arXiv subjects

Jonathan Keeling

Publications and source records attributed to Jonathan Keeling.

At least 19 recordsLinked to original sources

arXiv2026

Tensor network methods for non-perturbative dynamics of open quantum systems

The description of open quantum system dynamics beyond the perturbative treatment (usually associated with Markovian master equations) is a computationally challenging task due to the unfavorable exponential scaling of memory kernels. Developed over recent decades in the context of quantum information and condensed matter, tensor networks provide both a new formalism and a toolbox for overcoming previous computational bottlenecks. This framework enables the formulation of non-perturbative, numerically exact methods for describing the dynamics of open quantum systems to controllable numerical accuracy. In this review, we present these methods and discuss their commonalities and differences to paint a comprehensive view of the field.

quant-ph↗

arXiv2026

Coherent room-temperature dipole synchronization in nanocavity sheets

Plasmonic nanocavities enable the synchronization of spatially distant emissive dipoles through strong near-field coupling in sub-nm gaps. We report formation of a room-temperature synchronized dipole state in locally-ordered plasmonic nanogap 2D arrays under non-resonant continuous-wave pumping. Unlike lasers, photonic Bose-Einstein condensates, or exciton-polariton condensates, this system exhibits spatial coherence across the dipoles, while rapid radiative and non-radiative emission suppresses temporal photon coherence. A change of behaviour is observed with increasing pumping, marked by the spatial spread of g(1) coherence, but without spectral narrowing or directional emission. This driven-dissipative system exhibits fast temporal coherence decay and complex spatial correlations, offering a new platform for studying synchronization at room temperature. Combining ultralow mode volumes, high Purcell enhancement, and scalable ambient operation, it opens pathways for novel photonic and quantum technologies.

cond-mat.mes-hall↗

arXiv2026

Permutation-symmetric quantum trajectories

We show how one may perform a stochastic unravelling which respects weak permutation symmetry for general models of $N$ emitters coupled to a common system (e.g. a cavity mode). Our work extends prior work by Zhang et al. [2018 New J. Phys. 20 112001] which provided an efficient quantum jump approach for a restricted subset of such problems. For problems involving $2$-level emitters, such an unravelling reduces the computational cost from $\mathcal{O}(N^5)$ to $\mathcal{O}(N^2)$, and with additional refinements, allows reduction to $\mathcal{O}(N)$. This significantly increases the range of system sizes for which one can model exact quantum dynamics of such systems. We further show how the method can also be applied to $d$-level systems, with computational effort scaling as $\mathcal{O}(N^{d(d-1)/2})$, and we show it allows large-$N$ simulations for $d=3$.

quant-ph↗

arXiv2026

Superradiant Charge Density Waves in a Driven Cavity-Matter Hybrid

Optical cavities enable strong, long-range, light-matter interactions that can drive collective ordering phenomena, such as superradiant self-organization in ultracold atomic gases. Extending these ideas to solid-state electron systems could enable continuous-wave optical control of electronic order, but is impeded by the mismatch between optical wavelengths and electronic length scales. Here, we propose a platform for realizing superradiant charge density waves (sCDWs) in doped, driven transition-metal dichalcogenides coupled to an optical cavity. A nanoscale grating generates electric fields at large in-plane optical momenta, allowing cavity photons to couple efficiently to electronic density fluctuations through exciton-polaron processes. Using a linear-stability analysis, we determine the threshold for superradiant ordering and map out the driven phase diagram. We show that tuning the grating periodicity to match the enhanced electronic density fluctuations - such as those near Wigner crystallization - substantially lowers the required pump intensity. Our results establish a novel route toward cavity-controlled electronic order in quantum materials.

cond-mat.str-el↗

arXiv2026

Efficient construction of time-invariant process tensors for simulating high-dimensional non-Markovian open quantum systems

Numerical methods for obtaining exact dynamics of non-Markovian open quantum systems are mostly limited to either small systems or to short-time evolution only. Here, we propose a new algorithm for computing process tensors--matrix product operator (MPO) representations that capture the environment influence--which achieves greatly enhanced computational scalings with system size, while maintaining linear scaling with simulation length. We build on recent developments in the field which allow for long-time evolutions through process tensors which have a time-translational invariance. These can be built for general Gaussian environments and generic coupling operators with the system using infinite time-evolving block decimation (iTEBD). We introduce a modified iTEBD algorithm using intermediate compression steps which bring down the computation time scaling with system size $d$ from $\mathcal{O}(d^8)$ to $\mathcal{O}(d^4)$, as well as significantly lowering the required memory. To illustrate the power of this method, we apply it to the problem of dispersive qubit readout in circuit QED, which was previously out-of-reach numerically. The full treatment of the measurement resonator, which requires a large system space, combined with the long simulation times precipitated by the separation of timescales between the measurement drive and the environment dissipation, is now possible. The algorithm we introduce not only allows for capturing non-Markovian dynamics in large open quantum systems, but also further extends all the existing capabilities of process tensors, for example in quantum optimal control, or in computation of multi-time correlations or of steady states, to more complex systems with tens of levels.

