arXiv subjects

Jun Sugiyama

Publications and source records attributed to Jun Sugiyama.

28 records · Page 2Linked to original sources

arXiv2014

Na-ion dynamics in Quasi-1D compound NaV2O4

We have used the pulsed muon source at ISIS to study high-temperature Na-ion dynamics in the quasi-one-dimensional (Q1D) metallic antiferromagnet NaV2O4. By performing systematic zero-field and longitudinal-field measurements as a function of temperature we clearly distinguish that the hopping rate increases exponentially above Tdiff=250 K. The data is well fitted to an Arrhenius type equation typical for a diffusion process, showing that the Na-ions starts to be mobile above Tdiff . Such results makes this compound very interesting for the tuning of Q1D magnetism using atomic-scale ion-texturing through the periodic potential from ordered Na-vacancies. Further, it also opens the door to possible use of NaV2O4 and related compounds in energy related applications.

cond-mat.mtrl-sci↗

arXiv2014

Magnetic nano-fluctuations in a frustrated magnet

Frustrated systems exhibit remarkable properties due to the high degeneracy of their ground states. Stabilised by competing interactions, a rich diversity of typically nanometre-sized phase structures appear in polymer and colloidal systems, while the surface of ice pre-melts due to geometrically frustrated interactions. Atomic spin systems where magnetic interactions are frustrated by lattice geometry provide a fruitful source of emergent phenomena, such as fractionalised excitations analogous to magnetic monopoles. The degeneracy inherent in frustrated systems may prevail all the way down to absolute zero temperature, or it may be lifted by small perturbations or entropic effects. In the geometrically frustrated Ising--like magnet Ca3Co2O6, we follow the temporal and spatial evolution of nanoscale magnetic fluctuations firmly embedded inside the spin--density--wave magnetic structure. These fluctuations are a signature of a competing ferrimagnetic phase with an incommensurability that is different from, but determined by the host. As the temperature is lowered, the fluctuations slow down into a super-paramagnetic regime of stable spatiotemporal nano-structures.

cond-mat.str-el↗

arXiv2011

Magnetic order and transitions in the spin-web compound Cu3TeO6

The spin-web compound Cu3TeO6, belongs to an intriguing group of materials where magnetism is governed by 3d9 copper Cu2+ ions. This compound has been sparsely experimentally studied and we here present the first investigation of its local magnetic properties using muon-spin relaxation/rotation (μ+SR). Our results show a clear long-range 3D magnetic order below TN as indicated by clear zero-field (ZF) muon-precessions. At TN = 61.7 K a very sharp transition is observed in the weak transverse-field (wTF) as well as ZF data. Contrary to suggestions by susceptibility measurements and inelastic neutron scattering, we find no evidence for either static or dynamic (on the time-scale of μ+SR) spin-correlations above TN.

cond-mat.str-el↗

arXiv2011

Magnetic order and frustrated dynamics in Li(Ni0.8Co0.1Mn0.1)O2: a study by μ+SR and SQUID magnetometry

Recently, the mixed transition metal oxides of the form Li(Ni1-y-zCoyMnz)O2, have become the center of attention as promising candidates for novel battery material. These materials have also revealed very interesting magnetic properties due to the alternate stacking of planes of metal oxides on a 2D triangular lattice and the Li-layers. The title compound, Li(Ni0.8Co0.1Mn0.1)O2, has been investigated by both magnetometry and measurements and μ+SR. We find the evolution of localized magnetic moments with decreasing temperature below 70 K. The magnetic ground state (T = 2 K) is, however, shown to be a frustrated system in 3D, followed by a transition into a possible 2D spinglass above 22 K. With further increasing temperature the compound show the presence of remaining correlations with increasing effective dimensionality all the way up to the ferrimagnetic transition at TC = 70 K.

cond-mat.str-el↗

arXiv2010

The magnetic structure of the $zigzag$ chain family Na$_{x}$Ca$_{1-x}$V$_2$O$_4$ determined by muon-spin rotation

