arXiv subjects

Jonathan M. C. Rawlings

Publications and source records attributed to Jonathan M. C. Rawlings.

16 recordsLinked to original sources

arXiv2026

MAJORS II: HCO+& HCN Abundances in W40

We present observations of HCN and HCO$^+$ J = $3 - 2$ in the central $424'' \times 424''$ region of the W40 massive star forming region. The observations were taken as part of a pilot project for the MAJORS large program at the JCMT telescope. By incorporating prior knowledge of N(H$_2$) and $T_K$, assuming a constant density, and using the RADEX radiative transfer code we found that the HCN and HCO$^+$ abundances range from $X$(HCN) = $0.4-7.0 \times 10^{-8}$ and $X$(HCO$^+$) = $0.4-7.3 \times 10^{-9}$. Additional modelling using the NAUTILUS chemical evolution code, that takes H$_2$ density variations into account, however, suggests the HCN and HCO$^+$ abundances may be fairly constant. Careful modelling of three different positions finds $X$(HCN) = $1.3-1.7 \times 10^{-8}$, $X$(HCO$^+$) = $1.3-3.1 \times 10^{-9}$. Cross-comparison of the two models also provides a crude estimate of the gas density producing the HCN and HCO$^+$ emission, with H$_2$ densities in the range $5 \times 10^4 - 5 \times 10^5$ cm$^{-3}$, suggesting that the HCN and HCO$^+$ emission does indeed arise from dense gas. High UV intensity (e.g. $G_o >$ a few thousand) has no effect on the abundances in regions where the visual extinction is large enough to effectively shield the gas from the UV field. In regions where $A_V < 6$, however, the abundance of both species is lowered due to destructive reactions with species that are directly affected by the radiation field.

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arXiv2022

Towards a better understanding of ice mantle desorption by cosmic rays

The standard model of cosmic ray heating-induced desorption of interstellar ices is based on a continuous representation of the sporadic desorption of ice mantle components from classical (0.1 micron) dust grains. This has been re-evaluated and developed to include tracking the desorption through (extended) grain cooling profiles, consideration of grain size-dependencies and constraints to the efficiencies. A model was then constructed to study the true, sporadic, nature of the process with possible allowances from species co-desorption and whole mantle desorption from very small grains. The key results from the study are that the desorption rates are highly uncertain, but almost certainly significantly larger than have been previously determined. For typical interstellar grain size distributions it is found that the desorption is dominated by the contributions from the smallest grains. The sporadic desorption model shows that, if the interval between cosmic ray impacts is comparable to, or less than, the freeze-out timescale, the continuous representation is inapplicable; chemical changes may occur on very long timescales, resulting in strong gas phase chemical enrichments that have very non-linear dependences on the cosmic ray flux. The inclusion of even limited levels of species co-desorption and/or the contribution from very small grains further enhances the rates, especially for species such as H2O. In general we find that cosmic-ray heating is the dominant desorption mechanism in dark environments. These results may have important chemical implications for protostellar and protoplanetary environments.

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arXiv2019

A gas-phase primordial origin of O2 in comet 67P/Churyumov-Gerasimenko

Recent observations made by the Rosetta/ROSINA instrument have detected molecular oxygen in the coma of comet 67P/Churyumov-Gerasimenko with abundances at the 1-10% level relative to H2O. Previous studies have indicated that the likely origin of the O2 may be surface chemistry of primordial (dark cloud) origin, requiring somewhat warmer, denser and extreme H-atom poor conditions than are usually assumed. In this study we propose a primordial gas-phase origin for the O2 which is subsequently frozen and effectively hidden until the ice mantles are sublimated in the comet's coma. Our study presents results from a three-phase astrochemical model that simulates the chemical evolution of ices in the primordial dark cloud phase, its gravitational collapse, and evolution in the early protosolar nebula. We find that the O2 abundance can be produced and is fairly robust to the choice of the free parameters. Good matches for the O2:H2O ratio and, to a lesser extent, the N2:CO and CO:H2O ratios are obtained, but the models significantly over-produce N2. We speculate that the low value of N2:O2 that is observed is a consequence of the specific thermal history of the comet.

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arXiv2017

A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation rate in this region could lead to a more efficient non-thermal desorption of this species formed on grain surfaces, but it would also mean that this species is destroyed in a relatively short timescale. In a first step, we run chemical models with a high cosmic ray ionisation rate and find that this scenario can only reproduce the lowest abundances of methanol derived in this region ($\sim$10$^{-9}$-10$^{-8}$). In a second step, we investigate another scenario based on episodic explosions of grain mantles. We find a good agreement between the predicted abundances of methanol and the observations. We find that the dominant route for the formation of methanol is through hydrogenation of CO on the grains followed by the desorption due to the grain mantle explosion. The cyclic aspect of this model can explain the widespread presence of methanol without requiring any additional mechanism. We also model silicon monoxide (SiO), another species detected in several molecular clouds of the Galactic Centre. An agreement is found with observations for a high depletion of Si (Si/H $\sim$ 10$^{-8}$) with respect to the solar abundance.

