arXiv subjects

Julianne I. Moses

Publications and source records attributed to Julianne I. Moses.

At least 19 recordsLinked to original sources

arXiv2026

Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

astro-ph.EP↗

arXiv2026

The Mid-Infrared Transmission Spectrum of the Temperate Sub-Neptune TOI-270 d

Observations of temperate sub-Neptunes with JWST have ushered in a new era for atmospheric characterization of small exoplanets. In particular, the MIRI instrument provides a unique opportunity to search for molecules that are not easily accessible in the near-infrared, as demonstrated by recent mid-infrared observations of K2-18 b. In this work, we present the first mid-infrared transmission spectrum of TOI-270 d observed using the JWST MIRI LRS (5-12 $μ$m) instrument. By leveraging archival MIRI LRS data, we establish a new empirical relation between the detector settling timescale and the flux, which helps accurately model the spectral light curves and improve the precision of the transmission spectrum. We find that there is notable evidence of molecular features in the MIRI transmission spectrum of TOI-270 d, favouring the presence of atmospheric absorption at $\ln B$ = 2.8-5.3 when comparing physically plausible atmospheric models with and without molecular line absorption. The data show excess absorption beyond what could be attributed to CH$_4$ and CO$_2$ detected previously, in line with recent near-infrared results. Through an agnostic search for 203 species, we identify several candidate trace molecules, most of which are complex molecules, evaluate their physical plausibility, and compare them against inferences from near-infrared observations. We also compare the MIRI spectrum of TOI-270 d to that of K2-18 b and find that random or systematic noise is unlikely to explain these observations. Future follow-up observations are necessary to definitively identify the additional absorbers beyond CH$_4$ and CO$_2$. These observations demonstrate the unique capability of JWST MIRI for atmospheric characterisation of temperate sub-Neptunes.

astro-ph.EP↗

arXiv2026

Transmission Spectrum of the Benchmark Temperate Exo-Neptune TOI-1231 b

The JWST is revolutionizing our understanding of the temperate sub-Neptune population through atmospheric spectroscopy. The nature of these planets remains debated, as their bulk properties are compatible with a range of interior scenarios, including mini-Neptunes, hycean worlds, and gas dwarfs, with different predicted atmospheric compositions. While theoretical studies have predicted compositional diagnostics for shallow- versus deep-atmosphere scenarios, there is a critical need for empirical constraints for a temperate planet that is a priori known to possess a deep H$_2$-rich atmosphere. The temperate exo-Neptune TOI-1231 b provides one such benchmark target. In this work, we present the JWST near-infrared (0.65--5.2 $μ$m) transmission spectrum of TOI-1231 b, observed with NIRISS single-object slitless spectroscopy and NIRSpec G395H, representing the first for a temperate exo-Neptune. The density of TOI-1231 b requires a thick H$_2$-rich atmosphere, making the planet a keystone reference case for testing mini-Neptune scenarios for sub-Neptunes. We report a strong detection of CH$_4$ ($\ln B = 54.5$-$69.6$) and moderate to strong evidence for CO$_2$ ($\ln B = 2.9$-$6.6$). We do not find significant evidence for any other prominent molecule, although we find high 95\% upper limits on the mixing ratios of NH$_3$ and CO, both of which are expected in deep H$_2$-rich atmospheres. We also do not find any significant evidence for sulfur-bearing species that have been inferred for some temperate sub-Neptunes. This composition is consistent with expectations for a temperate Neptune possessing a deep H$_2$-rich atmosphere with no distinct surface. We discuss the implications of our results for the characterization of temperate sub-Neptunes.

astro-ph.EP↗

arXiv2026

Detection of propadiene (CH$_2$CCH$_2$), propene (C$_3$H$_6$) and non-detection of propane (C$_3$H$_8$) in Jupiter's northern polar stratosphere

