arXiv subjects

Joseph Rudnick

Publications and source records attributed to Joseph Rudnick.

At least 19 recordsLinked to original sources

arXiv2026

Casimir versus Helmholtz forces in the Gaussian model: exact results for Dirichlet--Dirichlet, Neumann--Dirichlet, Neumann--Neumann, and periodic boundary conditions

We present results and compare the behavior of two fluctuation-induced forces pertinent for their corresponding ensembles: the critical Casimir force in the grand canonical (fixed external field $h$) one and the critical Helmholtz force in the canonical (fixed average value of the order parameter $m$) one. We do so by deriving exact results for their behavior near the bulk critical point at $T=T_c$ in the three-dimensional Gaussian model. We consider Dirichlet-Dirichlet, Neumann-Dirichlet, Neumann-Neumann, and periodic boundary conditions. For every boundary condition examined, we confirm that both forces follow a finite-size scaling. We find that for Dirichlet-Dirichlet and Neumann-Dirichlet boundary conditions the Casimir and the Helmholtz force differ from each other. For Dirichlet-Dirichlet boundary conditions the Casimir force is always attractive, while the Helmholtz force can be both attractive and repulsive as a function of $T$ and $m$. For Neumann-Dirichlet boundary conditions the Casimir force changes sign from repulsive to attractive with increase of $h$, while the Helmholtz force stays always repulsive. Under periodic and Neumann-Neumann boundary conditions the Casimir force and the Helmholtz force coincide - the first does not depend on $h$, while the latter does not depend on $m$; they are always attractive.

cond-mat.stat-mech↗

arXiv2025

Casimir versus Helmholtz fluctuation induced force in { the Nagle}-Kardar model: Exact results

When used to describe \textit{finite} systems the {conjugate} statistical-mechanical ensembles are \textit{not} equivalent. This has physical implications for the behavior of the fluctuation induced forces pertinent to the different ensembles. Here, {we study the Nagle-Kardar model within the grand-canonical ensemble (GCE) and the canonical ensemble (CE) (with conserved total magnetization) for periodic boundary conditions (PBC)}. {We focus on two fluctuation-induce forces: the Casimir force (CF) in the GCE and the Helmholtz force (HF) in the CE}. In the infinite system limit the model exhibits a critical line, which ends at a tricritical point. Unexpectedly, the critical Casimir force (CCF) is \textit{repulsive} near the critical line and tricritical point, decaying rapidly upon departure from those two regions and becoming \textit{attractive}. This violates the widely-accepted ``boundary condition rule,'' which presumes that the CCF is attractive for equivalent boundary conditions (BC) and repulsive for conflicting BC. For the HF we find that it also changes sign as a function of temperature and the magnetization. We conclude, that CCF and HF have a behavior quite different from each other as a function of the tunable parameters (temperature, magnetic field, or magnetization) of the model. This dependence allows {for the control of the} \textit{sign} of these forces, as well as their magnitude.

cond-mat.stat-mech↗

arXiv2024

Finite-size Nagle-Kardar model: Casimir force

We derive exact results for the critical Casimir force (CCF) within the Nagle-Kardar model with periodic boundary conditions (PBC's). The model represents one-dimensional Ising chain with long-range equivalent-neighbor ferromagnetic interactions of strength $J_{l}/N>0$ superimposed on the nearest-neighbor interactions of strength $J_{s}$ which could be either ferromagnetic ($J_{s}>0$) or antiferromagnetic ($J_{s}<0$). In the infinite system limit the model exhibits in the plane $(K_s=\beta J_s,K_l=\beta J_l)$ a critical line $2 K_l=\exp{\left(-2 K_s\right)}, K_s>-\ln3/4$, which ends at a tricritical point $(K_l=-\sqrt{3}/2, K_s=-\ln3/4)$. The critical Casimir amplitudes are: $\Delta_{\rm Cas}^{\rm (cr)}=1/4$ at the critical line, and $\Delta_{\rm Cas}^{\rm (tr)}=1/3$ at the tricritical point. Quite unexpectedly, with the imposed PBC's the CCF exhibits very unusual behavior as a function of temperature and magnetic field. It is \textit{repulsive} near the critical line and tricritical point, decaying rapidly with separation from those two singular regimes fast away from them and becoming \textit{attractive}, displaying in which the maximum amplitude of the attraction exceeds the maximum amplitude of repulsion. This represents a violation of the widely-accepted ``boundary condition rule,'' which holds that the CCF is attractive for equivalent BC's and repulsive for conflicting BC's \textit{independently} of the actual bulk universality class of the phase transition under investigation.

cond-mat.stat-mech↗

arXiv2022

Exact expressions for the partition function of the one-dimensional Ising model in the fixed-$M$ ensemble

