arXiv subjects

Joseph P. Heremans

Publications and source records attributed to Joseph P. Heremans.

31 records · Page 2Linked to original sources

arXiv2018

Effect of magnons on interfacial phonon drag in YIG/metal systems

We examine substrate-to-film interfacial phonon drag on typical spin Seebeck heterostructures, in particular studying the effect of ferromagnetic magnons on the phonon-electron drag dynamics at the interface. We investigate with high precision the effect of magnons in the Pt|YIG heterostructure by designing a magnon drag thermocouple; a hybrid sample with both a Pt|YIG film and Pt|GGG interface accessible isothermally via a 6 nm Pt film patterned in a rectangular U shape with one arm on the 250 nm YIG film and the other on GGG. We measure the voltage between the isothermal ends of the U, while applying a temperature gradient parallel to the arms and perpendicular to the bottom connection. With a uniform applied temperature gradient, the Pt acts as a differential thermocouple. We conduct temperature-dependent longitudinal thermopower measurements on this sample. Results show that the YIG interface actually decreases the thermopower of the film, implying that magnons impede phonon drag. We repeat the experiment using metals with low spin Hall angles, Ag and Al, in place of Pt. We find that the phonon drag peak in thermopower is killed in samples where the metallic interface is with YIG. We also investigate magneto-thermopower and YIG film thickness dependence. These measurements confirm our findings that magnons impede the phonon-electron drag interaction at the metallic interface in these heterostructures.

cond-mat.mtrl-sci↗

arXiv2018

Magnons versus electrons in thermal spin transport through metallic interfaces

We develop a theory for spin transport in magnetic metals that treats the contribution of magnons and electrons on equal footing. As an application we consider thermally-driven spin injection across an interface between a magnetic metal and a normal metal, i.e., the spin-dependent Seebeck effect. We show that the ratio between magnonic and electronic contribution scales as $\sqrt{T/T_C}T_F/T_C$, with the Fermi temperature $T_F$ and the Curie temperature $T_C$. Since, typically, $T_C \ll T_F$, the magnonic contribution may dominate the thermal spin injection, even though the interface is more transparent for electronic spin current.

cond-mat.mes-hall↗

arXiv2017

Scalable Nernst Thermoelectric Power using a Coiled Galfenol Wire

The Nernst thermopower usually is considered far too weak in most metals for waste heat recovery. However, its transverse orientation gives it an advantage over the Seebeck effect on non-flat surfaces. Here, we experimentally demonstrate the scalable generation of a Nernst voltage in an air-cooled metal wire coiled around a hot cylinder. In this geometry, a radial temperature gradient generates an azimuthal electric field in the coil. A Galfenol (Fe$_{0.85}$Ga$_{0.15}$) wire is wrapped around a cartridge heater, and the voltage drop across the wire is measured as a function of axial magnetic field. As expected, the Nernst voltage scales linearly with the length of the wire. Based on heat conduction and fluid dynamic equations, finite-element method is used to calculate the temperature gradient across the Galfenol wire and determine the Nernst coefficient. A giant Nernst coefficient of -2.6 $μ$V/KT at room temperature is estimated, in agreement with measurements on bulk Galfenol. We expect that the giant Nernst effect in Galfenol arises from its magnetostriction, presumably through enhanced magnon-phonon coupling. Our results demonstrate the feasibility of a transverse thermoelectric generator capable of scalable output power from non-flat heat sources.

cond-mat.mtrl-sci↗

arXiv2017

Evidence for the role of the magnon energy relaxation length in the Spin Seebeck Effect

Temperature-dependent spin-Seebeck effect data on Pt|YIG (Y$_3$Fe$_5$O$_{12}$)|GGG (Gd$_3$Ga$_5$O$_{12}$) are reported for YIG films of various thicknesses. The effect is reported as a spin-Seebeck resistivity (SSR), the inverse spin-Hall field divided by the heat flux, to circumvent uncertainties about temperature gradients inside the films. The SSR is a non-monotonic function of YIG thickness. A diffusive model for magnon transport demonstrates how these data give evidence for the existence of two distinct length scales in thermal spin transport, a spin diffusion length and a magnon energy relaxation length.

cond-mat.mtrl-sci↗

arXiv2017

Dirac dispersion generates large Nernst effect in Weyl semimetals

Weyl semimetals expand research on topologically protected transport by adding bulk Berry monopoles with linearly dispersing electronic states and topologically robust, gapless surface Fermi arcs terminating on bulk node projections. Here, we show how the Nernst effect, combining entropy with charge transport, gives a unique signature for the presence of Dirac bands. The Nernst thermopower of NbP (maximum of 800 microV K-1 at 9 T, 109 K) exceeds its conventional thermopower by a hundredfold and is significantly larger than the thermopower of traditional thermoelectric materials. The Nernst effect has a pronounced maximum near T_M=90 +/- 20 K=mu_0/kB (mu_0 is chemical potential at T=0 K). A self-consistent theory without adjustable parameters shows that this results from electrochemical potential pinning to the Weyl point energy at T>=TM, driven by charge neutrality and Dirac band symmetry. Temperature and field dependences of the Nernst effect, an even function of the charge polarity, result from the intrinsically bipolar nature of the Weyl fermions. Through this study, we offer an understanding of the temperature dependence of the position of the electrochemical potential vis-a-vis the Weyl point, and we show a direct connection between topology and the Nernst effect, a potentially robust experimental tool for investigating topological states and the chiral anomaly.

