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Juan M. Florez

Publications and source records attributed to Juan M. Florez.

7 recordsLinked to original sources

Topographic Disorder, Wind Coupling, and Directional Fire Spread: Critical Behavior in a Terrain-Weighted Forest Fire Model

We introduce the Terrain-Weighted Forest Fire Model (TFFM), a lattice model in which fire spreads on a spatially correlated Gaussian height field with the asymmetric bond probability $p_{i\to j}=\mathrm{clip}[e^{-β+γ(h_j-h_i)},0,1]$, plus an additive wind bias. Simulations on lattices up to $L=8192$ reveal a sharp active-to-inactive transition whose critical suppression threshold $β_c$ is even in $γ$, decreases with $|γ|$, and decreases as the terrain correlation length $σ_h$ is reduced: slope asymmetry acts as a suppressant because downhill bonds are penalized and fire stalls at local elevation maxima. For rough terrain and low tree density the fire fails to percolate even at zero suppression. Finite-size scaling on a fine $β$ grid at $L=2048$--$8192$ gives a correlation-length exponent $ν=1.8\pm0.17$ from both the susceptibility peak and the width of the transition, and a front-velocity exponent $δ=0.34\pm0.03$, identical for smooth and rough terrain; neither matches directed percolation ($ν_\perp=0.73$, $ν_\parallel-ν_\perp\approx0.56$) or isotropic percolation ($ν=4/3$, $\approx0.18$). The single-seed survival probability at $β_c$ is independent of $L$ and decays extremely slowly, with a running exponent falling from $\approx0.09$ to $\approx0.04$, excluding directed percolation and pointing to a survival probability that remains finite at criticality, consistent with the $L$-independent value $P^*\approx0.5$ at which $P_{\rm surv}$ drops to zero. Wind raises $β_c$ by a factor of $2$--$4$, produces a sharp onset of downwind fire-scar drift at weak coupling, and, at high terrain coupling, decreases the burned fraction at boundary crossing---a terrain-wind competition effect absent from isotropic bond-disorder models. The model yields fire-risk thresholds and fire-scar signatures comparable to satellite burn-scar data.

cond-mat.stat-mech↗

Tuning Boron-Vacancy Qubit Coherence through Layer Number in hBN

The negatively charged boron vacancy ($\VB$) in hexagonal boron nitride (\hBN{}) was the first optically addressable spin qubit identified inside a van der Waals crystal, allowing atomically defined placement relative to a target. Its coherence in bulk \hBN{} is limited by the boron nuclei of the layers flanking the defect plane, which a thin flake removes. Here, we use a generalized cluster-correlation expansion with an extended central-spin block to calculate the Hahn-echo coherence time of $\VB$ in h$^{11}$B$^{15}$N as a function of layer number. Our results show that $T_2$ rises from $199\ns$ in the bulk limit to $653\ns$ in a monolayer, a factor of $3.3$ that is already saturated at three layers and that a sublattice decomposition attributes entirely to boron. The enhancement is confined to low field, is insensitive to stacking registry and twist angle, and requires alignment to within about two degrees, an onset we reproduce with no free parameters. Under dynamical decoupling, a $1/e$ threshold returns $206\ns$ for every thickness, but this is a zero of the first-shell modulation rather than a decay: measured without a threshold, the layer contrast survives and reaches a factor of $170$. Layer number thus emerges as a design parameter for $\VB$-based sensing.

cond-mat.mes-hall↗

Slide and Twist: Manipulating Polarization in Multilayer Hexagonal Boron-Nitride

This study explores the world of across-layer sliding ferroelectricity in multilayer hexagonal boron nitride (hBN) and gallium nitride (hGaN), aiming to control out-of-plane polarization. By investigating the effects of sliding single or dual layers in various hBN stacking configurations, we uncover methods for reversing polarization with energy barriers between 5 and 30 meV/f.u., making these methods experimentally viable. Our results show that single-interface sliding is more energetically favorable, with lower barriers compared to multiple interfaces. Certain pathways reveal stable polarization plateaus, where polarization remains constant during specific sliding phases, promising robust polarization control. Moreover, rotated multilayer structures maintain consistent net out-of-plane polarization across different rotation angles. In trilayer ABT structures, rotating the top layer and sliding the bottom layer can reverse polarization, expanding device design possibilities. While the primary focus is on hBN, similar phenomena in hGaN suggest broader applicability for this class of polar materials. The identified energy barriers support the feasibility of fabricating devices based on these multilayer structures.

cond-mat.mtrl-sci↗

First-principles based Monte Carlo modeling of oxygen deficient Fe-substituted SrTiO$_3$ experimental magnetization

