arXiv subjects
Publications and source records attributed to Jun Chul Park.
In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of thermodynamic relation in non-equilibrium thermodynamic processes.
It is a well established result that, in classical dynamical systems with sufficient time-scale separation, the fast chaotic degrees of freedom are well modeled by (Gaussian) white noise. In this paper, we present the stochastic dynamical description for intermediate time-scale motions with insufficient time-scale separation from the slow dynamical system. First, we analyze how the fast deterministic dynamics can be viewed as stochastic dynamics under experimental observation by intrinsic errors of measurement. Then, we present how the stochastic dynamical description should be modified if intermediate time-scale motions exist: the time correlation of the noise ξis modified to <ξ(t)ξ(t')> = C(x,p)δ(t-t'), where C(x,p) is a smooth function of the slow coordinate (x,p), and generally the cumulants of ξexcept its average vary as a smooth function of the slow coordinates (x,p). The analysis given in this work actually shows that, regardless of the sufficiency of time-scale separation, any complex (chaotic and ergodic) dynamical system can be well described using Markov process, if we perfectly construct the deterministic part of (extended) stochastic dynamics.