cond-mat.mes-hall↗

arXiv2017

Fermi arc mediated entropy transport in topological semimetals

In topological Weyl semimetals, the low energy excitations are comprised of linearly dispersing Weyl fermions, which act as monopoles of Berry curvature in momentum space and result in topologically protected Fermi arcs on the surfaces. We propose that these Fermi arcs in Weyl semimetals lead to an anisotropic magnetothermal conductivity, strongly dependent on externally applied magnetic field and resulting from entropy transport driven by circulating electronic currents. The circulating currents result in no net charge transport, but they do result in a net entropy transport. This translates into a magnetothermal conductivity that should be a unique experimental signature for the existence of the arcs. We analytically calculate the Fermi arc-mediated magnetothermal conductivity in the low-field semiclassical limit as well as in the high-field ultra-quantum limit, where only the chiral Landau levels are involved. By numerically including the effects of higher Landau levels, we show how the two limits are linked at intermediate magnetic fields. This work provides the first proposed signature of Fermi arc-mediated thermal transport and sets the stage for utilizing and manipulating the topological Fermi arcs in experimental thermal applications.

cond-mat.mes-hall↗

arXiv2016

Observation of spin Seebeck contribution to the transverse thermopower in Ni-Pt and MnBi-Au bulk nanocomposites

Transverse thermoelectric devices produce electric fields perpendicular to an incident heat flux. Classically, this process is driven by the Nernst effect in bulk solids, wherein a magnetic field generates a Lorentz force on thermally excited electrons. The spin Seebeck effect (SSE) also produces magnetization-dependent transverse electric fields. SSE is traditionally observed in thin metallic films deposited on electrically insulating ferromagnets, but the films' high resistance limits thermoelectric conversion efficiency. Combining Nernst and SSE in bulk materials would enable devices with simultaneously large transverse thermopower and low electrical resistance. Here we demonstrate experimentally this is possible in composites of conducting ferromagnets (Ni or MnBi) containing metallic nanoparticles with strong spin-orbit interactions (Pt or Au). These materials display positive shifts in transverse thermopower attributable to inverse spin Hall electric fields in the nanoparticles. This more than doubles the power output of the Ni-Pt materials, establishing proof-of-principle that SSE persists in bulk nanocomposites.

cond-mat.mtrl-sci↗

arXiv2016

Magnon-drag thermopower and Nernst coefficient in Fe, Co, and Ni

Magnon-drag is shown to dominate the thermopower of elemental Fe from 2 to 80 K and of elemental Co from 150 to 600 K; it is also shown to contribute to the thermopower of elemental Ni from 50 to 500 K. Two theoretical models are presented for magnon-drag thermopower. One is a hydrodynamic theory based purely on non-relativistic, Galilean, spin-preserving electron-magnon scattering. The second is based on spin-motive forces, where the thermopower results from the electric current pumped by the dynamic magnetization associated with a magnon heat flux. In spite of their very different microscopic origins, the two give similar predictions for pure metals at low temperature, allowing us to semi-quantitatively explain the observed thermopower of elemental Fe and Co without adjustable parameters. We also find that magnon-drag may contribute to the thermopower of Ni. A spin-mixing model is presented that describes the magnon-drag contribution to the Anomalous Nernst Effect in Fe, again enabling a semi-quantitative match to the experimental data without fitting parameters. Our work suggests that particle non-conserving processes may play an important role in other types of drag phenomena, and also gives a predicative theory for improving metals as thermoelectric materials.

cond-mat.mtrl-sci↗

arXiv2016

Spin Seebeck effect through antiferromagnetic NiO

We report temperature-dependent spin-Seebeck measurements on Pt/YIG bilayers and Pt/NiO/YIG trilayers, where YIG (Yttrium iron garnet, Y$_3$Fe$_5$O$_{12}$) is an insulating ferrimagnet and NiO is an antiferromagnet at low temperatures. The thickness of the NiO layer is varied from 0 to 10 nm. In the Pt/YIG bilayers, the temperature gradient applied to the YIG stimulates dynamic spin injection into the Pt, which generates an inverse spin Hall voltage in the Pt. The presence of a NiO layer dampens the spin injection exponentially with a decay length of $2 \pm 0.6$ nm at 180 K. The decay length increases with temperature and shows a maximum of $5.5 \pm 0.8$ nm at 360 K. The temperature dependence of the amplitude of the spin-Seebeck signal without NiO shows a broad maximum of $6.5 \pm 0.5$ $μ$V/K at 20 K. In the presence of NiO, the maximum shifts sharply to higher temperatures, likely correlated to the increase in decay length. This implies that NiO is most transparent to magnon propagation near the paramagnet-antiferromagnet transition. We do not see the enhancement in spin current driven into Pt reported in other papers when 1-2 nm NiO layers are sandwiched between Pt and YIG.