We report the first detection of stratospheric propadiene (CH$_2$CCH$_2$) and propene (C$_3$H$_6$) at Jupiter's mid-to-high northern latitudes using IRTF-TEXES measurements recorded on March 5-6, 2025. Using radiative transfer software to quantitatively test for the presence of propadiene and propene, we report a $>$12-$σ$ detection of propadiene and a $>$17-$σ$ detection of propene inside Jupiter's northern auroral region (henceforth 'NAR'), where the species are most concentrated. For example, at 62$^\circ$N inside Jupiter's NAR, we derive a 1-mbar propadiene abundance of 2.0 $\pm$ 0.2 ppbv, which is 40 $\pm$ 3 higher than abundances predicted by the Moses & Poppe (2017) photochemical model (henceforth 'MP17'), and significantly higher than the 1.2-ppbv upper limit abundance derived at 42$^\circ$N (the lowest latitude sampled by the observations). Similarly, we derive a 1-mbar propene abundance of 8.1 $\pm$ 0.5 ppbv at 62$^\circ$N inside Jupiter's NAR, which is 28 $\pm$ 2 higher than the MP17 predicted abundance and higher than the 6-ppbv 1-mbar upper limit abundance derived at 42$^\circ$N. The fact that propadiene and propene are most enriched inside Jupiter's NAR strongly suggests that perturbations to the chemistry by auroral-related heating and exogenous ions/electrons are responsible for their significant enrichment. Spectral features of propane (C$_3$H$_8$) were not detected at any of the locations sampled by the data: 3-$σ$ upper limits of 10 ppbv were derived at the 10-mbar level at 62$^\circ$N inside Jupiter's NAR. The non-detection of propane could, in part, be explained by the vertical sensitivity of its spectral features to deeper pressures, where there is negligible auroral-related heating. The results of this work advocate for development of ion-neutral chemistry models of Jupiter's polar stratosphere.

astro-ph.EP↗

arXiv2026

The compositions of the HR 8799 planets reflect accretion of both solids and metal-enriched gas

With four giant planets ($m\sim5-10~M_{\rm Jup}$, $T_\rm{eff}\sim900-1200$ K) orbiting between 15-70 au, HR 8799 provides an unparalleled testbed for studying giant planet formation and probing compositional trends across the protoplanetary disk. We present new JWST/NIRSpec IFU observations ($2.85-5.3~μ$m, $R\approx2700$) that now include the spectrum of HR 8799 b, and higher S/N spectra for HR 8799 c, d, and e compared to that in Ruffio & Xuan et al. We detect CO, CH$_4$, H$_2$O, H$_2$S, CO$_2$, and for planet b, NH$_3$. We combine the NIRSpec spectra with $1-5 μ$m photometry to perform atmospheric retrievals that account for disequilibrium chemistry and clouds, and allow C/H, O/H, N/H, and S/H to scale independently. While the four planets are similarly enriched in carbon and oxygen, with C/H and O/H between $3-5\times$ stellar, we observe a tentative trend of increasing S/H - a tracer of refractory solids - from $2-5 \times$ stellar with increasing orbital distance. From HR 8799 b's NH$_3$ abundance, we estimate $\rm N/H=21.2^{+16.2}_{-8.8}\times$ stellar, suggesting the outer planet accreted significant amounts of N-rich gas. Overall, the elemental abundance patterns we observe are consistent with a picture where planet b formed between the CO snowline and the more-distant N$_2$ snowline, while the inner planets accreted $3 \times$ stellar CO-enriched disk gas within the CO snowline. The excess volatile mass from pebble drift and evaporation implies an integrated pebble flux of $750 \pm 200~M_{\oplus}$. The increase in the planets' S/H with orbital distance implies more solid accretion further out, which is quantitatively compatible with expectations from both pebble and planetesimal accretion ($2 \times$ Minimum Mass Solar Nebula) paradigms.