We present muon-spin rotation measurements on polycrystalline samples of the complete family of the antiferromagnetic (AF) $zigzag$ chain compounds, Na$_x$Ca$_{1-x}$V$_2$O$_4$. In this family, we explore the magnetic properties from the metallic NaV$_2$O$_4$ to the insulating CaV$_2$O$_4$. We find a critical $x_c(\sim0.833)$ which separates the low and high Na-concentration dependent transition temperature and its magnetic ground state. In the $x x_c$ compounds, multiple sub-phases appear with temperature and $x$. Based on the muon data obtained in zero external magnetic field, a careful dipolar field simulation was able to reproduce the muon behavior and indicates a modulated helical incommensurate spin structure of the metallic AF phase. The incommensurate modulation period obtained by the simulation agrees with that determined by neutron diffraction.

cond-mat.str-el↗

arXiv2010

The magnetic phase of the perovskite CaCrO$_3$ studied with $μ^{+}$SR

We investigated the magnetic phase of the perovskite CaCrO$_3$ by using the muon spin relaxation technique accompanied by susceptibility measurements. A thermal hysteresis loop is identified with a width of about 1 K at the transition temperature. Within the time scale of the muon lifetime, a static antiferromagnetic order is revealed with distinct multiple internal fields which are experienced in the muon interstitial sites below the phase-transition temperature, $T_N=90 K$. Above $T_N$, lattice deformations are indicated by transverse-field muon-spin rotation and relaxation suggesting a magneto-elastic mechanism.

cond-mat.str-el↗

arXiv2009

Li diffusion in Li$_x$CoO$_2$ probed by muon-spin spectroscopy

The diffusion coefficient of Li$^+$ ions ($D_{\rm Li}$) in the battery material Li$_x$CoO$_2$ has been investigated by muon-spin relaxation ($μ^+$SR). Based on the experiments in zero-field and weak longitudinal-fields at temperatures up to 400 K, we determined the fluctuation rate ($ν$) of the fields on the muons due to their interaction with the nuclear moments. Combined with susceptibility data and electrostatic potential calculations, clear Li$^+$ ion diffusion was detected above $\sim150$K. The $D_{\rm Li}$ estimated from $ν$ was in very good agreement with predictions from first-principles calculations, and we present the $μ^+$SR technique as an % novel and optimal probe to detect $D_{\rm Li}$ for materials containing magnetic ions.

cond-mat.mtrl-sci↗

arXiv2003

Penta-quark baryon from the QCD Sum Rule

Exotic penta-quark baryon with strangeness +1, Θ^+, is studied in the QCD sum rule approach. We derive sum rules for the positive and negative parity baryon states with J=1/2 and I=0. It is found that the standard values of the QCD condensates predict a negative parity Θ^+ of mass \simeq 1.5 GeV, while no positive parity state is found. We stress the roles of chiral-odd condensates in determining the parity and mass of Θ^+.

hep-ph↗

arXiv2003

Vector Component of Confinement Force and P-Wave Spectrum of D mesons

The mass spectrum and the pionic decay widths of the P-wave $D$ mesons are studied using the Dirac equation for the light quark. Our aim is to determine the Lorentz property of the confinement force. We find that the Lorentz scalar confinement is consistent with the mass spectrum, while a significant mixture of the Lorentz vector confinement is necessary to explain the decay widths.

hep-ph↗

arXiv2003

Static magnetic order in Na$_{0.75}$CoO$_2$ detected by muon spin rotation and relaxation

The nature of the magnetic transition of the Na-rich thermoelectric Na$_{0.75}$CoO$_2$ at 22K was studied by positive muon-spin-rotation and relaxation ($μ^+$SR) spectroscopy, using a polycrystalline sample in the temperature range between 300 and 2.5 K. Zero field $μ$SR measurements indicated the existence of a static internal magnetic field at temperatures below 22 K (= $T_{\rm m}$). The observed muon spin precession signal below $T_{\rm m}$ consisted of three components with different precession frequencies, corresponding to three inequivalent muon$^+$ sites in the Na$_{0.75}$CoO$_2$ lattice. The total volume fraction of the three components was estimated as $\sim$21% at 2.5 K; thus, this magnetic transition was not induced by impurities but is an intrinsic change in the magnetism of the sample, although the sample was magnetically inhomogeneous otherwise. On the other hand, a similar experiment on a Na$_{0.65}$CoO$_2$ sample exhibited no magnetic transition down to 2.5 K; which indicates that the average valence of the Co ions is responsible for inducing the magnetic transition at 22 K.

cond-mat.str-el↗