We obtain exact closed-form expressions for the partition function of the one-dimensional Ising model in the fixed-$M$ ensemble, for three commonly-used boundary conditions: periodic, antiperiodic and Dirichlet. These expressions allow for the determination of fluctuation-induced forces in the canonical ensemble, which we term Helmholtz forces. The thermodynamic expressions and the calculations flowing from them should provide insights into the nature and behavior of fluctuation induced forces in interesting and as-yet unexplored regimes.

cond-mat.stat-mech↗

arXiv2022

The propagation of infection fronts in spatially distributed compartment models in epidemiology

Spatio-temporal extensions of familiar compartment models for disease transmission incorporating diffusive behavior, or interactions between individuals at separate locations, are explored. The models considered have the character of reaction-diffusion systems, which allow familiar techniques to be applied. The focus is largely on the appearance of soliton-like moving fronts that spread infection to previously uninfected regions. Near threshold dynamical critical behavior and a degree of universality are revealed. Extending two of the models to include a simple nonlinearity in the strength of the binary interaction between a susceptible individual and an infected one, we find the possibility of static coexistence between spatial regions with different levels of infection and an analogy with first-order transitions in thermodynamics.

physics.bio-ph↗

arXiv2022

The Spanning Tree Model and the Assembly Kinetics of RNA Viruses

Single-stranded (ss) RNA viruses self-assemble spontaneously in solutions that contain the viral RNA genome molecules and viral capsid proteins. The self-assembly of empty capsids can be understood on the basis of free energy minimization. However, during the self-assembly of complete viral particles in the cytoplasm of an infected cell, the viral genome molecules must be selected from a large pool of very similar host messenger RNA molecules and it is not known whether this also can be understood by free energy minimization. We address this question using a simple mathematical model recently proposed for the assembly of small ssRNA viruses (submitted to PLOS Biocomputation). We present a statistical physics analysis of the properties of the model finding an effect kinetic RNA selection mechanism with selection taking place during the formation of the nucleation complex. Surprisingly, kinetic selectivity is greatly enhanced by a modest level of supersaturation and by reduced protein to RNA concentration ratios. The mechanism is related to the Hopfield kinetic proofreading scenario.

physics.bio-ph↗

arXiv2021

The Spanning Tree Model and the Assembly Kinetics of RNA Viruses

Single-stranded (ss) RNA viruses self-assemble spontaneously in solutions that contain the viral RNA genome molecules and the viral capsid proteins. The self-assembly of empty capsids can be understood on the basis of free energy minimization of rather simple models. However, during the self-assembly of complete viral particles in the cytoplasm of an infected cell, the viral genome molecules must be selected from a large pool of very similar host messenger RNA molecules. It is known that the assembly process takes the form of preferential heterogeneous nucleation of capsid proteins on viral RNA molecules ("selective nucleation"). Recently, a simple mathematical model was proposed for the selective nucleation of small ssRNA viruses. In this paper we present a statistical physics analysis of the thermal equilibrium and kinetic properties of that model and show that it can account, at least qualitatively, for numerous observations of the self-assembly of small ssRNA viruses.

physics.bio-ph↗

arXiv2021

The Spanning Tree Model for the Assembly Kinetics of RNA Viruses

We present a simple kinetic model for the assembly of small single-stranded RNA viruses that can be used to carry out analytical packaging contests between different types of RNA molecules. The RNA selection mechanism is purely kinetic and based on small differences between the assembly energy profiles. RNA molecules that win these packaging contests are characterized by having a minimum "Maximum Ladder Distance" and a maximum "Wrapping Number".The former is a topological invariant that measures the "branchiness" of the genome molecule while the latter measures the ability of the genome molecule to maximally associate with the capsid proteins. The model can also be used study the applicability of the theory of nucleation and growth to viral assembly, which breaks down with increasing strength of the RNA-protein interaction.

physics.bio-ph↗

arXiv2019

Invariant Theory and Orientational Phase Transitions

The Landau theory of phase transitions has been productively applied to phase transitions that involve rotational symmetry breaking, such as the transition from an isotropic fluid to a nematic liquid crystal. It even can be applied to the orientational symmetry breaking of simple atomic or molecular clusters that are not true phase transitions. In this paper we address fundamental problems that arise with the Landau theory when it is applied to rotational symmetry breaking transitions of more complex particle clusters that involve order parameters characterized by larger values of the $l$ index of the dominant spherical harmonic that describes the broken symmetry state. The problems are twofold. First, one may encounter a thermodynamic instability of the expected ground state with respect to states with lower symmetry. A second problem concerns the proliferation of quartic invariants that may or may not be physical. We show that the combination of a geometrical method based on the analysis of the space of invariants, developed by Kim to study symmetry breaking of the Higgs potential, with modern visualization tools provides a resolution to these problems. The approach is applied to the outcome of numerical simulations of particle ordering on a spherical surface and to the ordering of protein shells.