astro-ph.EP↗

arXiv2025

A JWST Transmission Spectrum of the Temperate Sub-Neptune TOI-732 c

In recent years, JWST has facilitated detections of carbon-bearing molecules in the atmospheres of temperate sub-Neptunes orbiting M dwarfs, ushering in a new era in the characterization of this intriguing planetary regime. We report the transmission spectrum of the temperate sub-Neptune TOI-732 c, observed with JWST NIRISS, NIRSpec G395H and MIRI LRS between 0.9-12 $μ$m. The observations provide evidence for methane (CH$_4$) in a H$_2$-rich atmosphere, at a volume mixing ratio of $\sim$1\%, and non-detection of NH$_3$ and HCN, along with nominal constraints on other prominent molecules H$_2$O, CO and CO$_2$, which are typically expected in H$_2$-rich atmospheres. We conduct a comprehensive survey of 250 chemical species and find moderate to strong evidence (up to $\ln B\sim 5.9$, $3.9σ$) for additional absorption due to one or more complex molecules including higher-order hydrocarbons and/or sulfur-bearing molecules. The spectral features are strongly degenerate among these molecules and with methane, which we find at $\ln B=3.2-8.8$ (up to $3.0-4.6$$σ$) significance. Two complex molecules are preferred with at least moderate evidence ($\ln B \gtrsim 2.5$) in both the near- and mid-infrared, while several others show such evidence in at least one of the two wavelength ranges. The preferred molecules are found in trace quantities on Earth, with no significant sources identified in other planetary atmospheres, requiring future work to assess their physical plausibility in this planet. Future observations are required to resolve the degeneracies and place more robust constraints on these species. We highlight the need for further theoretical and experimental work to robustly characterize the atmospheric and internal composition of TOI-732 c and similar sub-Neptunes.

astro-ph.EP↗

arXiv2025

The impact of organic hazes and graphite on the observation of CO2-rich sub-Neptune atmospheres

Many sub-Neptune and super-Earth exoplanets are expected to develop metal-enriched atmospheres due to atmospheric loss processes such as photoevaporation or core-powered mass loss. Thermochemical equilibrium calculations predict that at high metallicity and a temperature range of 300-700 K, CO2 becomes the dominant carbon species, and graphite may be the thermodynamically favored condensate under low-pressure conditions. Building on prior laboratory findings that such environments yield organic haze rather than graphite, we measured the transmittance spectra of organic haze analogues and graphite samples, and computed their optical constants across the measured wavelength range from 0.4 to 25 μm. The organic haze exhibits strong vibrational absorption bands, notably at 3.0, 4.5, and 6.0 μm, while graphite shows featureless broadband absorption. The derived optical constants of haze and graphite provide the first dataset for organic haze analogues formed in CO2-rich atmospheres and offer improved applicability over prior graphite data derived from bulk reflectance or ellipsometry. We implemented these optical constants into the Virga and PICASO cloud and radiative transfer models to simulate transit spectra for GJ 1214b. The synthetic spectra with organic hazes reproduce the muted spectral features in the NIR observed by Hubble and general trends observed by JWST for GJ 1214b, while graphite models yield flat spectra across the observed wavelengths. This suggests haze features may serve as observational markers of carbon-rich atmospheres, whereas graphite's opacity could lead to radius overestimation, offering a possible explanation for super-puff exoplanets. Our work supplies essential optical to infrared data for interpreting observations of CO2-rich exoplanet atmospheres.

astro-ph.EP↗

arXiv2025

Formation of organic hazes in CO$_2$-rich sub-Neptune atmospheres within the graphite-stability regime

Super-Earths and sub-Neptunes are the most common exoplanets, with a "radius valley" suggesting that super-Earths may form by shedding sub-Neptunes' gaseous envelopes. Exoplanets that lie closer to the super-Earth side of the valley are more likely to have lost a significant fraction of their original H/He envelopes and become enriched in heavier elements with CO$_2$ gaining in abundance. It remains unclear which types of haze would form in such atmospheres, potentially significantly affecting spectroscopic observations. To investigate this, we performed laboratory simulations of two CO$_2$-rich gas mixtures (with 2000 times solar metallicity at 300 K and 500 K). We found that under plasma irradiation, organic hazes were produced at both temperatures with higher haze production rate at 300 K probably because condensation occurs more readily at lower temperature. Gas-phase analysis demonstrates the formation of various hydrocarbons, oxygen- and nitrogen-containing species, including reactive gas precursors like C$_2$H$_4$, CH$_2$O, and HCN, for haze formation. The compositional analysis of the haze particles reveals various functional groups and molecular formulas in both samples. The 500 K haze sample has larger average molecular sizes, higher degree of unsaturation with more double or triple bonds presence, and higher nitrogen content incorporated as N-H, C=N bonds, indicating different haze formation pathways. These findings not only improve the haze formation theories in CO$_2$-rich exoplanet atmospheres but also offer important implications for the interpretation of future observational data.

