arXiv subjects

Jun Meng

Publications and source records attributed to Jun Meng.

At least 37 records · Page 2Linked to original sources

arXiv2024

Ultra-fast Oxygen Conduction in Sillén Oxychlorides

Oxygen ion conductors are crucial for enhancing the efficiency of various clean energy technologies, including fuel cells, batteries, electrolyzers, membranes, sensors, and more. In this study, LaBi2O4Cl is identified as an ultra-fast oxygen conductor from the MBi2O4X (M=rare-earth element, X=halogen element) family, discovered by a structure-similarity analysis of >60k oxygen-containing compounds. Ab initio studies reveal that LaBi2O4Cl has an ultra-low migration barrier of 0.1 eV for oxygen vacancy, significantly lower than 0.6-0.8 eV for interstitial oxygen. Frenkel pairs are the dominant defects in intrinsic LaBi2O4Cl, facilitating notable oxygen diffusion primarily through vacancies at higher temperatures. LaBi2O4Cl with extrinsic oxygen vacancies (2.8%) exhibits a conductivity of 0.3 S/cm at 25°C, maintains a 0.1 eV diffusion barrier up to 1100°C, and transitions from extrinsic to mixed extrinsic and intrinsic behavior as the Frenkel pair concentration increases at higher temperatures. Experimental results on synthesized LaBi2O4Cl and Sr-doped LaBi2O4Cl demonstrate comparable or higher oxygen conductivity than YSZ and LSGM below 400 °C, with lower activation energies. Further experimental optimization of LaBi2O4Cl, including aliovalent doping and microstructure refinement, could significantly enhance its performance and efficiency, facilitating fast oxygen conduction approaching room temperature.

cond-mat.mtrl-sci↗

arXiv2024

Computational Discovery of Fast Interstitial Oxygen Conductors

New highly oxygen-active materials may enhance many energy-related technologies by enabling efficient oxygen-ion transport at lower temperatures, e.g., below 400 Celsius. Interstitial oxygen conductors have the potential to realize such performance but have received far less attention than vacancy-mediated conductors. Here, we combine physically-motivated structure and property descriptors, ab initio simulations, and experiments to demonstrate an approach to discover new fast interstitial oxygen conductors. Multiple new families were found which adopt completely different structures from known oxygen conductors. From these families, we synthesized and studied oxygen kinetics in La4Mn5Si4O22+d (LMS), a representative member of perrierite/chevkinite family. We found LMS has higher oxygen ionic conductivity than the widely used yttria-stabilized ZrO2, and among the highest surface oxygen exchange rates at intermediate temperature of known materials. The fast oxygen kinetics is the result of simultaneously active interstitial and interstitialcy diffusion pathways. This work developed and demonstrated a powerful approach for discovering new families of interstitial oxygen conductors and suggests many more such materials remain to be discovered.

cond-mat.mtrl-sci↗

arXiv2024

GraphRelate3D: Context-Dependent 3D Object Detection with Inter-Object Relationship Graphs

Accurate and effective 3D object detection is critical for ensuring the driving safety of autonomous vehicles. Recently, state-of-the-art two-stage 3D object detectors have exhibited promising performance. However, these methods refine proposals individually, ignoring the rich contextual information in the object relationships between the neighbor proposals. In this study, we introduce an object relation module, consisting of a graph generator and a graph neural network (GNN), to learn the spatial information from certain patterns to improve 3D object detection. Specifically, we create an inter-object relationship graph based on proposals in a frame via the graph generator to connect each proposal with its neighbor proposals. Afterward, the GNN module extracts edge features from the generated graph and iteratively refines proposal features with the captured edge features. Ultimately, we leverage the refined features as input to the detection head to obtain detection results. Our approach improves upon the baseline PV-RCNN on the KITTI validation set for the car class across easy, moderate, and hard difficulty levels by 0.82%, 0.74%, and 0.58%, respectively. Additionally, our method outperforms the baseline by more than 1% under the moderate and hard levels BEV AP on the test server.

cs.CV↗

arXiv2024

Experimentally informed structure optimization of amorphous TiO2 films grown by atomic layer deposition

