arXiv subjects

Jonathan I. Lunine

Publications and source records attributed to Jonathan I. Lunine.

At least 55 records · Page 3Linked to original sources

arXiv2013

On the possible noble gas deficiency of Pluto's atmosphere

We use a statistical-thermodynamic model to investigate the formation and composition of noble-gas-rich clathrates on Pluto's surface. By considering an atmospheric composition close to that of today's Pluto and a broad range of surface pressures, we find that Ar, Kr and Xe can be efficiently trapped in clathrates if they formed at the surface, in a way similar to what has been proposed for Titan. The formation on Pluto of clathrates rich in noble gases could then induce a strong decrease in their atmospheric abundances relative to their initial values. A clathrate thickness of order of a few centimeters globally averaged on the planet is enough to trap all Ar, Kr and Xe if these noble gases were in protosolar proportions in Pluto's early atmosphere. Because atmospheric escape over an extended period of time (millions of years) should lead to a noble gas abundance that either remains constant or increases with time, we find that a potential depletion of Ar, Kr and Xe in the atmosphere would best be explained by their trapping in clathrates. A key observational test is the measurement of Ar since the Alice UV spectrometer aboard the New Horizons spacecraft will be sensitive enough to detect its abundance $\sim$10 times smaller than in the case considered here.

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arXiv2012

Building Terrestrial Planets

This paper reviews our current understanding of terrestrial planets formation. The focus is on computer simulations of the dynamical aspects of the accretion process. Throughout the chapter, we combine the results of these theoretical models with geochemical, cosmochemical and chronological constraints, in order to outline a comprehensive scenario of the early evolution of our Solar System. Given that the giant planets formed first in the protoplanetary disk, we stress the sensitive dependence of the terrestrial planet accretion process on the orbital architecture of the giant planets and on their evolution. This suggests a great diversity among the terrestrial planets populations in extrasolar systems. Issues such as the cause for the different masses and accretion timescales between Mars and the Earth and the origin of water (and other volatiles) on our planet are discussed at depth.

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arXiv2012

Planetesimal Compositions in Exoplanet Systems

We have used recent surveys of the composition of exoplanet host stars to investigate the expected composition of condensed material in planetesimals formed beyond the snow line in the circumstellar nebulae of these systems. Of the major solid forming elements, we find that, as for the Sun, the C and O abundances (and particularly the C/O abundance ratio) have the most significant effect on the composition of icy planetesimals formed in these systems. The calculations use a self-consistent model for the condensation sequence of volatile ices from the nebula gas after refractory (silicate and metal) phases have condensed. The resultant proportions of refractory phases and ices were calculated for a range of nebular temperature structure and redox conditions. Planetesimals in systems with sub-solar C/O should be water ice-rich, with lower than solar mass fractions of refractory materials, while in super-solar C/O systems planetesimals should have significantly higher fractions of refractories, in some cases having little or no water ice. C-bearing volatile ices and clathrates also become increasingly important with increasing C/O depending on the assumed nebular temperatures. These compositional variations in early condensates in the outer portions of the nebula will be significant for the equivalent of the Kuiper Belt in these systems, icy satellites of giant planets and the enrichment (over stellar values) of volatiles and heavy elements in giant planet atmospheres.

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arXiv2012

The dual origin of the nitrogen deficiency in comets: selective volatile trapping in the nebula and postaccretion radiogenic heating