quant-ph↗

arXiv2025

High-capacity associative memory in a quantum-optical spin glass

The Hopfield model describes a neural network that stores memories using all-to-all-coupled spins. Memory patterns are recalled under equilibrium dynamics. Storing too many patterns breaks the associative recall process because frustration causes an exponential number of spurious patterns to arise as the network becomes a spin glass. Despite this, memory recall in a spin glass can be restored, and even enhanced, under quantum-optical nonequilibrium dynamics because spurious patterns can now serve as reliable memories. We experimentally observe associative memory with high storage capacity in a driven-dissipative spin glass made of atoms and photons. The capacity surpasses the Hopfield limit by up to seven-fold in a sixteen-spin network. Atomic motion boosts capacity by dynamically modifying connectivity akin to short-term synaptic plasticity in neural networks, realizing a precursor to learning in a quantum-optical system.

quant-ph↗

arXiv2025

Process Tensor Approaches to Non-Markovian Quantum Dynamics

The paradigm of considering open quantum systems -- i.e. focusing only on the system of interest, and treating the rest of the world as an effective environment -- has proven to be a highly effective way to understand a range of quantum systems, across areas of study such as quantum optics, cold atoms, superconducting qubits, and impurities in solid-state systems. A common approach in many of these contexts has been to consider simplified approaches based on the Born and Markov approximations. While these approximations are indeed often appropriate in contexts such as quantum optics, the widespread application of these approximations has been driven more by simplicity than by accuracy. In particular, these Markovian treatments will fail in many cases, such as when coupling to the environment is not weak, when the environment is structured and has resonances, when the system couples to low-frequency modes of the environment, or when the questions of interest involve the propagation of information through the environment. Despite the fact that many real problems are non-Markovian, the Markov approximation is still widely used, as it is often assumed that a fully non-Markovian treatment is too complex to be practical. In this perspective we discuss a recently developed set of techniques that address this challenge. Centering our discussion around the notion of the process tensor, we demonstrate that the generality of the process tensor concept, coupled with efficient tensor-network methods, opens the door to the description of a wide range of observable non-Markovian processes in a wide range of open quantum systems.

quant-ph↗

arXiv2025

Phase Diagram and dynamical phases of self organization of a Bose-Einstein condensate in a transversely pumped red-detuned cavity

We study a transversely pumped atomic Bose-Einstein Condensate coupled to a single-mode optical cavity, where effective atom-atom interactions are mediated by pump and cavity photons. A number of experiments and theoretical works have shown the formation of a superradiant state in this setup, where interference of pump and cavity light leads to an optical lattice in which atoms self-consistently organize. This self-organization has been extensively studied using the approximate Dicke model (truncating to two momentum states), as well as through numerical Gross-Pitaevskii simulations in one and two dimensions. Here, we perform a full mean-field analysis of the system, including all relevant atomic momentum states and the cavity field. We map out the steady-state phase diagram vs pump strength and cavity detuning, and provide an in-depth understanding of the instabilities that are linked to the emergence of spatio-temporal patterns. We find and describe parameter regimes where mean-field predicts bistability, regimes where the dynamics form chaotic trajectories, instabilities caused by resonances between normal mode excitations, and states with atomic dynamics but vanishing cavity field.

cond-mat.quant-gas↗

arXiv2025

Theory of dynamical superradiance in organic materials

We develop the theory of dynamical superradiance -- the collective exchange of energy between an ensemble of initially excited emitters and a single-mode cavity -- for organic materials where electronic states are coupled to vibrational modes. We consider two models to capture the vibrational effects: first, vibrations treated as a Markovian bath for two-level emitters, via a pure dephasing term in the Lindblad master equation for the system; second, vibrational modes directly included in the system via the Holstein--Tavis--Cummings Hamiltonian. By exploiting the permutation symmetry of the emitters and weak U(1) symmetry, we develop a numerical method capable of exactly solving the Tavis-Cummings model with local dissipation for up to 140 emitters. Using the exact method, we validate mean-field and second-order cumulant approximations and use them to describe macroscopic numbers of emitters. We analyse the dynamics of the average cavity photon number, electronic coherence, and Bloch vector length, and show that the effect of vibrational mode coupling goes beyond simple dephasing. Our results show that superradiance is possible in the presence of vibrational mode coupling; for negative cavity detunings, the vibrational coupling may even enhance superradiance. We identify asymmetry of the photon number rise time as a function of the detuning of the cavity frequency as an experimentally accessible signature of such vibrationally assisted superradiance.

