arXiv subjects

Junko Morikawa

Publications and source records attributed to Junko Morikawa.

At least 19 recordsLinked to original sources

arXiv2026

Oxidation of Tantalum Nano-Film by Microwave Exposure

Oxidation and ablation of 200 nm tantalum films were carried out by three routes: (i) femtosecond (fs-)laser direct write, (ii) high-temperature annealing (HTA) in a tube furnace, and (iii) annealing in a 2.45 GHz microwave cavity. Complete conversion of the 200 nm Ta layer into 409 nm of Ta2O5 required one hour at 600 C in the furnace, but only minutes at ~ 50 W of microwave power. Fs-laser (515 nm/200 fs) oxidation of the Ta nano-film set in at an average single-pulse fluence of ~ 0.1 J/cm2 under strong pulse-to-pulse overlap (900 pulses per focal spot), i.e. within a narrow window bounded from above by the onset of ablation. Under microwave annealing, both the cavity resonance frequency and the quality factor Q changed markedly at the metal-to-oxide transition, reflecting the collapse of the real and imaginary parts of the permittivity at 2.45 GHz. This dielectric contrast turns the cavity into a sensor: the oxidation can be followed in real time from the shift of the cavity resonance, providing a non-invasive, in-situ diagnostic tool.

cond-mat.mtrl-sci↗

arXiv2026

Diamond membranes: platform for photonic and opto-mechanical applications

Diamond 1 - 10 micrometers thick membranes are platform for photonic, quantum and opto-mechanic devices with applications across UV-IR spectral ranges. IR characterization of diamond gratings in reflection and transmission showed a change of the IR absorbance dichroism between positive and negative when the grating period was 1-2 wavelengths (free space) including inside the region of the intrinsic diamond absorbance. Femtosecond laser cutting of micrometers-wide and mm-long structures are demonstrated by steps of carbonization > 0.4 J/cm2/pulse (1030 nm/200 fs) and oxidation of diamond membranes. Light intensity distribution inside form-birefringent diamond structure was modeled for a scaled-down structure and wavelength to reveal characteristic interference patterns for different polarizations.

physics.optics↗

arXiv2026

Olivine annealed up to 1500 C: changes traced by polarised IR reflectance and magnetization

Spectral analysis at the infrared (IR) spectral range is introduced with assignment of synthetic red-green-blue (RGB) colours defined by adjustable wavelength and bandwidth. The RGB bands were selected at the phase-specific absorbance A or reflectance R bands of olivine and related materials, which can be formed via high temperature annealing (HTA) of natural minerals up to 1500 C. Natural olivines were collected from quarry at volcanic site in Mortlake, Victoria, Australia and spectrally characterised during IR-THz spectroscopy beamtime experiments at Australian Synchrotron. Phase changes in HTA natural olivines were traced by correlation of optical IR 4-polarisation spectroscopy, X-ray energy dispersive spectroscopy and magnetisation. After HTA, olivine samples were magnetized via precipitation of Fe-rich oxides.

physics.geo-ph↗

arXiv2026

Nanoscale Surface Analysis of High Entropy Alloy

Nanoscale surface analysis of 1 micrometer thick high entropy alloys (HEAs) was carried out using nano-IR for hyperspectral imaging and single point spectroscopy in the 700-1700 1/cm spectral range. Nano-IR is based on the detection of scattered light from an oscillating metal coated nano-tip in one of the arms of the Fourier transform infrared spectrometer and has a resolution defined by the tip radius of the probe, 20 nm, regardless of the excitation wavelength. HEA CuPdAgPtAu showed an absorption and reflection increase at 900-1100 1/cm band, which is consistent with Drude-Lorenz modeling of permittivity, however, could also signify oxide formation as tested by X-ray photoelectron spectroscopy of CuPdAgPtAu and CrFeCoNiCuMo. Realization of polarization analysis for nano-IR nano-spectroscopy in the plane perpendicular to the sample's surface is discussed and modeled. The currently available modality of surface analysis with the excitation-detection mode of the p-pol. antenna can be extended to full 3D analysis of the orientational dependencies of local absorbance and refractive index.