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arXiv2016

$\textit{Herschel}$/SPIRE Observations of Water Production Rates and Ortho-to-Para Ratios in Comets

This paper presents $\textit{Herschel}$/SPIRE spectroscopic observations of several fundamental rotational ortho- and para-water transitions seen in three Jupiter-family comets and one Oort-cloud comet. Radiative transfer models that include excitation by collisions with neutrals and electrons, and by solar infrared radiation were used to produce synthetic emission line profiles originating in the cometary coma. Ortho-to-para ratios (OPRs) were determined and used to derived water production rates for all comets. Comparisons are made with the water production rates derived using an OPR of 3. The OPR of three of the comets in this study are much lower than the statistical equilibrium value of 3, however they agree with observations of comets 1P/Halley and C/2001 A2 (LINEAR), and the protoplanetary disc TW Hydrae. These results provide evidence suggesting that OPR variation is caused by post-sublimation gas-phase nuclear-spin conversion processes. The water production rates of all comets agree with previous work and, in general, decrease with increasing nucleocentric offset. This could be due to a temperature profile, additional water source, or OPR variation in the comae, or model inaccuracies.

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arXiv2014

Champagne Flutes and Brandy Snifters: Modelling Protostellar Outflow-Cloud Chemical Interfaces

A rich variety of molecular species has now been observed towards hot cores in star forming regions and in the interstellar medium. An increasing body of evidence from millimetre interferometers suggests that many of these form at the interfaces between protostellar outflows and their natal molecular clouds. However, current models have remained unable to explain the origin of the observational bias towards wide-angled "brandy snifter" shaped outflows over narrower "champagne flute" shapes in carbon monoxide imaging. Furthermore, these wide-angled systems exhibit unusually high abundances of the molecular ion HCO$^+$. We present results from a chemo-dynamic model of such regions where a rich chemistry arises naturally as a result of turbulent mixing between cold, dense molecular gas and the hot, ionized outflow material. The injecta drives a rich and rapid ion-neutral chemistry in qualitative and quantitative agreement with the observations. The observational bias towards wide-angled outflows is explained naturally by the geometry-dependent ion injection rate causing rapid dissociation of CO in the younger systems.

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arXiv2013

Is acetylene essential for carbon dust formation?

We have carried out an investigation of the chemical evolution of gas in different carbon-rich circumstellar environments. Previous studies have tended to invoke terrestrial flame chemistries, based on acetylene (C2H2) combustion to model the formation of carbon dust, via Polycyclic Aromatic Hydrocarbons (PAHs). In this work we pay careful attention to the accurate calculation of the molecular photoreaction rate coefficients to ascertain whether there is a universal formation mechanism for carbon dust in strongly irradiated astrophysical environments. A large number of possible chemical channels may exist for the formation of PAHs, so we have concentrated on the viability of the formation of the smallest building block species, C2H2, in a variety of carbon-rich stellar outflows. C2H2 is very sensitive to dissociation by UV radiation. This sensitivity is tested, using models of the time-dependent chemistry. We find that C2H2 formation is sensitive to some of the physical parameters and that in some known sources of dust-formation it can never attain appreciable abundances. Therefore multiple (and currently ill-defined) dust-formation channels must exist.

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arXiv2012

The Chemical Effects of Mutual Shielding in Photon Dominated Regions

We investigate the importance of the shielding of chemical photorates by molecular hydrogen photodissociation lines and the carbon photoionization continuum deep within models of photon dominated regions. In particular, the photodissociation of N2 and CN are significantly shielded by the H2 photodissociation line spectrum. We model this by switching off the photodissociation channels for these species behind the HI to H2 transition. We also model the shielding effect of the carbon photoionization continuum as an attenuation of the incident radiation field shortwards of 1102Å. Using recent line and continuum cross section data, we present calculations of the direct and cosmic ray induced photorates for a range of species, as well as optically thick shielding factors for the carbon continuum. Applying these to a time dependent PDR model we see enrichments in the abundances of N2, N2H+, NH3 and CN by factors of roughly 3-100 in the extinction band Av=2.0 to Av=4.0 for a range of environments. While the precise quantitative results of this study are limited by the simplicity of our model, they highlight the importance of these mutual shielding effects, neither of which has been discussed in recent models.