Amorphous titanium dioxide TiO2 (a-TiO2) has been widely studied, particularly as a protective coating layer on semiconductors to prevent corrosion and promote electron-hole conduction in photoelectrochemical reactions. The stability and longevity of a-TiO2 is strongly affected by the thickness and structural heterogeneity, implying that understanding the structure properties of a-TiO2 is crucial for improving the performance. This study characterized the structural and electronic properties of a-TiO2 thin films (~17nm) grown on Si by Atomic Layer Deposition (ALD). Fluctuation spectra V(k) and angular correlation functions were determined with 4-dimensional scanning transmission electron microscopy (4D-STEM), which revealed the distinctive medium-range ordering in the a-TiO2 film. A realistic atomic model of a-TiO2 was established guided by the medium-range ordering and the previously reported short-range ordering of a-TiO2 film, as well as the interatomic potential. The structure was optimized by the StructOpt code using a genetic algorithm that simultaneously minimizes energy and maximizes match to experimental short- and medium-range ordering. The StructOpt a-TiO2 model presents an improved agreements with the medium-range ordering and the k-space location of the dominant 2-fold angular correlations compared with a traditional melt-quenched model. The electronic structure of the StructOpt a-TiO2 model was studied by ab initio calculation and compared to the crystalline phases and experimental results. This work uncovered the medium-range ordering in a-TiO2 thin film and provided a realistic a-TiO2 structure model for further investigation of structure-property relationships and materials design. In addition, the improved multi-objective optimization package StructOpt was provided for structure determination of complex materials guided by experiments and simulations.

cond-mat.mtrl-sci↗

arXiv2023

Regional Greening as a `Positive' Tipping Phenomenon

Earth system tipping elements have been predominantly investigated for their potential to trigger \textit{negative} ecological, climatic, and societal shifts. Yet, an overlooked but seminal avenue exists in the form of \textit{positive} tipping phenomena, whose underlying mechanisms and benefits remain largely underexplored. To bridge this gap, our research introduces a fundamental percolation-based framework to assess the criticality and resilience of planetary terrestrial vegetation systems. Leveraging high-resolution satellite data, we focus on greening-induced positive tipping dynamics driven by global warming. We feature the Qinghai-Tibetan Plateau (QTP) and the Sahel region as contrasting yet analogous case studies. Our analysis uncovers an intriguing phenomenon where vegetation fragmentation aligns with a percolation threshold, exhibiting a scale-invariant pattern characterized by nearly perfect power laws with three critical exponents. Remarkably, contrary to conventional destructive tipping elements, these regions act as favorable tipping elements, transitioning from fragmented to cohesive vegetation patterns due to anthropogenic climate change and afforestation efforts. Furthermore, we propose an \textit{optimal resilience enhancement model} to reinforce vegetation robustness while minimizing socio-economic costs. This study provides valuable insights into the favorable aspects of tipping elements under climate change and offers effective strategies for enhancing ecological resilience against environmental threats.

physics.geo-ph↗

arXiv2023

Roller-Quadrotor: A Novel Hybrid Terrestrial/Aerial Quadrotor with Unicycle-Driven and Rotor-Assisted Turning

The Roller-Quadrotor is a novel quadrotor that combines the maneuverability of aerial drones with the endurance of ground vehicles. This work focuses on the design, modeling, and experimental validation of the Roller-Quadrotor. Flight capabilities are achieved through a quadrotor configuration, with four thrust-providing actuators. Additionally, rolling motion is facilitated by a unicycle-driven and rotor-assisted turning structure. By utilizing terrestrial locomotion, the vehicle can overcome rolling and turning resistance, thereby conserving energy compared to its flight mode. This innovative approach not only tackles the inherent challenges of traditional rotorcraft but also enables the vehicle to navigate through narrow gaps and overcome obstacles by taking advantage of its aerial mobility. We develop comprehensive models and controllers for the Roller-Quadrotor and validate their performance through experiments. The results demonstrate its seamless transition between aerial and terrestrial locomotion, as well as its ability to safely navigate through gaps half the size of its diameter. Moreover, the terrestrial range of the vehicle is approximately 2.8 times greater, while the operating time is about 41.2 times longer compared to its aerial capabilities. These findings underscore the feasibility and effectiveness of the proposed structure and control mechanisms for efficient navigation through challenging terrains while conserving energy.