physics.optics↗

arXiv2026

High Entropy Alloy under Shock Compression: Optical-Pump X-Ray-Probe

High entropy alloys (HEAs) are multi-principal-element alloys designed for tailorable mechanical performance and have been attracting significant engineering interest, yet their fundamental behaviour under extreme dynamic conditions, such as shock loading, remains unexplored. Here, we report laser-shock experiments on two different types of 1-micrometers-thick HEA microfilms, CuPdAgPtAu and CrFeCoNiCuMo, on 25-micrometers-thick black-Kapton ablator driven by a high intensity laser pulse (532 nm, 5 ns, 16 J, 0.5-mm diameter focal spot) and probed by an X-ray free electron laser (XFEL) pulse (12 keV, 7 fs). Time-resolved X-ray diffraction (XRD) shows the formation of a transient phase with a lattice compression up to 5.1% of the CuPdAgPtAu HEA along the (111) plane; this transient compressed phase existed for 0.3 ns. The impedance matching Hugoniot analysis estimated a shock pressure of 55 +/- 6 GPa in the HEA film, while Au- and Fe-based equations of state (EoS) modelling predict 80 GPa (0.8 MBar) at the free HEA surface. The free HEA surface reached maximum velocities of ~ 5 km/s as recorded from in situ monitoring with the velocity interferometry system for any reflector (VISAR) imaging. These initial HEA results show the suitability of HEA sample preparation and XFEL-based XRD characterisation under extreme shock loading, and are promising for experimental determination of the EoS of this emerging class of materials (beamtime proposal No.: 2024A8503 for a 6-hour preliminary experiment).

cond-mat.mtrl-sci↗

arXiv2026

Structure orientation determined in transmission and reflection: q-plate

Determination of orientation in the imaged sample/scene has a large application potential when the anisotropy of properties is analysed, usually, under a linearly polarised illumination. This study combined several improvements of microscopy imaging: use of an incoherent white illumination source (a lamp) with a spectral filter to define a spectral window, a plastic circular polariser to image with circularly polarised light (instead of linear), and a 4-pol. camera with integrated polarisers for simultaneous acquisition of images at four pi/4-azimuth shifts. In the transmission mode, a high-fidelity readout of form birefringent optical elements, q-plates, was achieved using a fitting procedure based on the analytical expression of S0 (intensity) Stokes parameters at the pixel level. In the reflection mode, the S0 fit was used to determine the azimuth orientation of the q-plates, as well as a generic Amp x cos(2Q1 - 2Q0) + Offset fit (at pixel level) applied to images taken at four Q1 azimuths. The 4-pol. analysis in reflection under circularly polarised illumination is discussed.

physics.optics↗

arXiv2025

Omics-scale polymer computational database transferable to real-world artificial intelligence applications

Developing large-scale foundational datasets is a critical milestone in advancing artificial intelligence (AI)-driven scientific innovation. However, unlike AI-mature fields such as natural language processing, materials science, particularly polymer research, has significantly lagged in developing extensive open datasets. This lag is primarily due to the high costs of polymer synthesis and property measurements, along with the vastness and complexity of the chemical space. This study presents PolyOmics, an omics-scale computational database generated through fully automated molecular dynamics simulation pipelines that provide diverse physical properties for over $10^5$ polymeric materials. The PolyOmics database is collaboratively developed by approximately 260 researchers from 48 institutions to bridge the gap between academia and industry. Machine learning models pretrained on PolyOmics can be efficiently fine-tuned for a wide range of real-world downstream tasks, even when only limited experimental data are available. Notably, the generalisation capability of these simulation-to-real transfer models improve significantly as the size of the PolyOmics database increases, exhibiting power-law scaling. The emergence of scaling laws supports the "more is better" principle, highlighting the significance of ultralarge-scale computational materials data for improving real-world prediction performance. This unprecedented omics-scale database reveals vast unexplored regions of polymer materials, providing a foundation for AI-driven polymer science.

