arXiv subjects

Jonathan Ruhman

Publications and source records attributed to Jonathan Ruhman.

At least 19 recordsLinked to original sources

arXiv2026

Superconductivity from interband coupling to ferroelectric quantum critical fluctuations in two dimensions

Soft critical fluctuations associated with ferroelectric quantum phase transitions are typically transverse owing to their polar nature. This implies that the conventional density--density electron--phonon coupling to these modes is strongly suppressed, which is puzzling as a variety of materials exhibit enhanced superconductivity in the vicinity of ferroelectricity. An alternative coupling mechanism is an interband ``Stark''-like coupling that connects bands of opposite parity. In the limit where one of the bands is far in energy, these processes generate an effective quadratic (two-phonon) coupling. In contrast, when both bands lie close to the Fermi energy, the resulting interaction develops singular behavior due to the additional gapless electronic states, motivating a detailed study into the dynamics of this effective two-phonon coupling. To this end, we construct the quantum critical Eliashberg theory for a two-dimensional system across a wide range of interband gap magnitudes, near the quantum critical point. We find that the critical temperature $T_c$ is strongly enhanced relative to conventional BCS expectations. In the large-gap limit, the pairing kernel acquires higher-order logarithmic contributions, leading to a parametrically enhanced $T_c$ governed by cubic and quadratic logarithmic terms. In the small-gap regime, the pairing scale exhibits a modified BCS-like form with an enhanced dependence on the inverse square root of the dimensionless coupling constant. The enhancement is due to the dynamics of the two-phonon pairing whose infrared cutoff is set by $T_c$, resulting in a significant enhancement of superconductivity compared to three-dimensional systems, where it is set by the Fermi energy. Our results elucidate the unique dynamical properties of effective two-phonon interactions, and may be relevant to layered compounds like Td-MoTe$_2$ and doped SrTiO$_3$ membranes.

cond-mat.supr-con↗

arXiv2026

Competing incommensurability, electronic correlations, and superconductivity in a hybrid transition metal dichalcogenide

The engineering of superlattices in two-dimensional van der Waals materials has enabled the realization of rich phase diagrams hosting topological and strongly correlated phases. While incommensurability is widespread in three-dimensional systems, the role of moir\'e potentials in bulk materials remains largely unexplored. Here, using scanning tunneling microscopy, we demonstrate that a bulk transition-metal dichalcogenide polytype, 4Hb-TaS$_2$, hosts an emergent incommensurate potential between its alternating 1T and 1H layers. Interplay with a concomitant incommensurate charge-density wave suppresses the long-range order of this potential, leading to intricate coupling with electronic correlations in the doped 1T surface layer. Combining density functional theory with dynamical mean-field theory, we show that the lattice mismatch locally modulates the interlayer distance, thereby tuning both hybridization and charge transfer between the correlated 1T and metallic 1H layers. This redistribution of charge drives the system towards a doped Mott regime, in which the remaining local moments become self-screened, giving rise to a zero-bias resonance. We further find that bulk superconductivity competes with both the underlying landscape and the associated charge transfer. Our results establish incommensurate potentials as a previously overlooked ingredient in hybrid transition-metal dichalcogenides, highlighting their central role in the interplay between electronic correlations, charge-density-wave order, and unconventional superconductivity.

cond-mat.str-el↗

arXiv2026

Reduced pair breaking from extended disorder in unconventional superconductors: implications to 4Hb-TaS$_2$

Unconventional superconductivity is generally expected to be strongly suppressed by nonmagnetic disorder, as captured by Abrikosov--Gor'kov (AG) theory. However, several materials, including transition metal dichalcogenides, exhibit signatures of unconventional pairing despite relatively high resistivities, suggesting a breakdown of the conventional relation between momentum relaxation and pair breaking. Here, we study this problem in H-phase transition metal dichalcogenides by computing the disorder-dressed pairing susceptibility. We employ a multiband model with spin-orbit coupling and include an impurity potential that mimics a common lattice defect, namely a chalcogen vacancy or site ad-atom. This yields to an extended impurity potential, which we compare with the commonly considered on-site (point defect) potential. We evaluate the momentum-relaxation rate and the pair-breaking rate on equal footing. We find that extended impurity potentials lead to a parametrically reduced pair-breaking rate compared to the transport scattering rate, with $\Gamma \tau_D \sim 1/3$ over a wide parameter range. This reduction originates from the momentum structure of the disorder potential, which partially matches the internal structure of the superconducting gap and suppresses pair-breaking processes. As a result, unconventional pairing states are significantly more robust than predicted by standard AG theory. Our results provide a natural explanation for the persistence of unconventional superconductivity in systems with strong disorder and substantially alleviate the apparent conflict between high resistivity and unconventional pairing in materials such as 4Hb-TaS$_2$.