Ferroics based on transition-metal (TM) substituted SrTiO$_{3}$ have called much attention as magnetism and/or ferroelectricity can be tuned by using cations substitution and defects, strain and/or oxygen deficiency. C. A. Ross et al. [Phys. Rev. Applied 7, 024006 (2017)] demonstrated the SrTi$_{1-x}$Fe$_{x}$O$_{3-δ}$ (STF) magnetization behavior for different deposition oxygen-pressures, substrates and magnetic fields. The relation between oxygen deficiency and ferroic orders is yet to be well understood, for which the full potential of oxygen-stoichiometry engineered materials remain an open question. Here, we use hybrid-DFT to calculate different oxygen vacancy ($v_{o}$) states in STF with a variety of TM distributions. The resulting cations' magnetic states and alignments associated to the $v_{o}$ ground-states for $x=\{0.125,0.25\}$ are used within a Monte Carlo scope for collinear magnetism to simulate the spontaneous magnetization. Our model captures several experimental STF features i.e., display a maximum of the magnetization at intermediate number of vacancies, a monotonous quenching from $\sim{0.35}μ{_{B}}$ for small $δ$, and a slower decreasing of such saturation for larger number of vacancies. Moreover, our approach gives a further insight into the relations between defects stabilization and magnetization, vacancy density and the oxygen pressure required to maximize such ferroic order, and sets guidelines for future Machine Learning based computational synthesis of multiferroic oxides.

cond-mat.mtrl-sci↗

Ferroelectric response to interlayer shifting and rotations in trilayer hexagonal Boron Nitride

From monolayers composed of different atoms, we can build structures with spontaneous vertical polarization by conveniently stacking multiple layers. We have studied, using first-principles methods and based on modern polarization theory, a system composed of three layers of hexagonal Boron-Nitride(h-BN) in all possible stackings. We obtain for each of the configurations how charge transfers between the layers and how it impacts on the polarization of the system. In addition, we studied a system of three layers, one of them rotated, and we found that not only did the magnitude of the polarization increase comparing with the bilayer but also, depending on the initial stacking and the rotated layer, we can create a variety of mosaic-like polarization arrangements, which are composed of regions with either triangular or hexagonal symmetry.

cond-mat.mtrl-sci↗

Oxygen deficiency and migration mediated electric polarization in Fe,Co-substituted SrTiO$_{3-δ}$

We use density functional theory (DFT) calculations to show that oxygen vacancies ($v_\mathrm{O}$) and mobility induce noncentrosymmetric polar structures in SrTi$_{1-x-y}$Fe$_{x}$Co$_{y}$O$_{3-δ}$ ($x=y=0.125$) with $δ= \{0.125, 0.25\}$, enhance the saturation magnetization and give rise to large changes in the electric polarization $\vertΔP\vert$. We present an intuitive set of rules for SrTiFeCoO$_{3-δ}$ (STFC), which are based on the interplay between (Co/Fe)-$v_\mathrm{O}$ defects, magnetic cations coordination and topological vacancy disorder. STFC structures convey layered crystals with sheets of linear organized O$_{4,5,6}$-coordinated Fe-Co pairs, sandwiched with layers of O$_{5}$-coordinated Ti. Co,Fe-$v_\mathrm{O}$ defects are the source of the crystal distortions, cations off-centering and bending of the oxygen octahedra, which added to the charge redistribution mediated by $v_\mathrm{O}$, the cations electronegativity and valence states trigger an effective electric polarization. Oxygen migrations for $δ=0.125$ provides us with $\vertΔ\mathbf{P}\vert$ $>\sim10 μ$C/cm$^2$ due to a quantum-of-polarization differences between $δ=0.125$ structures. Increasing the deficiency to $δ=0.25$ yields $\vertΔ\mathbf{P}\vert$ whose O-migration resolved polarization for $δ=0.25$ is $>\sim3 μ$C/cm$^2$ in the worst case scenario. Magnetism is dominated by the Fe,Co spin states for $δ=0.125$ while there is a raid of Ti magnetic moments ($\sim1μ_{B}$) for $δ=0.25$. Magnetic and electric order parameters change for variations of $δ$ or oxygen migrations for a given deficiency. Our results capture characteristics observed in the end-members of the series SrTi(Co,Fe)O$_{3}$, and suggest the existence of a broader set of rules for oxygen deficient multiferroic oxides.

cond-mat.mtrl-sci↗

Oxygen-vacancy tuning of magnetism in SrTi$_{0.75}$Fe$_{0.125}$Co$_{0.125}$O$_{3-δ}$ perovskite

We use density functional theory to calculate the structure, band-gap and magnetic properties of oxygen-deficient SrTi$_{1-x-y}$Fe$_x$Co$_y$O$_{3-δ}$ with x = y = 0.125 and $δ$ = (0,0.125,0.25). The valence and the high or low spin-states of the Co and Fe ions, as well as the lattice distortion and the band-gap, depend on the oxygen deficiency, the locations of the vacancies, and on the direction of the Fe-Co axis. A charge redistribution that resembles a self-regulatory response lies behind the valence spin-state changes. Ferromagnetism dominates, and both the magnetization and the band gap are greatest at $δ$ = 0.125. This qualitatively mimics the previously reported magnetization measured for SrTiFeO$_{3-δ}$, which was maximum at an intermediate deposition pressure of oxygen.

cond-mat.mtrl-sci↗