We propose a scenario that explains the apparent nitrogen deficiency in comets in a way consistent with the fact that the surfaces of Pluto and Triton are dominated by nitrogen-rich ice. We use a statistical thermodynamic model to investigate the composition of the successive multiple guest clathrates that may have formed during the cooling of the primordial nebula from the most abundant volatiles present in the gas phase. These clathrates agglomerated with the other ices (pure condensates or stoichiometric hydrates) and formed the building blocks of comets. We report that molecular nitrogen is a poor clathrate former, when we consider a plausible gas phase composition of the primordial nebula. This implies that its trapping into cometesimals requires a low disk temperature ($\sim$20 K) in order to allow the formation of its pure condensate. We find that it is possible to explain the lack of molecular nitrogen in comets as a consequence of their postformation internal heating engendered by the decay of short-lived radiogenic nuclides. This scenario is found consistent with the presence of nitrogen-rich ice covers on Pluto and Triton. Our model predicts that comets should present xenon-to-water and krypton-to-water ratios close to solar xenon-to-oxygen and krypton-to-oxygen ratios, respectively. In contrast, the argon-to-water ratio is predicted to be depleted by a factor of $\sim$300 in comets compared to solar argon-to-oxygen, as a consequence of poor trapping efficiency and radiogenic heating.

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arXiv2012

Chemical Constraints on the Oxygen Abundances in Jupiter and Saturn

We perform a comparative analysis of the chemical kinetics of CO and $\rm PH_3$ in Jupiter and Saturn to assess the full set of constraints available on the troposphere water abundance in the two giant planets. For carbon monoxide we employ both a widely used CO kinetic scheme from Yung et al, and a newly identified CO chemical scheme from Visscher and Moses. For $\rm PH_3$ chemical scheme, we use the same chemical scheme as in Visscher and Fegley. Yung's chemical scheme for CO yields a water enrichment of 0.95 - 23.0 times solar abundance on Jupiter, and an upper limit of 14.0 for Saturn. Visscher's chemical scheme in contrast produces a water enrichment of 0.24 - 2.6 times solar abundance in Jupiter, and for Saturn an upper limit for water enrichment of 8.0. From this scheme, which takes advantage of the most up-to-date kinetics, we preclude high water enrichments on Jupiter and Saturn, and show that the kinetics approach yields Jovian bulk abundance in which values of C/O elevated relative to solar are admissible. Our result is consistent with recent reinterpretation of Galileo Probe data in which Jupiter formed in a water-depleted portion of the protoplanetary disk (Mousis et al).

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arXiv2012

Nebular water depletion as the cause of Jupiter's low oxygen abundance

Motivated by recent spectroscopic observations suggesting that atmospheres of some extrasolar giant-planets are carbon-rich, i.e. carbon/oxygen ratio (C/O) $\ge$ 1, we find that the whole set of compositional data for Jupiter is consistent with the hypothesis that it be a carbon-rich giant planet. We show that the formation of Jupiter in the cold outer part of an oxygen-depleted disk (C/O $\sim$1) reproduces the measured Jovian elemental abundances at least as well as the hitherto canonical model of Jupiter formed in a disk of solar composition (C/O = 0.54). The resulting O abundance in Jupiter's envelope is then moderately enriched by a factor of $\sim$2 $\times$ solar (instead of $\sim$7 $\times$ solar) and is found to be consistent with values predicted by thermochemical models of the atmosphere. That Jupiter formed in a disk with C/O $\sim$1 implies that water ice was heterogeneously distributed over several AU beyond the snow line in the primordial nebula and that the fraction of water contained in icy planetesimals was a strong function of their formation location and time. The Jovian oxygen abundance to be measured by NASA's Juno mission en route to Jupiter will provide a direct and strict test of our predictions.

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arXiv2011

Carbon-rich Giant Planets: Atmospheric Chemistry, Thermal Inversions, Spectra, and Formation conditions

