arXiv subjects

Jun Gouchi

Publications and source records attributed to Jun Gouchi.

16 recordsLinked to original sources

arXiv2026

Nearly Isotropic Quantum-Critical Transport in Single-Crystal CeNiC2

Pressure-induced superconductivity and $T$-linear resistivity have been reported in polycrystalline CeNiC$_2$, but orientational averaging has left the directional character of the critical scattering unresolved. We report pressure-dependent resistivity of high-quality single crystals for current along each crystallographic axis. These crystals have substantially lower residual resistivity and a slightly higher maximum onset $T_c$ than the polycrystalline sample, placing superconductivity in a cleaner transport regime. Near $P_c \approx 9.5-10$ GPa, the normal-state resistivity becomes nearly $T$-linear along every axis, the fitted residual resistivity is strongly enhanced, and superconductivity forms a narrow dome. For $I \parallel b$, the $T$-linear normal state remains nearly unchanged in magnetic fields up to 9 T applied along $a$ and $c$; the upper critical field is large and only moderately anisotropic. The common evolution along all three axes establishes a nearly isotropic quantum-critical transport regime, inconsistent with a simple low-dimensional spin-fluctuation picture and implicates valence fluctuations as the leading source of critical scattering associated with the superconducting dome.

cond-mat.supr-con↗

arXiv2024

Pressure-induced nearly perfect rectangular lattice and superconductivity in an organic molecular crystal (DMET-TTF)$_2$AuBr$_2$

External pressure and associated changes in lattice structures are key to realizing exotic quantum phases such as high-$T_{\rm c}$ superconductivity. While applying external pressure is a standard method to induce novel lattice structures, its impact on organic molecular crystals has been less explored. Here we report a unique structural phase transition in (DMET-TTF)$_2$AuBr$_2$ under pressure. By combining advanced high-pressure techniques and $ab$ $initio$ calculations, we elucidate that (DMET-TTF)$_2$AuBr$_2$ undergoes a transition from a quasi-one-dimensional lattice to a nearly perfect rectangular lattice at 0.9 GPa. This transition leads to the realization of an antiferromagnetic Mott insulator with $T_{\rm N}=66$ K, the highest $T_{\rm N}$ in low-dimensional molecular crystal solids to date. Upon increasing the pressure, the antiferromagnetic ordering is suppressed, and a superconducting phase with $T_{\rm c}=4.8$ K emerges around 6 GPa. Our study reveals the significant impact of external pressure on lattice structures of organic molecular crystals and highlights the intricate relationship between geometrical frustration and superconductivity. Our findings also pave the way for realizing functional organic molecular crystals through changes in lattice structures by pressure.

cond-mat.str-el↗

arXiv2023

Quantum Criticality in YbCu4Ni

We report on the quantum criticality of YbCu$_4$Ni as revealed by our combined micro- and macro-measurements. We determine the crystal structure of YbCu$_4$Ni with site mixing by neutron diffraction measurements, which suggests the possible presence of Kondo disorder. However, decreasing the local spin susceptibility distribution and the development of spin fluctuations below 10 K at ambient pressure by muon spin rotation and relaxation measurements suggests that YbCu4Ni exhibits quantum criticality. Therefore, our experimental results indicate that YbCu4Ni is a new material that exhibits quantum criticality under a zero magnetic field and ambient pressure.

cond-mat.str-el↗

arXiv2023

Investigation of the atomic coordinates of CeNiC$_2$ under pressure: switching of the Ce-Ce first nearest neighbor direction

When pressurized, the heavy fermion compound CeNiC$_2$ reveals a rich electronic phase diagram and shows unconventional superconductivity with a transition temperature $T_c$ $\sim$ 3.7 K, the highest among Ce-based heavy fermion superconductors [S. Katano et al., Phys. Rev. B. 99, 100501(R) (2019)]. Understanding of this appearance of superconductivity in the vicinity of magnetic quantum critical point is still lacking. Given that physical properties of CeNiC$_2$ are sensitive to subtle changes in the interatomic distances, information on atomic coordinates may offer essential insights into the local lattice arrangements, thus the mechanisms behind the exotic phases and phase transitions. However, extraction of precise information on the atomic coordinates under pressure remains a challenge. To find a correlation between the local lattice environments and exotic physical properties in CeNiC$_2$, we investigate its crystal structure from ambient pressure to 18.6 GPa via single crystal X-ray diffraction. The pressure dependence of lattice parameters reveals anisotropic linear compressibility, $|\kappa|$, following the relationship $|\kappa_{a}|$ (3.70$\times$10$^{-3}$ GPa$^{-1}$) $>$ $|\kappa_{c}|$ (1.97$\times$10$^{-3}$ GPa$^{-1}$) $>$ $|\kappa_{b}|$ (1.39$\times$10$^{-3}$ GPa$^{-1}$), and a large bulk modulus, B$_0$ $\sim$ 134 GPa. Although the atomic coordinates between Ce and Ni remain unchanged under applied pressure, direction of the first nearest and the second nearest neighbors between both the Ce-Ce and Ni-Ni atoms switch $\sim$ 7 GPa. Notably, this is the same pressure that antiferromagnetic ordering temperature reaches maximum in the pressure temperature phase diagram of CeNiC$_2$. Our results suggest that the direction of nearest neighbors interchange might play a key role in the suppression of magnetic order and the enhancement of Kondo effect.