cond-mat.soft↗

arXiv2019

Exact solution for the order parameter profiles and the Casimir force in $^4$He superfluid films in an effective field theory

We present an analytical solution of an effective field theory which, in one of its formulations, is equivalent to the Ginzburg's $Ψ$-theory for the behavior of the Casimir force in a film of $^4$He in equilibrium with its vapor near the superfluid transition point. We consider three versions of the theory, depending on the way one determines its parameters from the experimental measurements. We present exact results for the behavior of the order parameter profiles and of the Casimir force within this theory, which is characterized by $d=3$, $ν=2/3$ and $β=1/3$, where $d$ is the bulk spatial dimension and $ν$ and $β$ are the usual critical exponents. In addition, we revisit relevant experiments \cite{GC99} and \cite{GSGC2006} in terms of our findings. We find reasonably good agreement between our theoretical predictions and the experimental data. We demonstrate analytically that our calculated force is attractive. The position of the extremum is predicted to be at $x_{\rm min}=π$, with $x=(L/ξ_0)(T/T_λ-1)^{1/ν}$, which value effectively coincides with the experimental finding $x_{\rm min}=3.2\pm 0.18$. Here $L$ is the thickness of the film, $T_λ$ is the bulk critical temperature and $ξ_0$ is the correlation length amplitude of the system for temperature $T>T_λ$. The theoretically predicted position of the minimum does not depend on the one adjustable parameter, $M$, entering the theory.

cond-mat.stat-mech↗

arXiv2018

Exact solution of Ginzburg's $Ψ$-theory for the Casimir force in $^4$He superfluid films

We present an analytical solution of the Ginzburg's $Ψ$-theory for the behavior of the Casimir force in a film of $^4$He in equilibrium with its vapor near the superfluid transition point, and we revisit the corresponding experiments in light of our findings. We find reasonably good agreement between the $Ψ$-theory predictions and the experimental data. Our calculated force is attractive, and the largest absolute value of the scaling function is $1.848$, while experiment yields $1.30$. The position of the extremum is predicted to be at $x=(L/ξ_0)(T/T_λ-1)^{1/ν}=π$, while experiment is consistent with $x=3.8$. Here $L$ is the thickness of the film, $T_λ$ is the bulk critical temperature and $ξ_0$ is the correlation length amplitude of the system for $T>T_λ$.

cond-mat.stat-mech↗

arXiv2017

Manipulation and amplification of the Casimir force through surface fields using helicity

We present both exact and numerical results for the behavior of the Casimir force in $O(n)$ systems with a finite extension in one direction when the system is subjected to surface fields that induce helicity in the order parameter. We show that for such systems the Casimir force in certain temperature ranges is of the order of $L^{-2}$, both above and below the critical temperature, $T_c$, of the bulk system. An example of such a system would be one with chemically modulated bounding surfaces, in which the modulation couples directly to the system's order parameter. We demonstrate that, depending on the parameters of the system, the Casimir force can be either attractive or repulsive. The exact calculations presented are for the one dimensional $XY$ and Heisenberg models under twisted boundary conditions resulting from finite surface fields that differ in direction by a specified angle and the three dimensional Gaussian model with surface fields in the form of plane waves that are shifted in phase with respect to each other. Additionally, we present exact and numerical results for the mean field version of the three dimensional $O(2)$ model with finite surface fields on the bounding surfaces. We find that all significant results are consistent with the expectations of finite size scaling.

cond-mat.stat-mech↗

arXiv2017

Orientational Phase Transitions and the Assembly of Viral Capsids

We present a generalized Landau-Brazovskii free energy for the solidification of chiral molecules on a spherical surface in the context of the assembly of viral shells. We encounter two types of icosahedral solidification transitions. The first type is a conventional first-order phase transition from the uniform to the icosahedral state. It can be described by a single icosahedral spherical harmonic of even $l$. The chiral pseudo-scalar term in the free energy creates secondary terms with chiral character but it does not affect the thermodynamics of the transition. The second type, associated with icosahedral spherical harmonics with odd $l$, is anomalous. Pure odd $l$ icosahedral states are unstable but stability is recovered if admixture with the neighboring $l+1$ icosahedral spherical harmonic is included, generated by the non-linear terms. This is in conflict with the principle of Landau theory that symmetry-breaking transitions are characterized by only a \textit{single} irreducible representation of the symmetry group of the uniform phase and we argue that this principle should be removed from Landau theory. The chiral term now directly affects the transition because it lifts the degeneracy between two isomeric mixed-$l$ icosahedral states. A direct transition is possible only over a limited range of parameters. Outside this range, non-icosahedral states intervene. For the important case of capsid assembly dominated by $l=15$, the intervening states are found to be based on octahedral symmetry.