The recent inference of a carbon-rich atmosphere, with C/O >= 1, in the hot Jupiter WASP-12b motivates the exotic new class of carbon-rich planets (CRPs). We report a detailed study of the atmospheric chemistry and spectroscopic signatures of carbon-rich giant planets (CRGs) and the compositions of icy planetesimals required for their formation, and the apportionment of ices, rock, and volatiles in their envelopes. For C/O >= 1, most of the atmospheric oxygen is occupied by CO for T > 1400 K and pressure (P) < 1 bar, causing a substantial depletion in H2O, and an overabundance of CH4 compared to those obtained by assuming solar abundances (C/O = 0.54) in chemical equilibrium. These differences in chemistry cause distinctly observable signatures in spectra. We also find that a C/O >= 1 strongly depletes the abundances of TiO and VO available to form thermal inversions, which is adequate to rule out thermal inversions due to TiO/VO even in the most highly irradiated hot Jupiters, such as WASP-12b. Adopting stellar abundances (C/O = 0.44) for the primordial disk composition and low-temperature formation conditions (T <= 30 K) for WASP-12b leads to a C/O ratio of 0.27 in accreted planetesimals, and, consequently, in the planet's envelope. In contrast, a C/O ratio of 1 in the envelope of WASP-12b requires a substantial depletion of oxygen in the disk, by a factor of ~0.41 for the same formation conditions. This scenario also satisfies the constraints on the C/H and O/H ratios reported for WASP-12b. If, alternatively, hotter conditions prevailed in a stellar composition disk such that only H2O is condensed, the remaining gas can potentially have a C/O ~ 1. However, a high C/O in WASP-12b caused predominantly by gas accretion would preclude super-stellar C/H ratios which also fit the data.

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arXiv2011

Removal of Titan's Atmospheric Noble Gases by their Sequestration in Surface Clathrates

A striking feature of the atmosphere of Titan is that no heavy noble gases other than argon were detected by the Gas Chromatograph Mass Spectrometer (GCMS) aboard the Huygens probe during its descent to Titan's surface in January 2005. Here we provide an explanation of the mysterious absence or rarity of these noble gases in Titan's atmosphere: the thermodynamic conditions prevailing at the surface-atmosphere interface of the satellite allow the formation of multiple guest clathrates that preferentially store some species, including all heavy noble gases, over others. The clean water ice needed for formation of these clathrates could be delivered by successive episodes of cryovolcanic lavas that have been hypothesized to regularly cover the surface of Titan. The formation of clathrates in the porous lavas and their propensity for trapping Ar, Kr and Xe would progressively remove these species from the atmosphere of Titan over its history. In some circumstances, a global clathrate crust with an average thickness not exceeding a few meters could be sufficient on Titan for a complete removal of the heavy noble gases from the atmosphere.

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arXiv2010

Impact regimes and post-formation sequestration processes: implications for the origin of heavy noble gases in terrestrial planets

The difference between the measured atmospheric abundances of neon, argon, krypton and xenon for Venus, the Earth and Mars is striking. Because these abundances drop by at least two orders of magnitude as one moves outward from Venus to Mars, the study of the origin of this discrepancy is a key issue that must be explained if we are to fully understand the different delivery mechanisms of the volatiles accreted by the terrestrial planets. In this work, we aim to investigate whether it is possible to quantitatively explain the variation of the heavy noble gas abundances measured on Venus, the Earth and Mars, assuming that cometary bombardment was the main delivery mechanism of these noble gases to the terrestrial planets. To do so, we use recent dynamical simulations that allow the study of the impact fluxes of comets upon the terrestrial planets during the course of their formation and evolution. Assuming that the mass of noble gases delivered by comets is proportional to rate at which they collide with the terrestrial planets, we show that the krypton and xenon abundances in Venus and the Earth can be explained in a manner consistent with the hypothesis of cometary bombardment. In order to explain the krypton and xenon abundance differences between the Earth and Mars, we need to invoke the presence of large amounts of CO2-dominated clathrates in the Martian soil that would have efficiently sequestered these noble gases.