physics.chem-ph↗

arXiv2025

Mid infrared imaging of mass transport in polymer electrolyte membranes of an operating microfluidic water electrolyzer

This study investigates water transport in a polymer electrolyte membrane (PEM) electrolyzer using operando infrared spectroscopic imaging. By testing different H2SO4 anolyte concentrations, it examines electrochemical performance, water diffusion, and membrane hydration. Higher anolyte concentrations increased standard deviations in current densities and led to water diffusion gradients revealed by infrared imaging and confirming localized water transport variations. The study highlights the need for improved water management and optimized electrolyzer design for stable and efficient PEM electrolysis in industrial applications.

cond-mat.soft↗

arXiv2025

Anisotropy analysis of bamboo and tooth using 4-angle polarization micro-spectroscopy

To investigate the anisotropic properties of biomaterials, two distinct classes are considered: polymer-based (e.g., cellulose in plants) and crystalline-based (e.g., enamel in teeth), each demonstrating distinct structural and functional characteristics. Four-angle polarization (4-pol.) spectral mapping of sub-1 {\mu}m bamboo slices was carried out in the mid-IR spectral range (2.5-20 {\mu}m) to reveal the 3D organization of the chemical bonding of cellulose using the key characteristic absorption bands associated with C-O-C and C-N vibrational modes. The longitudinal and transverse microtome slices revealed a switch between the presence and absence of dichroism in parenchyma cell walls and vascular bundles. The cell wall showed continuous alignment of the C-O-C stretching vibrational mode (8.6 {\mu}m/1163 cm-1) down to the pixel resolution of ~ 4 {\mu}m (the step size in imaging) in the transverse slice; the cell wall thickness is ~ 1 {\mu}m. Thin microtomed slices of a tooth were measured in transmission and reflection modes. The single-point reflection measurements, performed using two perpendicular orientations, revealed orientational anisotropy in the enamel, which was absent in the dentin region. High sub-diffraction limited lateral resolution was numerically validated using a simplified-model of a Gaussian beam reading out material pixels with a defined orientation of absorption. It is shown that the orientation of small ~ {\lambda}/10 ~ 1 {\mu}m objects can be revealed using a focal spot of ~ {\lambda}/NA ~ 20 {\mu}m, defining the diffraction limit for the objective lens with a numerical aperture NA ~ 0.5.

physics.bio-ph↗

arXiv2025

Bridging Spectroscopy and Advanced Molecular Orientation Analysis with New 4+ Angle Polarization Toolbox in Quasar

Anisotropy plays a critical role in governing the mechanical, thermal, electrical, magnetic, and optical properties of materials, influencing their behavior across diverse applications. Probing and quantifying this directional dependence is crucial for advancing materials science and biomedical research, as it provides a deeper understanding of structural orientations at the molecular level, encompassing both scientific and industrial benefits. This study introduces the "4+ Angle Polarization" widget, an innovative extension to the open-source Quasar platform (https://quasar.codes/), tailored for advanced multiple-angle polarization analysis. This toolbox enables precise molecular orientation analysis of complex microspectroscopic datasets through a streamlined workflow. Using polarized Fourier transform infrared (p-FTIR) spectroscopy, we demonstrate its versatility across various sample types, including polylactic acid (PLA) organic crystals, murine cortical bone, and human osteons. By overcoming the limitations of traditional two-angle methods, the widget significantly enhances the accuracy of structural and orientational analysis. This novel analytical tool expands the potential of multiple-angle p-FTIR techniques into advanced characterization of structural anisotropy in heterogeneous systems, providing transformative insights for materials characterization, biomedical imaging and beyond.

cond-mat.mtrl-sci↗

arXiv2024

Interferometric microscale measurement of refractive index at VIS and IR wavelengths