cond-mat.str-el↗

arXiv2022

Pressure-induced structural phase transition and new superconducting phase in UTe2

We report on the crystal structure and electronic properties of the heavy fermion superconductor UTe2 at high pressure up to 11 GPa, as investigated by X-ray diffraction and electrical resistivity experiments. The X-ray diffraction measurements under high pressure using a synchrotron light source reveal anisotropic linear compressibility of the unit cell up to 3.5 GPa, while a pressure-induced structural phase transition is observed above 3.5-4GPa at room temperature, where the body-centered orthorhombic crystal structure with the space group Immm changes into a body-centered tetragonal structure with the space group I4/mmm. The molar volume drops abruptly at the critical pressure, while the distance between the first-nearest neighbor of U atoms increases, implying a switch from the heavy electronic states to the weakly correlated electronic states. Surprisingly, a new superconducting phase at pressures higher than 7 GPa was detected at Tsc above 2K with a relatively low upper-critical field, Hc2(0). The resistivity above 3.5GPa, thus, in the high-pressure tetragonal phase, shows a large drop below 230 K, which may also be related to a considerable change from the heavy electronic states to the weakly correlated electronic states.

cond-mat.str-el↗

arXiv2022

Evidence for pressure induced unconventional quantum criticality in the coupled spin ladder antiferromagnet C$_9$H$_{18}$N$_2$CuBr$_4$

Quantum phase transitions in quantum matter occur at zero temperature between distinct ground states by tuning a nonthermal control parameter. Often, they can be accurately described within the Landau theory of phase transitions, similarly to conventional thermal phase transitions. However, this picture can break down under certain circumstances. Here, we present a comprehensive study of the effect of hydrostatic pressure on the magnetic structure and spin dynamics of the spin-1/2 ladder compound C$_9$H$_{18}$N$_2$CuBr$_4$. Single-crystal heat capacity and neutron diffraction measurements reveal that the N$\rm \acute{e}$el-ordered phase breaks down beyond a critical pressure of $P_{\rm c}$$\sim$1.0 GPa through a continuous quantum phase transition. Estimates of the critical exponents suggest that this transition may fall outside the traditional Landau paradigm. The inelastic neutron scattering spectra at 1.3 GPa are characterized by two well-separated gapped modes, including one continuum-like and another resolution-limited excitation in distinct scattering channels, which further indicates an exotic quantum-disordered phase above $P_{\rm c}$.

cond-mat.str-el↗

arXiv2022

Superconducting and structural properties of non-centrosymmetric Re6Hf superconductor under high pressure

We report the effect of high pressure on the superconducting, vortex pinning, and structural properties of a polycrystalline non-centrosymmetric superconductor Re6Hf. The superconducting transition temperature, Tc, reveals a modest decrease as pressure P increases with a slope -0.046 K/GPa (-0.065 K/GPa) estimated from resistivity measurements up to 8 GPa (magnetization measurement ~ 1.1 GPa). Structural analysis up to ~18 GPa reveals monotonic decreases of lattice constant without undergoing any structural transition and a high value of bulk modulus B0= 333.63 GPa, indicating the stability of the structure. Furthermore, the upper critical field and lower critical field at absolute temperature (Hc2(0) & Hc1(0)) decreases slightly from the ambient pressure value as pressure increases up to 2.5 GPa. In addition, up to P ~ 2.5 GPa using thermally activated flux flow of vortices revealed a double linearity field dependence of activation energy of vortices, confirming the coexistence of single and collective pinning vortex states. Moreover, analysis of critical current density using the collective pinning theory showed the transformation of δTc to δl pinning as pressure increases, possibly due to migration of grain boundaries. Besides, the band structure calculations using density functional theory show that density of states decreases modestly with pressure, which may be a possible reason for such a small decrease in Tc by pressure.

cond-mat.supr-con↗

arXiv2022

Structural Phase Transition and Possible Valence Instability of Ce$-4f$ Electron Induced by Pressure in CeCoSi