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arXiv2009

Elemental abundances and minimum mass of heavy elements in the envelope of HD 189733b

Oxygen (O) and carbon (C) have been inferred recently to be subsolar in abundance from spectra of the atmosphere of the transiting hot Jupiter HD 189733b. Yet, the mass and radius of the planet coupled with structure models indicate a strongly supersolar abundance of heavy elements in the interior of this object. Here we explore the discrepancy between the large amount of heavy elements suspected in the planet's interior and the paucity of volatiles measured in its atmosphere. We describe the formation sequence of the icy planetesimals formed beyond the snow line of the protoplanetary disk and calculate the composition of ices ultimately accreted in the envelope of HD 189733b on its migration pathway. This allows us to reproduce the observed volatile abundances by adjusting the mass of ices vaporized in the envelope. The predicted elemental mixing ratios should be 0.15--0.3 times solar in the envelope of HD 189733b if they are fitted to the recent O and C determinations. However, our fit to the minimum mass of heavy elements predicted by internal structure models gives elemental abundances that are 1.2--2.4 times oversolar in the envelope of HD189733b. We propose that the most likely cause of this discrepancy is irradiation from the central star leading to development of a radiative zone in the planet's outer envelope which would induce gravitational settling of elements. Hence, all strongly irradiated extrasolar planets should present subsolar abundances of volatiles. We finally predict that the abundances of nitrogen (N), sulfur (S) and phosphorus (P) are of $\sim$ $2.8 \times 10^{-5}$, $5.3 \times 10^{-6}$ and $1.8 \times 10^{-7}$ relative to H$_2$, respectively in the atmosphere of HD 189733b.

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arXiv2009

A primordial origin for the atmospheric methane of Saturn's moon Titan

The origin of Titan's atmospheric methane is a key issue for understanding the origin of the Saturnian satellite system. It has been proposed that serpentinization reactions in Titan's interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan's planetesimals before its formation. Here, we point out that serpentinization reactions in Titan's interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan's water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan's interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/H ratio is its direct capture in the satellite's planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan's interior can be up to 1,300 times the current mass of atmospheric methane.

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arXiv2009

Dynamical Models of Terrestrial Planet Formation

We review the problem of the formation of terrestrial planets, with particular emphasis on the interaction of dynamical and geochemical models. The lifetime of gas around stars in the process of formation is limited to a few million years based on astronomical observations, while isotopic dating of meteorites and the Earth-Moon system suggest that perhaps 50-100 million years were required for the assembly of the Earth. Therefore, much of the growth of the terrestrial planets in our own system is presumed to have taken place under largely gas-free conditions, and the physics of terrestrial planet formation is dominated by gravitational interactions and collisions. The earliest phase of terrestrial-planet formation involve the growth of km-sized or larger planetesimals from dust grains, followed by the accumulations of these planetesimals into ~100 lunar- to Mars-mass bodies that are initially gravitationally isolated from one-another in a swarm of smaller planetesimals, but eventually grow to the point of significantly perturbing one-another. The mutual perturbations between the embryos, combined with gravitational stirring by Jupiter, lead to orbital crossings and collisions that drive the growth to Earth-sized planets on a timescale of 10-100 million years. Numerical treatment of this process has focussed on the use of symplectic integrators which can rapidly integrate the thousands of gravitationally-interacting bodies necessary to accurately model planetary growth. While the general nature of the terrestrial planets--their sizes and orbital parameters--seem to be broadly reproduced by the models, there are still some outstanding dynamical issues. One of these is the presence of an embryo-sized body, Mars, in our system in place of the more massive objects that simulations tend to yield. [Abridged]

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arXiv2008

Determination of the minimum masses of heavy elements in the envelopes of Jupiter and Saturn