cs.RO↗

arXiv2023

Catch Planner: Catching High-Speed Targets in the Flight

Catching high-speed targets in the flight is a complex and typical highly dynamic task. In this paper, we propose Catch Planner, a planning-with-decision scheme for catching. For sequential decision making, we propose a policy search method based on deep reinforcement learning. In order to make catching adaptive and flexible, we propose a trajectory optimization method to jointly optimize the highly coupled catching time and terminal state while considering the dynamic feasibility and safety. We also propose a flexible constraint transcription method to catch targets at any reasonable attitude and terminal position bias. The proposed Catch Planner provides a new paradigm for the combination of learning and planning and is integrated on the quadrotor designed by ourselves, which runs at 100hz on the onboard computer. Extensive experiments are carried out in real and simulated scenes to verify the robustness of the proposed method and its expansibility when facing a variety of high-speed flying targets.

cs.RO↗

arXiv2023

Dynamic Arctic weather variability and connectivity

The rapidly shrinking Arctic sea ice is changing weather patterns and disrupting the balance of nature. Dynamics of Arctic weather variability (WV) plays a crucial role in weather forecasting and is closely related to extreme weather events. Yet, assessing and quantifying the WV for both local Arctic regions and its planetary impacts under anthropogenic climate change is still unknown. Here, we develop a complexity-based approach to systematically evaluate and analyze the dynamic behaviour of WV. We reveal that the WV within and around the Arctic is statistically correlated to the Arctic Oscillation at the intraseasonal time scale. We further find that the variability of the daily Arctic sea ice is increasing due to its dramatic decline under a warming climate. Unstable Arctic weather conditions can disturb regional weather patterns through atmospheric teleconnection pathways, resulting in higher risk to human activities and greater weather forecast uncertainty. A multivariate climate network analysis reveals the existence of such teleconnections and implies a positive feedback loop between the Arctic and global weather instabilities. This enhances the mechanistic understanding of the influence of Arctic amplification on mid-latitude severe weather. Our framework provides a fresh perspective on the linkage of complexity science, WV and the Arctic.

physics.ao-ph↗

arXiv2022

Teleconnections among Tipping Elements in the Earth System

Tipping elements of the Earth system may shift abruptly and irreversibly from one state to another at tipping points, resulting in a growing threat to our society. Yet, it is not fully clear how to assess and quantify the influence of a tipping element and how to explore the teleconnections between different tipping elements. To fill this knowledge gap, we propose a climate network approach to quantitatively analyze the global impacts of a prominent tipping element, the Amazon Rainforest Area (ARA). We find that regions, such as, the Tibetan Plateau (TP) and West Antarctic ice sheet, are characterized by higher network weighted links and exhibit strong correlations with the ARA. We then identify a teleconnection propagation path between the ARA and the TP. This path is robust under climate change as simulated by various climate models of CMIP5 and CMIP6. In addition, we detect early warning signals for critical transition in the snow cover extent on the Tibetan Plateau by applying critical slowing down indicators, lag-1 autocorrelation and detrended fluctuation analysis. We find that the snow cover of the TP has been losing stability since 2008, revealing that the TP is operating like a tipping element and approaching a potential tipping point. We further uncover that various climate extremes between the ARA and the TP are significantly synchronized under climate change. Our framework provides new insights into how tipping elements are linked to each other and into the potential predictability of cascading tipping dynamics.

physics.soc-ph↗

arXiv2022

Emergence of universal scaling in weather extreme events

The frequency and magnitude of weather extreme events have increased significantly during the past few years in response to anthropogenic climate change. However, global statistical characteristics and underlying physical mechanisms are still not fully understood. Here, we adopt a statistical physics and probability theory based method to investigate the nature of extreme weather events, particularly the statistics of the day-to-day air temperature differences. These statistical measurements reveal that the distributions of the magnitudes of the extreme events satisfy a universal \textit{Gumbel} distribution, while the waiting time of those extreme events is governed by a universal \textit{Gamma} function. Further finite-size effects analysis indicates robust scaling behaviours. We additionally unveil that the cumulative distribution of logarithmic waiting times between the record events follows an \textit{Exponential} distribution and that the evolution of this climate system is directional where the underlying dynamics are related to a decelerating release of tension. The universal scaling laws are remarkably stable and unaffected by global warming. Counterintuitively, unlike as expected for record dynamics, we find that the number of quakes of the extreme temperature variability does not decay as one over time but with deviations relevant to large-scale climate extreme events. Our theoretical framework provides a fresh perspective on the linkage of universality, scaling, and climate systems. The findings throw light on the nature of the weather variabilities and could guide us to better forecast extreme events.

