Anomalous Thermal Conductivity Reversal Driven by a Fluctuating Charge Density Wave
For more than a century, the lattice thermal conductivity of crystalline solids has been known to decrease with increasing temperature, as the phonons that carry heat scatter more strongly via Umklapp processes. Here we report a pronounced violation of this rule in the layered charge-density-wave (CDW) metal 2H-TaSe2. Its in-plane thermal conductivity is strongly nonmonotonic: it peaks sharply at the 122 K ordering transition, collapses to a deep minimum near 210 K, and then anomalously reverses, rising with temperature to at least 350 K. Such a high-temperature reversal, in which a crystal conducts heat more efficiently as it is heated, is rare in crystalline solids. Its thermal conductivity minimum lies deep in the disordered phase well above the ordering transition, unlike the weak, transition-centered anomalies of other charge-density-wave systems, pointing to heat conduction governed by fluctuating rather than established order. Combining inelastic X-ray scattering, selected-area electron diffraction, and synchrotron X-ray diffraction, we attribute the reversal to phonons scattering off persistent, fluctuating charge order that survives more than 150 K above the long-range transition, to at least 300 K. A phenomenological phonon-CDW scattering model, tied directly to the measured diffraction linewidth and intensity, quantitatively reproduces the entire nonmonotonic curve. We also reveal that the charge order melts not abruptly but through a fluctuation- and defect-driven, weak first-order process, leaving short-range correlations far above the transition. This work establishes fluctuating charge order as a sensitive control knob for thermal transport in quantum materials and thermal conductivity as a powerful probe of the hidden charge order.