We calculate the minimum mass of heavy elements required in the envelopes of Jupiter and Saturn to match the observed oversolar abundances of volatiles. Because the clathration efficiency remains unknown in the solar nebula, we have considered a set of sequences of ice formation in which the fraction of water available for clathration is varied between 0 and 100 %. In all the cases considered, we assume that the water abundance remains homogeneous whatever the heliocentric distance in the nebula and directly derives from a gas phase of solar composition. Planetesimals then form in the feeding zones of Jupiter and Saturn from the agglomeration of clathrates and pure condensates in proportions fixed by the clathration efficiency. A fraction of Kr and Xe may have been sequestrated by the H3+ ion in the form of stable XeH3+ and KrH3+ complexes in the solar nebula gas phase, thus implying the formation of at least partly Xe- and Kr-impoverished planetesimals in the feeding zones of Jupiter and Saturn. These planetesimals were subsequently accreted and vaporized into the hydrogen envelopes of Jupiter and Saturn, thus engendering volatiles enrichments in their atmospheres, with respect to hydrogen. Taking into account both refractory and volatile components, and assuming plausible molecular mixing ratios in the gas phase of the outer solar nebula, we show that it is possible to match the observed enrichments in Jupiter and Saturn, whatever the clathration efficiency. Our calculations predict that the O/H enrichment decreases from 6.7 to 5.6 times solar (O/H) in the envelope of Jupiter and from 18.1 to 15.4 times solar (O/H) in the envelope of Saturn with the growing clathration efficiency in the solar nebula.

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arXiv2008

Clathration of Volatiles in the Solar Nebula and Implications for the Origin of Titan's atmosphere

We describe a scenario of Titan's formation matching the constraints imposed by its current atmospheric composition. Assuming that the abundances of all elements, including oxygen, are solar in the outer nebula, we show that the icy planetesimals were agglomerated in the feeding zone of Saturn from a mixture of clathrates with multiple guest species, so-called stochiometric hydrates such as ammonia hydrate, and pure condensates. We also use a statistical thermodynamic approach to constrain the composition of multiple guest clathrates formed in the solar nebula. We then infer that krypton and xenon, that are expected to condense in the 20-30 K temperature range in the solar nebula, are trapped in clathrates at higher temperatures than 50 K. Once formed, these ices either were accreted by Saturn or remained embedded in its surrounding subnebula until they found their way into the regular satellites growing around Saturn. In order to explain the carbon monoxide and primordial argon deficiencies of Titan's atmosphere, we suggest that the satellite was formed from icy planetesimals initially produced in the solar nebula and that were partially devolatilized at a temperature not exceeding 50 K during their migration within Saturn's subnebula. The observed deficiencies of Titan's atmosphere in krypton and xenon could result from other processes that may have occurred both prior or after the completion of Titan. Thus, krypton and xenon may have been sequestrated in the form of XH3+ complexes in the solar nebula gas phase, causing the formation of noble gas-poor planetesimals ultimately accreted by Titan. Alternatively, krypton and xenon may have also been trapped efficiently in clathrates located on the satellite's surface or in its atmospheric haze.

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arXiv2008

Constraints from deuterium on the formation of icy bodies in the Jovian system and beyond

We consider the role of deuterium as a potential marker of location and ambient conditions during the formation of small bodies in our Solar system. We concentrate in particular on the formation of the regular icy satellites of Jupiter and the other giant planets, but include a discussion of the implications for the Trojan asteroids and the irregular satellites. We examine in detail the formation of regular planetary satellites within the paradigm of a circum-Jovian subnebula. Particular attention is paid to the two extreme potential subnebulae - "hot" and "cold". In particular, we show that, for the case of the "hot" subnebula model, the D:H ratio in water ice measured from the regular satellites would be expected to be near-Solar. In contrast, satellites which formed in a "cold" subnebula would be expected to display a D:H ratio that is distinctly over-Solar. We then compare the results obtained with the enrichment regimes which could be expected for other families of icy small bodies in the outer Solar system - the Trojan asteroids and the irregular satellites. In doing so, we demonstrate how measurements by Laplace, the James Webb Space Telescope, HERSCHEL and ALMA will play an important role in determining the true formation locations and mechanisms of these objects.

