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Jonathan J. Fortney

Publications and source records attributed to Jonathan J. Fortney.

At least 91 records · Page 5Linked to original sources
arXiv2023

Outgassing Composition of the Murchison Meteorite: Implications for Volatile Depletion of Planetesimals and Interior-atmosphere Connections for Terrestrial Exoplanets

Outgassing is a central process during the formation and evolution of terrestrial planets and their atmospheres both within and beyond the solar system. Although terrestrial planets' early atmospheres likely form via outgassing during planetary accretion, the connection between a planet's bulk composition and its initial atmospheric properties is not well understood. One way to inform this connection is to analyze the outgassing compositions of meteorites, and in particular carbonaceous chondrites, because they are some of the most volatile-rich, primitive materials (in terms of their bulk compositions) that are available for direct study. In addition, they may serve as compositional analogs for the building block materials of terrestrial planets in our solar system and around other Sun-like stars. This study builds upon previous outgassing experiments that monitored the abundances of volatile species (e.g., H2O, CO, and CO2) released from the Murchison meteorite. To gain a more complete understanding of Murchison's outgassing composition, we perform a series of heating experiments under atmospheric pressure (1 bar) and vacuum (1E-9 bar) conditions on samples of the Murchison meteorite and subsequent bulk element analysis to inform the outgassing trends of a suite of major elements in Murchison (e.g., Fe, Mg, Zn, and S). Under both pressure conditions, sulfur outgases significantly at the highest temperatures (800C - 1000C). For the samples heated under vacuum conditions, we also detect outgassing of zinc. Combined with prior outgassing experiments, this study provides important insights into the volatile depletion patterns of undifferentiated planetesimals and the early outgassing compositions of terrestrial exoplanets.

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arXiv2023

Nitrogen as a Tracer of Giant Planet Formation. II.: Comprehensive Study of Nitrogen Photochemistry and Implications for Observing NH3 and HCN in Transmission and Emission Spectra

Atmospheric nitrogen may provide important constraints on giant planet formation. Following our semi-analytical work (Ohno & Fortney 2022), we further pursue the relation between observable NH3 and an atmosphere's bulk nitrogen abundance by applying the photochemical kinetics model VULCAN across planetary equilibrium temperature, mass, age, eddy diffusion coefficient, atmospheric composition, and stellar spectral type. We confirm that the quenched NH3 abundance coincides with the bulk nitrogen abundance only at sub-Jupiter mass (< 1MJ) planets and old ages (> 1 Gyr) for solar composition atmospheres, highlighting important caveats for inferring atmospheric nitrogen abundances. Our semi-analytical model reproduces the quenched NH3 abundance computed by VULCAN and thus helps to infer the bulk nitrogen abundance from a retrieved NH3 abundance. By computing transmission and emission spectra, we predict that the equilibrium temperature range of 400--1000 K is optimal for detecting NH3 because NH3 depletion by thermochemistry and photochemistry is significant at hotter planets whereas entire spectral features become weak at colder planets. For Jupiter-mass planets around Sun-like stars in this temperature range, NH3 leaves observable signatures of $\sim$ 50 ppm at 1.5, 2.1, and 11 $\rm μm$ in transmission spectra and > 300--100 ppm at 6 $\rm μm$ and 11 $\rm μm$ in emission spectra. The photodissociation of NH3 leads HCN to replace NH3 at low pressures. However, the low HCN column densities lead to much weaker absorption features than for NH3. The NH3 features are readily accessible to JWST observations to constrain atmospheric nitrogen abundances, which may open a new avenue to understand the formation processes of giant exoplanets.

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arXiv2023

Water absorption in the transmission spectrum of the water-world candidate GJ9827d

