time of their formation in the protosolar nebula. To explain this gradient, several studies have investigated the radial transport of trace species and the effect of icelines on the abundance profiles of solids and vapors formed in the disk. However, these models only consider the presence of solids in the forms of pure condensates or amorphous ice during the evolution of the protosolar nebula. They usually neglect the possible crystallization and destabilization of clathrates, along with the resulting interplay between the abundance of water and those of these crystalline forms. This study is aimed at pushing this kind of investigation further by considering all possible solid phases together in the protosolar nebula: pure condensates, amorphous ice, and clathrates. To this end, we used a one-dimensional (1D) protoplanetary disk model coupled with modules describing the evolution of trace species in the vapor phase, as well as the dynamics of dust and pebbles. Eleven key species are considered here, including H$_2$O, CO, CO$_2$, CH$_4$, H$_2$S, N$_2$, NH$_3$, Ar, Kr, Xe, and PH$_3$. Two sets of initial conditions are explored for the protosolar nebula. In a first scenario, the disk is initially filled with icy grains in the forms of pure condensates. In this case, we show that clathrates can crystallize and form enrichment peaks up to about ten times the initial abundances at their crystallization lines. In a second scenario, the volatiles were delivered to the protosolar nebula in the forms of amorphous grains. In this case, the presence of clathrates is not possible because there is no available crystalline water ice in their formation region. Enrichment peaks of pure condensates also form beyond the snowline up to about seven times the initial abundances.

astro-ph.EP↗

arXiv2022

Jupiter's Temperature Structure: A Reassessment of the Voyager Radio Occultation Measurements

The thermal structure of planetary atmospheres is an essential input for predicting and retrieving the distribution of gases and aerosols, as well as the bulk chemical abundances. In the case of Jupiter, the temperature at a reference level - generally taken at 1 bar - serves as the anchor in models used to derive the planet's interior structure and composition. Most models assume the temperature measured by the Galileo probe (Seiff et al. 1998). However, those data correspond to a single location, an unusually clear, dry region, affected by local atmospheric dynamics. On the other hand, the Voyager radio occultation observations cover a wider range of latitudes, longitudes, and times (Lindal et al. 1981). The Voyager retrievals were based on atmospheric composition and radio refractivity data that require updating and were never properly tabulated: the few existing tabulations are incomplete and ambiguous. Here, we present a systematic electronic digitization of all available temperature profiles from Voyager, followed by their reanalysis, employing currently accepted values of the abundances and radio refractivities of atmospheric species. We find the corrected temperature at the 1 bar level to be up to 4 K greater than previously published values, i.e., 170.3{\pm}3.8 K at 12°S (Voyager 1 ingress) and 167.3{\pm}3.8 K at 0°N (Voyager 1 egress). This is to be compared with the Galileo probe value of 166.1{\pm}0.8 K at the edge of an unusual feature at 6.57°N. Altogether, this suggests that Jupiter's tropospheric temperatures may vary spatially by up to 7 K between 7°N and 12°S.

astro-ph.EP↗

arXiv2022

Revelations on Jupiter's Formation, Evolution and Interior: Challenges from Juno Results

The Juno mission has revolutionized and challenged our understanding of Jupiter. As Juno transitioned to its extended mission, we review the major findings of Jupiter's internal structure relevant to understanding Jupiter's formation and evolution. Results from Juno's investigation of Jupiter's interior structure imply that the planet has compositional gradients and is accordingly non-adiabatic, with a complex internal structure. These new results imply that current models of Jupiter's formation and evolution require a revision. In this paper, we discuss potential formation and evolution paths that can lead to an internal structure model consistent with Juno data, and the constraints they provide. We note that standard core accretion formation models, including the heavy-element enrichment during planetary growth is consistent with an interior that is inhomogeneous with composition gradients in its deep interior. However, such formation models typically predict that this region, which could be interpreted as a primordial dilute core, is confined to about 10% of Jupiter's total mass. In contrast, structure models that fit Juno data imply that this region contains 30% of the mass or more. One way to explain the origin of this extended region is by invoking a relatively long (about 2 Myrs) formation phase where the growing planet accretes gas and planetesimals delaying the runaway gas accretion. Alternatively, Jupiter's fuzzy core could be a result of a giant impact or convection post-formation. These novel scenarios require somewhat special and specific conditions. Clarity on the plausibility of such conditions could come from future high-resolution observations of planet-forming regions around other stars, from the observed and modeled architectures of extrasolar systems with giant planets, and future Juno data obtained during its extended mission.