physics.ao-ph↗

arXiv2022

Climate network and complexity based El Niño forecast for 2022

The El Niño Southern Oscillation (ENSO) is the most important driver of interannual global climate variability and can trigger extreme weather events and disasters in various parts of the globe. Recently, we have developed two approaches for the early forecasting of El Niño. The climate network-based approach allows forecasting the onset of an El Niño event about 1 year ahead. The complexity-based approach allows additionally to forecast the magnitude of an upcoming El Niño event in the calendar year before. Here we communicate the forecasts of both methods for 2022.

physics.ao-ph↗

arXiv2020

Statistical physics approaches to the complex Earth system

Global climate change, extreme climate events, earthquakes and their accompanying natural disasters pose significant risks to humanity. Yet due to the nonlinear feedbacks, strategic interactions and complex structure of the Earth system, the understanding and in particular the predicting of such disruptive events represent formidable challenges for both scientific and policy communities. During the past years, the emergence and evolution of Earth system science has attracted much attention and produced new concepts and frameworks. Especially, novel statistical physics and complex networks-based techniques have been developed and implemented to substantially advance our knowledge for a better understanding of the Earth system, including climate extreme events, earthquakes and Earth geometric relief features, leading to substantially improved predictive performances. We present here a comprehensive review on the recent scientific progress in the development and application of how combined statistical physics and complex systems science approaches such as, critical phenomena, network theory, percolation, tipping points analysis, as well as entropy can be applied to complex Earth systems (climate, earthquakes, etc.). Notably, these integrating tools and approaches provide new insights and perspectives for understanding the dynamics of the Earth systems. The overall aim of this review is to offer readers the knowledge on how statistical physics approaches can be useful in the field of Earth system science.

physics.soc-ph↗

arXiv2020

Satellite-based estimates of decline and rebound in China's CO$_2$ emissions during COVID-19 pandemic

Changes in CO$_2$ emissions during the COVID-19 pandemic have been estimated from indicators on activities like transportation and electricity generation. Here, we instead use satellite observations together with bottom-up information to track the daily dynamics of CO$_2$ emissions during the pandemic. Unlike activity data, our observation-based analysis can be independently evaluated and can provide more detailed insights into spatially-explicit changes. Specifically, we use TROPOMI observations of NO$_2$ to deduce ten-day moving averages of NO$_x$ and CO$_2$ emissions over China, differentiating emissions by sector and province. Between January and April 2020, China's CO$_2$ emissions fell by 11.5% compared to the same period in 2019, but emissions have since rebounded to pre-pandemic levels owing to the fast economic recovery in provinces where industrial activity is concentrated.

physics.ao-ph↗

arXiv2020

Network-based Approach and Climate Change Benefits for Forecasting the Amount of Indian Monsoon Rainfall

The Indian summer monsoon rainfall (ISMR) has a decisive influence on India's agricultural output and economy. Extreme deviations from the normal seasonal amount of rainfall can cause severe droughts or floods, affecting Indian food production and security. Despite the development of sophisticated statistical and dynamical climate models, a long-term and reliable prediction of the ISMR has remained a challenging problem. Towards achieving this goal, here we construct a series of dynamical and physical climate networks based on the global near surface air temperature field. We uncover that some characteristics of the directed and weighted climate networks can serve as efficient long-term predictors for ISMR forecasting. The developed prediction method produces a forecast skill of 0.5 with a 5-month lead-time in advance by using the previous calendar year's data. The skill of our ISMR forecast, is comparable to the current state-of-the-art models, however, with quite a short (i.e., within one month) lead-time. We discuss the underlying mechanism of our predictor and associate it with network-delayed-ENSO and ENSO-monsoon connections. Moreover, our approach allows predicting the all India rainfall, as well as forecasting the different Indian homogeneous regions' rainfall, which is crucial for agriculture in India. We reveal that global warming affects the climate network by enhancing cross-equatorial teleconnections between Southwest Atlantic, Western part of the Indian Ocean, and North Asia-Pacific with significant impacts on the precipitation in India. We find a hotspots area in the mid-latitude South Atlantic, which is the basis for our predictor. Remarkably, the significant warming trend in this area yields an improvement of the prediction skill.

physics.ao-ph↗

arXiv2019

Complexity based approach for El Nino magnitude forecasting before the "spring predictability barrier"