quant-ph↗

arXiv2025

A multimode cavity QED Ising spin glass

We realize a driven-dissipative Ising spin glass using cavity QED in a novel ``4/7" multimode geometry. Gases of ultracold atoms trapped within the cavity by optical tweezers serve as effective spins. They are coupled via randomly signed, all-to-all Ising cavity-mediated interactions. Networks of up to n = 25 spins are holographically imaged via cavity emission. The system is driven through a frustrated transverse-field Ising transition, and we show that the entropy of the spin glass states depends on the rate at which the transition is crossed. Despite being intrinsically nonequilibrium, the system exhibits phenomena associated with Parisi's theory of equilibrium spin glasses, namely replica symmetry breaking (RSB) and ultrametric structure. For system sizes up to n = 16, we measure the Parisi function q(x), Edwards-Anderson overlap q_EA, and ultrametricity K-correlator; all indicate a deeply ordered spin glass under RSB. The system can serve as an associative memory and enable aging and rejuvenation studies in driven-dissipative spin glasses at the microscopic level.

quant-ph↗

arXiv2025

Extracting Coupling-Mode Spectral Densities with Two-Dimensional Electronic Spectroscopy

Methods for reconstructing the spectral density of a vibrational environment from experimental data can yield key insights into the impact of the environment on molecular function. Although such experimental methods exist, they generally only access vibrational modes that couple diagonally to the electron system. Here we present a method for extracting the spectral density of modes that couple to the transition between electronic states, using two-dimensional electronic spectroscopy. To demonstrate this, we use a process-tensor method that can simulate two-dimensional electronic spectroscopy measurements in a numerically exact way. To explain how the extraction works, we also derive an approximate analytical solution, which illustrates that the non-Markovianity of the environment plays an essential role in the existence of the simulated signal.

physics.chem-ph↗

arXiv2024

Non-Markovian effects in long-range polariton-mediated energy transfer

Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular systems have opened new possibilities to control energy transfer. In particular, long-distance energy transfer between molecules has been reported as the result of their mutual coupling to cavity photon modes, and the formation of hybrid polariton states. In addition to strong coupling to light, molecular systems also show strong interactions between electronic and vibrational modes. The latter can act as a reservoir for energy to facilitate off-resonant transitions, and thus energy relaxation between polaritonic states at different energies. However, the non-Markovian nature of those modes makes it challenging to accurately simulate these effects. Here we capture them via process tensor matrix product operator (PT-MPO) methods, to describe exactly the vibrational environment of the molecules combined with a mean-field treatment of the light-matter interaction. In particular, we study the emission dynamics of a system consisting of two spatially separated layers of different species of molecules coupled to a common photon mode, and show that the strength of coupling to the vibrational bath plays a crucial role in governing the dynamics of the energy of the emitted light; at strong vibrational coupling this dynamics shows strongly non-Markovian effects, eventually leading to polaron formation. Our results shed light on polaritonic long-range energy transfer, and provide further understanding of the role of vibrational modes of relevance to the growing field of molecular polaritonics.

cond-mat.mes-hall↗

arXiv2024

Many-Body Open Quantum Systems

These Lecture Notes discuss the recent theoretical advances in the understanding of open quantum many-body physics in platforms where both dissipative and coherent processes can be tuned and controlled to a high degree. We start by reviewing the theoretical frameworks and methods used to describe and tackle open quantum many-body systems. We then discuss the use of dissipative processes to engineer many-body stationary states with desired properties and the emergence of dissipative phase transitions arising out of the competition between coherent evolution and dissipation. We review the dynamics of open quantum many body systems in the presence of correlated many-body dissipative processes, such as heating and many-body losses. Finally we provide a different perspective on open quantum many-body systems by looking at stochastic quantum trajectories, relevant for the case in which the environment represents a monitoring device, and the associated measurement-induced phase transitions.

quant-ph↗

arXiv2024

OQuPy: A Python package to efficiently simulate non-Markovian open quantum systems with process tensors

