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Juan C. Oller

Publications and source records attributed to Juan C. Oller.

2 recordsLinked to original sources

Low-energy electron attachment to $\text{NO}_2$: absolute cross sections

Resonances from electron attachment to $\text{NO}_2$ have been identified in the total electron scattering cross sections (TCS) measured with a magnetically confined electron transmission apparatus. The corresponding absolute electron attachment cross sections have been derived from the TCS values through a self-consistent scattering channel deconvolution process. The positions of some of these resonances are consistent with previous elastic scattering calculations and dissociative electron attachment experiments. However, both the observed positions and the magnitude of the present resonance cross sections are in contradiction with the available recommended TCS values thus suggesting that electron scattering cross section databases need to be updated. Keywords: electron scattering resonances, negative ion formation, electron attachment cross sections

physics.chem-ph

Electron attachment to nitric oxide (NO) controversy

We report novel total electron scattering cross sections (TCS) from nitric oxide (NO) in the impact energy range from 1 to 15 eV by using a magnetically confined electron transmission apparatus. The accuracy of the data to within 5% and its consistency across the energy range investigated, shows significant discrepancies from previous works as to the major resonance features and magnitude of the TCS. Within the shape of the TCS, we have identified nine features which have been assigned to electron attachment resonances, most of them reported for the first time, while a comprehensive analysis of those peaking at 7.0, 7.8, and 8.8 eV has led to solve the controversy about dissociative electron attachment (DEA) cross-section that persisted for more than 50 years.

physics.chem-ph