astro-ph.EP↗

arXiv2025

New Constraints on DMS and DMDS in the Atmosphere of K2-18 b from JWST MIRI

The sub-Neptune frontier has opened a new window into the rich diversity of planetary environments beyond the solar system. The possibility of hycean worlds, with planet-wide oceans and H$_2$-rich atmospheres, significantly expands and accelerates the search for habitable environments elsewhere. Recent JWST transmission spectroscopy of the candidate hycean world K2-18 b in the near-infrared led to the first detections of carbon-bearing molecules CH$_4$ and CO$_2$ in its atmosphere, with a composition consistent with predictions for hycean conditions. The observations also provided a tentative hint of dimethyl sulfide (DMS), a possible biosignature gas, but the inference was of low statistical significance. We report a mid-infrared transmission spectrum of K2-18 b obtained using the JWST MIRI LRS instrument in the ~6-12 $μ$m range. The spectrum shows distinct features and is inconsistent with a featureless spectrum at 3.4-$σ$ significance compared to our canonical model. We find that the spectrum cannot be explained by most molecules predicted for K2-18 b with the exception of DMS and dimethyl disulfide (DMDS), also a potential biosignature gas. We report new independent evidence for DMS and/or DMDS in the atmosphere at 3-$σ$ significance, with high abundance ($\gtrsim$10 ppmv) of at least one of the two molecules. More observations are needed to increase the robustness of the findings and resolve the degeneracy between DMS and DMDS. The results also highlight the need for additional experimental and theoretical work to determine accurate cross sections of important biosignature gases and identify potential abiotic sources. We discuss the implications of the present findings for the possibility of biological activity on K2-18 b.

astro-ph.EP↗

arXiv2024

Volatile-rich Sub-Neptunes as Hydrothermal Worlds: The Case of K2-18 b

Temperate exoplanets between the sizes of Earth and Neptune, known as "sub-Neptunes", have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH4, ~1% CO2, and a non-detection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b-like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH4/CO2 ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO2 ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step towards understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better constrained CO and NH$_3$ mixing ratios could further help distinguish between possible interior compositions of K2-18 b.

astro-ph.EP↗

arXiv2024

A photochemical PHO network for hydrogen-dominated exoplanet atmospheres

Due to the detection of phosphine PH3 in the Solar System gas giants Jupiter and Saturn, PH3 has long been suggested to be detectable in exosolar substellar atmospheres too. However, to date, a direct detection of phosphine has proven to be elusive in exoplanet atmosphere surveys. We construct an updated phosphorus-hydrogen-oxygen (PHO) photochemical network suitable for simulation of gas giant hydrogen-dominated atmospheres. Using this network, we examine PHO photochemistry in hot Jupiter and warm Neptune exoplanet atmospheres at Solar and enriched metallicities. Our results show for HD 189733b-like hot Jupiters that HOPO, PO and P2 are typically the dominant P carriers at pressures important for transit and emission spectra, rather than PH3. For GJ1214b-like warm Neptune atmospheres our results suggest that at Solar metallicity PH3 is dominant in the absence of photochemistry, but is generally not in high abundance for all other chemical environments. At 10 and 100 times Solar, small oxygenated phosphorus molecules such as HOPO and PO dominate for both thermochemical and photochemical simulations. The network is able to reproduce well the observed PH3 abundances on Jupiter and Saturn. Despite progress in improving the accuracy of the PHO network, large portions of the reaction rate data remain with approximate, uncertain or missing values, which could change the conclusions of the current study significantly. Improving understanding of the kinetics of phosphorus-bearing chemical reactions will be a key undertaking for astronomers aiming to detect phosphine and other phosphorus species in both rocky and gaseous exoplanetary atmospheres in the near future.