Recent work on the characterization of small exoplanets has allowed us to accumulate growing evidence that the sub-Neptunes with radii greater than $\sim2.5\,R_\oplus$ often host H$_2$/He-dominated atmospheres both from measurements of their low bulk densities and direct detections of their low mean-molecular-mass atmospheres. However, the smaller sub-Neptunes in the 1.5-2.2 R$_\oplus$ size regime are much less understood, and often have bulk densities that can be explained either by the H$_2$/He-rich scenario, or by a volatile-dominated composition known as the "water world" scenario. Here, we report the detection of water vapor in the transmission spectrum of the $1.96\pm0.08$ R$_\oplus$ sub-Neptune GJ9827d obtained with the Hubble Space Telescope. We observed 11 HST/WFC3 transits of GJ9827d and find an absorption feature at 1.4$μ$m in its transit spectrum, which is best explained (at 3.39$σ$) by the presence of water in GJ9827d's atmosphere. We further show that this feature cannot be caused by unnoculted star spots during the transits by combining an analysis of the K2 photometry and transit light-source effect retrievals. We reveal that the water absorption feature can be similarly well explained by a small amount of water vapor in a cloudy H$_2$/He atmosphere, or by a water vapor envelope on GJ9827d. Given that recent studies have inferred an important mass-loss rate ($>0.5\,$M$_\oplus$/Gyr) for GJ9827d making it unlikely to retain a H-dominated envelope, our findings highlight GJ9827d as a promising water world candidate that could host a volatile-dominated atmosphere. This water detection also makes GJ9827d the smallest exoplanet with an atmospheric molecular detection to date.

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arXiv2023

Methane Throughout the Atmosphere of the Warm Exoplanet WASP-80b

The abundances of major carbon and oxygen bearing gases in the atmospheres of giant exoplanets provide insights into atmospheric chemistry and planet formation processes. Thermochemistry suggests that methane should be the dominant carbon-bearing species below $\sim$1000 K over a range of plausible atmospheric compositions; this is the case for the Solar System planets and has been confirmed in the atmospheres of brown dwarfs and self-luminous directly imaged exoplanets. However, methane has not yet been definitively detected with space-based spectroscopy in the atmosphere of a transiting exoplanet, but a few detections have been made with ground-based, high-resolution transit spectroscopy including a tentative detection for WASP-80b. Here we report transmission and emission spectra spanning 2.4-4.0 micrometers of the 825 K warm Jupiter WASP-80b taken with JWST's NIRCam instrument, both of which show strong evidence for methane at greater than 6-sigma significance. The derived methane abundances from both viewing geometries are consistent with each other and with solar to sub-solar C/O and ~5$\times$ solar metallicity, which is consistent with theoretical predictions.

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arXiv2023

ELemental abundances of Planets and brown dwarfs Imaged around Stars (ELPIS): I. Potential Metal Enrichment of the Exoplanet AF Lep b and a Novel Retrieval Approach for Cloudy Self-luminous Atmospheres

AF Lep A+b is a remarkable planetary system hosting a gas-giant planet that has the lowest dynamical mass among directly imaged exoplanets. We present an in-depth analysis of the atmospheric composition of the star and planet to probe the planet's formation pathway. Based on new high-resolution spectroscopy of AF Lep A, we measure a uniform set of stellar parameters and elemental abundances (e.g., [Fe/H] = $-0.27 \pm 0.31$ dex). The planet's dynamical mass ($2.8^{+0.6}_{-0.5}$ M$_{\rm Jup}$) and orbit are also refined using published radial velocities, relative astrometry, and absolute astrometry. We use petitRADTRANS to perform chemically-consistent atmospheric retrievals for AF Lep b. The radiative-convective equilibrium temperature profiles are incorporated as parameterized priors on the planet's thermal structure, leading to a robust characterization for cloudy self-luminous atmospheres. This novel approach is enabled by constraining the temperature-pressure profiles via the temperature gradient $(d\ln{T}/d\ln{P})$, a departure from previous studies that solely modeled the temperature. Through multiple retrievals performed on different portions of the $0.9-4.2$ $μ$m spectrophotometry, along with different priors on the planet's mass and radius, we infer that AF Lep b likely possesses a metal-enriched atmosphere ([Fe/H] $> 1.0$ dex). AF Lep b's potential metal enrichment may be due to planetesimal accretion, giant impacts, and/or core erosion. The first process coincides with the debris disk in the system, which could be dynamically excited by AF Lep b and lead to planetesimal bombardment. Our analysis also determines $T_{\rm eff} \approx 800$ K, $\log{(g)} \approx 3.7$ dex, and the presence of silicate clouds and dis-equilibrium chemistry in the atmosphere. Straddling the L/T transition, AF Lep b is thus far the coldest exoplanet with suggested evidence of silicate clouds.