Determination of refractive index of micro-disks of a calcinated ($1100^\circ$C in air) photo-resist SZ2080$^\mathrm{TM}$ was carried out using transmission and reflection spectroscopy. Interference fringes at specific wavenumbers/wavelengths were selected for determination of the optical thickness, hence, the refractive index when the thickness of micro-disks was measured by scanning electron microscopy (SEM). Refractive index of disks of $\sim 6\pm 1~\mu$m thickness were determined at visible and IR (2.5-13~$\mu$m) spectral ranges and where $2.2\pm 0.2$ at visible and IR wavelengths. Peculiarities of optical characterisation of micro-optical structures are discussed in view of possible uncertainties in the definition of geometric parameters, shape and mass density redistribution.

physics.optics↗

arXiv2023

Determination of Stokes vector from a single image acquisition

Four Stokes parameters (1852) define the polarisation state of light. Measured changes of the Stokes vector of light traversing an inhomogeneous sample are linked to the local anisotropies of absorption and refraction and are harnessed over an increasing range of applications in photonics, material, and space/earth observation. Several independent polarisation sensitive measurements are usually required for determination of the all four Stokes parameters, which makes such characterisation procedure time-consuming or requires complex setups. Here we introduce a single-snapshot approach to Stokes polarimetry in transmission by use of a 4-polarisation camera with the on-chip integrated polarisers. A quarter-waveplate was added in front of the sample and was illuminated by a linearly polarised light. This approach is demonstrated by measuring birefringence $\Delta n\sim 0.012$ of spider silk of only $\sim 6~\mu$m-diameter using microscopy, however, due to its generic nature, it is transferable to other spectral ranges and imaging applications, e.g., imaging from a fast moving satellite or drone or monitoring fast changing events such as phase transitions.

physics.optics↗

arXiv2022

RadonPy: Automated Physical Property Calculation using All-atom Classical Molecular Dynamics Simulations for Polymer Informatics

The rapid growth of data-driven materials research has made it necessary to develop systematically designed, open databases of material properties. However, there are few open databases for polymeric materials compared to other material systems such as inorganic crystals. To this end, we developed RadonPy, the world-first open-source Python library for fully automated all-atom classical molecular dynamics (MD) simulations. For a given polymer repeating unit, the entire process of molecular modeling, equilibrium and nonequilibrium MD calculations, and property calculations can be conducted fully automatically. In this study, 15 different properties, including the thermal conductivity, density, specific heat capacity, thermal expansion coefficients, and refractive index, were calculated for more than 1,000 unique amorphous polymers. The calculated properties were compared and validated systematically with experimental values from PoLyInfo. During the high-throughput data production, eight amorphous polymers with extremely high thermal conductivities, exceeding 0.4 W/mK, were identified, including six polymers with unreported thermal conductivities. These polymers were found to have a high density of hydrogen bonding units or rigid backbones. A decomposition analysis of the heat conduction, which is implemented in RadonPy, revealed the underlying mechanisms that yield a high thermal conductivity of the amorphous polymers: heat transfer via hydrogen bonds and dipole-dipole interactions between the polymer chains with their hydrogen bonding units or via the covalent bonds of the polymer backbone with high rigidity. The creation of massive amounts of computational property data using RadonPy will facilitate the development of polymer informatics, similar to how the emergence of the first-principles computational database for inorganic crystals had significantly advanced materials informatics.

cond-mat.mtrl-sci↗

arXiv2020

Tilted black-Si: ~0.45 form-birefringence from sub-wavelength needles

The self-organised conical needles produced by plasma etching of silicon (Si), known as black silicon (b-Si), create a form-birefringent surface texture when etching of Si orientated at angles of $θ_i < 50 - 70^\circ$ (angle between the Si surface and vertical plasma E-field). The height of the needles in the form-birefringent region following 15~min etching was $d\sim 200$ nm and had a 100 $μ$m width of the optical retardance/birefringence, characterised using polariscopy. The height of the b-Si needles corresponds closely to the skin-depth of Si $\simλ/4$ for the visible spectral range. Reflection-type polariscope with a voltage-controlled liquid-crystal retarder is proposed to directly measure the retardance $Δn\times d/λ\approx 0.15$ of the region with tilted b-Si needles. The quantified form birefringence of $Δn = - 0.45$ over $λ= 400-700$~nm spectral window was obtained. Such high values of $Δn$ at visible wavelengths can only be observed in the most birefringence calcite or barium borate as well as in liquid crystals. The replication of b-Si into Ni-shim with high fidelity was also demonstrated and can be used for imprinting of the b-Si nanopattern into other materials.