astro-ph.EP↗

arXiv2024

Towards a self-consistent evaluation of gas dwarf scenarios for temperate sub-Neptunes

The recent JWST detections of carbon-bearing molecules in a habitable-zone sub-Neptune have opened a new era in the study of low-mass exoplanets. The sub-Neptune regime spans a wide diversity of planetary interiors and atmospheres not witnessed in the solar system, including mini-Neptunes, super-Earths, and water worlds. Recent works have investigated the possibility of gas dwarfs, with rocky interiors and thick H$_2$-rich atmospheres, to explain aspects of the sub-Neptune population, including the radius valley. Interactions between the H$_2$-rich envelope and a potential magma ocean may lead to observable atmospheric signatures. We report a coupled interior-atmosphere modelling framework for gas dwarfs to investigate the plausibility of magma oceans on such planets and their observable diagnostics. We find that the surface-atmosphere interactions and atmospheric composition are sensitive to a wide range of parameters, including the atmospheric and internal structure, mineral composition, volatile solubility and atmospheric chemistry. While magma oceans are typically associated with high-temperature rocky planets, we assess if such conditions may be admissible and observable for temperate sub-Neptunes. We find that a holistic modelling approach is required for this purpose and to avoid unphysical model solutions. We find using our model framework and considering the habitable-zone sub-Neptune K2-18 b as a case study that its observed atmospheric composition is incompatible with a magma ocean scenario. We identify key atmospheric molecular and elemental diagnostics, including the abundances of CO$_2$, CO, NH$_3$ and, potentially, S-bearing species. Our study also underscores the need for fundamental material properties for accurate modelling of such planets.

astro-ph.EP↗

arXiv2024

Probing Cold-to-Temperate Exoplanetary Atmospheres: The Role of Water Condensation on Surface Identification with JWST

Understanding the surface temperature and interior structure of cold-to-temperate sub-Neptunes is critical for assessing their habitability, yet direct observations are challenging. In this study, we investigate the impact of water condensation on the atmospheric compositions of sub-Neptunes, focusing on the implications for JWST spectroscopic observations. By modeling the atmospheric photochemistry of two canonical sub-Neptunes, K2-18 b and LHS 1140 b, both with and without water condensation and with and without thick atmospheres, we demonstrate that water condensation can significantly affect the predicted atmospheric compositions. This effect is driven by oxygen depletion from the condensation of water vapor and primarily manifests as an increase in the C/O ratio within the photochemically active regions of the atmosphere. This change in composition particularly affects planets with thin H2-dominated atmospheres, leading to a transition in dominant nitrogen and carbon carriers from N2 and oxygen-rich species like CO/CO2 towards heavier hydrocarbons and nitriles. While our models do not fully account for the loss mechanisms of these higher-order species, such molecules can go on to form more refractory molecules or hazes. Planets with thin H2-rich atmospheres undergoing significant water condensation are thus likely to exhibit very hazy atmospheres. The relatively flat JWST spectra observed for LHS 1140 b could be consistent with such a scenario, suggesting a shallow surface with extensive water condensation or a high atmospheric C/O ratio. Conversely, the JWST observations of K2-18 b are better aligned with a volatile-rich mini-Neptune with a thick atmosphere.

