arXiv subjects

Joseph Alexander

Publications and source records attributed to Joseph Alexander.

4 recordsLinked to original sources

arXiv2026

Isotopically enriched epitaxial CaWO$_{4}$ thin films for Er$^{3+}$ spin-photon quantum interfaces

Rare earth ion (REI)-doped oxide thin films are attractive for the application of quantum interconnects due to their stable optical levels and scalability$^{1-3}$. Among them, Er$^{3+}$ doped CaWO$_{4}$ is promising because it possesses narrow optical linewidth transitions and a long spin coherence time$^{4-6}$. The electron spin coherence is limited at high temperatures by paramagnetic impurities and by the presence of the 14.3% $^{183}$W nuclear spin. To further increase the spin coherence time at millikelvin temperatures, where the paramagnetic impurities are frozen out, our approach is to synthesize chemically and isotopically purified thin films as a host material. We first grow non-isotopically enriched Er$^{3+}$ doped CaWO$_{4}$ thin films, which exhibit a 214(13) MHz photoluminescence (PL) inhomogeneous linewidth, indicating the thin film has high crystalline quality. We then grow isotopically enriched CaWO$_{4}$ thin films using an isotopically purified $^{186}$WO$_{3}$ source. Time of flight secondary ion mass spectrometry (ToF-SIMS) was used to measure the relative concentration of W isotopes. $^{183}$W, the only W isotope that has a net nuclear spin and is the major cause of spin decoherence, was at a relative abundance of 1.2%, a factor of 10 lower than natural abundance. We also observed PL emission from single ions after integrating nano-photonic devices with the thin film. These results establish isotopically engineered CaWO$_{4}$ thin films as a promising platform for future studies of nuclear-spin-limited coherence and for scalable rare-earth-ion-based quantum nanophotonic devices.

quant-ph↗

arXiv2025

Coherent control of interacting solid-state spins below the diffraction limit

Optically addressed atomic defects in the solid-state are widely used as single-photon sources and memories for quantum network applications. The solid-state environment allows for a high density of electron and nuclear spins with the potential to form registers for coherent information processing. However, it is challenging to reliably address individual spins at nanometer separations where interactions are large. Rare-earth ions offer a unique solution, as their narrow homogeneous optical linewidth allows frequency-domain resolution of a large number of emitters without regard to their spatial separation. In this work, we realize coherent optical and spin control of a pair of interacting Er$^{3+}$ ions, together with a nearby nuclear spin ancilla. We demonstrate two-qubit electron-electron gates and use them to perform repeated quantum non-demolition measurements on one of the Er$^{3+}$ ions. We also demonstrate electron-nuclear gates to allow coherent storage and retrieval of qubit information in a nuclear spin, and show that the nuclear spin coherence survives readout of the electron spin. These techniques can be readily scaled to larger numbers of electron and nuclear spins, paving the way for massively multiplexed quantum network nodes.

quant-ph↗

arXiv2022

Coherent spin dynamics of rare-earth doped crystals in the high-cooperativity regime

Rare-earth doped crystals have long coherence times and the potential to provide quantum interfaces between microwave and optical photons. Such applications benefit from a high cooperativity between the spin ensemble and a microwave cavity -- this motivates an increase in the rare earth ion concentration which in turn impacts the spin coherence lifetime. We measure spin dynamics of two rare-earth spin species, $^{145}$Nd and Yb doped into Y$_{2}$SiO$_{5}$, coupled to a planar microwave resonator in the high cooperativity regime, in the temperature range 1.2 K to 14 mK. We identify relevant decoherence mechanisms including instantaneous diffusion arising from resonant spins and temperature-dependent spectral diffusion from impurity electron and nuclear spins in the environment. We explore two methods to mitigate the effects of spectral diffusion in the Yb system in the low-temperature limit, first, using magnetic fields of up to 1 T to suppress impurity spin dynamics and, second, using transitions with low effective g-factors to reduce sensitivity to such dynamics. Finally, we demonstrate how the `clock transition' present in the $^{171}$Yb system at zero field can be used to increase coherence times up to $T_{2} = 6(1)$ ms.

quant-ph↗

arXiv2021

Random-access quantum memory using chirped pulse phase encoding

As in conventional computing, key attributes of quantum memories are high storage density and, crucially, random access, or the ability to read from or write to an arbitrarily chosen register. However, achieving such random access with quantum memories in a dense, hardware-efficient manner remains a challenge, for example requiring dedicated cavities per qubit or pulsed field gradients. Here we introduce a protocol using chirped pulses to encode qubits within an ensemble of quantum two-level systems, offering both random access and naturally supporting dynamical decoupling to enhance the memory lifetime. We demonstrate the protocol in the microwave regime using donor spins in silicon coupled to a superconducting cavity, storing up to four multi-photon microwave pulses in distinct memory modes and retrieving them on-demand up to 2~ms later. A further advantage is the natural suppression of superradiant echo emission, which we show is critical when approaching unit cooperativity. This approach offers the potential for microwave random access quantum memories with lifetimes exceeding seconds, while the chirped pulse phase encoding could also be applied in the optical regime to enhance quantum repeaters and networks.

quant-ph↗