X-ray powder diffraction and electrical resistivity measurements were performed on the tetragonal compound CeCoSi under pressure to elucidate the phase boundary of the pressure-induced structural transition and the change in the 4$f$ electronic state. The temperature-pressure phase diagram has been determined from the shift of the Bragg peaks and from the anomaly in the resistivity. The critical pressure, $P_{\rm s}$ $\sim$ 4.9 GPa at 300 K, decreases to $P_{\rm s}$ $\sim$ 3.6 GPa at 10 K. The decrease of $P_{\rm s}$ is due not only to the decrease in volume of the unit cell but also to an anisotropic shrinkage by cooling. When crossing the boundary to the high-pressure phase, the resistivity shows a significant drop to exhibit a metallic temperature dependence. The results of this study strongly suggest that the structural phase transition can be ascribed to valence instability of Ce-$4f$ electron.

cond-mat.str-el↗

arXiv2021

Nearly room temperature ferromagnetism in pressure-induced correlated metallic state of van der Waals insulator CrGeTe$_3$

A complex interplay of different energy scales involving Coulomb repulsion, spin-orbit coupling and Hund's coupling energy in two-dimensional (2D) van der Waals (vdW) material produces novel emerging physical state. For instance, ferromagnetism in vdW charge transfer insulator CrGeTe$_3$, that provides a promising platform to simultaneously manipulate the magnetic and electrical properties for potential device implementation using few layers thick materials. Here, we show a continuous tuning of magnetic and electrical properties of CrGeTe$_3$ single crystal using pressure. With application of pressure, CrGeTe$_3$ transforms from a FM insulator with Curie temperature, $T_{\rm{C}} \sim $ 66 K at ambient condition to a correlated 2D Fermi metal with $T_{\rm{C}}$ exceeding $\sim$ 250 K. Notably, absence of an accompanying structural distortion across the insulator-metal transition (IMT) suggests that the pressure induced modification of electronic ground states are driven by electronic correlation furnishing a rare example of bandwidth-controlled IMT in a vdW material.

cond-mat.str-el↗

arXiv2021

Pressure induced multicriticality and electronic instability in quasi-kagome ferromagnet URhSn

We report an unconventional class of pressure induced quantum phase transition, possessing two bicritical points at 6.25 GPa in URhSn. This unique transformation accompanies a Fermi surface reconstruction, demarcating competing ordered phases suitably described with localized and itinerant description of the magnetic $5f$-electrons. Ferromagnetic fluctuations over a wide range of temperatures and pressures in the pressure-induced low temperature phase are evidenced by a robust $T^{5/3}$ temperature dependence of resistivity up to 11 GPa, which is a characteristic of elusive marginal Fermi-liquid state.

cond-mat.str-el↗

arXiv2020

Magneto-transport properties of tellurium under extreme conditions

This study investigates the transport properties of a chiral elemental semiconductor tellurium (Te) under magnetic fields and pressure. Application of hydrostatic pressure reduces the resistivity of Te, while its temperature dependence remains semiconducting up to 4 GPa, contrary to recent theoretical and experimental studies. Application of higher pressure causes structural as well as semiconductor--metal transitions. The resulting metallic phase above 4 GPa exhibits superconductivity at 2 K along with a noticeable linear magnetoresistance effect. On the other hand, at ambient pressure, we identified metallic surface states on the as-cleaved (10$\bar{1}$0) surfaces of Te. The nature of these metallic surface states has been systematically studied by analyzing quantum oscillations observed in high magnetic fields. We clarify that a well-defined metallic surface state exists not only on chemically etched samples that were previously reported, but also on as-cleaved ones.

cond-mat.str-el↗

arXiv2020

New diversity form of ice polymorphism: Discovery of second hydrogen ordered phase of ice VI

More than 20 crystalline and amorphous phases have been reported for ice so far. This extraordinary polymorphism of ice arises from the geometric flexibility of hydrogen bonds and hydrogen ordering, and makes ice a unique presence with its universality in the wide fields of material and earth and planetary science. A prominent unsolved question concerning the diversity is whether a hydrogen-disordered phase of ice transforms into only one hydrogen-ordered phase, as inferred from the current phase diagram of ice, although its possible hydrogen configurations have close energies. Recent experiments on a high-pressure hydrogen-disordered phase, ice VI, revealed an unknown hydrogen-ordered form ($β$-XV) besides the known ordered phase, ice XV, which would be a counterexample of the question. However, due to lack of experimental evidence, it has not been clarified whether $β$-XV is a distinct crystalline phase. Herein we report a second hydrogen-ordered phase for ice VI, ice XIX, unambiguously demonstrated by neutron diffraction measurements. The phase boundary between ice VI and ice XIX shows that ice VI contracts upon the hydrogen ordering, which thermodynamically stabilizes ice XIX in higher-pressure region than ice XV because of its smaller volume than ice XV. The pressure-driven phase competition between hydrogen-ordered phases, also theoretically suggested in other ice polymorphs, can induce hydrogen ordering of ice in different manners. Thus, this study demonstrates a hitherto undiscovered polymorphism of ice.