cond-mat.supr-con↗

arXiv2026

Interlayer Charge-Transfer Ferroelectric Fluctuations as a Pairing Mechanism in van der Waals Superconductors

Signatures of unconventional superconductivity have been reported in a wide range of van der Waals (vdW) materials. However, their microscopic origin remains unclear due to competing electronic orders, strong spin-orbit coupling, and structural instabilities in the normal state. Here we investigate the role of interlayer breathing and shear modes in superconducting vdW heterostructures. Contrary to conventional wisdom -- which assumes that weak interlayer bonding and large layer separation suppress electronic coupling to these modes -- we show that the associated charge transfer can generate a substantial pairing interaction. We develop a theory of superconductivity mediated by such interlayer modes and demonstrate that proximity to a ferroelectric or antiferroelectric quantum critical point provides a strong-coupling pairing channel. Within a two-dimensional model with SU(2) symmetry and in-plane isotropy, we find an accidental degeneracy between interlayer triplet states, which can occur even for an $s$-wave in-plane gap. We further show that Josephson coupling between layers, arising from either static magnetism or induced by paramagnetic correlations, can stabilize a time-reversal-symmetry-breaking superconducting state of the $s+i\,s$ type, which couples to magnetization when at least two mirror symmetries are absent. Our results are directly applicable to candidate chiral vdW superconductors such as 4Hb-TaS$_2$ and to sliding ferroelectric metals, exemplified by bilayer MoTe$_2$. More broadly, our work identifies ferroelectric fluctuations as a promising route to unconventional pairing in vdW systems and motivates experimental searches for chiral multicomponent superconductivity.

cond-mat.supr-con↗

arXiv2025

Mixed Triplet-Singlet Order Parameter in Decoupled Superconducting 1H Monolayers of Transition-Metal Dichalcogenides

Understanding the emergence of unconventional superconductivity, where the order parameter deviates from simple isotropic s-wave pairing, is a central puzzle in condensed matter physics. Transition-metal dichalcogenides (TMDCs), though generally regarded as conventional superconductors, display signatures of this unusual behavior and thus provide a particularly intriguing platform to explore how exotic states arise. Here we investigate the misfit compound (SnS)$_{1.15}$(TaS$_2$), a heterostructure composed of alternating SnS and 1H-TaS$_2$ layers. Using transport, photoemission, and scanning tunneling spectroscopy, we demonstrate that the SnS layers effectively decouple the TaS$_2$ into electronically isolated 1H sheets. In this limit, the tunneling density of states reveals a clear two-gap superconducting spectrum with T$_c \sim$ 3.1 K. A theoretical model based on lack of inversion symmetry and finite-range attraction reproduces the observed multi-gap structure as a mixed singlet-triplet state. These results establish misfit compounds as a powerful platform for studying unconventional superconductivity in isolated 1H layers and for realizing multiple uncoupled superconductors within a single crystal.

cond-mat.supr-con↗

arXiv2025

Comment on 2501.17230 and 2502.00103 "Phonon-mediated electron attraction in SrTiO3 via the generalized Frohlich and deformation potential mechanisms" and "Theory of ab initio downfolding with arbitrary range electron-phonon coupling"

This comment critically examines the claims made in arXiv papers arXiv:2501.17230 and arXiv:2502.00103, which argue that a multiplicity of polar optical phonons can generate a long-range attractive interaction via a generalized Frohlich coupling. I identify a fundamental flaw in their derivation, showing that their result relies on an unphysical assumption--specifically, neglecting the intermode Coulomb interactions between different polar optical phonons. By restoring these missing interactions I show the screened Coulomb interaction is always repulsive in the static limit.

cond-mat.supr-con↗

arXiv2025

Unveiling a Hidden Percolation Transition in Monitored Clifford Circuits: Inroads from ZX-Calculus

We revisit the measurement-induced phase transition (MPT) in Clifford circuits, which are both classically simulable and exhibit critical behavior widely believed to be distinct from classical percolation theory, using ZX-calculus. We analyze the MPT in a dynamical model composed of CNOT, SWAP, identity gates, and Bell-pair measurements, respectively, arranged randomly in a brickwork pattern. Our circuits exhibit a transition that is seemingly distinct from classical percolation based on standard arguments, that is in line with the prevailing understanding in the field. In contrast, by employing ZX-calculus based simplification techniques, we unveil a hidden percolation transition within the circuit structure. Over a range of parameters tied to the probabilities for applying different gates, we demonstrate that the classical percolation transition in the ZX-simplified network coincides with the MPT observed through mutual information. Our findings suggest that the MPT in Clifford circuits is, in fact, controlled by a classical percolation transition in disguise.