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arXiv2010

Chemistry in Evaporating Ices: Unexplored Territory

We suggest that three-body chemistry may occur in warm high density gas evaporating in transient co\textendash desorption events on interstellar ices. Using a highly idealised computational model we explore the chemical conversion from simple species of the ice to more complex species containing several heavy atoms, as a function of density and of adopted three body rate coefficients. We predict that there is a wide range of densities and rate coefficients in which a significant chemical conversion may occur. We discuss the implications of this idea for the astrochemistry of hot cores.

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arXiv2010

Investigating the effects of chemistry on molecular line profiles of infalling low mass cores

We have coupled a chemical model with two dynamical models of collapsing low mass star-forming cores to predict abundances across the core of the commonly used infall tracers, CS and HCO$^+$, at various stages of the collapse. The models investigated are a new ambipolar diffusion model and the `inside-out' collapse model. We have then used these results as an input to a radiative transfer model to predict the line profiles of several transitions of these molecules. For the inside-out collapse model, we predict significant molecular depletion due to freeze-out in the core centre, which prevents the formation of the blue asymmetry (believed to be the `signature' of infall) in the line profiles. Molecular depletion also occurs in the ambipolar diffusion model during the late stages of collapse, but the line profiles still exhibit a strong blue asymmetry due to extended infall. For the inside-out collapse model to exhibit the blue asymmetry it is necessary to impose a negative kinetic temperature gradient on the core and suppress freeze-out. Since freeze-out is observed in several class 0 protostars which are thought to be collapsing, this presents a major inconsistency in the inside-out collapse model of star formation.

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arXiv2008

Timescales for Low-Mass Star Formation in Extragalactic Environments: Implications for the Stellar IMF

We investigate the physical and chemical conditions necessary for low-mass star formation in extragalactic environments by calculating various characteristic timescales associated with star formation for a range of initial conditions. The balance of these timescales indicates whether low-mass star formation is enhanced or inhibited under certain physical conditions. In this study, we consider timescales for free-fall, cooling, freeze-out, desorption, chemistry and ambipolar diffusion and their variations with changes in the gas density, metallicity, cosmic ray ionisation rate and FUV radiation field strength. We find that extragalactic systems with high FUV radiation field strengths and high cosmic ray fluxes considered at a range of metallicities, are likely to have enhanced low-mass star formation unless the magnetic pressure is sufficient to halt collapse. Our results indicate that this is only likely to be the case for high-redshift galaxies approaching solar metallicities. Unless this is true for all high-redshift sources, this study finds little evidence for a high-mass biased IMF at high redshifts.

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arXiv2005

Modeling the Physical Structure of the Low Density Pre-protostellar Core Lynds 1498

Lynds 1498 is a pre-protostellar core (PPC) and was one of the initial objects toward which molecular depletion and differentiation was detected. Despite the considerable scrutiny of L1498, there has not been a extensive study of the density and temperature structure as derived from radiative transfer modeling of dust continuum observations. We present deep SCUBA observations of L1498 at 850 and 450 micron, high resolution BEARS maps of the N2H+ 1-0 transition, CSO observations of the N2H+ 3-2 transition, and GBT observations of the C3S 4-3 transition. We also present a comparison of derived properties between L1498 and nearby PPCs that have been observed at far-infrared and submillimeter wavelengths. We present a more realistic treatment of PPC heating which varies the strength of the ISRF, Sisrf, and includes attenuation of the ISRF due to dust grains at the outer radius of the core, Av. The best-fitted model consists of a Bonner-Ebert sphere with a central density of 1 - 3 x 10^4 cm-3, R_o ~ 0.29 pc, 0.5 <= Sisrf <= 1, Av ~ 1 mag, and a nearly isothermal temperature profile of ~ 10.5 K for OH8 opacities. C3S emission shows a central depletion hole while N2H+ emission is centrally peaked. The observed depletions of C3S and H2CO, the modest N2H+ abundance, and a central density that is an order of magnitude lower than other modeled PPCs suggests that L1498 may be a forming PPC. Our derived temperature and density profile will improve modeling of molecular line observations that will explicate the core's kinematical and chemical state. (abridged)

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arXiv2005

B335: A Laboratory for Astrochemistry in a Collapsing Cloud

We present observations of 25 transitions of 17 isotopologues of 9 molecules toward B335. With a goal of constraining chemical models of collapsing clouds, we compare our observations, along with data from the literature, to models of chemical abundances. The observed lines are simulated with a Monte Carlo code, which uses various physical models of density and velocity as a function of radius. The dust temperature as a function of radius is calculated self-consistently by a radiative transfer code. The gas temperature is then calculated at each radius, including gas-dust collisions, cosmic rays, photoelectric heating, and molecular cooling. The results provide the input to the Monte Carlo code. We consider both {\it ad hoc} step function models for chemical abundances and abundances taken from a self-consistent modeling of the evolution of a star-forming core. The step function models can match the observed lines reasonably well, but they require very unlikely combinations of radial variations in chemical abundances. Among the self-consistent chemical models, the observed lines are matched best by models with somewhat enhanced cosmic-ray ionization rates and sulfur abundances. We discuss briefly the steps needed to close the loop on the modeling of dust and gas, including off-center spectra of molecular lines.