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arXiv2023

ExoGemS High-Resolution Transmission Spectroscopy of WASP-76b with GRACES

We present high-resolution transmission spectroscopy of WASP-76b with GRACES/Gemini North obtained as part of the ExoGemS survey. With a broad spectral range of 400-1050 nm and a relatively high resolution of ~66,000, these observations are particularly well-suited to searching for atomic and molecular atmospheric species via the Doppler cross-correlation technique. We recover absorption features due to neutral iron (Fe I), sodium (Na I), and ionized calcium (Ca II) at high significance (>5$σ$), and investigate possible atmospheric temperatures and wind speeds. We also report tentative (>3$σ$) detections of Li I, K I, Cr I, and V I in the atmosphere of WASP-76b. Finally, we report non-detections of a number of other species, some of which have previously been detected with other instruments. Through model injection/recovery tests, we demonstrate that many of these species are not expected to be detected in our observations. These results allow us to place GRACES and the ExoGemS survey in context with other high-resolution optical spectrographs.

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arXiv2023

Brown Dwarf Retrievals on FIRE!: Atmospheric Constraints and Lessons Learned from High Signal-to-Noise Medium Resolution Spectroscopy of a T9 Dwarf

Brown dwarf spectra offer vital testbeds for our understanding of the chemical and physical processes that sculpt substellar atmospheres. Recently, atmospheric retrieval approaches have been applied to a number of low-resolution (R~100) spectra of brown dwarfs, yielding constraints on the abundances of chemical species and temperature structures of these atmospheres. Medium-resolution (R~1e3) spectra of brown dwarfs offer significant additional insight, as molecular features are more easily disentangled from one another and the thermal structure of the upper atmosphere is more readily probed. We present results from a GPU-based retrieval analysis of a high signal-to-noise, medium-resolution (R~6000) FIRE spectrum from 0.85-2.5 microns of a T9 dwarf. At 60x higher spectral resolution than previous brown dwarf retrievals, a number of novel challenges arise. We examine the strong effect of different opacity sources on our retrieved constraints, in particular for CH4. Furthermore, we find that flaws in the data such as errors from order stitching can greatly bias our results. We compare these results to those obtained for a R~100 spectrum of the same object, revealing how constraints on atmospheric abundances and temperatures improve by an order of magnitude or more (depending on the species) with increased spectral resolution. In particular, we precisely constrain the abundance of H2S, which is undetectable at lower spectral resolution. While these medium-resolution retrievals offer the potential of precise, stellar-like constraints on atmospheric abundances (~0.02 dex), our retrieved radius is unphysically small (R~0.50 R$_{Jup}$), indicating lingering shortcomings with our modeling framework. This work is an initial investigation into brown dwarf retrievals at medium spectral resolution, offering guidance for future ground-based studies and JWST observations of substellar objects.

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arXiv2023

Thermal emission from the Earth-sized exoplanet TRAPPIST-1 b using JWST

The TRAPPIST-1 system is remarkable for its seven planets that are similar in size, mass, density, and stellar heating to the rocky planets Venus, Earth, and Mars in our own Solar System (Gillon et al. 2017). All TRAPPIST-1 planets have been observed with the transmission spectroscopy technique using the Hubble or Spitzer Space Telescopes, but no atmospheric features have been detected or strongly constrained (Ducrot et al. 2018; de Wit et al. 2018; Zhang et al. 2018; Garcia et al. 2022). TRAPPIST-1 b is the closest planet to the system's M dwarf star, and it receives 4 times as much irradiation as Earth receives from the Sun. This relatively large amount of stellar heating suggests that its thermal emission may be measurable. Here we present photometric secondary eclipse observations of the Earth-sized TRAPPIST-1 b exoplanet using the F1500W filter of the MIRI instrument on JWST. We detect the secondary eclipse in each of five separate observations with 8.7-$σ$ confidence when all data are combined. These measurements are most consistent with the re-radiation of the TRAPPIST-1 star's incident flux from only the dayside hemisphere of the planet. The most straightforward interpretation is that there is little or no planetary atmosphere redistributing radiation from the host star and also no detectable atmospheric absorption from carbon dioxide (CO$_2$) or other species.