cond-mat.mtrl-sci↗

arXiv2015

Anisotropic defect-induced ferromagnetism and transport in Gd-doped GaN two-dimensional electron gasses

Here we report on the effect of rare earth Gd-doping on the magnetic properties and magnetotransport of GaN two-dimensional electron gasses (2DEGs). Samples are grown by plasma-assisted molecular beam epitaxy and consist of AlN/GaN heterostructures where Gd is delta-doped within a polarization-induced 2DEG. Ferromagnetism is observed in these Gd-doped 2DEGs with a Curie temperature above room temperature and an anisotropic spontaneous magnetization preferring an out-of-plane (c-axis) orientation. At magnetic fields up to 50 kOe, the magnetization remains smaller for in-plane configuration than for out-of-plane, which is indicative of exchange coupled spins locked along the polar c-axis. The sample with the lowest Gd concentration (2.3 $\times$ $10^{14}$ cm$^{-2}$) exhibits a saturation magnetization of 41.1 $μ_B/Gd^{3+}$ at 5 K revealing that the Gd ion spins (7 $μ_B$) alone do not account for the magnetization. Surprisingly, control samples grown without any Gd display inconsistent magnetic properties; in some control samples weak ferromagnetism is observed and in others paramagnetism. The ferromagnetic 2DEGs do not exhibit the anomalous Hall effect; the Hall resistance varies non-linearly with the magnetic field, but does not track the magnetization indicating the lack of coupling between the ferromagnetic phase and the conduction band electrons within the 2DEG.

cond-mat.mtrl-sci↗

arXiv2015

P-type doping of elemental bismuth with indium, gallium and tin: a novel doping mechanism in solids

A new doping mechanism is described, whereby a doping impurity does not simply transfer charge to the bands of a host semiconductor or semimetal, but rearranges the core energy levels deep in the valence band of the host. This, in turn, leads to a redistribution of all electrons in the host, and, if designed properly, changes the location of the Fermi level EF and the density of conducting charge carriers near EF. The principle is proven experimentally in elemental Bi, whereby group III elements In and Ga dope Bi p-type, in spite of the fact that all three atoms are trivalent in the solid state. Electronic structure calculations show the formation of a hyperdeep defect state (HDS) and its effect on the EF in Bi doped with In (Bi:In) and Ga (Bi:Ga). The HDS at -5 to -6 eV below the EF of elemental Bi hybridizes with the Bi 6p electrons, and deprives the Bi valence band of two electrons per impurity atom. This then perturbs the electron count in the solid and lowers the EF. The charge on the impurity atoms is unchanged. In principle, this doping action does not result in the appearance of ionized impurities that scatter conduction electrons and holes in conventional doping. Experimentally, Shubnikov - de Haas and Hall Effect measurements show that adding In to Bi results in an increase in the density of holes. Thermoelectric, galvanomagnetic and thermomagnetic data are given for single-crystal and polycrystalline samples. In-doping leads to an enhancement of the thermoelectric figure of merit, which suggests that the new doping mechanism also gives a route to develop better thermoelectric materials. The same mechanism is at work for Sn-doped Bi (Bi:Sn), although here ionized impurity scattering is not avoided.

cond-mat.mtrl-sci↗

arXiv2015

The effect of the magnon dispersion on the longitudinal spin Seebeck effect in yttrium iron garnets (YIG)

We study the temperature dependence of the longitudinal spin-Seebeck effect (LSSE) in a yttrium iron garnet Y3Fe5O12 (YIG) / Pt system for samples of different thicknesses. In this system, the thermal spin torque is magnon-driven. The LSSE signal peaks at a specific temperature that depends on the YIG sample thickness. We also observe freeze-out of the LSSE signal at high magnetic fields, which we attribute to the opening of an energy gap in the magnon dispersion. We observe partial freeze-out of the LSSE signal even at room temperature, where kBT is much larger than the gap. This suggests that a subset of the magnon population with an energy below kB x TC (TC about 40 K) contribute disproportionately to the LSSE; at temperatures below TC, we label these magnons subthermal magnons. The T-dependence of the LSSE at temperatures below the maximum is interpreted in terms of a new empirical model that ascribes most of the temperature dependence to that of the thermally driven magnon flux.

cond-mat.mtrl-sci↗

arXiv2013

Enhancement in the Figure of Merit of p-type BiSb alloys through multiple valence-band doping

N-type Bi100-xSbx alloys have the highest thermoelectric figure of merit (zT) of all materials below 200K; here we investigate how filling multiple valence band pockets at T and H-points of the Brillouin zone produces high zT in p-type Sn-doped material. This approach, theoretically predicted to potentially give zT>1 in Bi, was used successfully in PbTe. We report thermopower, electrical and thermal conductivity (2 to 400K) of single crystals with 12<x<37 and polycrystals (x=50-90), higher Sb concentrations than previous studies. We obtain a 60% improvement in zT to 0.13.

cond-mat.mtrl-sci↗