Low-temperature ageing of zirconia-toughened alumina ceramics and its implication in biomedical implants
Changes in crystalline phases resulting from low-temperature ageing of different yttria doped and non-doped zirconia-toughened alumina composites and nanocomposites were investigated under controlled humidity and temperature conditions in autoclave. A classical powder mixing processing route and a new modified colloidal processing route were used to process the composites. Different compositions ranging from 2.5 wt.% zirconia in a matrix of alumina to pure zirconia (3Y-TZP) were studied. It was observed that Al2O3+yttria stabilised ZrO2 composites exhibited significant ageing. However, ageing was much slower than traditionally observed for Y-TZP ceramics, due to the presence of the alumina matrix. Ageing was clearly limited for zirconia content beyond 25 wt.%. On the other side of the spectrum, Al2O3+2.5 wt.% ZrO2 initially presented a monoclinic fraction but did not show any ageing degradation. These composites seem to represent the best choice between slow crack growth and ageing resistance.