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José P. C. dos Santos

Publications and source records attributed to José P. C. dos Santos.

2 recordsLinked to original sources

An overview of the fractional-order gradient descent method and its applications

Recent studies have shown that fractional calculus is an effective alternative mathematical tool in various scientific fields. However, some investigations indicate that results established in differential and integral calculus do not necessarily hold true in fractional calculus. In this work we will compare various methods presented in the literature to improve the Gradient Descent Method, in terms of convergence of the method, convergence to the extreme point, and convergence rate. In general, these methods that generalize the gradient descent algorithm by replacing the gradient with a fractional-order operator are inefficient in achieving convergence to the extremum point of the objective function. To avoid these difficulties, we proposed to choose the Fractional Continuous Time algorithm to generalize the gradient method. In this approach, the convergence of the method to the extreme point of the function is guaranteed by introducing the fractional order in the time derivative, rather than in of the gradient. In this case, the issue of finding the extreme point is resolved, while the issue of stability at the equilibrium point remains. Fractional Continuous Time method converges to extreme point of cost function when fractional-order is between 0 and 1. The simulations shown in this work suggests that a similar result can be found when $1 \leq α\leq 2$. { This paper highlights the main advantages and disadvantages of generalizations of the gradient method using fractional derivatives, aiming to optimize convergence in complex problems. Some chemical problems, with n=11 and 24 optimization parameters, are employed as means of evaluating the efficacy of the propose algorithms. In general, previous studies are restricted to mathematical questions and simple illustrative examples.

math.OC↗

A speculative study of non-linear Arrhenius plot by using fractional calculus

In this study, the Van't Hoff differential equation is taken under consideration by making use of fractional derivative tools. In this context, the nonlinear Arrhenius behaviour can be obtained and some experimental values of reaction rate as function of temperature were fitted, with the proposed model. The new model showed better performance to fit rate constant data for different kinetics process, when compared with Arrhenius law. In these case, the Van't Hoff differential equation with noniteger order found relative percentage error less that 3% within experimental error. The fractional order plays an important role in modeling temperature dependence of these kinetic processes. Thus it provides a new perspective in the handling of many problems (e.g., as solubility as function of temperature; temperature dependency of the viscosity and conductivity, etc).

physics.chem-ph↗