Non-Markovian dynamics arising from the strong coupling of a system to a structured environment is essential in many applications of quantum mechanics and emerging technologies. Deriving an accurate description of general quantum dynamics including memory effects is however a demanding task, prohibitive to standard analytical or direct numerical approaches. We present a major release of our open source software package, OQuPy (Open Quantum System in Python), which provides several recently developed numerical methods that address this challenging task. It utilizes the process tensor approach to open quantum systems in which a single map, the process tensor, captures all possible effects of an environment on the system. The representation of the process tensor in a tensor network form allows an exact yet highly efficient description of non-Markovian open quantum systems (NM-OQS). The OQuPy package provides methods to (1) compute the dynamics and multi-time correlations of quantum systems coupled to single and multiple environments, (2) optimize control protocols for NM-OQS, (3) simulate interacting chains of NM-OQS, and (4) compute the mean-field dynamics of an ensemble of NM-OQS coupled to a common central system. Our aim is to provide an easily accessible and extensible tool for researchers of open quantum systems in fields such as quantum chemistry, quantum sensing, and quantum information.

quant-ph↗

arXiv2024

Tree-like process tensor contraction for automated compression of environments

The algorithm "automated compression of environments" (ACE) [Nat. Phys. 18, 662 (2022)] provides a versatile way of simulating an extremely broad class of open quantum systems. This is achieved by encapsulating the influence of the environment, which is determined by the interaction Hamiltonian(s) and initial states, into compact process tensor matrix product operator (PT-MPO) representations. The generality of the ACE method comes at high numerical cost. Here, we demonstrate that orders-of-magnitude improvement of ACE is possible by changing the order of PT-MPO contraction from a sequential to a tree-like scheme. The problem of combining two partial PT-MPOs with large inner bonds is solved by a preselection approach. The drawbacks of the preselection approach are that the MPO compression is suboptimal and that it is more prone to error accumulation than sequential combination and compression. We therefore also identify strategies to mitigate these disadvantages by fine-tuning compression parameters. This results in a scheme that is similar in compression efficiency and accuracy to the original ACE algorithm, yet is significantly faster. Our numerical experiments reach similar conclusions for bosonic and fermionic test cases, suggesting that our findings are characteristic of the combination of PT-MPOs more generally.

quant-ph↗

arXiv2024

Raman-phonon-polariton condensation in a transversely pumped cavity

Phonon polaritons are hybrid states of light and matter that are typically realised when optically active phonons couple strongly to photons. We suggest a new approach to realising phonon polaritons, by employing a transverse-pumping Raman scheme, as used in experiments on cold atoms in optical cavities. This approach allows hybridisation between an optical cavity mode and any Raman-active phonon mode. Moreover, this approach enables one to tune the effective phonon-photon coupling by changing the strength of the transverse pumping light. We show that such a system may realise a phonon-polariton condensate. To do this, we find the stationary states and use Floquet theory to determine their stability. We thus identify distinct superradiant and lasing states in which the polariton modes are macroscopically populated. We map out the phase diagram of these states as a function of pump frequencies and strengths. Using parameters for transition metal dichalcogenides, we show that realisation of these phases may be practicably obtainable. The ability to manipulate phonon mode frequencies and attain steady-state populations of selected phonon modes provides a new tool for engineering correlated states of electrons.

cond-mat.mes-hall↗

arXiv2024

Process tensor approaches to modeling two-dimensional spectroscopy

Problems in the field of open quantum systems often involve an environment that strongly influences the dynamics of excited states. Here we present a numerical method to model optical spectra of non-Markovian open quantum systems. The method employs a process tensor framework to efficiently compute multi-time correlations in a numerically exact way. To demonstrate the efficacy of our method, we compare 2D electronic spectroscopy simulations produced through our method to Markovian master equation simulations in three different system-bath coupling regimes.

quant-ph↗

arXiv2023

Directly observing replica symmetry breaking in a vector quantum-optical spin glass

Spin glasses are quintessential examples of complex matter. Although much about their order remains uncertain, abstract models of them inform, e.g., the classification of combinatorial optimization problems, the magnetic ordering in metals with impurities, and artificial intelligence -- where they form a mathematical basis for neural network computing and brain modeling. We demonstrate the ability of an active quantum gas microscope to realize a spin glass of a novel driven-dissipative and vector form. By microscopically visualizing its glassy spin states, the technique allows us to directly measure replica symmetry breaking and the resulting ultrametric hierarchical structure. Ultrametricity is known to be emergent in models of evolution, protein folding, climate change, and infinite-range equilibrium spin glasses; this work shows it to be directly observable in a physically realized system.

quant-ph↗