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Jun Kano

Publications and source records attributed to Jun Kano.

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Thermoelectric response of a ferroelectric insulator

Thermoelectric effects enable the conversion between heat and electricity without moving parts. While conventionally associated with mobile charges, we report thermoelectricity caused by bound charges in the form of temperature changes measured by multi-harmonic lock-in thermography of a ferroelectric under an ac electric field. The observed temperature gradient depends on the field-induced displacement current, a Peltier effect in a dielectric material. Its coefficient exceeds 100 V around the ferroelectric-paraelectric phase transition, which is several orders of magnitude greater than reported values in conductors. Our findings uncover previously hidden functionalities of ferroelectric materials for thermal management by directional heat transport in ferroelectrics.

cond-mat.mtrl-sci

Direct measurement of electrocaloric effect based on multi-harmonic lock-in thermography

In this study, we report on a direct measurement method for the electrocaloric effect, the heating/cooling upon application/removal of an electric field in dielectric materials, based on a lock-in thermography technique. By use of sinusoidal excitation and multi-harmonic detection, the actual temperature change can be measured by a single measurement in the frequency domain even when the electrocaloric effect shows nonlinear response to the excitation field. We have demonstrated the method by measuring the temperature dependence of the electric-field-induced temperature change for two Sr-doped BaTiO$_3$ systems with different ferroelectric-paraelectric phase transition temperatures, where the procedure for extracting the pure electrocaloric contribution free from heat losses and Joule heating due to leakage currents is introduced. This method can be used irrespective of the type of dielectric materials and enables simultaneous estimation of the polarization change and power dissipation during the application of the electric field, being a convenient imaging measurement method for the electrocaloric effect.

cond-mat.mtrl-sci

Bent Electronic Band Structure Induced by Ferroelectric Polarization

Bent band structures have been empirically described in ferroelectric materials to explain the functioning of recently developed ferroelectric tunneling junction and photovoltaic devices. This report presents experimental evidence for ferroelectric band bending, which was observed in the depth profiles of atomic orbitals of angle-resolved hard x-ray photoemission spectra of ferroelectric BaTiO3 thin films. The ferroelectric bent band structure is separated into three depth regions; the shallowest and deepest regions are slightly modulated by the screening effect at surface and interface, respectively, and the intermediate region exhibits the pure ferroelectric effect. In the pure ferroelectric bent band structure, we found that the binding energy of outer shell electrons shows a larger shift than that of inner shell electrons, and that the difference in energy shift is correlated with the atomic configuration of the soft phonon mode. These findings could lead to a simple understanding of the origin of electric polarization.

cond-mat.mtrl-sci

Magnetoelectric Effect driven by Magnetic Domain Modification in LuFe2O4

Magneto-capacitance effect was investigated using the impedance spectroscopy on single crystals of LuFe2O4. The intrinsic impedance response could be separated from the interfacial response and showed a clear hysteresis loop below TFerri ~ 240 K under the magnetic field. The neutron diffraction experiment under the magnetic field proves the origin of dielectric property related to the motion of nano-sized ferromagnetic domain boundary. These results imply that the modification of the microscopic domain structure is responsible for the magnetoelectric effect in LuFe2O4.

cond-mat.str-el