cond-mat.mtrl-sci↗

arXiv2020

Quantum Criticality of Valence Transition for the Unique Electronic State of Antiferromagnetic Compound EuCu2Ge2

The effect of pressure on the unique electronic state of the antiferromagnetic (AF) compound EuCu2Ge2 has been measured in a wide temperature range from 10 mK to 300 K by electrical resistivity measurements up to 10 GPa. The Neel temperature of TN = 15 K at ambient pressure increases monotonically with increasing pressure and becomes a maximum of TN = 27 K at 6.2 GPa but suddenly drops to zero at Pc = 6.5 GPa, suggesting the quantum critical point (QCP) of the valence transition of Eu from a nearly divalent state to that with trivalent weight. The rhomag0 and A values obtained from the low-temperature electrical resistivity based on the Fermi liquid relation of rhomag = rhomag0 + AT^2 exhibit huge and sharp peaks around Pc. The exponent n obtained from the power law dependence rhomag = rhomag0 + BT^n is clearly less than 1.5 at P = Pc = 6. 5 GPa, which is expected at the AF-QCP. These results indicate that Pc coincides with Pv, corresponding to the quantum criticality of the valence transition pressure Pv. The electronic specific heat coefficient, estimated from the generalized Kadowaki-Woods relation, is about 510 mJ/mol K^2 around Pc, suggesting the formation of a heavy-fermion state.

cond-mat.str-el↗

arXiv2020

Magnetoelectric Effect in the Antiferromagnetic Ordered State of Ce$_{3}$TiBi$_{5}$ with Ce Zig-Zag Chains

In this study, we investigate the magnetoelectric (ME) effect of the newly discovered antiferromagnetic (AFM) compound Ce$_{3}$TiBi$_{5}$ with a hexagonal structure (space group $P6_{3}$/$mcm$). In this system, Ce ions form zig-zag chains that extend along the $c$-axis. We focus on the lack of the local inversion symmetry at the Ce site, although the crystal structure has an inversion center. A theoretical study has predicted that magnetization can be induced by an electric current in the AFM ordering on the zig-zag chain. We conducted magnetization measurements on Ce$_{3}$TiBi$_{5}$ under an applied constant electric current and a static magnetic field around the AFM ordering temperature of $T_{\rm N}$ = 5.0 K. We successfully observed of the current-induced magnetization below $T_{\rm N}$. The magnitude of the current-induced magnetization has a linear electric current dependence and exhibits no magnetic field dependence. This behavior is consistent with the theoretical prediction of the ME effect in the ferrotoroidal ordered state.

cond-mat.str-el↗

arXiv2019

Superconductivity of Electron-Doped NdOBiS2 by Substitution of Mixed-Valence Ce ions

Superconductivity is achieved in Nd1-xCexOBiS2 via electron doping using mixed-valence Ce ions. Single crystals with x = 0.2, 0.3, 0.4, and 0.5 are generated using a CsCl flux method. Plate-like single crystals with dimensions of 0.8 0.8 0.2 mm3 were obtained. The magnetic susceptibility chi(T) indicates large diamagnetism, and the electrical resistivity rho(T) indicates zero resistivity. The maximum value of Tc is observed at 4.7 K in Nd0.8Ce0.2OBiS2 from chi(T). From the rho(T) measurements taken in several magnetic fields, the upper critical field mu0Hc2(0) is estimated to be about 12 and 0.34 T for the ab- and c-planes, respectively. We redetermined mu0Hc2(0) of NdO0.7F0.3BiS2, as about 35 and 0.78 T for the ab- and c-planes, respectively. The anisotropic parameter is estimated to be about 35 for Nd0.7Ce0.3OBiS2 and 45 for NdO0.7F0.3BiS2. The mu0Hc2(0) of Nd0.7Ce0.3OBiS2 is approximately two times smaller than that of NdO0.7F0.3BiS2, although the difference of Gamma is approximately 10.

cond-mat.supr-con↗

arXiv2017

Effect of Pressure on Magnetism of UIrGe

We report the effect of hydrostatic pressure on the electronic state of the antiferromagnet UIrGe, which is isostructural and isoelectronic with the ferromagnetic superconductors UCoGe and URhGe. The Neel temperature decreases with increasing pressure. We constructed a p-T phase diagram and estimated the critical pressure pc, where the antiferromagnetism vanishes, as 12 GPa. The antiferromagnetic/paramagnetic transition appears to be first order.

cond-mat.str-el↗