arXiv subjects

Junhong Yu

Publications and source records attributed to Junhong Yu.

3 recordsLinked to original sources

arXiv2021

Photo-Induced Ultrafast Symmetry Switch in SnSe

Layered tin selenide (SnSe) has recently emerged as a high-performance thermoelectric material with the current record for the figure of merit (ZT) observed in the high-temperature Cmcm phase. So far, access of the Cmcm phase has been mainly obtained via thermal equilibrium methods based on sample heating or application of external pressure, thus restricting the current understanding only to ground-state conditions. Here, we investigate the ultrafast carrier and phononic dynamics in SnSe. Our results demonstrate that optical excitations can transiently switch the point-group symmetry of the crystal from Pnma to Cmcm at room temperature in a few hundreds of femtoseconds with an ultralow threshold for the excitation carrier density. This non-equilibrium Cmcm phase is found to be driven by the displacive excitation of coherent Ag phonons and, given the absence of low-energy thermal phonons, exists in SnSe with the status of 'cold lattice with hot carriers'. Our findings provide important insight for understanding non-equilibrium thermoelectric properties of SnSe.

cond-mat.mtrl-sci↗

arXiv2019

Sustained biexciton emission in colloidal quantum wells assisted by dopant-host interaction

Biexcitons have been considered as one of the fundamental building blocks for quantum technology because of its overwhelming advantages in generating entangled photon pairs. Although many-body complexes have been demonstrated recently in mono-layer transition metal dichalcogenides (TMDs), the low emission efficiency and scale up capability hinder their applications. Colloidal nanomaterials, with high quantum efficiency and ease of synthesis/processing, are regarded to be an appealing complement to TMDs for biexciton sources. However, a progress towards biexciton emission in colloidal nanomaterials has been challenging largely by small binding energy and ultrafast non-radiative multiexciton recombination. Here, we demonstrate room-temperature biexciton emission in Cu-doped CdSe colloidal quantum wells (CQWs) under continuous-wave excitation with intensity as low as ~10 W/cm2. The characteristics of radiative biexciton states are investigated by their super linear emission with respect to excitation power, thermal stability and transient photophysics. The interaction between the quantum confined host carriers and the dopant ions increases biexciton binding energy by two folds compared to the undoped CQWs. Such strong binding energy together with suppressed Auger recombination and efficient, spectrally narrow photoluminescence in a quasi-2D semiconductor enables sustained biexciton emission at room temperature, providing a potential solution for efficient, scalable and stand-alone quantum devices.

cond-mat.mes-hall↗

arXiv2019

Manipulating Coherent Light Matter Interaction: Continuous Transition between Strong Coupling and Weak Coupling in MoS2 Monolayer Coupled with Plasmonic Nanocavities

Strong interactions between surface plasmons in ultra-compact nanocavities and excitons in two dimensional materials have attracted wide interests for its prospective realization of polariton devices at room temperature. Here, we propose a continuous transition from weak coupling to strong coupling between excitons in MoS2 monolayer and highly localized plasmons in ultra-compact nanoantenna. The nanoantenna is assembled by a silver nanocube positioned over a gold film and separated by a dielectric spacer layer. We observed a 1570-fold enhancement in the photoluminescence at weak coupling regime in hybrid nanocavities with thick spacer layers. The interaction between excitons and plasmons is then directly prompted to strong coupling regime by shrinking down the thickness of spacer layer. Room temperature formation of polaritons with Rabi splitting up to 190 meV was observed, which is the largest plasmon-exciton Rabi splitting reported in two dimensional materials. Numerical calculations quantified the relation between coupling strength, local density of states and spacer thickness, and revealed the transition between weak coupling and strong coupling in nanocavities. The findings in this work offer a guideline for feasible designs of plasmon-exciton interaction systems with gap plasmonic cavities.

cond-mat.mes-hall↗