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arXiv2023

The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems I: High Contrast Imaging of the Exoplanet HIP 65426 b from 2-16 $μ$m

We present JWST Early Release Science (ERS) coronagraphic observations of the super-Jupiter exoplanet, HIP 65426 b, with the Near-Infrared Camera (NIRCam) from 2-5 $μ$m, and with the Mid-Infrared Instrument (MIRI) from 11-16 $μ$m. At a separation of $\sim$0.82" (86$^{+116}_{-31}$ au), HIP 65426 b is clearly detected in all seven of our observational filters, representing the first images of an exoplanet to be obtained by JWST, and the first ever direct detection of an exoplanet beyond 5 $μ$m. These observations demonstrate that JWST is exceeding its nominal predicted performance by up to a factor of 10, depending on separation and subtraction method, with measured 5$σ$ contrast limits of $\sim$1$\times10^{-5}$ and $\sim$2$\times10^{-4}$ at 1" for NIRCam at 4.4 $μ$m and MIRI at 11.3 $μ$m, respectively. These contrast limits provide sensitivity to sub-Jupiter companions with masses as low as 0.3$M_\mathrm{Jup}$ beyond separations of $\sim$100 au. Together with existing ground-based near-infrared data, the JWST photometry are well fit by a BT-SETTL atmospheric model from 1-16 $μ$m, and span $\sim$97% of HIP 65426 b's luminous range. Independent of the choice of model atmosphere we measure an empirical bolometric luminosity that is tightly constrained between $\mathrm{log}\!\left(L_\mathrm{bol}/L_{\odot}\right)$=-4.31 to $-$4.14, which in turn provides a robust mass constraint of 7.1$\pm$1.2 $M_\mathrm{Jup}$. In totality, these observations confirm that JWST presents a powerful and exciting opportunity to characterise the population of exoplanets amenable to high-contrast imaging in greater detail.

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arXiv2023

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $μ$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $μ$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$σ$) and G395H (4.5$σ$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

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arXiv2023

A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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arXiv2022

Evidence for the volatile-rich composition of a 1.5-$R_\oplus$ planet

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone.

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arXiv2022

Nitrogen as a Tracer of Giant Planet Formation. I.: A Universal Deep Adiabatic Profile and Semi-analytical Predictions of Disequilibrium Ammonia Abundances in Warm Exoplanetary Atmospheres

A major motivation of spectroscopic observations of giant exoplanets is to unveil planet formation processes from atmospheric compositions. Several recent studies suggested that atmospheric nitrogen, like carbon and oxygen, can provide important constrains on planetary formation environments. Since nitrogen chemistry can be far from thermochemical equilibrium in warm atmospheres, we extensively investigate under what conditions, and with what assumptions, the observable NH3 abundances can diagnose an atmosphere's bulk nitrogen abundance. In the first paper of this series, we investigate atmospheric T-P profiles across equilibrium temperature, surface gravity, intrinsic temperature, atmospheric metallicity, and C/O ratio using a 1D radiative-convective equilibrium model. Models with the same intrinsic temperature and surface gravity coincide with a shared "universal" adiabat in the deep atmosphere, across a wide equilibrium temperature range (250--1200 K), which is not seen in hotter or cooler models. We explain this behavior in terms of the classic "radiative zero solution" and then establish a semi-analytical T-P profile of the deep atmospheres of warm exoplanets. This profile is then used to predict vertically quenched NH3 abundances. At solar metallicity, our results show that the quenched NH3 abundance only coincides with the bulk nitrogen abundance (within 10%) at low intrinsic temperature, corresponding to a planet with a sub-Jupiter mass (< 1 MJ) and old age (> 1 Gyr). If a planet has a high metallicity ($\ge$ 10$\times$ solar) atmosphere, the quenched NH3 abundance significantly underestimates the bulk nitrogen abundance at almost all planetary masses and ages. We suggest modeling and observational strategies to improve the assessment of bulk nitrogen from NH3.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $μ$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $μ$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere.

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arXiv2022

Early Release Science of the exoplanet WASP-39b with JWST NIRISS

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 μ$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator.