quant-ph↗

arXiv2024

The Smearing of Quasi-Particles: Signatures in the Entanglement Entropy of Excited Many-Particle Systems

The entanglement spectrum serves as a powerful tool for probing the structure and dynamics of quantum many-body systems, revealing key information about symmetry, topology, and excitations. While the entanglement entropy (EE) of ground states typically follows an area law, highly excited states obey a volume law, leading to a striking contrast in their scaling behavior. In this paper, we investigate the crossover between these two regimes, focusing on the role of quasi-particles (QPs) in mediating this transition. By analyzing the energy dependence of EE in various many-body systems, we explore how the presence of long-lived QPs influences the entanglement structure of excited states. We present numerical results for spinless fermions, a spin chain near a many-body localization transition, and the Sachdev-Ye-Kitaev (SYK) model, which lacks a conventional QP description. Our findings are complemented by a theoretical model based on Fermi liquid theory, providing insight into the interaction-dependent scaling of EE and its consistency with numerical simulations. We find that a hallmark of QPs is a linear dependence of the eigenstate EE on energy, which breaks down at high energy and in the limit of strong interaction. The slope of this linear dependence reflects the QP weight, which reduces with interaction strength.

cond-mat.quant-gas↗

arXiv2024

Strong Coupling Theory of Superconductivity and Ferroelectric Quantum Criticality in metallic SrTiO$_3$

Superconductivity in doped SrTiO$_3$ has remained an enduring mystery for over 50 years. The material's status as a ``quantum" ferroelectric metal, characterized by a soft polar mode, suggests that quantum criticality could play a pivotal role in the emergence of its superconducting state. We show that the system is amenable to a strong coupling (Eliashberg) pairing analysis, with the dominant coupling to the soft mode being a ``dynamical'' Rashba coupling. We compute the expected $T_c$ for the entire phase diagram, all the way to the quantum critical point and beyond. We demonstrate that the linear coupling is sufficient to obtain a rough approximation of the experimentally measured phase diagram, but that nonlinear coupling terms are crucial in reproducing the finer features in the ordered phase. The primary role of nonlinear terms at the peak of the superconducting dome is to enhance the effective linear coupling induced by the broken order, shifting the dome's maximum into the ordered phase. Our theory quantitatively reproduces the three-dimensional experimental phase diagram in the space of carrier density, distance from the quantum critical point and temperature, and allows us to estimate microscopic parameters from the experimental data.

cond-mat.str-el↗

arXiv2024

Flat band physics in the charge-density wave state of $1T$-TaS$_2$

1$T$-TaS$_2$ is the only insulating transition-metal dichalcogenide (TMD) with an odd number of electrons per unit cell. This insulating state is non-magnetic, making it a potential spin-liquid candidate. The unusual electronic behavior arises from a naturally occurring nearly flat mini-band, where the properties of the strongly correlated states are significantly influenced by the microscopic starting point, necessitating a detailed and careful investigation. We revisit the electronic band structure of 1$T$-TaS$_2$, starting with the tight-binding model without CDW order. Symmetry dictates the nature of spin-orbit coupling (SOC), which, unlike in the 2H TMD structure, allows for strong off-diagonal "spin-flip" terms as well as Ising SOC. Incorporating the CDW phase, we construct a 78$\times$78 tight-binding model to analyze the band structure as a function of various parameters. Our findings show that an isolated flat band is a robust feature of this model. Depending on parameters such as SOC strength and symmetry-allowed orbital splittings, the flat band can exhibit non-trivial topological classifications. These results have significant implications for the strongly correlated physics emerging from interacting electrons in the half-filled or doped flat band.

cond-mat.str-el↗

arXiv2024

The transition-metal-dichalcogenide family as a superconductor tuned by charge density wave strength