The El Nino Southern Oscillation (ENSO) is one of the most prominent interannual climate phenomena. An early and reliable ENSO forecasting remains a crucial goal, due to its serious implications for economy, society, and ecosystem. Despite the development of various dynamical and statistical prediction models in the recent decades, the ``spring predictability barrier'' (SPB) remains a great challenge for long (over 6-month) lead-time forecasting. To overcome this barrier, here we develop an analysis tool, the System Sample Entropy (SysSampEn), to measure the complexity (disorder) of the system composed of temperature anomaly time series in the Nino 3.4 region. When applying this tool to several near surface air-temperature and sea surface temperature datasets, we find that in all datasets a strong positive correlation exists between the magnitude of El Nino and the previous calendar year's SysSampEn (complexity). We show that this correlation allows to forecast the magnitude of an El Nino with a prediction horizon of 1 year and high accuracy (i.e., Root Mean Square Error $=0.23^\circ C$ for the average of the individual datasets forecasts). For the on-going 2018 El Nino event, our method forecasts a weak El Nino with a magnitude of $1.11\pm 0.23^\circ C$. Our framework presented here not only facilitates a long--term forecasting of the El Nino magnitude but can potentially also be used as a measure for the complexity of other natural or engineering complex systems.

physics.ao-ph↗

arXiv2019

Percolation Framework of the Earth's Topography

Self-similarity and long-range correlations are the remarkable features of the Earth's surface topography. Here we develop an approach based on percolation theory to study the geometrical features of Earth. Our analysis is based on high-resolution, 1 arc min, ETOPO1 global relief records.We find some evidence for abrupt transitions that occurred during the evolution of the Earth's relief network, indicative of a continental/cluster aggregation. We apply finite-size-scaling analysis based on a coarse-graining procedure to show that the observed transition is most likely discontinuous. Furthermore, we study the percolation on two-dimensional fractional Brownian motion surfaces with Hurst exponent $H$ as a model of long-range correlated topography, which suggests that the long-range correlations may play a key role in the observed discontinuity on Earth. Our framework presented here provides a theoretical model to better understand the geometrical phase transition on Earth, and it also identifies the critical nodes that will be more exposed to global climate change in the Earth's relief network.

physics.soc-ph↗

arXiv2018

A combined network and machine learning approaches for product market forecasting

Sustainable financial markets play an important role in the functioning of human society. Still, the detection and prediction of risk in financial markets remain challenging and draw much attention from the scientific community. Here we develop a new approach based on combined network theory and machine learning to study the structure and operations of financial product markets. Our network links are based on the similarity of firms' products and are constructed using the Securities Exchange Commission (SEC) filings of US listed firms. We find that several features in our network can serve as good precursors of financial market risks. We then combine the network topology and machine learning methods to predict both successful and failed firms. We find that the forecasts made using our method are much better than other well-known regression techniques. The framework presented here not only facilitates the prediction of financial markets but also provides insight and demonstrate the power of combining network theory and machine learning.

physics.soc-ph↗

arXiv2018

Climate network percolation reveals the expansion and weakening of the tropical component under global warming

Global climate warming poses a significant challenge to humanity; it is associated with, e.g., rising sea level and declining Arctic sea ice. Increasing extreme events are also considered to be a result of climate warming~\cite{pachauri2014climate,ogorman_contrasting_2014} and they may have widespread and diverse effects on health, agriculture, economics and political conflicts \cite{hsiang2011civil,helbing_globally_2013,schleussner_armed-conflict_2016,carleton_social_2016}. Still, the detection and quantification of climate change, both in observations and climate models, constitute a main focus of the scientific community. Here we develop a new approach based on network and percolation frameworks \cite{cohen2010complex} to study the impacts of climate changes in the past decades using historical models and reanalysis records, and we analyze the expected upcoming impacts using various future global warming scenarios. More specifically, we classify the globe area into evolving percolation clusters and find a discontinuous phase transition, which indicates a consistent poleward expansion of the largest (tropical) cluster, as well as the weakening of the link's strength. This is found both in the reanalysis data and in the Coupled Model Intercomparison Project Phase 5 (CMIP5) twenty-first century climate change simulations~\cite{taylor2012overview}. The analysis is based on high resolution surface (2~m) air temperature field records. We discuss the underlying mechanism for the observed expansion of the tropical cluster and associate it with changes in atmospheric circulation represented by the weakening and expansion of the Hadley cell. Our framework can also be useful for forecasting the extent of the tropical cluster in order to detect its influence on different areas in response to global warming.

physics.soc-ph↗