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arXiv2007

High-resolution simulations of the final assembly of Earth-like planets 2: water delivery and planetary habitability

The water content and habitability of terrestrial planets are determined during their final assembly, from perhaps a hundred 1000-km "planetary embryos" and a swarm of billions of 1-10 km "planetesimals." During this process, we assume that water-rich material is accreted by terrestrial planets via impacts of water-rich bodies that originate in the outer asteroid region. We present analysis of water delivery and planetary habitability in five high-resolution simulations containing about ten times more particles than in previous simulations (Raymond et al 2006a, Icarus, 183, 265-282). These simulations formed 15 terrestrial planets from 0.4 to 2.6 Earth masses, including five planets in the habitable zone. Every planet from each simulation accreted at least the Earth's current water budget; most accreted several times that amount (assuming no impact depletion). Each planet accreted at least five water-rich embryos and planetesimals from past 2.5 AU; most accreted 10-20 water-rich bodies. We present a new model for water delivery to terrestrial planets in dynamically calm systems, with low-eccentricity or low-mass giant planets -- such systems may be very common in the Galaxy. We suggest that water is accreted in comparable amounts from a few planetary embryos in a "hit or miss" way and from millions of planetesimals in a statistically robust process. Variations in water content are likely to be caused by fluctuations in the number of water-rich embryos accreted, as well as from systematic effects such as planetary mass and location, and giant planet properties.

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arXiv2006

The James Webb Space Telescope

The James Webb Space Telescope (JWST) is a large (6.6m), cold (50K), infrared-optimized space observatory that will be launched early in the next decade. The observatory will have four instruments: a near-infrared camera, a near-infrared multi-object spectrograph, and a tunable filter imager will cover the wavelength range, 0.6 to 5.0 microns, while the mid-infrared instrument will do both imaging and spectroscopy from 5.0 to 29 microns. The JWST science goals are divided into four themes. The End of the Dark Ages: First Light and Reionization theme seeks to identify the first luminous sources to form and to determine the ionization history of the early universe. The Assembly of Galaxies theme seeks to determine how galaxies and the dark matter, gas, stars, metals, morphological structures, and active nuclei within them evolved from the epoch of reionization to the present day. The Birth of Stars and Protoplanetary Systems theme seeks to unravel the birth and early evolution of stars, from infall on to dust-enshrouded protostars to the genesis of planetary systems. The Planetary Systems and the Origins of Life theme seeks to determine the physical and chemical properties of planetary systems including our own, and investigate the potential for the origins of life in those systems. To enable these observations, JWST consists of a telescope, an instrument package, a spacecraft and a sunshield. The telescope consists of 18 beryllium segments, some of which are deployed. The segments will be brought into optical alignment on-orbit through a process of periodic wavefront sensing and control. The JWST operations plan is based on that used for previous space observatories, and the majority of JWST observing time will be allocated to the international astronomical community through annual peer-reviewed proposal opportunities.

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arXiv2005

High-resolution simulations of the final assembly of Earth-like planets 1: terrestrial accretion and dynamics

The final stage in the formation of terrestrial planets consists of the accumulation of ~1000-km ``planetary embryos'' and a swarm of billions of 1-10 km ``planetesimals.'' During this process, water-rich material is accreted by the terrestrial planets via impacts of water-rich bodies from beyond roughly 2.5 AU. We present results from five high-resolution dynamical simulations. These start from 1000-2000 embryos and planetesimals, roughly 5-10 times more particles than in previous simulations. Each simulation formed 2-4 terrestrial planets with masses between 0.4 and 2.6 Earth masses. The eccentricities of most planets were ~0.05, lower than in previous simulations, but still higher than for Venus, Earth and Mars. Each planet accreted at least the Earth's current water budget. We demonstrate several new aspects of the accretion process: 1) The feeding zones of terrestrial planets change in time, widening and moving outward. Even in the presence of Jupiter, water-rich material from beyond 2.5 AU is not accreted for several millions of years. 2) Even in the absence of secular resonances, the asteroid belt is cleared of >99% of its original mass by self-scattering of bodies into resonances with Jupiter. 3) If planetary embryos form relatively slowly, following the models of Kokubo & Ida, then the formation of embryos in the asteroid belt may have been stunted by the presence of Jupiter. 4) Self-interacting planetesimals feel dynamical friction from other small bodies, which has important effects on the eccentricity evolution and outcome of a simulation.

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