Metallic transition metal dichalcogenides (TMDs), consisting of H-NbSe$_2$, H-NbS$_2$, H-TaSe$_2$ and H-TaS$_2$, remain superconducting down to a thickness of a single layer. In these materials, thickness affects a variety of properties, including Ising protection, two-band superconductivity, and the critical temperature $T_C$, which decreases for the Nb-based, and increases for the Ta-based materials. This contradicting trend is puzzling, and has precluded the development of a unified theory. We approach the question of thickness-evolution of $T_C$ and the superconducting gap $\Delta$ by measuring high-resolution tunneling spectra in TaS$_2$-based stacked devices. Our measurements allow for simultaneous evaluation of $\Delta$, $T_C$, and the upper critical field $H_{C2}$. The latter, we find, is strongly enhanced towards the single-layer limit, following a $H_{C2} \propto \Delta^2$ proportionality ratio. Our main finding is that the same ratio holds for the entire family of metallic TMDs: TaS$_2$ and NbSe$_2$ of all thicknesses, bulk TaSe$_2$ and bulk NbS$_2$, extending over 4 orders of magnitude in $H_{C2}$ and covering both clean and dirty limits. We propose that this tunability across the TMD family is controlled by the competing charge density wave (CDW) phase. Using Gor'kov's theory, we calculate how a CDW order affects the quasiparticle density of states and the resulting $T_C$ and $H_{C2}$. Our results suggest that CDW is the key determinant factor limiting $T_C$ in the TMD family. They also show that $H_{C2}$ is universally enhanced by a factor of two orders of magnitude above the expected value, an effect that remains an open question.

cond-mat.supr-con↗

arXiv2024

Singlet, triplet, and mixed all-to-all pairing states emerging from incoherent fermions

The electron-electron and electron-phonon coupling in complex materials can be more complicated than simple density-density interactions, involving intertwined dynamics of spin, charge, and spatial symmetries. This motivates studying universal models with complex interactions, and studying whether in this case BCS-type singlet pairing is still the ``natural'' fate of the system. To this end, we construct a Yukawa-SYK model with nonlocal couplings in both spin and charge channels. Furthermore, we provide for time-reversal-symmetry breaking dynamics by averaging over the Gaussian Unitary ensemble rather than the Orthogonal ensemble. We find that the ground state of the system can be an orbitally nonlocal superconducting state arising from incoherent fermions with no BCS-like analog. The superconductivity has an equal tendency to triplet and singlet pairing states separated by a non-Fermi liquid phase. We further study the fate of the system within the superconducting phase and find that the expected ground state, away from the critical point, is a mixed singlet/triplet state. Finally, we find that while at $T_c$ the triplet and singlet transitions are dual to one another, below $T_c$ the duality is broken, with the triplet state more susceptible to orbital fluctuations just by virtue of its symmetry. Our results indicate that such fluctuation-induced mixed states may be an inherent feature of strongly correlated materials.

cond-mat.str-el↗

arXiv2023

Nonunitary gates using measurements only

Measurement-based quantum computation (MBQC) is a universal platform to realize unitary gates, only using measurements which act on a pre-prepared entangled resource state. By deforming the measurement bases, as well as the geometry of the resource state, we show that MBQC circuits always transmit and act on the input state but generally realize nonunitary logical gates. In contrast to the stabilizer formalism which is often used for unitary gates, we find that ZX calculus is an ideal computation method of these nonunitary gates. As opposed to unitary gates, nonunitary gates can not be applied with certainty, due to the randomness of quantum measurements. We maximize the success probability of realizing nonunitary gates, and discuss applications including imaginary time evolution, which we demonstrate on a noisy intermediate scale quantum device.

quant-ph↗

arXiv2023

The field theory of a superconductor with repulsion

A superconductor emerges as a condensate of electron pairs, which bind despite their strong Coulomb repulsion. Eliashberg's theory elucidates the mechanisms enabling them to overcome this repulsion and predicts the transition temperature and pairing correlations. However, a comprehensive understanding of how repulsion impacts the phenomenology of the resulting superconductor remains elusive. We present a formalism that addresses this challenge by applying the Hubbard-Stratonovich transformation to an interaction including instantaneous repulsion and retarded attraction. We first decompose the interaction into frequency scattering channels and then integrate out the fermions. The resulting bosonic action is complex and the saddle point corresponding to Eliashberg's equations generally extends into the complex plane and away from the physical axis. We numerically determine this saddle point using the gradient descent method, which is particularly well-suited for the case of strong repulsion. We then turn to consider fluctuations around this complex saddle point. The matrix controlling fluctuations about the saddle point is found to be a non-Hermitian symmetric matrix, which generally suffers from exceptional points that are tuned by different parameters. These exceptional points may influence the thermodynamics of the superconductor. For example, within the quadratic approximation the upper critical field sharply peaks at a critical value of the repulsion strength related to an exceptional point appearing at $T_c$. Our work facilitates the mapping between microscopic and phenomenological theories of superconductivity, particularly in the presence of strong repulsion. It has the potential to enhance the accuracy of theoretical predictions for experiments in systems where the pairing mechanism is unknown.