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arXiv2022

A Circumplanetary Dust Ring May Explain the Extreme Spectral Slope of the 10 Myr Young Exoplanet K2-33b

Young exoplanets are attractive targets for atmospheric characterization to explore the early phase of planetary evolution and the surrounding environment. Recent observations of the 10 Myr young Neptune-sized exoplanet K2-33b revealed that the planet's transit depth drastically decreases from the optical to near-infrared wavelengths. Thao et al. (2022) suggested that a thick planetary haze and/or stellar spots may be the cause; however, even the best-fit model only barely explains the data. Here, we propose that the peculiar transmission spectrum may indicate that K2-33b possess a circumplanetary dust ring, an analog of Jupiter's dust ring. We demonstrate that the ring could produce a steep slope in the transmission spectrum even if its optical depth is as low as $\sim {10}^{-2}$. We then apply a novel joint atmosphere-ring retrieval to K2-33b and find that the ring scenario could well explain the observed spectrum for various possible ring compositions. Importantly, the dust ring also exhibits prominent absorption features of ring particles around $\sim$10 $\rmμm$, whose shape and strength depend on the composition of the ring. Thus, future observations by JWST-MIRI would be able to test not only the ring hypothesis but also, if it indeed exists, to constrain the composition of the ring -- providing a unique opportunity to explore the origins of the dust ring around its parent planet, soon after the planetary system's formation.

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arXiv2022

The Roasting Marshmallows Program with IGRINS on Gemini South I: Composition and Climate of the Ultra Hot Jupiter WASP-18 b

We present high-resolution dayside thermal emission observations of the exoplanet WASP-18b using IGRINS on Gemini South. We remove stellar and telluric signatures using standard algorithms, and we extract the planet signal via cross correlation with model spectra. We detect the atmosphere of WASP-18b at a signal-to-noise ratio (SNR) of 5.9 using a full chemistry model, measure H2O (SNR=3.3), CO (SNR=4.0), and OH (SNR=4.8) individually, and confirm previous claims of a thermal inversion layer. The three species are confidently detected (>4$σ$) with a Bayesian inference framework, which we also use to retrieve abundance, temperature, and velocity information. For this ultra-hot Jupiter (UHJ), thermal dissociation processes likely play an important role. Retrieving abundances constant with altitude and allowing the temperature-pressure profile to freely adjust results in a moderately super-stellar carbon to oxygen ratio (C/O=0.75^{+0.14}_{-0.17}) and metallicity ([M/H]=1.03^{+0.65}_{-1.01}). Accounting for undetectable oxygen produced by thermal dissociation leads to C/O=0.45^{+0.08}_{-0.10} and [M/H]=1.17^{+0.66}_{-1.01}. A retrieval that assumes radiative-convective-thermochemical-equilibrium and naturally accounts for thermal dissociation constrains C/O<0.34 (2$σ$) and [M/H]=0.48^{+0.33}_{-0.29}, in line with the chemistry of the parent star. Looking at the velocity information, we see a tantalising signature of different Doppler shifts at the level of a few km/s for different molecules, which might probe dynamics as a function of altitude and location on the planet disk. Our results demonstrate that ground-based, high-resolution spectroscopy at infrared wavelengths can provide meaningful constraints on the compositions and climate of highly irradiated planets. This work also elucidates potential pitfalls with commonly employed retrieval assumptions when applied to UHJ spectra.

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arXiv2022

The JWST Early Release Science Program for the Direct Imaging & Spectroscopy of Exoplanetary Systems

The direct characterization of exoplanetary systems with high contrast imaging is among the highest priorities for the broader exoplanet community. As large space missions will be necessary for detecting and characterizing exo-Earth twins, developing the techniques and technology for direct imaging of exoplanets is a driving focus for the community. For the first time, JWST will directly observe extrasolar planets at mid-infrared wavelengths beyond 5$μ$m, deliver detailed spectroscopy revealing much more precise chemical abundances and atmospheric conditions, and provide sensitivity to analogs of our solar system ice-giant planets at wide orbital separations, an entirely new class of exoplanet. However, in order to maximise the scientific output over the lifetime of the mission, an exquisite understanding of the instrumental performance of JWST is needed as early in the mission as possible. In this paper, we describe our 55-hour Early Release Science Program that will utilize all four JWST instruments to extend the characterisation of planetary mass companions to $\sim$15$μ$m as well as image a circumstellar disk in the mid-infrared with unprecedented sensitivity. Our program will also assess the performance of the observatory in the key modes expected to be commonly used for exoplanet direct imaging and spectroscopy, optimize data calibration and processing, and generate representative datasets that will enable a broad user base to effectively plan for general observing programs in future cycles.

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