astro-ph.EP↗

arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

astro-ph.EP↗

arXiv2024

Hydrogen sulfide and metal-enriched atmosphere for a Jupiter-mass exoplanet

As the closest transiting hot Jupiter to Earth, HD 189733b has been the benchmark planet for atmospheric characterization. It has also been the anchor point for much of our theoretical understanding of exoplanet atmospheres from composition, chemistry, aerosols to atmospheric dynamics, escape, and modeling techniques. Prior studies of HD 189733b have detected carbon and oxygen-bearing molecules H2O and CO in the atmosphere. The presence of CO2 and CH4 has been claimed but later disputed. The inferred metallicity based on these measurements, a key parameter in tracing planet formation locations, varies from depletion to enhancement, hindered by limited wavelength coverage and precision of the observations. Here we report detections of H2O (13.4 sigma), CO2 (11.2 sigma), CO (5 sigma), and H2S (4.5 sigma) in the transmission spectrum (2.4-5 micron) of HD 189733b. With an equilibrium temperature of ~1200K, H2O, CO, and H2S are the main reservoirs for oxygen, carbon, and sulfur. Based on the measured abundances of these three major volatile elements, we infer an atmospheric metallicity of 3-5 times stellar. The upper limit on the methane abundance at 5 sigma is 0.1 ppm which indicates a low carbon-to-oxygen ratio (<0.2), suggesting formation through the accretion of water-rich icy planetesimals. The low oxygen-to-sulfur and carbon-to-sulfur ratios also support the planetesimal accretion formation pathway.

astro-ph.EP↗

arXiv2024

A pole-to-pole map of hydrocarbons in Saturn's upper stratosphere and mesosphere

We analyze data from the final two years of the Cassini mission to retrieve the distributions of methane, ethane, acetylene, ethylene, and benzene in Saturn's upper stratosphere and mesosphere from stellar occultations observed by the Ultraviolet Imaging Spectrograph (UVIS), spanning pole-to-pole. These observations represent the first 2D snapshot with latitude and depth of Saturn's photochemical production region around northern summer solstice. Using UVIS occultations and CIRS limb scans, we derive temperature-pressure profiles and atmospheric structure models for each occultation latitude. W detect a strong meridional trend in the homopause pressure level, which ranges from approximately 0.05 microbar around the subsolar point to around 5 microbar at the poles, implying much weaker mixing at the poles than near the subsolar point. This trend could be explained by upwelling at low latitudes and downwelling at high latitudes, requiring vertical wind speeds under 2 cm/s. Photochemical product distributions follow this trend and also show a clear seasonal trend at pressures between 0.01 and 10 microbar, with higher abundances in the summer hemisphere. We compare the observed distributions with results from 1D seasonal photochemical models, with and without ion chemistry, to explore the impact of ion chemistry. We find that ion chemistry is particularly important for matching the observed C6H6 distribution, while its impact on other species is less pronounced. The best agreement between the models and the observations is obtained in the summer hemisphere. Disagreements between model and observations in the winter hemisphere and auroral region may be due to the lack of transport by global circulation and auroral electron and ion precipitation in our photochemical models. Finally, we compare C2H2 profiles from UVIS occultations with CIRS limb scans, finding good agreement where they overlap.

astro-ph.EP↗

arXiv2024

Day-night transport induced chemistry and clouds on WASP-39b I: Gas-phase composition

JWST has recently detected the first robust photochemical product on an exoplanet: sulfur dioxide (SO$_2$) on WASP-39b (Rustamkulov et al. 2023; Alderson et al. 2023; Tsai et al. 2023b). The data from the NIRISS instrument also reveal signs of partial coverage of clouds (Feinstein et al. 2023). Most of the previous studies have focused on interpreting spectral data with 1D models. To explore how the chemical species and cloud particles are altered by global circulation, we applied a 2D photochemical model and a 2D microphysical cloud model separately to post-process the thermal and dynamical structures simulated by a 3D general circulation model (GCM) of WASP-39b. We found that SO$_2$ produced by photochemistry on the dayside can be transported to the nightside owing to the efficient replenishment of horizontal transport. The morning-evening limb differences in methane (CH$_4$) abundances predicted by the 1D models disappeared after horizontal transport is included. Similarly, the inclusion of horizontal transport also reduced the limb differences in SO$_2$. Our modeling results suggest that the fast zonal wind results in minimal or negligible limb asymmetry in composition. Based on the synthetic spectra generated by our 2D atmosphere simulations, we propose that observing SO$_2$ absorption in the emission spectra of WASP-39b at different phases may offer opportunities to probe the horizontal quenching process of photochemical products. We will focus on the gas-phase chemistry in this paper and leave the results regarding clouds in the subsequent paper as part of the series.

astro-ph.EP↗

arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

astro-ph.EP↗