cond-mat.supr-con↗

arXiv2023

A mechanism for $\pi$ phase shifts in Little-Parks experiments: application to 4Hb-TaS$_2$ and to 2H-TaS$_2$ intercalated with chiral molecules

Recently, unusual $\pi$ phase shifts in Little-Parks experiments performed on two systems derived from the layered superconductor 2H-TaS$_2$ were reported. These systems share the common feature that additional layers have been inserted between the 1H-TaS$_2$ layers. In both cases, the $\pi$ phase shift has been interpreted as evidence for the emergence of exotic superconductivity in the 1H layers. Here, we propose an alternative explanation assuming that superconductivity in the individual 1H layers is of conventional $s$-wave nature derived from the parent 2H-TaS$_2$. We show that a negative Josephson coupling between otherwise decoupled neighboring 1H layers can explain the observations. Furthermore, we find that the negative coupling can arise naturally assuming a tunneling barrier containing paramagnetic impurities. An important ingredient is the suppression of non-spin-flip tunneling due to spin-momentum locking of Ising type in a single 1H layer together with the inversion symmetry of the double layer. In the exotic superconductivity scenario, it is challenging to explain why the critical temperature is almost the same as in the parent material and, in the 4Hb case, the superconductivity's robustness to disorder. Both are non-issues in our picture, which also exposes the common features that are special in these two systems.

cond-mat.supr-con↗

arXiv2022

Synergetic ferroelectricity and superconductivity in zero-density Dirac semimetals near quantum criticality

We study superconductivity in a three-dimensional zero-density Dirac semimetal in proximity to a ferroelectric quantum critical point. We find that the interplay of criticality, inversion-symmetry breaking, and Dirac dispersion gives rise to a robust superconducting state at the charge-neutrality point, where no Fermi surface is present. Using Eliashberg theory, we show that the ferroelectric quantum critical point is unstable against the formation of a ferroelectric density wave (FDW), whose fluctuations, in turn, lead to a first-order superconducting transition. Surprisingly, long-range superconducting and FDW orders are found to cooperate with each other, in contrast to the more usual scenario of phase competition. Therefore, we suggest that driving charge neutral Dirac materials, e.g., Pb$_x$Sn$_{1-x}$Te, through a ferroelectric quantum critical point may lead to superconductivity intertwined with FDW order.

cond-mat.supr-con↗

arXiv2022

A theory of criticality for quantum ferroelectric metals

A variety of compounds, for example doped paraelectrics and polar metals, exhibit both ferroelectricity and correlated electronic phenomena such as low-density superconductivity and anomalous transport. Characterizing such properties is tied to understanding the quantum dynamics of inversion symmetry breaking in the presence of itinerant electrons. Here, we present a comprehensive analysis of the normal state properties of a metal near a quantum critical transition to a ferroelectric state, in both two and three dimensions. Starting from a minimal model of electrons coupled to a \emph{transverse} polar phonon via a Rashba-type spin-orbit interaction, we compute the dynamical response of both electrons and phonons. We find that the system can evince both Fermi and non-Fermi liquid phases, as well as enhanced pairing in both singlet and triplet channels. Furthermore, we systematically compute corrections to one-loop theory and find a tendency to quantum order-by-disorder, leading to a phase diagram that can include second order, first order, and finite-momentum phase transitions. Finally, we show that the entire phase diagram can be controlled via application of external strain, either compressive or volume-preserving. Our results provide a map of the dynamical and thermodynamical phase space of quantum ferroelectic metals, which can serve in characterizing existing materials and in seeking applications for quantum technologies.

cond-mat.str-el↗

arXiv2022

Evidence of a two-component order parameter in 4Hb-TaS2 in the Little-Parks effect

Finding unambiguous evidence of non-trivial pairing states is one of the greatest experimental challenges in the field of unconventional superconductivity. Such evidence requires phase-sensitive probes susceptible to the internal structure of the order parameter. We measure the Little-Parks effect to provide clear evidence of an unconventional superconducting order parameter in 4Hb-TaS$_2$. Namely, we find a $\pi$-shift in the transition-temperature oscillations of rings made of a single crystal. We argue that such an effect can only occur if the underlying order parameter belongs to a two-dimensional representation, in other words there are two degenerate order parameters right at the transition. Additionally, we show that $T_c$ is enhanced as a function of the out-of-plane field when a constant in-plane field is applied. Such an increase is consistent with a chiral state, which again, in general only emerges from a two-component order parameter. In combination with previous experiments, our results strongly indicate that 4Hb-TaS$_2$ indeed realizes a chiral superconductor.

cond-mat.supr-con↗