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arXiv2002

Tracing the Mass during Low-Mass Star Formation. III. Models of the Submillimeter Dust Continuum Emission from Class 0 Protostars

Seven Class 0 sources mapped with SCUBA at 850 and 450 micron are modeled using a one dimensional radiative transfer code. The modeling takes into account heating from an internal protostar, heating from the ISRF, realistic beam effects, and chopping to model the normalized intensity profile and spectral energy distribution. Power law density models, n(r) ~ r^{-p}, fit all of the sources; best fit values are mostly p = 1.8 +/- 0.1, but two sources with aspherical emission contours have lower values (p ~ 1.1). Including all sources, = 1.63 +/- 0.33. Based on studies of the sensitivity of the best-fit p to variations in other input parameters, uncertainties in p for an envelope model are Δp = +/- 0.2. If an unresolved source (e.g., a disk) contributes 70% of the flux at the peak, p is lowered in this extreme case and Δp = ^{+0.2}_{-0.6}. The models allow a determination of the internal luminosity ( = 4.0 \lsun) of the central protostar as well as a characteristic dust temperature for mass determination ( = 13.8 +/- 2.4 K). We find that heating from the ISRF strongly affects the shape of the dust temperature profile and the normalized intensity profile, but does not contribute strongly to the overall bolometric luminosity of Class 0 sources. There is little evidence for variation in the dust opacity as a function of distance from the central source. The data are well-fitted by dust opacities for coagulated dust grains with ice mantles (Ossenkopf & Henning 1994). The density profile from an inside-out collapse model (Shu 1977) does not fit the data well, unless the infall radius is set so small as to make the density nearly a power-law.

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arXiv2001

Tracing the Mass during Low-Mass Star Formation. II. Modelling the Submillimeter Emission from Pre-Protostellar Cores

We have modeled the emission from dust in pre-protostellar cores, including a self-consistent calculation of the temperature distribution for each input density distribution. Model density distributions include Bonnor-Ebert spheres and power laws. The Bonnor-Ebert spheres fit the data well for all three cores we have modeled. The dust temperatures decline to very low values ($\Td \sim 7$ K) in the centers of these cores, strongly affecting the dust emission. Compared to earlier models that assume constant dust temperatures, our models indicate higher central densities and smaller regions of relatively constant density. Indeed, for L1544, a power-law density distribution, similar to that of a singular, isothermal sphere, cannot be ruled out. For the three sources modeled herein, there seems to be a sequence of increasing central condensation, from L1512 to L1689B to L1544. The two denser cores, L1689B and L1544, have spectroscopic evidence for contraction, suggesting an evolutionary sequence for pre-protostellar cores.

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arXiv2000

Tracing the Mass during Low-Mass Star Formation. I. Submillimeter Continuum Observations

We have obtained 850 and 450 micron continuum maps of 21 low mass cores with SED's ranging from pre-protostellar to Class I (18K < Tbol < 370K), using SCUBA at the JCMT. In this paper we present the maps, radial intensity profiles, and photometry. Pre-protostellar cores do not have power-law intensity profiles, whereas the intensity profiles of Class 0 and Class I sources can be fitted with power laws over a large range of radii. A substantial number of sources have companion sources within a few arcminutes (2 out of 5 pre-protostellar cores, 9 out of 16 Class 0/I sources). The mean separation between sources is 10800 AU. The median separation is 18000 AU including sources without companions as a lower limit. The mean value of the spectral index between 450 and 850 microns is 2.8 +- 0.4, with PPCs having slightly lower spectral indices (2.5 +- 0.4). The mean mass of the sample, based on the dust emission in a 120 arcsecond aperture, is 1.1 +- 0.9 solar masses. For the sources fitted by power-law intensity distributions (I_nu(b)/I_nu(0) = (b/b_0) ^ m), the mean value of m is 1.52 +- 0.45 for Class 0 and I sources at 850 microns and 1.44 +- 0.25 at 450 microns. Based on a simple analysis, assuming the emission is in the Rayleigh-Jeans limit and that T_d(r) ~ r ^ {-0.4}, these values of m translate into power-law density distributions (n ~ r ^ {-p}) with p ~ 2.1. However, we show that this result may be changed by more careful consideration of effects such as beam size and shape, finite outer radii, more realistic T_d(r), and failure of the Rayleigh-Jeans approximation.

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