astro-ph.EP↗

arXiv2021

Evidence for multiple Ferrel-like cells on Jupiter

Jupiter's atmosphere is dominated by multiple jet streams which are strongly tied to its 3D atmospheric circulation. Lacking a rigid bottom boundary, several models exist for how the meridional circulation extends into the planetary interior. Here we show, collecting evidence from multiple instruments of the Juno mission, the existence of mid-latitudinal meridional circulation cells which are driven by turbulence, similar to the Ferrel cells on Earth. Different than Earth, which contains only one such cell in each hemisphere, the larger, faster rotating Jupiter can incorporate multiple cells. The cells form regions of upwelling and downwelling, which we show are clearly evident in Juno's microwave data between latitude 60S and 60N. The existence of these cells is confirmed by reproducing the ammonia observations using a simplistic model. This study solves a long-standing puzzle regarding the nature of Jupiter's sub-cloud dynamics and provides evidence for 8 cells in each Jovian hemisphere.

astro-ph.EP↗

arXiv2021

The nature and composition of Jupiter's building blocks derived from the water abundance measurements by the Juno spacecraft

The microwave radiometer aboard the Juno spacecraft provided a measurement of the water abundance found to range between 1 and 5.1 times the protosolar abundance of oxygen in the near-equatorial region of Jupiter. Here, we aim to combine this up-to-date oxygen determination, which is likely to be more representative of the bulk abundance than the Galileo probe subsolar value, with the other known measurements of elemental abundances in Jupiter, to derive the formation conditions and initial composition of the building blocks agglomerated by the growing planet, and that determine the heavy element composition of its envelope. We investigate several cases of icy solids formation in the protosolar nebula, from the condensation of pure ices to the crystallization of mixtures of pure condensates and clathrates in various proportions. Each of these cases correspond to a distinct solid composition whose amount is adjusted in the envelope of Jupiter to match the O abundance measured by Juno. The volatile enrichments can be matched by a wide range of planetesimal compositions, from solids exclusively formed from pure condensates or from nearly exclusively clathrates, the latter case providing a slightly better fit. The total mass of volatiles needed in the envelope of Jupiter to match the observed enrichments is within the 4.3-39 Mearth range, depending on the crystallization scenario considered in the protosolar nebula. A wide range of masses of heavy elements derived from our fits is found compatible with the envelope's metallicity calculated from current interior models.

astro-ph.EP↗

arXiv2021

Spin Dynamics of Extrasolar Giant Planets in Planet-Planet Scattering

Planet-planet scattering best explains the eccentricity distribution of extrasolar giant planets. Past literature showed that the orbits of planets evolve due to planet-planet scattering. This work studies the spin evolution of planets in planet-planet scattering in 2-planet systems. Spin can evolve dramatically due to spin-orbit coupling made possible by the evolving spin and orbital precession during the planet-planet scattering phase. The main source of torque to planet spin is the stellar torque, and the total planet-plane torque contribution is negligible. As a consequence of the evolution of the spin, planets can end up with significant obliquity (the angle between a planet's own orbit normal and spin axis) like planets in our Solar System.

astro-ph.EP↗

arXiv2021

Cold traps of hypervolatiles in the protosolar nebula at the origin of comet C/2016 R2 (PanSTARRS)'s peculiar composition

Recent observations of the long period comet C/2016 R2 (PanSTARRS) indicate an unusually high N2/CO abundance ratio, typically larger than 0.05, and at least 2-3 times higher than the one measured in 67P/Churyumov-Gerasimenko. Another striking compositional feature of this comet is its heavy depletion in H2O, compared to other comets. Here, we investigate the formation circumstances of a generic comet whose composition reproduces these two key features. We first envisage the possibility that this comet agglomerated from clathrates, but we find that such a scenario does not explain the observed low water abundance. We then alternatively investigate the possibility that the building blocks of the comet C/2016 R2 (PanSTARRS) agglomerated from grains and pebbles made of pure condensates via the use of a disk model describing the radial transport of volatiles. We show that N2/CO ratios reproducing the value estimated in this comet can be found in grains condensed in the vicinity of the CO and N2 icelines. Moreover, high CO/H2O ratios (>100 times the initial gas phase value) can be found in grains condensed in the vicinity of the CO iceline. If the building blocks of a comet assembled from such grains, they should present N2/CO and CO/H2O ratios consistent with the measurements made in comet C/2016 R2 (PanSTARRS)'s coma. Our scenario indicates that comet C/2016 R2 (PanSTARRS) formed in a colder environment than the other comets that share more usual compositions. Our model also explains the unusual composition of the interstellar comet 2l/Borisov.

astro-ph.EP↗