physics.app-ph↗

arXiv2019

Nanoscale optical and structural characterisation of silk

Background: Nanoscale composition of silk defining its unique properties via a hierarchical structural anisotropy has to be analysed at the highest spatial resolution of tens-of-nanometers corresponding to the size of fibrils made of b-sheets, which are the crystalline building blocks of silk. Results: Nanoscale optical and structural properties of silk have been measured from 100-nm thick longitudinal slices of silk fibers with ~10 nm resolution, the highest so far. Optical sub-wavelength resolution in hyperspectral mapping of absorbance and molecular orientation were carried out for comparison at IR wavelengths 2-10 micrometers using synchrotron radiation. Conclusion: Reliable distinction of transmission changes by only 1-2% due to anisotropy of amide bands was obtained from nano-thin slices of silk.

physics.app-ph↗

arXiv2018

Paracetamol Micro-Structure Analysis by Optical Mapping

Domain structure of paracetamol -- popular antipyretic analgesic -- was investigated by infrared (IR) spectroscopy using synchrotron radiation. Absorbance and retardance maps reveal molecular orientation inside the micro-domains of the paracetamol form II which has a better water solubility and compressibility compared to the commercially used forms I. The developed method of analysis representing orientation of optical slow(fast)-axis is compared with azimuthal orientation of the absorbance at several specific IR bands using vector maps. High brightness of synchrotron radiation and hyper-spectral mapping of structural domains in paracetamol clearly reveals the domain boundaries and can potentially be used to observe \emph{in situ} intra-phase transformations of paracetamol forms-I, II, III and melting, which are important for making medical tablets and powders by an industrial process.

cond-mat.mtrl-sci↗

arXiv2018

Simple multi-wavelength imaging of birefringence: case study of silk

A polarised light imaging microscopy with an addition of liquid crystal (LC) phase retarder was implemented to determine the birefringence of silk fibers with the high 2 micrometers spatial resolution. The measurement was carried out with silk fiber (the optical slow axis) and the slow axis of the LC retarder set parallel (a perpendicular alignment can also be used). The direct fit of the transmission data provides a high fidelity determination of birefringence, $Dn = 1.63\times 10^{-2}$ (with 2% uncertainty) of the brown silk fiber (Antheraea pernyi) averaged over the wavelength range $l =$ (425-625) nm. By measuring retardance at four wavelengths it was possible to determine the true value of the birefringence of a thick sample when an optical path may include large number of wavelengths ($2p$ cycles in phase). The numerical procedures and required hardware are described for the do-it-yourself assembly of the imaging polariscope at a fractional budget compared with commercial units.

physics.ins-det↗

arXiv2018

Micro-thermocouple on nano-membrane: thermometer for nanoscale measurements

A thermocouple of Au-Ni with only 2.5-micrometers-wide electrodes on a 30-nm-thick Si3N4 membrane was fabricated by a simple low-resolution electron beam lithography and lift off procedure. The thermocouple is shown to be sensitive to heat generated by laser as well as an electron beam. Nano-thin membrane was used to reach a high spatial resolution of energy deposition and to realise a heat source of sub-1 micrometer diameter. This was achieved due to a limited generation of secondary electrons, which increase a lateral energy deposition. A low thermal capacitance of the fabricated devices is useful for the real time monitoring of small and fast temperature changes, e.g., due to convection, and can be detected through an optical and mechanical barrier of the nano-thin membrane. Temperature changes up to ~2x10^5 K/s can be measured at 10 kHz rate. A simultaneous down-sizing of both, the heat detector and heat source strongly required for creation of thermal microscopy is demonstrated. Peculiarities of Seebeck constant (thermopower) dependence on electron injection into thermocouple are discussed. Modeling of thermal flows on a nano-membrane with presence of a micro-thermocouple was carried out to compare with experimentally measured temporal response.

cond-mat.mes-hall↗