physics.bio-ph↗

arXiv2016

Landau Theory and the Emergence of Chirality in Viral Capsids

We present a generalized Landau-Brazovskii theory for the solidification of chiral molecules on a spherical surface. With increasing sphere radius one encounters first intervals where robust achiral density modulations appear with icosahedral symmetry via first-order transitions. Next, one en- counters intervals where fragile but stable icosahedral structures still can be constructed but only by superposition of multiple irreducible representations. Chiral icoshedral structures appear via continuous or very weakly first-order transitions. Outside these parameter intervals, icosahedral symmetry is broken along a three-fold axis or a five-fold axis. The predictions of the theory are compared with recent numerical simulations.

physics.bio-ph↗

arXiv2015

Reply to Comment on "Casimir force in the $O(n\to\infty)$ model with free boundary conditions"

The proceeding comment raises a few points concerning our paper Dantchev \textit{et al.}, Phys. Rev. E. {\bf 89}, 042116 (2014). In this reply we stress that while Refs. Diehl \textit{et al.} EPL {\bf 100}, 10004 (2012) and Phys. Rev. E. {\bf 89}, 062123 (2014) use three different models to study the the Casimir force for the $O(n \rightarrow \infty)$ model with free boundary conditions we study a single model over the entire range of temperatures, from above the bulk critical temperature, $T_c$, to absolute temperatures down to $T=0$. The use of a single model renders more transparent the crossover from effects dominated by critical fluctuations in the vicinity of the bulk transition temperature to effects controlled by Goldstone modes at low temperatures. Contrary to the assertion in the comment, we make no claim for the superiority of our model over any of those considered by Diehl \textit{et al}. We also present additional evidence supporting our conclusion in Dantchev \textit{et al.}, Phys. Rev. E. {\bf 89}, 042116 (2014) that the temperature range in which our low-temperature analytical expansion for the Casimir force increases as $L$ grows and remains accurate for values of the ratio $T/T_c$ that become closer and closer to unity, while $T$ remains well outside of the critical region.

cond-mat.stat-mech↗

arXiv2015

Protein viscoelastic dynamics: a model system

A model system inspired by recent experiments on the dynamics of a folded protein under the influence of a sinusoidal force is investigated and found to replicate many of the response characteristics of such a system. The essence of the model is a strongly over-damped oscillator described by a harmonic restoring force for small displacements that reversibly yields to stress under sufficiently large displacement. This simple dynamical system also reveals unexpectedly rich behavior, exhibiting a series of dynamical transitions and analogies with equilibrium thermodynamic phase transitions. The effects of noise and of inertia are briefly considered and described.

cond-mat.soft↗

arXiv2014

Casimir force in the O(n -> infinity) model with free boundary conditions

We present results for the temperature behavior of the Casimir force for a system with a film geometry with thickness $L$ subject to free boundary conditions and described by the $n\to\infty$ limit of the $O(n)$ model. These results extend over all temperatures, including the critical regime near the bulk critical temperature $T_c$, where the critical fluctuations determine the behavior of the force, and temperatures well below it, where its behavior is dictated by the Goldstone's modes contributions. The temperature behavior when the absolute temperature, $T$, is a finite distance below $T_c$, up to a logarithmic-in-$L$ proximity of the bulk critical temperature, is obtained both analytically and numerically; the critical behavior follows from numerics. The results resemble - but do not duplicate - the experimental curve behavior for the force obtained for $^4$He films.

cond-mat.stat-mech↗

arXiv2013

Shape transitions in soft spheres regulated by elasticity

We study elasticity-driven morphological transitions of soft spherical core shell structures in which the core can be treated as an isotropic elastic continuum and the surface or shell as a tensionless liquid layer, whose elastic response is dominated by bending. To generate the transitions, we consider the case where the surface area of the liquid layer is increased for a fixed amount of interior elastic material. We find that generically there is a critical excess surface area at which the isotropic sphere becomes unstable to buckling. At this point it adopts a lower symmetry wrinkled structure that can be described by a spherical harmonic deformation. We study the dependence of the buckled sphere and critical excess area of the transition on the elastic parameters and size of the system. We also relate our results to recent experiments on the wrinkling of gel-filled vesicles as their interior volume is reduced. The theory may have broader applications to a variety of related structures from the macroscopic to the microscopic, including the wrinkling of dried peas, raisins, as well as the cell nucleus.

cond-mat.soft↗