arXiv subjects

Juliette Zito

Publications and source records attributed to Juliette Zito.

4 recordsLinked to original sources

arXiv2025

Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and their Interplay with Tertiary Amines

Current syntheses of CsPbBr3 halide perovskite nanocrystals (NCs) rely on over-stoichiometric amounts of Pb2+ precursors, resulting in unreacted lead ions at the end of the process. In our synthesis scheme of CsPbBr3 NCs we replaced excess Pb2+ with different exogenous metal cations (M) and investigated their effect on the synthesis products. These cations can be divided into two groups: group 1 delivers monodisperse CsPbBr3 cubes capped with oleate species (as for the case when Pb2+ is used in excess) and with photoluminescence quantum yield (PLQY) as high as 90% with some cations (for example with M= In3+); group 2 yields irregularly shaped CsPbBr3 NCs with broad size distributions. In both cases, the addition of a tertiary ammonium cation (didodecylmethyl ammonium, DDMA+) during the synthesis, after the nucleation of the NCs, reshapes the NCs to monodisperse truncated cubes. Such NCs feature a mixed oleate/DDMA+ surface termination with PLQY values up to 90%. For group 1 cations, this happens only if the ammonium cation is directly added as a salt (DDMA-Br) while for group 2 cations this happens even if the corresponding tertiary amine (DDMA) is added, instead of DDMA-Br. This is attributed to the fact that only group 2 cations can facilitate the protonation of DDMA by the excess oleic acid present in the reaction environment. In all cases studied, the incorporation of M cations is marginal and the reshaping of the NCs is only transient: if the reactions are run for a long time the truncated cubes evolve to cubes.

cond-mat.mtrl-sci↗

arXiv2025

Improving the Stability of Colloidal CsPbBr3 Nanocrystals with an Alkylphosphonium Bromide as Surface Ligand Pair

In this study, we synthesised a phosphonium-based ligand, trimethyl(tetradecyl)phosphonium bromide (TTP-Br), and employed it in the post-synthesis surface treatment of Cs-oleate-capped CsPbBr3 NCs. The photoluminescence quantum yield (PLQY) of the NCs increased from 60% to more than 90%, as a consequence of replacing Cs-oleate with TTP-Br ligand pairs. Density functional theory calculations revealed that TTP+ ions bind to the NC surface by occupying Cs+ surface sites and orienting one of their P-CH3 bonds perpendicular to the surface, akin to quaternary ammonium passivation. Importantly, TTP-Br-capped NCs exhibited higher stability in air compared to didodecyldimethylammonium bromide-capped CsPbBr3 NCs (which is considered a benchmark system), retaining 90% of their PLQY after six weeks of air exposure. Light-emitting diodes fabricated with TTP-Br-capped NCs achieved a maximum external quantum efficiency of 17.2 %, demonstrating the potential of phosphonium-based molecules as surface ligands for CsPbBr3 NCs in optoelectronic applications.

cond-mat.mtrl-sci↗

arXiv2025

Nanocrystals Heterostructures based on Halide Perovskites and Metal Sulfides

We report the synthesis of nanocrystal heterostructures composed of CsPbCl3 and PbS domains sharing an epitaxial interface. We were able to promote the growth of a PbS domain (in competition with the more commonly observed Pb4S3Cl2 one) on top of the CsPbCl3 domain by employing Mn2$^+$ ions, the latter acting most likely as scavengers of Cl$^-$ ions. Complete suppression of the Pb4S3Cl2 domain growth was then achieved by additionally selecting an appropriate sulfur source (bis(trimethylsilyl)sulfide, which also acted as scavenger of Cl$^-$ ions), and reaction temperature. In the heterostructures, emission from the perovskite domain was quenched, while emission from the PbS domain was observed, pointing to a type-I band alignment, as confirmed by calculations. These heterostructures in turn could be exploited to prepare second-generation heterostructures through selective ion exchange on the individual domains (halide ion exchange on CsPbCl3, cation exchange on PbS). We demonstrate the cases of Cl$^-$ to Br$^-$ and Pb2$^+$ to Cu$^+$ exchanges, which deliver CsPbBr3@PbS and CsPbCl3@Cu2-xS epitaxial heterostructures, respectively.

cond-mat.mtrl-sci↗

arXiv2025

Halide Perovskite-Chalcohalide Nanocrystal Heterostructures as a Platform for the Synthesis and Investigation of the CsPbCl3-CsPbI3 Epitaxial Interface

Halide exchange in lead-based halide perovskites has been studied extensively. While mixed Cl-Br or Br-I alloy compositions can be formed with no miscibility gaps, this is precluded for mixed Cl-I compositions, due to the large difference in Cl and I ionic radii. Here, we exploit perovskite-chalcohalide CsPbCl3-Pb4S3Cl2 heterostructures to study the Cl-I exchange and isolate new types of intermediate structures. The epitaxial interface between the Pb4S3Cl2 chalcohalide and the CsPbCl3 perovskite domain significantly influences the intermediate stages of halide exchange in the perovskite domain, leading to coexisting CsPbCl3 and CsPbI3 domains, thereby delivering segmented CsPbI3-CsPbCl3-Pb4S3Cl2 energetically favorable heterostructures, with partial iodide alloying of the CsPbCl3 domain and at the perovskite-chalcohalide interface. The I:CsPbCl3 domain between CsPbI3 and Pb4S3Cl2 enables a gradual lattice expansion across the heterostructure. This design accommodates interfacial strain, with a 5.6% mismatch at the CsPbCl3-CsPbI3 interface and a 3.4% mismatch at the perovskite-chalcohalide interface. Full halide exchange leads to CsPbI3-Pb4S3Cl2 heterostructures. Both in intermediate and fully exchanged heterostructures, the CsPbI3 domain is emissive. In the intermediate structures, the band alignment between the two perovskite domains is type-I, with carriers photogenerated in the CsPbCl3 domain quickly transferring to the CsPbI3 domain, where they can recombine radiatively.

cond-mat.mtrl-sci↗